222:
392:
380:
24:
217:
221:
419:
monohydrate at 65 C. To help speed the drying of the product after filtration from the hot water, it can be rinsed with alcohol. The product is a fluffy powder (density=0.9 g/cm). To increase its bulk density to (1.2 g/cm), dextrin in the amount of (1%) of the weight of the nickel(II)
220:
245:
223:
987:
Chhabra, J.S; Talawar, M.B; Makashir, P.S; Asthana, S.N; Singh, Haridwar (2003). "Synthesis, characterization and thermal studies of (Ni/Co) metal salts of hydrazine: Potential initiatory compounds".
428:
The sensitivity of NHN straddles the line between highly sensitive primaries and a sensitive secondary, so it can be considered a true non-primary explosive detonator (NPED).
443:
NHN straddles the line between primary and secondary. Because of this it is a relatively safe explosive to work with having 80x less sensitivity to friction (16.0 N) than
1024:"Studies on nickel hydrazinium nitrate (NHN) and bis-(5-nitro-2H tetrazolato-N)tetraamino cobalt(III) perchlorate (BNCP): Potential lead-free advanced primary explosives"
948:
Xiang, Dong; Zhu, Weihua (15 February 2018). "Thermal decomposition of energetic MOFs nickel hydrazine nitrate crystals from an ab initio molecular dynamics simulation".
391:
379:
432:
238:
188:
1057:
286:
1095:
1090:
231:
265:
322:
165:
474:– 120 N, show that NHN is not very sensitive, and is thereby not exceedingly hazardous in handling.
1110:
1100:
1085:
459:
175:
54:
408:
310:
1022:
Talawar, M B; Agrawal, A P; Chhabra, J S; Ghatak, C K; Asthana, S N; Rao, K U B (August 2004).
1105:
1004:
915:
Hariharanath, B.; Chandrabhanu, K. S.; Rajendran, A. G.; Ravindran, M.; Kartha, C. B. (2006).
455:
155:
1038:
996:
957:
928:
412:
318:
88:
71:
64:
640:
Table 2. Comparative properties of Nickel hydrazine nitrate, lead azide and lead styphnate
975:
451:
280:
1000:
1079:
1058:"Hydrazynowe kompleksy metali przejściowych jako perspektywiczne materiały wybuchowe"
1023:
140:
961:
23:
317:
properties in between that of primary explosive and a secondary explosive. It is a
435:) in a cardboard shell, eliminating the danger of shrapnel from a metal shell.
252:
1060:[Hydrazine complexes of transition metals as perspective explosives].
444:
119:
416:
314:
1008:
1042:
450:
Friction sensitivities of some traditional explosives (lead azide – 0.1N;
933:
916:
251:
244:
237:
230:
203:
478:
Table 1. General and structural properties of Nickel hydrazine nitrate
326:
742:
Pressure output in closed vessel (100 mg in 48 cm) (kg/cm)
279:
Except where otherwise noted, data are given for materials in their
797:
Impact sensitivity (cm, 400 g wt, 20 mg sample, 50% explosion)
463:
917:"Detonator using Nickel Hydrazine Nitrate as Primary Explosive"
893:
Experimental value, literature value, and theoretical value
471:
467:
910:
908:
906:
397:
Improperly made (Hard chunks, grains of sand consistency)
215:
976:
https://www.youtube.com/watch?v=rPxdDSUGxo4&t=11s
431:
Another benefit of NHN is that it will make the DDT (
1031:Journal of Scientific & Industrial Research
219:
70:
63:
1056:Wojewódka, Andrzej; Bełzowski, Janusz (2011).
385:Properly made (talcum powder like consistency)
8:
571:Nitrogen content in coordination sphere (%)
595:Moisture content (at 333 K for 10 min) (%)
15:
932:
654:
492:
974:Nickel Hydrazine Nitrate (Dextrinated)
902:
375:
424:Non-primary explosive detonator (NPED)
273:219 °C (426 °F; 492 K)
603:Average mol wt of combustion products
433:deflagration to detonation transition
7:
636:Values in brackets are theoretical
407:NHN can be synthesized by reacting
420:nitrate hexahydrate can be added.
14:
38:Tris(hydrazine)nickel(II) nitrate
390:
378:
100:
94:
22:
962:10.1016/j.commatsci.2017.11.006
950:Computational Materials Science
825:Vol. of detonation gases (ml/g)
283:(at 25 °C , 100 kPa).
989:Journal of Hazardous Materials
329:with a reaction equation of 3N
299:Nickel hydrazine nitrate (NHN)
109:
106:
1:
1001:10.1016/S0304-3894(02)00247-9
447:(0.1N) as shown in table 2.
783:Friction sensitivity (kg f)
1127:
839:Detonation temperature (K)
755:Onset of decomposition (K)
714:Heat of formation (kJ/mol)
700:Heat of combustion (kJ/kg)
611:Percent condensable Ni (l)
539:Average particle size (μm)
411:hexahydrate with a dilute
40:Trihydrazinenickel nitrate
865:Detonation velocity (m/s)
852:Detonation pressure (GPa)
769:Peak of decomposition (K)
728:Heat of explosion (kJ/kg)
661:Nickel hydrazine nitrate
277:
197:
149:
81:
47:
35:
30:
21:
17:Nickel hydrazine nitrate
301:, (chemical formula: (NO
921:Defence Science Journal
672:Crystal Density (g/cm)
531:Crystal density (g/cm)
226:
627:Oxygen balance %
555:Hydrazine content (%)
323:coordination compound
225:
182:7,000 m/s @ 1.7 g/cm
934:10.14429/dsj.56.1904
208:(fire diamond)
180:3,600 m/s @ .8 g/cm
166:Friction sensitivity
1096:Hazardous materials
811:ESD sensitivity (J)
563:Nitrate content (%)
176:Detonation velocity
127: g·mol
18:
686:Oxygen balance (%)
547:Nickel content (%)
409:nickel(II) nitrate
311:energetic material
287:Infobox references
227:
16:
891:
890:
634:
633:
619:Oxygen-fuel ratio
586:); 1356,1321 (-NO
496:Molecular formula
458:(white) – 5.0 N;
456:mercury fulminate
295:Chemical compound
293:
292:
156:Shock sensitivity
1118:
1091:Nickel compounds
1070:
1069:
1053:
1047:
1046:
1028:
1019:
1013:
1012:
984:
978:
972:
966:
965:
945:
939:
938:
936:
912:
882:1.05 (1.7 g/cm)
874:5200 (2.9 g/cm)
871:4630 (3.0 g/cm)
868:7000 (1.7 g/cm)
858:16.1 (3.0 g/cm)
855:20.8 (1.7 g/cm)
655:
652:
651:
647:
579:FTIR peaks, (cm)
493:
490:
489:
485:
413:aqueous solution
394:
382:
254:
247:
240:
233:
218:
193:1.05 @ 1.7 g/cm
126:
111:
108:
102:
96:
89:Chemical formula
74:
67:
26:
19:
1126:
1125:
1121:
1120:
1119:
1117:
1116:
1115:
1076:
1075:
1074:
1073:
1055:
1054:
1050:
1026:
1021:
1020:
1016:
986:
985:
981:
973:
969:
947:
946:
942:
914:
913:
904:
899:
667:Lead styphnate
653:
649:
645:
643:
642:
589:
585:
574:30.25 (30.14)
566:44.47 (44.49)
558:34.46 (34.45)
550:21.16 (21.06)
510:
506:
502:
491:
487:
483:
481:
480:
441:
426:
405:
398:
395:
386:
383:
372:
368:
364:
360:
356:
352:
348:
344:
340:
336:
332:
308:
304:
296:
289:
284:
270:
267:
259:
258:
257:
256:
249:
242:
235:
228:
224:
216:
150:Explosive data
124:
114:
105:
99:
91:
77:
57:
43:
41:
39:
12:
11:
5:
1124:
1122:
1114:
1113:
1108:
1103:
1098:
1093:
1088:
1078:
1077:
1072:
1071:
1048:
1043:123456789/5478
1037:(8): 677–681.
1014:
979:
967:
940:
901:
900:
898:
895:
889:
888:
886:
885:.8 (3.0 g/cm)
883:
880:
876:
875:
872:
869:
866:
862:
861:
859:
856:
853:
849:
848:
846:
843:
840:
836:
835:
832:
829:
826:
822:
821:
818:
815:
812:
808:
807:
804:
801:
798:
794:
793:
790:
787:
784:
780:
779:
776:
773:
770:
766:
765:
762:
759:
756:
752:
751:
749:
746:
743:
739:
738:
735:
732:
729:
725:
724:
721:
718:
715:
711:
710:
707:
704:
701:
697:
696:
693:
690:
687:
683:
682:
679:
676:
673:
669:
668:
665:
662:
659:
641:
638:
632:
631:
628:
624:
623:
620:
616:
615:
612:
608:
607:
604:
600:
599:
596:
592:
591:
587:
583:
582:3238, 1630 (NH
580:
576:
575:
572:
568:
567:
564:
560:
559:
556:
552:
551:
548:
544:
543:
540:
536:
535:
532:
528:
527:
526:Purple Violet
524:
520:
519:
516:
515:Formula weight
512:
511:
508:
504:
500:
497:
479:
476:
452:lead styphnate
440:
437:
425:
422:
404:
401:
400:
399:
396:
389:
387:
384:
377:
370:
366:
362:
358:
354:
350:
346:
342:
338:
334:
330:
306:
302:
294:
291:
290:
285:
281:standard state
278:
275:
274:
271:
264:
261:
260:
250:
243:
236:
229:
214:
213:
212:
211:
209:
200:
199:
195:
194:
191:
185:
184:
178:
172:
171:
168:
162:
161:
158:
152:
151:
147:
146:
143:
137:
136:
133:
129:
128:
122:
116:
115:
112:
103:
97:
92:
87:
84:
83:
79:
78:
76:
75:
68:
60:
58:
53:
50:
49:
45:
44:
37:
33:
32:
28:
27:
13:
10:
9:
6:
4:
3:
2:
1123:
1112:
1109:
1107:
1104:
1102:
1099:
1097:
1094:
1092:
1089:
1087:
1084:
1083:
1081:
1067:
1063:
1059:
1052:
1049:
1044:
1040:
1036:
1032:
1025:
1018:
1015:
1010:
1006:
1002:
998:
995:(3): 225–39.
994:
990:
983:
980:
977:
971:
968:
963:
959:
955:
951:
944:
941:
935:
930:
926:
922:
918:
911:
909:
907:
903:
896:
894:
887:
884:
881:
878:
877:
873:
870:
867:
864:
863:
860:
857:
854:
851:
850:
847:
844:
841:
838:
837:
833:
830:
827:
824:
823:
819:
816:
813:
810:
809:
805:
802:
799:
796:
795:
791:
788:
785:
782:
781:
777:
774:
771:
768:
767:
763:
760:
757:
754:
753:
750:
747:
744:
741:
740:
736:
733:
730:
727:
726:
722:
719:
716:
713:
712:
708:
705:
702:
699:
698:
694:
691:
688:
685:
684:
680:
677:
674:
671:
670:
666:
663:
660:
657:
656:
648:
639:
637:
629:
626:
625:
621:
618:
617:
613:
610:
609:
605:
602:
601:
597:
594:
593:
581:
578:
577:
573:
570:
569:
565:
562:
561:
557:
554:
553:
549:
546:
545:
541:
538:
537:
533:
530:
529:
525:
522:
521:
517:
514:
513:
498:
495:
494:
486:
477:
475:
473:
469:
465:
461:
457:
453:
448:
446:
438:
436:
434:
429:
423:
421:
418:
414:
410:
402:
393:
388:
381:
376:
374:
328:
324:
320:
316:
312:
300:
288:
282:
276:
272:
269:
263:
262:
255:
248:
241:
234:
210:
207:
206:
202:
201:
196:
192:
190:
187:
186:
183:
179:
177:
174:
173:
169:
167:
164:
163:
159:
157:
154:
153:
148:
144:
142:
141:Boiling point
139:
138:
135:purple solid
134:
131:
130:
123:
121:
118:
117:
93:
90:
86:
85:
80:
73:
69:
66:
62:
61:
59:
56:
52:
51:
46:
34:
29:
25:
20:
1065:
1061:
1051:
1034:
1030:
1017:
992:
988:
982:
970:
953:
949:
943:
927:(3): 383–9.
924:
920:
892:
664:Lead azide
635:
449:
442:
430:
427:
406:
298:
297:
266:Autoignition
204:
181:
48:Identifiers
36:Other names
1068:(1): 20–27.
956:: 170–181.
403:Preparation
268:temperature
132:Appearance
82:Properties
1111:Detonators
1101:Hydrazines
1086:Explosives
1080:Categories
897:References
445:lead azide
170:15.6906 N
120:Molar mass
72:82434-34-2
65:69101-54-8
55:CAS Number
879:RE Factor
470:– 120 N;
462:– 8.0 N;
460:tetrazene
454:– 1.5 N;
417:hydrazine
341:O + Ni(NO
315:explosive
189:RE factor
1106:Nitrates
1009:12758009
658:Property
466:– 60 N;
205:NFPA 704
198:Hazards
160:18.82 J
145:explode
778:583.15
764:533.15
695:-19.00
692:– 5.50
689:– 5.74
622:0.8571
518:278.69
313:having
125:278.839
1062:Chemik
1007:
820:.0002
817:0.004
644:": -->
630:-5.74
606:27.35
482:": -->
439:Safety
349:→〔Ni(N
327:nickel
309:is an
31:Names
1027:(PDF)
845:5600
842:2342
814:0.02
803:10.5
789:0.02
772:506.5
758:505.7
748:8.2
737:1912
734:1610
723:-385
717:– 449
709:5234
706:2635
681:3.02
678:4.38
675:2.129
598:0.34
523:Color
321:of a
1005:PMID
834:368
831:308
828:884
792:.15
775:618
761:463
745:17.5
731:4390
720:469
703:5225
646:edit
534:2.1
499:Ni H
484:edit
464:PETN
369:＋ 3H
361:〕(NO
319:salt
1039:hdl
997:doi
958:doi
954:143
929:doi
806:11
800:21
786:1.6
614:18
542:13
472:HMX
468:RDX
415:of
325:of
42:NHN
1082::
1066:65
1064:.
1035:63
1033:.
1029:.
1003:.
993:99
991:.
952:.
925:56
923:.
919:.
905:^
590:)
501:12
373:O
337:·H
253:OX
107:Ni
98:12
1045:.
1041::
1011:.
999::
964:.
960::
937:.
931::
650:]
588:3
584:2
509:6
507:O
505:8
503:N
488:]
371:2
367:2
365:)
363:3
359:3
357:)
355:4
353:H
351:2
347:2
345:)
343:3
339:2
335:4
333:H
331:2
307:2
305:)
303:3
246:3
239:1
232:1
113:6
110:O
104:8
101:N
95:H
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