911:
346:
215:
51:
61:
719:
38:
729:
724:
714:
910:
906:
1473:
1396:
1753:, the remaining inhabitants of a mostly evacuated village resist an occupying military force by directing the exhaust from a poorly-tuned internal combustion engine onto a continually renewed "waste heap" of powdered nickel outside a machine shop (under the guise of civilian business) in order to eliminate the occupiers, at the cost of their own lives.
1200:
1661:, and the concentration that is immediately fatal to humans would be 30 ppm. Some subjects exposed to puffs up to 5 ppm described the odour as musty or sooty, but because the compound is so exceedingly toxic, its smell provides no reliable warning against a potentially fatal exposure.
934:
909:
1649:
are far greater than that implied by its CO content, reflecting the effects of the nickel if released in the body. Nickel carbonyl may be fatal if absorbed through the skin or more likely, inhaled due to its high volatility. Its
1283:, although the Mond Process has fallen out of common usage due to the health hazards in working with the compound. Nickel carbonyl is one of the most dangerous substances yet encountered in nickel chemistry due to its very high
694:
1299:
for nickel is assigned as zero, because the Ni−C bonding electrons come from the C atom and are still assigned to C in the hypothetical ionic bond which determines the oxidation states. The formula conforms to the
1691:
which starts after typically 16 hours with symptoms of cough, breathlessness and extreme fatigue. These reach greatest severity after four days, possibly resulting in death from cardiorespiratory or
3160:
3241:
927:
2998:
1859:
1825:
1036:
1213:
845:
1723:
2014:
1340:
by the direct reaction of nickel metal with carbon monoxide. This pioneering work foreshadowed the existence of many other metal carbonyl compounds, including those of
912:
140:
1941:
1556:, releasing CO gas. Other halogens behave analogously. This reaction provides a convenient method for precipitating the nickel portion of the toxic compound.
1416:
for the purification of nickel or plating onto surfaces. Thermal decomposition commences near 180 °C (356 °F) and increases at higher temperature.
1412:
decomposes to carbon monoxide and nickel metal. Combined with the easy formation from CO and even very impure nickel, this decomposition is the basis for the
5189:
1428:
is susceptible to attack by nucleophiles. Attack can occur at nickel center, resulting in displacement of CO ligands, or at CO. Thus, donor ligands such as
395:
5841:
4662:
2299:
2545:
1324:
studies have been performed on this molecule, and the Ni−C and C−O distances have been calculated to be 1.838(2) and 1.141(2) angstroms respectively.
849:
2292:
5677:
5421:
1719:
643:
797:
2215:
616:
2508:
1740:, features a poisoned, dying crime lord who asks Dr. Quincy to autopsy his still-living body. Quincy identifies the poison—nickel carbonyl.
1726:(42 U.S.C. 11002), and is subject to strict reporting requirements by facilities which produce, store, or use it in significant quantities.
2239:
Stedman, D. H.; Hikade, D. A.; Pearson, R. Jr.; Yalvac, E. D. (1980). "Nickel
Carbonyl: Decomposition in Air and Related Kinetic Studies".
2518:
5814:
5646:
5370:
5314:
5236:
3757:
3373:
2031:
6164:
5139:
3388:
3378:
2108:
2064:
360:
1463:
and related ligands behave similarly. The monosubstitution of nickel tetracarbonyl with other ligands can be used to determine the
5582:
5182:
3216:
2659:
6149:
5074:
4624:
2847:
1363:
At 323 K (50 °C; 122 °F), carbon monoxide is passed over impure nickel. The optimal rate occurs at 130 °C.
5909:
5537:
4723:
4655:
4105:
3914:
3668:
2141:
675:
5515:
5478:
5451:
4827:
4100:
3348:
2538:
833:
1220:
793:
728:
5575:
4696:
3700:
3246:
1380:
783:
293:
50:
3317:
6159:
5921:
5876:
5749:
5738:
5719:
5522:
5175:
3482:
3426:
3420:
3342:
3211:
2774:
2293:"40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities"
1464:
1179:
1174:
1159:
324:
60:
873:
5564:
4611:
4321:
3789:
3368:
3115:
1060:
1047:
6154:
5760:
4648:
4579:
3987:
3784:
222:
718:
37:
5891:
5467:
4296:
4281:
3889:
3799:
3633:
3446:
3271:
2531:
2199:
1669:
1280:
1164:
1139:
957:
809:
5776:
920:
5980:
5712:
5670:
3844:
3839:
3414:
2523:
1651:
1129:
1119:
853:
210:
5865:
5784:
5504:
5113:
4928:
4841:
3869:
3623:
3451:
2802:
2792:
2639:
1781:
1673:
1244:
1144:
592:
817:
713:
6169:
5834:
5553:
5444:
5414:
5402:
4241:
3768:
3569:
3477:
1264:
1169:
1134:
1124:
1114:
737:
706:
551:
80:
1788:, etc.) and metals (iron, nickel and cobalt); these are stored as solid carbonyl for transfer back to
723:
5884:
5129:
5093:
4878:
4862:
4854:
4758:
4568:
4396:
4316:
4090:
3977:
3904:
3859:
3824:
3804:
3353:
2852:
2722:
2716:
2563:
2303:
2250:
1981:
1906:
1688:
1321:
861:
857:
1897:. I. Molecular Structure by Gaseous Electron Diffraction. II. Refinement of Quadratic Force Field".
775:
5493:
5264:
5041:
4910:
4902:
4894:
4781:
4750:
4715:
4601:
4261:
4029:
3957:
3952:
3884:
3809:
3492:
3441:
3312:
3302:
3072:
2883:
2710:
2684:
2674:
2644:
1700:
1692:
1550:
1154:
341:
106:
1360:. It was also applied industrially to the purification of nickel by the end of the 19th century.
805:
5486:
5008:
4952:
4940:
4870:
4804:
4773:
4629:
4487:
4442:
4401:
4301:
3779:
3746:
3673:
3487:
3281:
2649:
2274:
2191:
2052:
2048:
1576:
1429:
1149:
877:
563:
152:
1460:
821:
825:
5624:
5336:
5286:
5101:
4796:
4447:
4306:
4226:
3874:
3834:
3794:
3648:
3467:
3462:
3408:
3403:
3383:
3337:
2597:
2485:
2456:
2413:
2370:
2349:
2266:
2241:
2221:
2211:
2163:
2137:
2104:
2060:
2027:
1750:
1658:
1384:
1085:
837:
5629:
5602:
5341:
4849:
4819:
4674:
4584:
4411:
4291:
3854:
3829:
3819:
3497:
3363:
3307:
3062:
3044:
3013:
3008:
3003:
2993:
2988:
2983:
2935:
2924:
2784:
2624:
2603:
2592:
2558:
2477:
2446:
2438:
2403:
2395:
2341:
2258:
2203:
2129:
2019:
1989:
1972:
1949:
1914:
1301:
1248:
865:
755:
509:
492:
418:
302:
192:
116:
5693:
5354:
5298:
5294:
5257:
5248:
4923:
4735:
4467:
4246:
3962:
3715:
3638:
3618:
3540:
2634:
2614:
1873:
1789:
1784:
a team of eight private miners reach a near-earth asteroid to extract volatiles (water, CO
1708:
1313:
1296:
970:
241:
2503:
1679:
Nickel carbonyl poisoning is characterized by a two-stage illness. The first consists of
1375:
is not readily available commercially. It is conveniently generated in the laboratory by
1091:
2254:
1985:
1910:
345:
214:
172:
6036:
5902:
5730:
5704:
5656:
5436:
5395:
5388:
5380:
5281:
5271:
5198:
4996:
4964:
4918:
4386:
4326:
4251:
4190:
3924:
3864:
3613:
3054:
2825:
2750:
2664:
2451:
2426:
2408:
2383:
1879:
1383:. It can also be prepared by reduction of ammoniacal solutions of nickel sulfate with
1256:
1191:
1105:
789:
525:
6143:
4590:
4537:
4532:
4462:
4406:
4271:
4256:
4210:
4035:
3998:
3967:
3814:
3663:
3546:
3472:
3398:
2769:
2694:
2619:
2345:
1745:
1696:
1376:
481:
471:
203:
2278:
885:
5213:
4542:
4492:
4276:
4266:
4221:
4215:
4185:
4180:
3938:
3849:
3751:
3695:
3658:
3607:
3586:
3535:
3502:
3431:
3393:
3332:
3297:
3195:
2817:
2797:
2669:
2568:
1766:
1736:
1413:
1268:
2262:
2023:
1687:
lasting a few hours, usually followed by a short remission. The second phase is a
743:
266:
1792:, and used for in-situ fabrication of a spacecraft, via decomposition in vacuum.
829:
4552:
4527:
4482:
4345:
4311:
4175:
4170:
4135:
4130:
4125:
4120:
4115:
4095:
4014:
4003:
3993:
3705:
3436:
3327:
3322:
3256:
2965:
2955:
2940:
2912:
2894:
2875:
2866:
2758:
2579:
2361:
Sunderman, F. W. (1989). "A Pilgrimage into the
Archives of Nickel Toxicology".
2158:
1932:
1564:
1337:
1305:
1018:
994:
946:
514:
2012:
Lascelles, K.; Morgan, L. G.; Nicholls, D.; Beyersmann, D. "Nickel
Compounds".
1851:
1467:, a measure of the electron donating or withdrawing ability of a given ligand.
17:
4502:
4497:
4477:
4472:
4457:
4452:
4365:
4360:
4336:
4160:
4145:
4140:
4085:
4080:
3762:
3643:
3602:
3596:
3580:
3563:
3557:
3524:
3516:
3457:
3251:
3023:
2929:
2918:
2740:
2734:
2513:
2442:
2399:
2133:
1821:
1769:. It is mentioned that the process creates a "fatal toxin" (nickel carbonyl).
1684:
801:
518:
503:
433:
183:
5151:
4597:
4547:
4522:
4512:
4437:
4165:
4155:
4150:
4070:
4050:
4024:
4009:
3947:
3894:
3653:
3591:
3574:
3552:
3529:
3266:
3107:
2900:
2764:
2703:
2629:
2100:
1761:
1680:
1495:
1349:
841:
813:
771:
535:
313:
5167:
2489:
2460:
2417:
2270:
2225:
1563:
with alkyl and aryl halides often result in carbonylated organic products.
1395:
767:
2481:
2374:
2353:
1893:
Hedberg, L.; Iijima, T.; Hedberg, K. (1979). "Nickel tetracarbonyl, Ni(CO)
759:
5346:
4606:
4507:
4416:
4381:
4286:
4200:
4110:
4060:
3943:
3932:
3909:
3899:
3879:
3774:
3741:
3735:
3725:
3125:
3097:
3092:
3087:
2728:
2587:
1953:
1522:. These compounds can also be obtained by reduction of nickel carbonyl.
1345:
1341:
1309:
1284:
933:
926:
919:
892:
1575:
followed by sodium methoxide. Such reactions also probably proceed via
5276:
4355:
4350:
4065:
4055:
4045:
4040:
3730:
3358:
3276:
3261:
3236:
3231:
3226:
3221:
3190:
3185:
3180:
3175:
3170:
3140:
3135:
3130:
3120:
3028:
3018:
2978:
2973:
2950:
2945:
2679:
2159:"Reaction of Aryl Halides with π-Allylnickel Halides: Methallylbenzene"
1704:
1317:
1276:
461:
253:
223:
1472:
4671:
4573:
4236:
4231:
4019:
3165:
3155:
3150:
3145:
2807:
2609:
2084:. Vol. 2 (2nd ed.). NY: Academic Press. pp. 1747–1748.
1994:
1967:
1918:
1568:
1357:
1272:
1260:
575:
1936:
1190:
Except where otherwise noted, data are given for materials in their
4640:
2207:
4517:
4432:
4391:
3678:
3082:
3077:
3067:
2906:
2889:
2842:
1757:
1546:
1529:
with carbon nucleophiles (Nu) results in acyl derivatives such as
1471:
1394:
1236:
751:
747:
277:
163:
139:
129:
2047:
869:
3688:
3683:
1699:
is often extremely protracted, often complicated by exhaustion,
1353:
1073:
881:
763:
451:
5171:
4644:
2527:
2196:
Acute
Exposure Guideline Levels for Selected Airborne Chemicals
4075:
3628:
2332:
Shi, Z. (1991). "Nickel
Carbonyl: Toxicity and Human Health".
1856:
Immediately
Dangerous to Life or Health Concentrations (IDLH)
1579:. Allylic halides give the π-allylnickel compounds, such as
1567:
halides, such as PhCH=CHBr, are converted to the unsaturated
1287:, compounded with high volatility and rapid skin absorption.
3161:
Octamethylene-bis(5-dimethylcarbamoxyisoquinolinium bromide)
1968:"The Extraction of Nickel from its Ores by the Mond Process"
329:
59:
49:
3242:
2-Ethoxycarbonyl-1-methylvinyl cyclohexyl methylphosphonate
1722:
in the United States as defined in
Section 302 of the U.S.
1715:
is a matter of debate, but is presumed to be significant.
1707:
on exertion. Permanent respiratory damage is unusual. The
2509:
National
Pollutant Inventory – Nickel carbonyl fact sheet
904:
2080:
F. Seel (1963). "Nickel
Carbonyl". In G. Brauer (ed.).
1208:
2468:
Barceloux, D. G.; Barceloux, Donald (1999). "Nickel".
2190:
Board on Environmental Studies and Toxicology (2008).
1676:
quickly in air, with a half-life of about 40 seconds.
1657:
for a 30-minute exposure has been estimated at 3
1860:
National Institute for Occupational Safety and Health
1826:
National Institute for Occupational Safety and Health
5122:
5086:
4708:
4681:
4561:
4425:
4374:
4335:
4199:
3976:
3923:
3714:
3515:
3290:
3204:
3106:
3053:
3037:
2964:
2874:
2865:
2835:
2816:
2783:
2749:
2702:
2693:
2578:
2192:"Nickel Carbonyl: Acute Exposure Guideline Levels"
1724:Emergency Planning and Community Right-to-Know Act
1765:, a machine is made that purifies nickel via the
1541:Reactions with electrophiles and oxidizing agents
379:InChI=1/4CO.Ni/c4*1-2;/rC4NiO4/c6-1-5(2-7,3-8)4-9
265:
1734:"Requiem for the Living" (1978), an episode of
1420:Reactions with nucleophiles and reducing agents
908:
115:
2126:Encyclopedia of Reagents for Organic Synthesis
2015:Ullmann's Encyclopedia of Industrial Chemistry
5183:
4656:
2539:
2124:Pinhas, A. R. (2003). "Tetracarbonylnickel".
1424:Like other low-valent metal carbonyls, Ni(CO)
8:
2519:IARC Monograph "Nickel and Nickel compounds"
2427:"The Toxicology of Nickel Carbonyl. Part II"
2384:"The Toxicology of Nickel Carbonyl. Part I"
2157:Semmelhack, M. F.; Helquist, P. M. (1972).
2082:Handbook of Preparative Inorganic Chemistry
5190:
5176:
5168:
4663:
4649:
4641:
2871:
2699:
2546:
2532:
2524:
1399:Spheres of nickel made by the Mond process
476:−17.2 °C (1.0 °F; 256.0 K)
344:
213:
191:
29:
2450:
2407:
2363:Annals of Clinical and Laboratory Science
2007:
2005:
1993:
1549:. Chlorine oxidizes nickel carbonyl into
1255:. This colorless liquid is the principal
301:
5132:
1820:NIOSH Pocket Guide to Chemical Hazards.
1633:
1629:
1625:
1617:
1609:
1605:
1601:
1597:
1590:
1586:
1582:
1532:
1517:
1513:
1505:
1501:
1455:
1451:
1447:
1439:
1435:
2504:International Chemical Safety Card 0064
2097:Organometallics: A Concise Introduction
2059:. Vol. I. Oxford: Pergamon Press.
1801:
400:
365:
340:
5223:
3427:Methylphosphonyl dichloride (dichloro)
3421:Methylphosphonyl difluoride (difluoro)
2514:NIOSH Pocket Guide to Chemical Hazards
2095:Elschenbroich, C.; Salzer, A. (1992).
2057:Comprehensive Organometallic Chemistry
1846:
1844:
1815:
1813:
1811:
1809:
1807:
1805:
204:
6025:
3669:Tetramethylenedisulfotetramine (TETS)
1937:"Action of Carbon Monoxide on Nickel"
1838:Nickel tetracarbonyl, carcinogenicity
965:60 °C (140 °F; 333 K)
486:43 °C (109 °F; 316 K)
372:Key: AWDHUGLHGCVIEG-UHFFFAOYSA-N
171:
7:
5209:
1641:Toxicology and safety considerations
3758:Dimethyl(trifluoromethylthio)arsine
951:4 °C (39 °F; 277 K)
382:Key: AWDHUGLHGCVIEG-ARWXMKMZAJ
256:
3374:Dimethylamidophosphoric dichloride
1935:; Langer, C.; Quincke, F. (1890).
689:Potential occupational carcinogen
25:
3389:Ethylphosphonoselenoic dichloride
3379:Dimethylamidophosphoric dicyanide
1336:was first synthesised in 1890 by
1245:nickel(0) organometallic compound
3217:Dicyclohexyl phosphorofluoridate
2660:2,3,7,8-Tetrachlorodibenzodioxin
2334:Science of the Total Environment
1198:
727:
722:
717:
712:
36:
4625:List of chemical warfare agents
2848:Dibutylchloromethyltin chloride
1899:The Journal of Chemical Physics
1271:for producing very high-purity
1194:(at 25 °C , 100 kPa).
676:Occupational safety and health
1:
2263:10.1126/science.208.4447.1029
2024:10.1002/14356007.a17_235.pub2
1720:extremely hazardous substance
1295:In nickel tetracarbonyl, the
1041:(US health exposure limits):
3701:Trimethylolpropane phosphite
3247:Neopentylene fluorophosphate
2346:10.1016/0048-9697(94)90406-5
1381:bis(cyclooctadiene)nickel(0)
3483:3,3,5-Trimethylcyclohexanol
3343:N,N-Diisopropylaminoethanol
3212:Diisopropyl fluorophosphate
1465:Tolman electronic parameter
1408:On moderate heating, Ni(CO)
1387:under an atmosphere of CO.
1180:Tetrairidium dodecacarbonyl
1175:Tetrarhodium dodecacarbonyl
1160:Triruthenium dodecacarbonyl
1067:TWA 0.001 ppm (0.007 mg/m)
1054:TWA 0.001 ppm (0.007 mg/m)
983:or concentration (LD, LC):
45:
6186:
6027:
4322:Hexamethylene diisocyanate
3790:Phenylcarbylamine chloride
3116:Dimethylcarbamoyl fluoride
2300:Government Printing Office
2178:, vol. 6, p. 722
2099:(2nd ed.). Weinheim:
1571:upon treatment with Ni(CO)
1379:of commercially available
438:170.73 g/mol
5225:
5206:
4620:
4580:Fluoroethyl fluoroacetate
3785:Perchloromethyl mercaptan
3196:4-686-293-01 (Agent 1-10)
2443:10.1017/S0022172400015989
2400:10.1017/S0022172400033507
2298:(July 1, 2008 ed.).
2134:10.1002/047084289X.rt025m
2128:. John Wiley & Sons.
1525:Thus, treatment of Ni(CO)
1188:
1097:
1035:
979:
693:
673:
668:
585:
544:
411:
391:
356:
99:
89:
79:
74:
44:
35:
6165:IARC Group 1 carcinogens
4297:Chloroacetophenone oxime
4282:Bromomethyl ethyl ketone
3890:Trifluoroacetyl chloride
3800:Tetrachlorodinitroethane
3447:Phosphorus pentachloride
3272:Methanesulfonyl fluoride
2200:National Academies Press
1281:organometallic chemistry
1165:Triosmium dodecacarbonyl
1140:Dimanganese decacarbonyl
784:Precautionary statements
610:320 J K mol
4576:(variants and mixtures)
3845:Trichloronitrosomethane
3840:Trifluoronitrosomethane
3415:Methyldichlorophosphine
2018:. Weinheim: Wiley-VCH.
1718:It is classified as an
1545:Nickel carbonyl can be
1498:gives clusters such as
1404:Thermal decarbonylation
1130:Seaborgium hexacarbonyl
1120:Molybdenum hexacarbonyl
1029:42 ppm (rabbit, 30 min)
1007:10 ppm (mouse, 10 min)
1003:35 ppm (rabbit, 30 min)
498:0.018 g/100 mL (10 °C)
456:musty, like brick dust
369:InChI=1S/4CO.Ni/c4*1-2;
6150:Organonickel compounds
4375:Cornea-clouding agents
3870:Phosphorus trichloride
3452:Phosphorus trichloride
3186:Miotine (AR-28/T-1843)
2640:Phosphorus trifluoride
1756:In chapter 199 of the
1489:
1400:
1145:Dirhenium decacarbonyl
1031:7 ppm (mouse, 30 min)
1027:30 ppm (human, 30 min)
1005:94 ppm (mouse, 30 min)
915:
65:
55:
3769:Disulfur decafluoride
3570:Chlorophenylsilatrane
3478:2,4,5-Trichlorophenol
2482:10.1081/CLT-100102423
2425:Armit, H. W. (1908).
2382:Armit, H. W. (1907).
1980:(1516): 63–64. 1898.
1664:The vapours of Ni(CO)
1645:The hazards of Ni(CO)
1475:
1398:
1291:Structure and bonding
1170:Dicobalt octacarbonyl
1135:Vanadium hexacarbonyl
1125:Tungsten hexacarbonyl
1115:Chromium hexacarbonyl
1025:360 ppm (dog, 90 min)
1001:266 ppm (cat, 30 min)
914:
552:Coordination geometry
94:Nickel carbonyl (1:4)
63:
53:
31:Nickel tetracarbonyl
4569:Methyl fluoroacetate
4397:Methyl cyanoacrylate
4317:Allyl isothiocyanate
3905:Uranium hexafluoride
3860:Dinitrogen tetroxide
3805:Chlorine trifluoride
2853:Selenium oxychloride
2723:Phenyldichloroarsine
2717:Methyldichloroarsine
2655:Nickel tetracarbonyl
2309:on February 25, 2012
2202:. pp. 213–259.
1954:10.1039/CT8905700749
1942:J. Chem. Soc. Trans.
1743:In the 1979 novella
1689:chemical pneumonitis
1322:Electron diffraction
995:median concentration
897:(fire diamond)
92:Nickel tetracarbonyl
4262:Bromobenzyl cyanide
4030:Dimethylheptylpyran
3958:Diphenylcyanoarsine
3953:Diphenylchlorarsine
3885:Methyl vinyl ketone
3810:Perchloryl fluoride
3674:Bicyclic phosphates
3493:Trimethyl phosphite
3442:Phosphoryl chloride
2711:Ethyldichloroarsine
2685:Chloral cyanohydrin
2675:Acetone cyanohydrin
2645:Methyl cyanoformate
2470:Clinical Toxicology
2255:1980Sci...208.1029S
2249:(4447): 1029–1031.
2053:Wilkinson, Geoffrey
2049:Stone, F. Gordon A.
1986:1898Natur..59...63.
1911:1979JChPh..70.3224H
1780:bestselling author
1693:acute kidney injury
1559:Reactions of Ni(CO)
1476:Structure of Ni(PPh
1241:tetracarbonylnickel
1155:Diiron nonacarbonyl
493:Solubility in water
153:Beilstein Reference
84:Tetracarbonylnickel
32:
6160:Carbonyl complexes
4630:CB military symbol
4488:Enterotoxin type B
4443:Cyclopiazonic acid
4402:N-Methylmorpholine
4302:Ethyl bromoacetate
3780:Ethyl bromoacetate
3747:Perfluoroisobutene
3488:Triethyl phosphite
2759:Levinstein mustard
2650:Iron pentacarbonyl
2431:Journal of Hygiene
2388:Journal of Hygiene
1772:In the 2019 novel
1730:In popular culture
1577:oxidative addition
1490:
1430:triphenylphosphine
1401:
1304:. The molecule is
1221:Infobox references
1150:Iron pentacarbonyl
1098:Related compounds
1076:(Immediate danger)
916:
66:
56:
30:
6137:
6136:
6131:
6130:
5165:
5164:
4638:
4637:
4448:Histrionicotoxins
4426:Biological toxins
4307:Ethyl iodoacetate
3875:Methyl isocyanate
3835:Selenoyl fluoride
3825:Mercuric chloride
3795:Tetranitromethane
3649:Sulfuryl fluoride
3634:HN3 hydrochloride
3629:HN2 hydrochloride
3624:HN1 hydrochloride
3511:
3510:
3468:Phenacyl chloride
3463:Pinacolyl alcohol
3409:Isopropyl alcohol
3404:4-Hydroxycoumarin
3338:1,8-Dibromooctane
2861:
2860:
2785:Nitrogen mustards
2598:Cyanogen chloride
2217:978-0-309-11213-0
2176:Collected Volumes
2164:Organic Syntheses
1852:"Nickel carbonyl"
1751:Gordon R. Dickson
1385:sodium dithionite
1367:Laboratory routes
1229:Chemical compound
1227:
1226:
1086:Safety data sheet
738:Hazard statements
530:315 mmHg (20 °C)
508:miscible in most
446:colorless liquid
325:CompTox Dashboard
141:Interactive image
70:
69:
27:Chemical compound
16:(Redirected from
6177:
6155:Nickel compounds
5607:
5210:
5192:
5185:
5178:
5169:
5156:
5135:
5070:
5069:
5068:
5060:
5059:
5051:
5050:
5037:
5036:
5035:
5027:
5026:
5018:
5017:
4990:
4989:
4977:
4976:
4813:
4812:
4790:
4789:
4767:
4766:
4744:
4743:
4665:
4658:
4651:
4642:
4612:White phosphorus
4589:post-combustion
4585:Depleted uranium
4412:Osmium tetroxide
4292:Phenacyl bromide
3855:Nitrogen dioxide
3830:Selenium dioxide
3820:Cadmium chloride
3277:Dimefox (TL-792)
2872:
2700:
2625:Hydrogen sulfide
2604:Hydrogen cyanide
2593:Cyanogen bromide
2559:chemical warfare
2548:
2541:
2534:
2525:
2493:
2464:
2454:
2421:
2411:
2378:
2357:
2340:(2–3): 293–298.
2319:
2318:
2316:
2314:
2308:
2302:. Archived from
2297:
2289:
2283:
2282:
2236:
2230:
2229:
2187:
2181:
2179:
2172:
2154:
2148:
2147:
2121:
2115:
2114:
2092:
2086:
2085:
2077:
2071:
2070:
2044:
2038:
2037:
2009:
2000:
1999:
1997:
1995:10.1038/059063a0
1964:
1958:
1957:
1929:
1923:
1922:
1919:10.1063/1.437911
1905:(7): 3224–3229.
1890:
1884:
1883:
1878:(7th ed.).
1870:
1864:
1863:
1848:
1839:
1836:
1830:
1829:
1817:
1790:near Earth orbit
1637:
1593:
1536:
1521:
1509:
1458:
1443:
1302:18-electron rule
1211:
1205:
1202:
1201:
1019:lowest published
971:Explosive limits
936:
929:
922:
907:
887:
883:
879:
875:
871:
867:
863:
859:
855:
851:
847:
843:
839:
835:
831:
827:
823:
819:
815:
811:
807:
803:
799:
795:
791:
777:
773:
769:
765:
761:
757:
753:
749:
745:
731:
726:
721:
716:
660:
633:
606:
586:Thermochemistry
510:organic solvents
419:Chemical formula
349:
348:
333:
331:
305:
269:
258:
242:Gmelin Reference
225:
217:
206:
195:
175:
143:
119:
46:
40:
33:
21:
6185:
6184:
6180:
6179:
6178:
6176:
6175:
6174:
6140:
6139:
6138:
6133:
6132:
6040:
5984:
5929:
5925:
5917:
5913:
5908:
5906:
5901:
5899:
5895:
5890:
5888:
5880:
5875:
5873:
5869:
5861:
5857:
5853:
5849:
5845:
5840:
5838:
5818:
5780:
5772:
5768:
5764:
5759:
5757:
5753:
5748:
5746:
5742:
5734:
5729:
5727:
5723:
5718:
5716:
5708:
5703:
5701:
5697:
5689:
5685:
5681:
5676:
5674:
5660:
5650:
5633:
5608:
5605:
5598:
5590:
5586:
5581:
5579:
5574:
5572:
5568:
5563:
5561:
5557:
5549:
5545:
5541:
5536:
5534:
5530:
5526:
5521:
5519:
5514:
5512:
5508:
5503:
5501:
5497:
5492:
5490:
5482:
5477:
5475:
5471:
5463:
5459:
5455:
5450:
5448:
5440:
5435:
5433:
5429:
5425:
5420:
5418:
5410:
5406:
5401:
5399:
5394:
5392:
5384:
5374:
5358:
5353:
5350:
5326:
5322:
5318:
5302:
5297:
5293:
5290:
5270:
5268:
5263:
5261:
5252:
5244:
5240:
5217:
5202:
5196:
5166:
5161:
5157:
5154:
5147:
5143:
5134:
5130:
5118:
5109:
5105:
5097:
5082:
5078:
5067:
5064:
5063:
5062:
5058:
5055:
5054:
5053:
5049:
5046:
5045:
5044:
5042:
5034:
5031:
5030:
5029:
5025:
5022:
5021:
5020:
5016:
5013:
5012:
5011:
5009:
5004:
5000:
4988:
4985:
4984:
4983:
4981:
4975:
4972:
4971:
4970:
4968:
4960:
4956:
4948:
4944:
4936:
4932:
4914:
4906:
4898:
4890:
4886:
4882:
4874:
4866:
4858:
4845:
4835:
4831:
4823:
4811:
4808:
4807:
4806:
4800:
4788:
4785:
4784:
4783:
4777:
4765:
4762:
4761:
4760:
4754:
4742:
4739:
4738:
4737:
4731:
4727:
4719:
4704:
4700:
4692:
4677:
4669:
4639:
4634:
4616:
4557:
4468:Botulinum toxin
4421:
4370:
4331:
4247:Benzyl chloride
4202:
4195:
3979:
3972:
3963:Cacodyl cyanide
3925:Vomiting agents
3919:
3717:
3710:
3619:Dimethylmercury
3541:Botulinum toxin
3507:
3286:
3200:
3102:
3055:Novichok agents
3049:
3033:
2960:
2857:
2831:
2812:
2779:
2751:Sulfur mustards
2745:
2689:
2635:Carbon monoxide
2615:Cacodyl cyanide
2574:
2573:
2557:Agents used in
2552:
2500:
2467:
2424:
2381:
2360:
2331:
2328:
2326:Further reading
2323:
2322:
2312:
2310:
2306:
2295:
2291:
2290:
2286:
2238:
2237:
2233:
2218:
2198:. Vol. 6.
2189:
2188:
2184:
2174:
2156:
2155:
2151:
2144:
2123:
2122:
2118:
2111:
2094:
2093:
2089:
2079:
2078:
2074:
2067:
2046:
2045:
2041:
2034:
2011:
2010:
2003:
1966:
1965:
1961:
1931:
1930:
1926:
1896:
1892:
1891:
1887:
1875:The Merck Index
1872:
1871:
1867:
1850:
1849:
1842:
1837:
1833:
1819:
1818:
1803:
1798:
1787:
1732:
1714:
1709:carcinogenicity
1667:
1655:
1648:
1643:
1635:
1631:
1627:
1619:
1611:
1607:
1603:
1599:
1595:
1592:
1588:
1584:
1580:
1574:
1562:
1554:
1543:
1534:
1530:
1528:
1519:
1515:
1511:
1507:
1503:
1499:
1494:Treatment with
1487:
1483:
1479:
1457:
1453:
1449:
1445:
1441:
1437:
1433:
1427:
1422:
1411:
1406:
1393:
1374:
1369:
1335:
1330:
1314:carbon monoxide
1297:oxidation state
1293:
1254:
1233:Nickel carbonyl
1230:
1223:
1218:
1217:
1216: ?)
1207:
1203:
1199:
1195:
1184:
1108:
1106:metal carbonyls
1077:
1064:
1051:
1030:
1028:
1026:
1022:
1016:
1006:
1004:
1002:
998:
992:
962:
959:
941:
940:
939:
938:
931:
924:
917:
913:
905:
786:
740:
709:
686:
661:
658:
652:
648:
645:
644:Std enthalpy of
634:
631:
625:
621:
618:
617:Std enthalpy of
607:
604:
597:
594:
578:
566:
564:Molecular shape
554:
540:3.05 x 10 Pa s
512:
495:
427:
421:
407:
404:
399:
398:
387:
384:
383:
380:
374:
373:
370:
364:
363:
352:
334:
327:
308:
288:
272:
259:
244:
235:
198:
178:
155:
146:
133:
122:
109:
95:
93:
85:
64:Nickel carbonyl
54:Nickel carbonyl
28:
23:
22:
18:Nickel carbonyl
15:
12:
11:
5:
6183:
6181:
6173:
6172:
6167:
6162:
6157:
6152:
6142:
6141:
6135:
6134:
6129:
6128:
6125:
6122:
6119:
6116:
6113:
6110:
6107:
6104:
6101:
6098:
6095:
6092:
6089:
6086:
6082:
6081:
6078:
6075:
6072:
6069:
6066:
6063:
6060:
6057:
6054:
6051:
6048:
6045:
6042:
6038:
6034:
6030:
6029:
6026:
6023:
6022:
6019:
6016:
6013:
6010:
6007:
6004:
6001:
5998:
5995:
5992:
5989:
5986:
5982:
5978:
5975:
5972:
5969:
5966:
5963:
5959:
5958:
5955:
5952:
5949:
5946:
5943:
5940:
5937:
5934:
5931:
5927:
5923:
5919:
5915:
5911:
5904:
5897:
5893:
5886:
5882:
5878:
5871:
5867:
5863:
5859:
5855:
5851:
5847:
5843:
5836:
5832:
5829:
5826:
5823:
5820:
5816:
5812:
5808:
5807:
5804:
5801:
5798:
5795:
5792:
5789:
5786:
5782:
5778:
5774:
5770:
5766:
5762:
5755:
5751:
5744:
5740:
5736:
5732:
5725:
5721:
5714:
5710:
5706:
5699:
5695:
5691:
5687:
5683:
5679:
5672:
5668:
5665:
5662:
5658:
5654:
5652:
5648:
5644:
5640:
5639:
5636:
5631:
5627:
5622:
5619:
5616:
5613:
5610:
5604:
5600:
5596:
5592:
5588:
5584:
5577:
5570:
5566:
5559:
5555:
5551:
5547:
5543:
5539:
5532:
5528:
5524:
5517:
5510:
5506:
5499:
5495:
5488:
5484:
5480:
5473:
5469:
5465:
5461:
5457:
5453:
5446:
5442:
5438:
5431:
5427:
5423:
5416:
5412:
5408:
5404:
5397:
5390:
5386:
5382:
5378:
5376:
5372:
5368:
5364:
5363:
5360:
5356:
5348:
5344:
5339:
5334:
5331:
5328:
5324:
5320:
5316:
5312:
5308:
5307:
5304:
5300:
5288:
5284:
5279:
5274:
5266:
5259:
5255:
5250:
5246:
5242:
5238:
5234:
5230:
5229:
5226:
5224:
5222:
5220:
5215:
5208:
5207:
5204:
5203:
5199:Metal carbonyl
5197:
5195:
5194:
5187:
5180:
5172:
5163:
5162:
5160:
5159:
5153:
5149:
5145:
5141:
5137:
5126:
5124:
5120:
5119:
5117:
5116:
5111:
5107:
5103:
5099:
5095:
5090:
5088:
5084:
5083:
5081:
5080:
5076:
5072:
5065:
5056:
5047:
5039:
5032:
5023:
5014:
5006:
5002:
4998:
4994:
4993:
4992:
4986:
4979:
4973:
4966:
4958:
4954:
4950:
4946:
4942:
4938:
4934:
4930:
4926:
4921:
4916:
4912:
4908:
4904:
4900:
4896:
4892:
4888:
4884:
4880:
4876:
4872:
4868:
4864:
4860:
4856:
4852:
4847:
4843:
4839:
4838:
4837:
4833:
4829:
4821:
4817:
4816:
4815:
4809:
4798:
4794:
4793:
4792:
4786:
4775:
4771:
4770:
4769:
4763:
4752:
4748:
4747:
4746:
4740:
4733:
4729:
4725:
4717:
4712:
4710:
4706:
4705:
4703:
4702:
4698:
4694:
4690:
4685:
4683:
4679:
4678:
4670:
4668:
4667:
4660:
4653:
4645:
4636:
4635:
4633:
4632:
4627:
4621:
4618:
4617:
4615:
4614:
4609:
4604:
4595:
4594:
4593:
4591:uranium oxides
4582:
4577:
4571:
4565:
4563:
4559:
4558:
4556:
4555:
4550:
4545:
4540:
4535:
4530:
4525:
4520:
4515:
4510:
4505:
4500:
4495:
4490:
4485:
4480:
4475:
4470:
4465:
4460:
4455:
4450:
4445:
4440:
4435:
4429:
4427:
4423:
4422:
4420:
4419:
4414:
4409:
4404:
4399:
4394:
4389:
4384:
4378:
4376:
4372:
4371:
4369:
4368:
4363:
4358:
4353:
4348:
4342:
4340:
4333:
4332:
4330:
4329:
4327:Crotonaldehyde
4324:
4319:
4314:
4309:
4304:
4299:
4294:
4289:
4284:
4279:
4274:
4269:
4264:
4259:
4254:
4252:Benzyl bromide
4249:
4244:
4239:
4234:
4229:
4224:
4219:
4213:
4207:
4205:
4197:
4196:
4194:
4193:
4191:Chlorpromazine
4188:
4183:
4178:
4173:
4168:
4163:
4158:
4153:
4148:
4143:
4138:
4133:
4128:
4123:
4118:
4113:
4108:
4103:
4098:
4093:
4088:
4083:
4078:
4073:
4068:
4063:
4058:
4053:
4048:
4043:
4038:
4033:
4027:
4022:
4017:
4012:
4007:
4001:
3996:
3991:
3984:
3982:
3978:Incapacitating
3974:
3973:
3971:
3970:
3965:
3960:
3955:
3950:
3941:
3936:
3929:
3927:
3921:
3920:
3918:
3917:
3912:
3907:
3902:
3897:
3892:
3887:
3882:
3877:
3872:
3867:
3865:Sulfur dioxide
3862:
3857:
3852:
3847:
3842:
3837:
3832:
3827:
3822:
3817:
3812:
3807:
3802:
3797:
3792:
3787:
3782:
3777:
3772:
3766:
3760:
3755:
3749:
3744:
3739:
3733:
3728:
3722:
3720:
3718:choking agents
3712:
3711:
3709:
3708:
3703:
3698:
3693:
3692:
3691:
3686:
3681:
3671:
3666:
3661:
3656:
3651:
3646:
3641:
3636:
3631:
3626:
3621:
3616:
3614:Tetraethyllead
3611:
3605:
3600:
3594:
3589:
3584:
3578:
3572:
3567:
3561:
3555:
3550:
3544:
3538:
3533:
3527:
3521:
3519:
3513:
3512:
3509:
3508:
3506:
3505:
3500:
3495:
3490:
3485:
3480:
3475:
3470:
3465:
3460:
3455:
3449:
3444:
3439:
3434:
3429:
3424:
3418:
3412:
3406:
3401:
3396:
3391:
3386:
3381:
3376:
3371:
3366:
3361:
3356:
3351:
3346:
3340:
3335:
3330:
3325:
3320:
3318:A.P.C. complex
3315:
3310:
3305:
3300:
3294:
3292:
3288:
3287:
3285:
3284:
3279:
3274:
3269:
3264:
3259:
3254:
3249:
3244:
3239:
3234:
3229:
3224:
3219:
3214:
3208:
3206:
3202:
3201:
3199:
3198:
3193:
3188:
3183:
3178:
3173:
3168:
3163:
3158:
3153:
3148:
3143:
3138:
3133:
3128:
3123:
3118:
3112:
3110:
3104:
3103:
3101:
3100:
3095:
3090:
3085:
3080:
3075:
3070:
3065:
3059:
3057:
3051:
3050:
3048:
3047:
3041:
3039:
3035:
3034:
3032:
3031:
3029:V-sub x (GD-7)
3026:
3021:
3016:
3011:
3006:
3001:
2996:
2991:
2986:
2981:
2976:
2970:
2968:
2962:
2961:
2959:
2958:
2953:
2948:
2943:
2938:
2933:
2927:
2922:
2916:
2910:
2904:
2898:
2892:
2887:
2880:
2878:
2869:
2863:
2862:
2859:
2858:
2856:
2855:
2850:
2845:
2839:
2837:
2833:
2832:
2830:
2829:
2826:Phosgene oxime
2822:
2820:
2814:
2813:
2811:
2810:
2805:
2800:
2795:
2789:
2787:
2781:
2780:
2778:
2777:
2772:
2767:
2762:
2755:
2753:
2747:
2746:
2744:
2738:
2732:
2726:
2720:
2714:
2708:
2706:
2697:
2695:Blister agents
2691:
2690:
2688:
2687:
2682:
2677:
2672:
2667:
2665:Glycolonitrile
2662:
2657:
2652:
2647:
2642:
2637:
2632:
2627:
2622:
2617:
2612:
2607:
2601:
2595:
2590:
2584:
2582:
2576:
2575:
2572:
2571:
2566:
2564:incapacitation
2561:
2554:
2553:
2551:
2550:
2543:
2536:
2528:
2522:
2521:
2516:
2511:
2506:
2499:
2498:External links
2496:
2495:
2494:
2476:(2): 239–258.
2465:
2437:(5): 565–610.
2422:
2394:(4): 525–551.
2379:
2358:
2327:
2324:
2321:
2320:
2284:
2231:
2216:
2208:10.17226/12018
2182:
2149:
2142:
2116:
2109:
2087:
2072:
2065:
2039:
2033:978-3527306732
2032:
2001:
1959:
1924:
1894:
1885:
1865:
1840:
1831:
1800:
1799:
1797:
1794:
1785:
1778:New York Times
1731:
1728:
1712:
1665:
1653:
1646:
1642:
1639:
1572:
1560:
1552:
1542:
1539:
1526:
1492:
1491:
1485:
1481:
1477:
1432:react to give
1425:
1421:
1418:
1409:
1405:
1402:
1392:
1389:
1372:
1368:
1365:
1333:
1329:
1326:
1292:
1289:
1252:
1228:
1225:
1224:
1219:
1197:
1196:
1192:standard state
1189:
1186:
1185:
1183:
1182:
1177:
1172:
1167:
1162:
1157:
1152:
1147:
1142:
1137:
1132:
1127:
1122:
1117:
1111:
1109:
1103:
1100:
1099:
1095:
1094:
1089:
1082:
1081:
1078:
1072:
1069:
1068:
1065:
1059:
1056:
1055:
1052:
1046:
1043:
1042:
1033:
1032:
1023:
1014:
1012:
1009:
1008:
999:
990:
988:
985:
984:
977:
976:
973:
967:
966:
963:
956:
953:
952:
949:
943:
942:
932:
925:
918:
903:
902:
901:
900:
898:
889:
888:
846:P303+P361+P353
787:
782:
779:
778:
741:
736:
733:
732:
710:
705:
702:
701:
691:
690:
687:
684:
681:
680:
671:
670:
666:
665:
662:
656:
650:
642:
639:
638:
635:
629:
623:
615:
612:
611:
608:
602:
591:
588:
587:
583:
582:
579:
574:
571:
570:
567:
562:
559:
558:
555:
550:
547:
546:
542:
541:
538:
532:
531:
528:
526:Vapor pressure
522:
521:
506:
500:
499:
496:
491:
488:
487:
484:
478:
477:
474:
468:
467:
464:
458:
457:
454:
448:
447:
444:
440:
439:
436:
430:
429:
425:
422:
417:
414:
413:
409:
408:
406:
405:
402:
394:
393:
392:
389:
388:
386:
385:
381:
378:
377:
375:
371:
368:
367:
359:
358:
357:
354:
353:
351:
350:
337:
335:
323:
320:
319:
316:
310:
309:
307:
306:
298:
296:
290:
289:
287:
286:
282:
280:
274:
273:
271:
270:
262:
260:
252:
249:
248:
245:
240:
237:
236:
234:
233:
229:
227:
219:
218:
208:
200:
199:
197:
196:
188:
186:
180:
179:
177:
176:
168:
166:
160:
159:
156:
151:
148:
147:
145:
144:
136:
134:
127:
124:
123:
121:
120:
112:
110:
105:
102:
101:
97:
96:
91:
87:
86:
83:
77:
76:
72:
71:
68:
67:
57:
42:
41:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
6182:
6171:
6168:
6166:
6163:
6161:
6158:
6156:
6153:
6151:
6148:
6147:
6145:
6126:
6123:
6120:
6117:
6114:
6111:
6108:
6105:
6102:
6099:
6096:
6093:
6090:
6087:
6084:
6083:
6079:
6076:
6073:
6070:
6067:
6064:
6061:
6058:
6055:
6052:
6049:
6046:
6043:
6041:
6035:
6032:
6031:
6024:
6020:
6017:
6014:
6011:
6008:
6005:
6002:
5999:
5996:
5993:
5990:
5987:
5985:
5979:
5976:
5973:
5970:
5967:
5964:
5961:
5960:
5956:
5953:
5950:
5947:
5944:
5941:
5938:
5935:
5932:
5930:
5920:
5918:
5907:
5900:
5889:
5883:
5881:
5874:
5864:
5862:
5839:
5833:
5830:
5827:
5824:
5821:
5819:
5813:
5810:
5809:
5805:
5802:
5799:
5796:
5793:
5790:
5787:
5785:
5783:
5781:
5775:
5773:
5758:
5747:
5737:
5735:
5728:
5717:
5711:
5709:
5702:
5692:
5690:
5675:
5669:
5666:
5663:
5661:
5655:
5653:
5651:
5645:
5642:
5641:
5637:
5635:
5628:
5626:
5623:
5620:
5617:
5614:
5611:
5609:
5601:
5599:
5593:
5591:
5580:
5573:
5562:
5552:
5550:
5535:
5520:
5513:
5502:
5491:
5485:
5483:
5476:
5466:
5464:
5449:
5443:
5441:
5434:
5419:
5413:
5411:
5400:
5393:
5387:
5385:
5379:
5377:
5375:
5369:
5366:
5365:
5361:
5359:
5352:
5345:
5343:
5340:
5338:
5335:
5332:
5329:
5327:
5313:
5310:
5309:
5305:
5303:
5296:
5292:
5285:
5283:
5280:
5278:
5275:
5273:
5269:
5262:
5256:
5254:
5247:
5245:
5235:
5232:
5231:
5227:
5221:
5219:
5212:
5211:
5205:
5200:
5193:
5188:
5186:
5181:
5179:
5174:
5173:
5170:
5158:
5150:
5148:
5138:
5136:
5128:
5127:
5125:
5121:
5115:
5112:
5110:
5100:
5098:
5092:
5091:
5089:
5085:
5079:
5073:
5071:
5040:
5038:
5007:
5005:
4995:
4991:
4963:
4962:
4961:
4951:
4949:
4939:
4937:
4927:
4925:
4922:
4920:
4917:
4915:
4909:
4907:
4901:
4899:
4893:
4891:
4877:
4875:
4869:
4867:
4861:
4859:
4853:
4851:
4848:
4846:
4840:
4836:
4826:
4825:
4824:
4818:
4814:
4803:
4802:
4801:
4795:
4791:
4780:
4779:
4778:
4772:
4768:
4757:
4756:
4755:
4749:
4745:
4734:
4732:
4722:
4721:
4720:
4714:
4713:
4711:
4707:
4701:
4695:
4693:
4687:
4686:
4684:
4680:
4676:
4673:
4666:
4661:
4659:
4654:
4652:
4647:
4646:
4643:
4631:
4628:
4626:
4623:
4622:
4619:
4613:
4610:
4608:
4605:
4603:
4602:its compounds
4599:
4596:
4592:
4588:
4587:
4586:
4583:
4581:
4578:
4575:
4572:
4570:
4567:
4566:
4564:
4560:
4554:
4551:
4549:
4546:
4544:
4541:
4539:
4538:Tetanospasmin
4536:
4534:
4533:T-2 mycotoxin
4531:
4529:
4526:
4524:
4521:
4519:
4516:
4514:
4511:
4509:
4506:
4504:
4501:
4499:
4496:
4494:
4491:
4489:
4486:
4484:
4481:
4479:
4476:
4474:
4471:
4469:
4466:
4464:
4463:Batrachotoxin
4461:
4459:
4456:
4454:
4451:
4449:
4446:
4444:
4441:
4439:
4436:
4434:
4431:
4430:
4428:
4424:
4418:
4415:
4413:
4410:
4408:
4407:Allyl alcohol
4405:
4403:
4400:
4398:
4395:
4393:
4390:
4388:
4385:
4383:
4380:
4379:
4377:
4373:
4367:
4364:
4362:
4359:
4357:
4354:
4352:
4349:
4347:
4344:
4343:
4341:
4338:
4334:
4328:
4325:
4323:
4320:
4318:
4315:
4313:
4310:
4308:
4305:
4303:
4300:
4298:
4295:
4293:
4290:
4288:
4285:
4283:
4280:
4278:
4275:
4273:
4272:Chloroacetone
4270:
4268:
4265:
4263:
4260:
4258:
4257:Benzyl iodide
4255:
4253:
4250:
4248:
4245:
4243:
4240:
4238:
4235:
4233:
4230:
4228:
4225:
4223:
4220:
4217:
4214:
4212:
4211:Xylyl bromide
4209:
4208:
4206:
4204:
4198:
4192:
4189:
4187:
4184:
4182:
4179:
4177:
4174:
4172:
4169:
4167:
4164:
4162:
4159:
4157:
4154:
4152:
4149:
4147:
4144:
4142:
4139:
4137:
4134:
4132:
4129:
4127:
4124:
4122:
4119:
4117:
4114:
4112:
4109:
4107:
4104:
4102:
4099:
4097:
4094:
4092:
4089:
4087:
4084:
4082:
4079:
4077:
4074:
4072:
4069:
4067:
4064:
4062:
4059:
4057:
4054:
4052:
4049:
4047:
4044:
4042:
4039:
4037:
4034:
4031:
4028:
4026:
4023:
4021:
4018:
4016:
4013:
4011:
4008:
4005:
4002:
4000:
3999:Butyrophenone
3997:
3995:
3992:
3989:
3986:
3985:
3983:
3981:
3975:
3969:
3968:o-Dianisidine
3966:
3964:
3961:
3959:
3956:
3954:
3951:
3949:
3945:
3942:
3940:
3937:
3934:
3931:
3930:
3928:
3926:
3922:
3916:
3913:
3911:
3908:
3906:
3903:
3901:
3898:
3896:
3893:
3891:
3888:
3886:
3883:
3881:
3878:
3876:
3873:
3871:
3868:
3866:
3863:
3861:
3858:
3856:
3853:
3851:
3848:
3846:
3843:
3841:
3838:
3836:
3833:
3831:
3828:
3826:
3823:
3821:
3818:
3816:
3815:Cadmium oxide
3813:
3811:
3808:
3806:
3803:
3801:
3798:
3796:
3793:
3791:
3788:
3786:
3783:
3781:
3778:
3776:
3773:
3770:
3767:
3764:
3761:
3759:
3756:
3753:
3750:
3748:
3745:
3743:
3740:
3737:
3734:
3732:
3729:
3727:
3724:
3723:
3721:
3719:
3713:
3707:
3704:
3702:
3699:
3697:
3694:
3690:
3687:
3685:
3682:
3680:
3677:
3676:
3675:
3672:
3670:
3667:
3665:
3664:Batrachotoxin
3662:
3660:
3657:
3655:
3652:
3650:
3647:
3645:
3642:
3640:
3637:
3635:
3632:
3630:
3627:
3625:
3622:
3620:
3617:
3615:
3612:
3609:
3606:
3604:
3601:
3598:
3595:
3593:
3590:
3588:
3585:
3582:
3579:
3576:
3573:
3571:
3568:
3565:
3562:
3559:
3556:
3554:
3551:
3548:
3547:Tetanospasmin
3545:
3542:
3539:
3537:
3534:
3531:
3528:
3526:
3523:
3522:
3520:
3518:
3514:
3504:
3501:
3499:
3496:
3494:
3491:
3489:
3486:
3484:
3481:
3479:
3476:
3474:
3471:
3469:
3466:
3464:
3461:
3459:
3456:
3453:
3450:
3448:
3445:
3443:
3440:
3438:
3435:
3433:
3430:
3428:
3425:
3422:
3419:
3416:
3413:
3410:
3407:
3405:
3402:
3400:
3397:
3395:
3392:
3390:
3387:
3385:
3382:
3380:
3377:
3375:
3372:
3370:
3367:
3365:
3362:
3360:
3357:
3355:
3352:
3350:
3347:
3344:
3341:
3339:
3336:
3334:
3331:
3329:
3326:
3324:
3321:
3319:
3316:
3314:
3311:
3309:
3306:
3304:
3301:
3299:
3296:
3295:
3293:
3289:
3283:
3280:
3278:
3275:
3273:
3270:
3268:
3265:
3263:
3260:
3258:
3255:
3253:
3250:
3248:
3245:
3243:
3240:
3238:
3235:
3233:
3230:
3228:
3225:
3223:
3220:
3218:
3215:
3213:
3210:
3209:
3207:
3203:
3197:
3194:
3192:
3189:
3187:
3184:
3182:
3179:
3177:
3174:
3172:
3169:
3167:
3164:
3162:
3159:
3157:
3154:
3152:
3149:
3147:
3144:
3142:
3139:
3137:
3134:
3132:
3129:
3127:
3124:
3122:
3119:
3117:
3114:
3113:
3111:
3109:
3105:
3099:
3096:
3094:
3091:
3089:
3086:
3084:
3081:
3079:
3076:
3074:
3071:
3069:
3066:
3064:
3061:
3060:
3058:
3056:
3052:
3046:
3043:
3042:
3040:
3036:
3030:
3027:
3025:
3022:
3020:
3017:
3015:
3012:
3010:
3007:
3005:
3002:
3000:
2997:
2995:
2992:
2990:
2987:
2985:
2982:
2980:
2977:
2975:
2972:
2971:
2969:
2967:
2963:
2957:
2954:
2952:
2949:
2947:
2944:
2942:
2939:
2937:
2934:
2931:
2928:
2926:
2923:
2920:
2917:
2914:
2911:
2908:
2905:
2902:
2899:
2896:
2893:
2891:
2888:
2885:
2882:
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2620:Cacodyl oxide
2618:
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2110:3-527-28165-7
2106:
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2068:
2066:0-08-025269-9
2062:
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2029:
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2017:
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1782:Daniel Suarez
1779:
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1747:
1746:Amanda Morgan
1741:
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1738:
1729:
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1725:
1721:
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1710:
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1702:
1698:
1697:Convalescence
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1378:
1377:carbonylation
1366:
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1096:
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1084:
1083:
1079:
1075:
1071:
1070:
1066:
1063:(Recommended)
1062:
1058:
1057:
1053:
1050:(Permissible)
1049:
1045:
1044:
1040:
1039:
1034:
1024:
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987:
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678:
677:
672:
667:
664:−1180 kJ/mol
663:
655:
647:
641:
640:
636:
628:
620:
614:
613:
609:
601:
596:
590:
589:
584:
580:
577:
576:Dipole moment
573:
572:
568:
565:
561:
560:
556:
553:
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548:
543:
539:
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533:
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501:
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482:Boiling point
480:
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472:Melting point
470:
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342:DTXSID0024212
339:
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209:
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205:ECHA InfoCard
202:
201:
194:
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174:
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62:
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52:
48:
47:
43:
39:
34:
19:
6170:Blood agents
5594:
4688:
4543:Tetrodotoxin
4493:Grayanotoxin
4277:Bromoacetone
4267:Thiophosgene
4222:Mace (spray)
4216:Pepper spray
4201:Lachrymatory
4186:Fluphenazine
4181:Procarbazine
4091:Sleeping gas
3939:Chloropicrin
3850:Nitric oxide
3752:Chloropicrin
3696:Cloflubicyne
3659:Oxotremorine
3608:Antillatoxin
3587:Tetrodotoxin
3536:Bungarotoxin
3432:Nitromethane
3394:Formaldoxime
3333:Cyclohexanol
3298:Acetonitrile
3045:GV (EA-5365)
2867:Nerve agents
2670:Lactonitrile
2654:
2580:Blood agents
2569:riot control
2473:
2469:
2434:
2430:
2391:
2387:
2366:
2362:
2337:
2333:
2311:. Retrieved
2304:the original
2287:
2246:
2240:
2234:
2195:
2185:
2175:
2168:
2162:
2152:
2125:
2119:
2096:
2090:
2081:
2075:
2056:
2042:
2013:
1977:
1971:
1962:
1945:
1940:
1927:
1902:
1898:
1888:
1874:
1868:
1855:
1834:
1777:
1773:
1771:
1767:Mond Process
1760:
1755:
1744:
1742:
1737:Quincy, M.E.
1735:
1733:
1717:
1678:
1672:. The vapor
1663:
1644:
1621:
1613:
1558:
1544:
1524:
1493:
1423:
1414:Mond process
1407:
1370:
1362:
1331:
1308:, with four
1294:
1269:Mond process
1265:intermediate
1263:. It is an
1240:
1232:
1231:
1037:
980:
958:Autoignition
893:
695:
685:Main hazards
674:
653:
637:−632 kJ/mol
626:
599:
569:Tetrahedral
557:Tetrahedral
403:#C(C#)(C#)C#
278:RTECS number
100:Identifiers
90:Other names
5087:Nickel(III)
4553:Veratridine
4528:Shiga toxin
4483:Domoic acid
4346:Thioacetone
4312:Iodoacetone
4176:Pentazocine
4171:Sevoflurane
4136:CAR-302,668
4131:CAR-302,282
4126:CAR-302,196
4121:CAR-301,060
4116:CAR-226,086
4096:Carfentanil
3994:Apomorphine
3915:Green Cross
3706:Domoic acid
3517:Neurotoxins
3437:OPA mixture
3328:Chlorosoman
3323:Chlorosarin
3257:Phospholine
2956:Crotylsarin
2941:Fluorotabun
2913:Chlorosoman
2895:Chlorosarin
2369:(1): 1–16.
2313:October 29,
1948:: 749–753.
1531:[Ni(CO)
1338:Ludwig Mond
1328:Preparation
1306:tetrahedral
981:Lethal dose
960:temperature
947:Flash point
679:(OHS/OSH):
515:nitric acid
513:soluble in
466:1.319 g/cm
443:Appearance
412:Properties
211:100.033.322
173:CHEBI:30372
6144:Categories
5603:(Cu(CO)Cl)
5123:Nickel(IV)
4709:Nickel(II)
4503:Maitotoxin
4498:Guanitoxin
4478:Ciguatoxin
4473:Brevetoxin
4458:Anatoxin-a
4453:Aflatoxins
4366:Putrescine
4361:Cadaverine
4337:Malodorant
4161:Isoflurane
4146:Desflurane
4141:Benperidol
4086:Psilocybin
4081:PAVA spray
3763:Diphosgene
3716:Pulmonary/
3644:Picrotoxin
3603:Strychnine
3597:Brevetoxin
3581:Maitotoxin
3564:Guanitoxin
3558:Ciguatoxin
3525:Anatoxin-a
3458:Pinacolone
3291:Precursors
3252:Selenophos
3108:Carbamates
3024:Chinese VX
2930:Cyclosarin
2919:Ethylsarin
2890:Sarin (GB)
2741:Lewisite 3
2735:Lewisite 2
2704:Arsenicals
2143:0471936235
1796:References
1701:depression
1685:chest pain
1674:decomposes
1670:autoignite
1496:hydroxides
1461:Bipyridine
707:Pictograms
646:combustion
545:Structure
519:aqua regia
504:Solubility
434:Molar mass
303:1ZYL78UWZN
184:ChemSpider
128:3D model (
117:13463-39-3
107:CAS Number
81:IUPAC name
5583:HC(Co(CO)
5272:(HC=CH)CO
5265:(C=C)(CO)
5201:complexes
4682:Nickel(0)
4675:compounds
4598:Plutonium
4548:Volkensin
4523:Saxitoxin
4513:Palytoxin
4438:Aconitine
4166:Halothane
4156:Bufotenin
4151:Enflurane
4071:Kolokol-1
4051:Pethidine
4025:Etoxadrol
4010:Etorphine
4006:(CS-4640)
3990:(CS-4030)
3948:glycerine
3895:Salcomine
3654:Tremorine
3592:Aconitine
3575:Palytoxin
3553:Ryanodine
3530:Saxitoxin
3267:Ro 3-0422
3038:GV agents
2901:Thiosarin
2630:Phosphine
2101:Wiley-VCH
1762:Dr. Stone
1711:of Ni(CO)
1681:headaches
1391:Reactions
1350:manganese
1247:with the
1092:ICSC 0064
878:P403+P235
874:P403+P233
866:P370+P378
854:P308+P313
850:P304+P340
698:labelling
619:formation
593:Std molar
536:Viscosity
314:UN number
285:QR6300000
232:236-669-2
224:EC Number
5075:Ni(acac)
4607:Polonium
4508:Modeccin
4417:Acrolein
4382:Lewisite
4287:Acrolein
4111:CS-27349
4061:Ibogaine
3944:Litharge
3933:Adamsite
3910:Diborane
3900:Fluomine
3880:Ethenone
3775:Acrolein
3742:Fluorine
3736:Phosgene
3726:Chlorine
3126:EA-3887A
3098:C01-A042
3093:C01-A039
3088:C01-A035
2966:V-agents
2876:G-agents
2761:(EA-229)
2729:Lewisite
2588:Cyanogen
2490:10382559
2461:20474374
2418:20474327
2279:31344783
2271:17779026
2226:25032325
2055:(eds.).
1933:Mond, L.
1862:(NIOSH).
1828:(NIOSH).
1600:+ 2 ClCH
1596:2 Ni(CO)
1547:oxidized
1535:C(O)Nu)]
1346:chromium
1342:vanadium
1310:carbonyl
1285:toxicity
1257:carbonyl
1104:Related
894:NFPA 704
669:Hazards
158:6122797
6028:
4978:/ Ni(NO
4842:Ni(SCN)
4697:Ni(COD)
4356:Skatole
4351:Allicin
4066:EA-3834
4056:EA-3580
4046:EA-3443
4041:EA-3167
4036:EA-2148
4020:CS-4297
4015:EA-2092
4004:EA-4941
3731:Bromine
3369:EA-1224
3349:EA-1250
3262:R-16661
3237:EA-2613
3232:EA-2098
3227:EA-2054
3222:EA-2012
3191:3152 CT
3181:TL-1317
3176:TL-1299
3171:TL-1238
3141:EA-4056
3136:EA-3990
3131:EA-3966
3121:EA-3887
3019:EA-1763
2979:EA-3148
2974:EA-2192
2951:EA-4352
2946:EA-1356
2680:Stibine
2452:2167169
2409:2236193
2375:2644888
2354:8029705
2251:Bibcode
2242:Science
1982:Bibcode
1907:Bibcode
1822:"#0444"
1774:Delta-v
1705:dyspnea
1581:(allyl)
1565:Vinylic
1512:[Ni
1500:[Ni
1318:ligands
1277:reagent
1267:in the
1249:formula
1243:) is a
1214:what is
1212: (
595:entropy
462:Density
428:
254:PubChem
6037:La(CO)
5981:Sg(CO)
5903:Os(CO)
5885:Os(CO)
5877:Re(CO)
5815:Ba(CO)
5777:Pd(CO)
5731:Ru(CO)
5713:Ru(CO)
5705:Tc(CO)
5686:Mo(CO)
5671:Mo(CO)
5647:Sr(CO)
5595:Ni(CO)
5576:Co(CO)
5546:Fe(CO)
5531:Fe(CO)
5516:Fe(CO)
5487:Fe(CO)
5479:Mn(CO)
5460:Cr(CO)
5445:Cr(CO)
5407:Ti(CO)
5396:Ti(CO)
5389:Ti(CO)
5381:Sc(CO)
5371:Ca(CO)
5355:(ClCO)
5295:H(CO)F
4929:Ni(ClO
4855:Ni(OH)
4832:Ni(CN)
4820:Ni(CN)
4689:Ni(CO)
4672:Nickel
4574:Napalm
4339:agents
4203:agents
4106:JB-336
4101:JB-318
4076:LSD-25
4032:(DMHP)
3980:agents
3639:A-8564
3599:(PbTX)
3549:(TeNT)
3166:TL-599
3156:T-1194
3151:T-1152
3146:T-1123
2915:(ClGD)
2897:(ClGB)
2808:TL-301
2610:Arsine
2488:
2459:
2449:
2416:
2406:
2373:
2352:
2277:
2269:
2224:
2214:
2140:
2107:
2063:
2030:
1973:Nature
1636:+ 8 CO
1569:esters
1446:Ni(CO)
1434:Ni(CO)
1371:Ni(CO)
1358:cobalt
1356:, and
1332:Ni(CO)
1275:and a
1273:nickel
1261:nickel
1251:Ni(CO)
1239:name:
1209:verify
1206:
1088:(SDS)
975:2–34%
424:Ni(CO)
396:SMILES
75:Names
5835:W(CO)
5657:Y(CO)
5437:V(CO)
5430:V(CO)
5415:V(CO)
5299:(FCO)
5258:C(CO)
5114:NiOOH
4997:Ni(CO
4965:Ni(NO
4953:Ni(NO
4941:Ni(NO
4911:NiSeO
4903:NiTiO
4895:NiCrO
4562:Other
4518:Ricin
4433:Abrin
4392:KB-16
3679:IPTBO
3610:(ATX)
3583:(MTX)
3577:(PTX)
3566:(GTX)
3560:(CTX)
3543:(BTX)
3399:Nital
3205:Other
3083:A-262
3078:A-242
3073:A-234
3068:A-232
3063:A-208
2907:Soman
2903:(SGB)
2884:Tabun
2843:KB-16
2836:Other
2307:(PDF)
2296:(PDF)
2275:S2CID
2171:: 115
1880:Merck
1776:from
1758:manga
1608:→ Ni
1604:CH=CH
1237:IUPAC
1038:NIOSH
772:H360D
581:zero
361:InChI
318:1259
267:26039
247:3135
193:24253
164:ChEBI
130:JSmol
5926:(CO)
5914:(CO)
5896:(CO)
5870:(CO)
5858:(CO)
5769:(CO)
5754:(CO)
5743:(CO)
5724:(CO)
5698:(CO)
5625:SeCO
5569:(CO)
5558:(CO)
5509:(CO)
5498:(CO)
5472:(CO)
5323:(CO)
5315:Mg(O
5241:(CO)
5152:MNiO
4924:NiSe
4871:NiSO
4863:NiCO
4782:NiBr
4774:NiBr
4759:NiCl
4751:NiCl
4600:and
4218:(OC)
3935:(DM)
3765:(DP)
3754:(PS)
3738:(CG)
3689:TBPS
3684:TBPO
3532:(TZ)
3454:(TH)
3423:(DF)
3417:(SW)
3411:(TB)
3384:DMHP
3364:DEHP
3354:DIHP
3345:(KB)
3282:MSPI
2932:(GF)
2921:(GE)
2909:(GD)
2886:(GA)
2828:(CX)
2775:CEES
2743:(L3)
2737:(L2)
2725:(PD)
2719:(MD)
2713:(ED)
2606:(AC)
2600:(CK)
2486:PMID
2457:PMID
2414:PMID
2371:PMID
2350:PMID
2315:2011
2267:PMID
2222:PMID
2212:ISBN
2138:ISBN
2105:ISBN
2061:ISBN
2028:ISBN
1703:and
1683:and
1668:can
1616:-Cl)
1551:NiCl
1516:(CO)
1510:and
1504:(CO)
1484:(CO)
1450:(PPh
1444:and
1438:(PPh
1354:iron
1080:Ca
1074:IDLH
886:P501
882:P405
870:P391
862:P320
858:P310
842:P284
838:P281
834:P280
830:P273
826:P271
822:P260
818:P243
814:P242
810:P241
806:P240
802:P233
798:P210
794:P202
790:P201
776:H410
768:H351
764:H330
760:H310
756:H304
752:H301
748:H300
744:H225
452:Odor
294:UNII
6127:No
6124:Md
6121:Fm
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6112:Bk
6109:Cm
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6094:Pa
6091:Th
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6085:**
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6077:Tm
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5828:Hf
5825:Lu
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5806:Xe
5800:Te
5797:Sb
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5788:Cd
5667:Nb
5664:Zr
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5342:SCO
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5330:Al
5311:Na
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5282:OCO
5277:NCO
5253:BCO
5233:Li
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5144:NiF
5131:NiF
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4883:(PO
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4728:NiF
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3771:(Z)
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2793:HN1
2731:(L)
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630:298
603:298
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5630:Br
5571:12
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5554:Co
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5494:Fe
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