Knowledge (XXG)

Metaborate

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Yongquan Zhou, Souta Higa, Chunhui Fang, Yan Fang, Wenqian Zhang, and Toshio Yamaguchi (2017): "B(OH)4− hydration and association in sodium metaborate solutions by X-ray diffraction and empirical potential structure refinement".
531:, consisting of a six-membered ring of alternating boron and oxygen atoms with one extra oxygen atom attached to each boron atom. This form is found, for example, in some anhydrous 790: 1221:
Fayan Zhu, Yongquan Zhou, Chunhui Fang, Yan Fang, Haiwen Ge, and Hongyan Liu (2017): "Ion association in lithium metaborate solution: a Raman and ab initio insight".
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C. S. Willand and A. C. Albrecht (1986): "The second-order nonlinear optical properties of β-barium metaborate: A semiempirical theoretical investigation".
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Yongquan Zhou, Chunhui Fang, Yan Fang, Fayan Zhu, Song Tao, Sha Xu (2012): "Structure of aqueous sodium metaborate solutions: X-ray diffraction study".
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through shared oxygen atoms. In these anions, the boron atom forms covalent bonds with either three or four oxygen atoms. Some of the structures are:
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Mitsuru Asano, Yoshihiko Yasue, and Kenji Kubo (1984): "Mass Spectrometric Study of Ions Formed from Cesium Metaborate Vapor under Electron Impact".
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P. Ney, M. D. Fontana, A. Maillard, and K. Polgár (1998): "Assignment of the Raman lines in single crystal barium metaborate (β-BaB2O4)".
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Robert K. Momii and Norman H. Nachtrieb (1967): "Nuclear Magnetic Resonance Study of Borate-Polyborate Equilibria in Aqueous Solution".
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M. Marezio and J. P. Remeika (1966): "Polymorphism of LiMO2 Compounds and High‐Pressure Single‐Crystal Synthesis of LiBO2".
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Y. Roussigné, R. Farhi, C. Dugautier, and J. Godard (1992): "A Raman study of both phases of barium metaborate (BBO)".
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M. Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "The bond lengths in the sodium metaborate structure",
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David H. Feather and Alfred Buechler (1973): "Gaseous thallium(I) metaborate and thallium(I) aluminum fluoride".
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W. Schneider and G. B. Carpenter (1970) "Bond lengths and thermal parameters of potassium metaborate, K3B3O6".
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M. Marezio, H. A. Plettinger and W. H. Zachariasen (1963): "Refinement of the calcium metaborate structure".
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I. C. Hisatsune and Noelia Haddock Suarez (1964): "Infrared Spectra of Metaborate Monomer and Trimer Ions".
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In 1937, Nielsen and Ward claimed that the metaborate anion in solution has a linear symmetric structure
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Shifeng Jin, G. Chai, J. Liu, W. Wang and X. Chen (2009): "The centrosymmetric metal meta-borate KCdB
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J. Rud Nielsen and N. E. Ward (1937): "Raman Spectrum and Structure of the Metaborate Ion".
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tetrahedra sharing oxygen vertices, as in the high-pressure and high-temperature γ form of
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W. H. Zachariasen (1937): "The Crystal Structure of Potassium Metaborate, K3(B3O6)".
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W. H. Zachariasen (1931): "The Crystal Lattice of Calcium Metaborate, CaB2O4".
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Russian Journal of Physical Chemistry, volume 86, issue 8, pages 1236–1244.
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with negative charges on the oxygens and a positive charge on the boron, or
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tetrahedral groups, as in "zinc metaborate", which is actually a mixed salt
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of metaborate anions in dilute solid solutions of potassium salt in alkali
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with negative charge on the boron. However, this claim has been disproved.
1161:(1964): "The crystal structure of anhydrous zinc metaborate Zn4O(BO2)6". 464: 430: 1350: 1330: 1210: 1648: 1270: 26: 1290: 1190: 982: 1388: 931: 588: 368: 357: 302: 333:
Except where otherwise noted, data are given for materials in their
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as well as ionized versions thereof. The same situation holds for
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salts of the latter are often improperly named "metaborates".
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units connected by single shared-oxygen bridges; that is,
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The cyclic trimer anions dissociate almost completely in
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Proceedings of the National Academy of Sciences (PNAS)
764: 1141:(1961): "A new structural type of metaborate anion". 748: 1017:, volume 57, issue 2, 15 February , Pages 146-152. 784: 579:. The three B–O distances are nearly equal in the 771: 770: 81: 1373: 926:In 1964 Hisatsune and Surez investigated the 8: 1380: 1366: 1358: 190: 145: 18: 1303:Journal of Nuclear Science and Technology 772: 765: 763: 754: 752: 750: 749: 747: 1325:, volume 77, issue 12, pages 1599–1600. 914: 903: 899: 895: 888: 849: 845: 837: 833: 829: 821: 817: 813: 806: 795: 738: 725: 698: 687: 675: 662: 651: 639: 635: 628: 624: 611: 575: 571: 561: 557: 553: 549: 527: 511: 458: 425: 421: 414: 410: 400: 946: 755: 418:, and esters such as methyl metaborate 236: 211: 186: 1415: 1205:, volume 6, issue 6, pages 1189-1192. 1105:, volume 17, issue 11, pages 617-619. 1085:, volume C65, issue 7, pages i42-i44. 448:In aqueous solutions metaborate anion 16:Boron-oxygen anion or functional group 2243: 1225:, volume 55, issue 2, pages 186-195. 1037:. volume 82, issue 4, pages 287-293. 785:{\displaystyle {\ce {<=>>}}} 587:) but significantly different in the 218:Key: VDLZIANVOYDKFH-UHFFFAOYSA-N 125: 7: 1398: 1345:, volume 3, issue 2, pages 168-174. 1305:, volume 21, issue 8,pages 614-624. 1055:Journal of Physics: Condensed Matter 803:Other molecules and anions, such as 429:). Metaborate is one of the boron's 1263:Physical Chemistry Chemical Physics 1185:, volume 44, issue 9, pages 3348-. 753: 1057:, volume 10, issue 3, pages 673-. 995:Acta Crystallographica - Section B 684:A tridimensional regular array of 394:of such anion (e.g. salts such as 14: 591:one (128.0, 143.3, and 143.3 pm). 1223:Physics and Chemistry of Liquids 1163:Zeitschrift für Kristallographie 1143:Zeitschrift für Kristallographie 1083:Acta Crystallographica Section C 977:, volume 5, issue 11, page 919. 463:. For this reason, solutions or 386:. Metaborate also refers to any 38: 25: 1283:The Journal of Chemical Physics 1265:, volume 19, pages 27878-27887 337:(at 25 °C , 100 kPa). 1285:, volume 5, Issue 3, page 201 773: 756: 583:salt (133.1, 139.8, and 139.8 1: 1323:Journal of Physical Chemistry 1311:10.1080/18811248.1984.9731090 1231:10.1080/00319104.2016.1183003 1171:10.1524/zkri.1964.119.5-6.375 1151:10.1524/zkri.1961.115.5-6.460 610:···(−B(−O)−O−) 1125:, volume 16, pages 390-392. 1043:10.1016/0038-1098(92)90643-N 1023:10.1016/0030-4018(86)90146-X 997:volume B26, pages 1189-1191 957:, volume 16, pages 594-595. 648:A tridimensional network of 567:potassium cadmium metaborate 484:, metaborate ions are often 480:In the solid state of their 1183:Journal of Chemical Physics 975:Journal of Chemical Physics 862:are less than 5% at 26 °C. 2542: 2245: 1063:10.1088/0953-8984/10/3/018 1035:Solid State Communications 1417: 1395: 1249:10.1134/S0036024412060349 1145:, volume 115, issue 5-6. 1131:10.1107/S0365110X63001031 1091:10.1107/S0108270109021477 1003:10.1107/S0567740870003849 963:10.1107/S0365110X63001596 331: 288: 247: 227: 202: 65: 55: 50: 37: 24: 1165:, volume 119, issue 5-6 565:, and in the mixed salt 32:Monomeric metaborate ion 215:InChI=1S/BO2/c2-1-3/q-1 45:Trimeric metaborate ion 1123:Acta Crystallographica 1111:10.1073/pnas.17.11.617 955:Acta Crystallographica 786: 508:A trimer with formula 1015:Optics Communications 885:has neutral monomers 787: 657:zinc metaborate oxide 433:. Metaborates can be 746: 541:potassium metaborate 2521:Inorganic compounds 2516:Industrial minerals 1351:10.1021/ic50012a003 1343:Inorganic Chemistry 1331:10.1021/j100631a027 1211:10.1021/ic50052a026 1203:Inorganic Chemistry 910:thallium metaborate 759: 659:, with the formula 284: g·mol 21: 1271:10.1039/C7CP05107G 936:potassium chloride 782: 777: 761: 717:tetrahydroxyborate 694:lithium metaborate 620:calcium metaborate 616:··· 454:tetrahydroxyborate 406:calcium metaborate 341:Infobox references 323:Tetrahydroxyborate 289:Related compounds 19: 2493: 2492: 2487: 2486: 1291:10.1063/1.1750008 1191:10.1063/1.1727236 983:10.1063/1.1749962 928:infrared spectrum 883:cesium metaborate 779: 545:barium metaborate 537:sodium metaborate 396:sodium metaborate 373:empirical formula 349:Chemical compound 347: 346: 295:Related compounds 171:CompTox Dashboard 107:Interactive image 2533: 1399: 1382: 1375: 1368: 1359: 1353: 1339: 1333: 1319: 1313: 1299: 1293: 1279: 1273: 1258: 1252: 1239: 1233: 1219: 1213: 1199: 1193: 1179: 1173: 1159: 1153: 1139: 1133: 1119: 1113: 1099: 1093: 1071: 1065: 1051: 1045: 1031: 1025: 1011: 1005: 991: 985: 971: 965: 951: 917: 907: 891: 872: 868: 861: 860: 859: 856: 841: 825: 809: 799: 791: 789: 788: 783: 781: 780: 778: 776: 769: 762: 760: 751: 742: 736: 735: 732: 713:aqueous solution 707:Aqueous solution 701: 691: 678: 673: 672: 669: 654: 642: 631: 617: 607: 606: 605: 602: 578: 564: 530: 523: 522: 521: 518: 503: 502: 501: 498: 462: 428: 417: 403: 385: 384: 383: 380: 283: 270: 269: 268: 265: 255:Chemical formula 195: 194: 179: 177: 159:Gmelin Reference 149: 129: 109: 85: 42: 29: 22: 2541: 2540: 2536: 2535: 2534: 2532: 2531: 2530: 2506:Borate minerals 2496: 2495: 2494: 2489: 2488: 2450: 2446: 2435: 2431: 2427: 2411: 2407: 2403: 2395: 2391: 2387: 2379: 2372: 2368: 2364: 2360: 2358: 2354: 2350: 2343: 2339: 2335: 2331: 2329: 2325: 2321: 2298: 2290: 2286: 2282: 2274: 2270: 2262: 2258: 2170: 2162: 2158: 2154: 2146: 2142: 2110: 2106: 2098: 2094: 2090: 2079: 2075: 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893: 890: 886: 879: 870: 866: 857: 854: 853: 851: 847: 843: 839: 835: 831: 827: 823: 819: 815: 811: 808: 804: 797: 793: 744: 743: 740: 733: 730: 729: 727: 723: 709: 700: 696: 689: 685: 677: 670: 667: 666: 664: 660: 653: 649: 641: 637: 633: 630: 626: 622: 615: 609: 603: 600: 599: 597: 577: 573: 569: 563: 559: 555: 551: 547: 529: 525: 519: 516: 515: 513: 509: 499: 496: 495: 493: 478: 473: 460: 456: 427: 423: 419: 416: 412: 408: 402: 398: 381: 378: 377: 375: 350: 343: 338: 327: 296: 281: 266: 263: 262: 260: 257: 243: 240: 235: 234: 223: 220: 219: 216: 210: 209: 198: 188:DTXSID901317310 180: 173: 161: 152: 132: 112: 99: 88: 75: 61: 46: 43: 33: 30: 17: 12: 11: 5: 2539: 2537: 2529: 2528: 2523: 2518: 2513: 2508: 2498: 2497: 2491: 2490: 2485: 2484: 2481: 2478: 2475: 2472: 2467: 2464: 2461: 2458: 2455: 2452: 2448: 2444: 2440: 2437: 2433: 2429: 2425: 2421: 2418: 2414: 2413: 2409: 2405: 2401: 2397: 2393: 2389: 2385: 2381: 2377: 2373: 2370: 2366: 2362: 2356: 2352: 2348: 2344: 2341: 2337: 2333: 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1152: 1148: 1144: 1138: 1135: 1132: 1128: 1124: 1118: 1115: 1112: 1108: 1104: 1098: 1095: 1092: 1088: 1084: 1070: 1067: 1064: 1060: 1056: 1050: 1047: 1044: 1040: 1036: 1030: 1027: 1024: 1020: 1016: 1010: 1007: 1004: 1000: 996: 990: 987: 984: 980: 976: 970: 967: 964: 960: 956: 950: 947: 941: 939: 937: 933: 929: 921: 919: 911: 884: 881:The vapor of 876: 874: 863: 766: 722: 721: 720: 718: 714: 706: 695: 683: 682: 658: 647: 646: 621: 614: 596:A polymer of 595: 594: 590: 586: 582: 568: 546: 542: 538: 534: 507: 506: 505: 491: 487: 483: 475: 470: 468: 466: 455: 451: 446: 444: 440: 436: 432: 407: 397: 393: 389: 374: 370: 366: 362: 359: 355: 342: 336: 330: 324: 321: 319: 316: 314: 311: 309: 306: 304: 301: 300: 298: 293: 292: 287: 280: 278: 275: 274: 259: 256: 252: 251: 246: 237: 233: 226: 212: 208: 201: 193: 189: 185: 184: 182: 172: 168: 167: 163: 160: 156: 155: 148: 144: 143: 141: 139: 136: 135: 128: 124: 123: 121: 119: 116: 115: 108: 104: 103: 101: 97: 92: 91: 84: 80: 79: 77: 74: 70: 69: 64: 58: 54: 49: 41: 36: 28: 23: 1342: 1337: 1322: 1317: 1302: 1297: 1282: 1277: 1262: 1256: 1242: 1237: 1222: 1217: 1202: 1197: 1182: 1177: 1162: 1157: 1142: 1137: 1122: 1117: 1102: 1097: 1082: 1069: 1054: 1049: 1034: 1029: 1014: 1009: 994: 989: 974: 969: 954: 949: 925: 880: 864: 802: 710: 618:. Occurs in 612: 533:alkali metal 479: 447: 353: 351: 66:Identifiers 892:and dimers 686:[B(−O−) 535:salts like 526:(−B(−O)−O−) 476:Solid state 318:Tetraborate 313:Orthoborate 248:Properties 127:CHEBI:30173 20:Metaborate 2500:Categories 942:References 794:[B(OH) 486:oligomeric 457:[B(OH) 450:hydrolyzes 439:oligomeric 354:metaborate 308:Boric acid 277:Molar mass 138:ChemSpider 94:3D model ( 83:14100-65-3 73:CAS Number 60:Metaborate 57:IUPAC name 2526:Oxyanions 877:Gas phase 774:⇀ 767:− 757:↽ 719:anions: 581:potassium 490:polymeric 471:Structure 443:polymeric 435:monomeric 431:oxyanions 934:such as 465:hydrated 2511:Borates 2246:  1749:FeB(OH) 1389:Borates 932:halides 371:, with 271: 147:2283207 898:[B 842:, and 828:[B 812:[B 665:(O)(BO 589:sodium 369:oxygen 358:borate 303:Borate 232:SMILES 51:Names 2011:-SbBO 1907:Rb•2H 938:KCl. 871:O=B=O 867:O−B−O 805:B(OH) 737:+ 6 H 634:Ca(BO 482:salts 409:Ca(BO 392:ester 365:boron 361:anion 356:is a 282:42.81 239:B(=O) 207:InChI 164:1047 118:ChEBI 96:JSmol 2443:U(BO 2376:ErBO 2295:NdBO 2167:BiBO 2026:-TeO 2019:-TeO 2000:InBO 1900:(OH) 1859:-SeO 1852:-SeO 1844:-AsO 1836:-GeO 1828:-GaO 1821:GaBO 1742:FeBO 1692:TiBO 1684:ScBO 1574:AlBO 1524:NaBO 1517:NaBO 1448:+(CO 913:TlBO 887:CsBO 852:(OH) 836:(OH) 820:(OH) 697:LiBO 661:(Zn) 570:KCdB 399:NaBO 388:salt 367:and 2483:No 2480:Md 2477:Fm 2474:Es 2466:Bk 2463:Cm 2460:Am 2457:Pu 2454:Np 2439:Pa 2428:(BO 2420:Ac 2417:** 2314:Tb 2311:Gd 2308:Eu 2305:Sm 2302:Pm 2267:CeB 2255:LaB 2239:Og 2236:Ts 2233:Lv 2230:Mc 2227:Fl 2224:Nh 2221:Cn 2218:Rg 2215:Ds 2212:Mt 2209:Hs 2206:Bh 2203:Sg 2200:Db 2197:Rf 2194:Lr 2191:** 2188:Ra 2185:Fr 2180:Rn 2177:At 2174:Po 2155:(BO 2135:Hg 2132:Au 2129:Pt 2126:Ir 2123:Os 2120:Re 2114:Ta 2103:HfB 2072:BaB 2063:•4H 2055:CsB 2038:Xe 2007:Sn 1988:(BO 1968:Pd 1965:Rh 1962:Ru 1959:Tc 1956:Mo 1953:Nb 1942:ZrB 1934:YBO 1920:(BO 1892:RbB 1875:Kr 1871:+Br 1866:+Se 1809:(BO 1793:(BO 1777:(BO 1761:(BO 1731:(BO 1715:(BO 1707:Cr 1700:-VO 1670:(BO 1657:•4H 1641:•4H 1623:Ar 1619:+Cl 1611:+SO 1604:-SO 1592:+PO 1585:-PO 1581:Si 1562:(BO 1509:·8H 1499:Ne 1484:+NO 1469:(NH 1456:+(C 1441:Be 1420:He 1347:doi 1327:doi 1307:doi 1287:doi 1267:doi 1245:doi 1227:doi 1207:doi 1187:doi 1167:doi 1147:doi 1127:doi 1107:doi 1087:doi 1081:". 1059:doi 1039:doi 1019:doi 999:doi 979:doi 959:doi 632:or 623:CaB 539:or 524:or 488:or 452:to 441:or 404:or 390:or 176:EPA 2502:: 2470:Cf 2424:Th 2410:12 2400:Yb 2394:12 2384:Tm 2361:Ho 2357:15 2347:Ho 2332:Dy 2328:15 2318:Dy 2289:21 2285:10 2279:Pr 2251:* 2151:Pb 2143:BO 2139:Tl 2117:W 2097:12 2087:Lu 2083:* 2048:BO 2044:Cs 2034:+I 1984:Cd 1976:BO 1972:Ag 1916:Sr 1898:16 1894:11 1885:BO 1881:Rb 1805:Zn 1789:Cu 1773:Ni 1757:Co 1727:Fe 1711:Mn 1666:Ca 1649:KB 1600:+S 1558:Mg 1552:13 1542:Na 1535:BO 1531:Na 1505:Na 1495:+F 1491:O 1477:BO 1444:B 1426:Li 1407:BO 918:. 894:Cs 855:2− 826:, 810:, 792:3 731:3− 650:BO 598:BO 585:pm 552:(B 548:Ba 517:3− 494:BO 445:. 437:, 424:BO 420:CH 376:BO 352:A 261:BO 2449:2 2447:) 2445:3 2434:4 2432:) 2430:3 2426:3 2408:O 2406:5 2404:B 2402:3 2392:O 2390:5 2388:B 2386:3 2378:3 2371:9 2369:O 2367:4 2365:B 2363:2 2355:O 2353:6 2351:B 2349:4 2342:9 2340:O 2338:4 2336:B 2334:2 2326:O 2324:6 2322:B 2320:4 2297:3 2287:O 2283:B 2281:4 2273:6 2271:O 2269:3 2261:6 2259:O 2257:3 2169:3 2161:2 2159:) 2157:3 2153:3 2145:3 2141:3 2109:5 2107:O 2105:2 2095:O 2093:5 2091:B 2089:3 2078:4 2076:O 2074:2 2067:O 2065:2 2061:8 2059:O 2057:5 2050:3 2046:3 2028:3 2021:4 2013:4 2002:3 1994:2 1992:) 1990:3 1986:3 1978:3 1974:3 1948:5 1946:O 1944:2 1936:3 1926:2 1924:) 1922:3 1918:3 1911:O 1909:2 1902:2 1896:O 1887:3 1883:3 1861:3 1854:4 1846:4 1838:4 1830:4 1823:3 1815:x 1813:) 1811:3 1807:x 1799:2 1797:) 1795:3 1791:3 1783:2 1781:) 1779:3 1775:3 1767:2 1765:) 1763:3 1759:3 1751:4 1744:3 1737:2 1735:) 1733:3 1729:3 1721:2 1719:) 1717:3 1713:3 1702:4 1694:3 1686:3 1676:2 1674:) 1672:3 1668:3 1661:O 1659:2 1655:8 1653:O 1651:5 1645:O 1643:2 1639:7 1637:O 1635:4 1633:B 1631:2 1629:K 1613:4 1606:4 1594:4 1587:4 1576:3 1568:2 1566:) 1564:3 1560:3 1550:O 1548:8 1546:B 1544:2 1537:3 1533:3 1526:3 1519:2 1513:O 1511:2 1507:2 1486:3 1479:3 1475:3 1473:) 1471:4 1464:) 1462:4 1460:O 1458:2 1452:) 1450:3 1436:7 1434:O 1432:4 1430:B 1428:2 1409:3 1405:3 1403:H 1381:e 1374:t 1367:v 1349:: 1329:: 1309:: 1289:: 1269:: 1247:: 1229:: 1209:: 1189:: 1169:: 1149:: 1129:: 1109:: 1089:: 1079:6 1077:O 1075:3 1061:: 1041:: 1021:: 1001:: 981:: 961:: 915:2 906:] 904:4 902:O 900:2 896:2 889:2 858:4 850:5 848:O 846:4 844:B 840:] 838:5 834:3 832:O 830:3 824:] 822:4 818:3 816:O 814:3 807:3 798:] 796:4 741:O 739:2 734:6 728:O 726:3 724:B 702:. 699:2 690:] 688:4 679:. 676:6 674:) 671:2 668:− 663:4 652:4 643:. 640:2 638:) 636:2 629:4 627:O 625:2 613:n 604:2 601:− 576:6 574:O 572:3 562:2 560:) 558:6 556:O 554:3 550:3 528:3 520:6 514:O 512:3 510:B 500:2 497:− 461:] 459:4 426:2 422:3 415:2 413:) 411:2 401:2 382:2 379:− 267:2 264:− 178:) 174:( 98:)

Index

Monomeric metaborate ion
Trimeric metaborate ion
IUPAC name
CAS Number
14100-65-3
JSmol
Interactive image
ChEBI
CHEBI:30173
ChemSpider
2283207
Gmelin Reference
CompTox Dashboard
DTXSID901317310
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InChI
SMILES
Chemical formula
Molar mass
Borate
Boric acid
Orthoborate
Tetraborate
Tetrahydroxyborate
standard state
Infobox references
borate
anion
boron
oxygen

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