514:
477:
1691:
522:
131:
1355:
915:
1375:
458:, the Cr–O stretching vibrations are at 1006 cm and 1016 cm and the Cr–F stretching vibrations are at 727 cm and 789 cm. The difference is much too large to be due to the different masses of O and F atoms. Rather, it shows that the Cr–O bond is much stronger than the Cr–F bond. M–O bonds are generally considered to be
2007:
Fourati, Mohieddine; Chaabouni, Moncef; Belin, Claude Henri; Charbonnel, Monique; Pascal, Jean Louis; Potier, Jacqueline (1986). "A strongly chelating bidentate CLO4. New synthesis route and crystal structure determination of Ti(CLO4)".
368:. For example, chromyl chloride is hydrolyzed to chromate in the reverse of the synthetic reaction, above. The driving force for this reaction is the formation of A-O bonds which are stronger than A-Cl bonds. This gives a favourable
1889:
Margrave, J. L.; Sharp, K. G.; Wilson, P. W. (9 September 1969). "Silicon-Fluorine
Chemistry IX: The Reactions of Silicon Difluoride and Silicon Tetrafluoride with Water and Some Reactions of Tetrafluorodisiloxane".
741:). All are easily hydrolyzed. Indeed, thionyl chloride can be used as a dehydration agent as the water molecules are converted into gaseous products, leaving behind the anhydrous solid chloride.
306:. If an oxygen atom is simply replaced by a halogen atom the charge increases by +1, but the coordination number is unchanged. This is illustrated by the reaction of a mixture of a
2119:
2096:
Dewan, John. C.; Edwards, Anthony J.; Calves, Jean Y.; Guerchais, Jacques E. (1997). "Fluoride crystal structures. Part 28. Bis(tetraethylammonium)μ-oxo-bis".
241:
In addition, various oxohalides can be made by halogen exchange reactions and this reaction can also lead to the formation of mixed oxohalides such as
1809:
Synthesis of individual compounds can be found in
Housecroft & Sharpe and Greenwood & Earnshaw in sections relating to the specific element, A
1458:
are relatively weak oxidizing agents, so fewer oxobromides and oxoiodides are known. Structures for compounds with d configuration are predicted by
2056:
Strauss, Steven H.; Noirot, Mark D.; Anderson, Oren P. (1985). "Preparation and characterization of silver(I) teflate complexes: bridging OTeF
2272:
1782:
form oxochlorides of general formula MOCl. MOBr and MOI are also known for Sb and Bi. Many of their crystal structures have been determined.
1725:
ions, in the order Cl-Bi-O-Bi-Cl-Cl-Bi-O-Bi-Cl. This layered, graphite-like structure results in a relatively low hardness of bismoclite (
789:(A = S, Se, Te). They are non-linear with the A-O-A angle of 142.5, 142.4 and 145.5° for S, Se and Te, respectively. The tellurium anion
2319:
2304:
2290:
2184:
1858:
264:
In relation to the oxide or halide, for a given oxidation state of an element A, if two halogen atoms replace one oxygen atom, or
1726:
955:
is shown below, and more detailed lists are available in the literature. X indicates various halides, most often F and Cl.
1251:
1242:
1205:
1192:
447:
of many oxohalides have been assigned in detail. They give useful information on relative bond strengths. For example, in
357:
produced has no electrical charge and is a volatile covalent molecule that can be distilled out of the reaction mixture.
1791:
1283:
1266:
1218:
1183:
1174:
1073:
1306:
1296:
1127:
1033:
1588:
444:
284:
2211:
The
Mercury Minerals from Terlingua, Texas: Kleinite, Terlinguaite, Eglestonite, Montroydite, Calomel, Mercury
2086:
Housectroft & Sharpe, Chapters 21 and 22 illustrate many structures, including M-O and M-Cl bond lengths.
1082:
470:
307:
1572:
bonding between the metal and oxygen atoms. Oxygen bridges are present in more complex configurations like
1003:
870:
273:
2264:
2113:
881:
731:
600:
1556:
groups joined by a bridging oxygen atom. Each metal has an octahedral environment. The unusual linear
2143:
Crossman, Martin C.; Hope, Eric G.; Saunders, Graham C. (1996). "Cyclopentadienyl metal teflate (OTeF
462:
and this is backed up by measurements of M–O bond lengths. It implies that the elements A and O are
2339:
1698:
1091:
896:
830:
513:
384:
269:
2170:
Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Bismoclite".
1489:
579:
414:
311:
95:
91:
2179:. Vol. III (Halides, Hydroxides, Oxides). Chantilly, VA: Mineralogical Society of America.
469:
Oxohalides of elements in high oxidation states are intensely coloured owing to ligand to metal
364:, with oxidizing power similar to the corresponding oxide or halide. Most oxohalides are easily
2315:
2300:
2286:
2268:
2208:
2180:
1854:
1706:
1561:
716:
701:
627:
623:
575:
555:
373:
32:
2256:
2220:
2152:
2101:
2069:
2017:
1980:
1899:
1760:
1161:
1106:
952:
818:
690:
631:
559:
545:
354:
44:
1641:
1443:
801:, is a large and rather stable anion, useful for forming stable salts with large cations.
643:
608:
567:
361:
303:
172:
2171:
1500:
476:
437:
2333:
655:
607:
to yield poorly-characterized oxyfluoride polymers, but slow and careful reaction at
463:
315:
119:
1730:
1690:
1459:
1474:
798:
521:
459:
115:
130:
2224:
1710:
1702:
1511:
675:
388:
380:
365:
299:
87:
622:
forms two series of oxohalides with nitrogen in oxidation states 3, NOX, X =
1779:
1741:
1679:
1675:
775:
20:
1984:
1763:
in a number of stages is another example of a secondary oxohalide mineral.
566:(X = Cl), which is produced industrially by a carbon-catalyzed reaction of
2156:
2105:
1771:
1694:
Crystal structure of bismoclite. Colours: red – O, green – Cl, grey – Bi.
1633:
1447:
771:
619:
571:
563:
369:
295:
99:
75:
71:
48:
2124:. The structure is illustrated in Housectroft & Sharpe, Figure 22.5.
2073:
2034:
Greenwood & Earnshaw, Chapters 22–25, section halides and oxohalides
2021:
1903:
1354:
1775:
1729:
2–2.5) and most other oxohalide minerals. Those other minerals include
1451:
659:
111:
79:
67:
40:
1374:
914:
1637:
1455:
1439:
686:
143:
83:
36:
1947:
Oberhammer, Heinz; Seppelt, Konrad (1978). "Molecular
Structure of F
16:
Chemical compounds with oxygen and a halogen bonded to the same atom
1851:
Infrared and Raman spectra of inorganic and coordination compounds
1689:
1373:
1353:
973:
913:
866:
646:, Cl. They are made by halogenation of nitrogen oxides. Note that
604:
406:) with more halide ions acting as Lewis bases. Another example is
139:
1971:: d-Orbital Participation in Bonds between Main Group Elements".
1438:
High oxidation states of the metal are dictated by the fact that
118:
substances with the same overall chemical formula, but having an
1767:
387:
3 or 4 which, in accepting one or more electron pairs from a
2314:(3rd ed.). Oxford: Clarendon Press. pp. 384–392.
1740:, formed by the weathering of mercury-containing minerals.
360:
Oxohalides of elements in high oxidation states are strong
1713:
symmetry and can be thought of as consisting of layers of
268:, the overall charge on the molecule is unchanged and the
138:
Oxohalides can be seen as compounds intermediate between
778:
form similar compounds and also the oxo-bridged species
272:
of the central atom decreases by one. For example, both
175:
increases by two and the electrical charge is unchanged.
391:, become 5- or 6-coordinate. Oxohalide anions such as
809:
The halogens form various oxofluorides with formulae
611:
yields the oxyfluoride hexafluorodisiloxane as well.
399:
can be seen as acid-base complexes of the oxohalide (
1822:McGraw-Hill: New York, 1946; Vol. 2, pp. 205–207.
1705:) is a rare example of a mineral oxohalide. The
689:forms oxohalides in oxidation state +4, such as
146:. There are three general methods of synthesis:
86:(I) in their molecules. The element A may be a
383:. This is particularly so with oxohalides of
8:
2118:: CS1 maint: multiple names: authors list (
2060:groups in the solid state and in solution".
2299:, 3rd edn. Oxford University Press, 1999.
2207:Hillebrand, W. F.; W. T. Schaller (1907).
1861:, Tables II-4c, II-6g, II-6h, II-7b, II-8c
1560:structure can be rationalized in terms of
1870:Shriver & Atkins, Figure 13.8, p. 447
1892:Journal of the American Chemical Society
1755:
1751:
1747:
1735:
1670:
1662:
1658:
1651:
1647:
1625:
1621:
1617:
1613:
1609:
1605:
1598:
1594:
1583:
1579:
1575:
1552:
1544:
1540:
1532:
1528:
1517:
1506:
1495:
1484:
1480:
1469:
1465:
1400:
1396:
1392:
1388:
1384:
1380:
1365:
1361:
1345:
1341:
1334:
1330:
1317:
1308:
1298:
1289:
1285:
1277:
1268:
1253:
1244:
1236:
1232:
1224:
1220:
1211:
1207:
1198:
1194:
1185:
1176:
1167:
1163:
1155:
1148:
1144:
1137:
1129:
1120:
1112:
1108:
1093:
1084:
1075:
1067:
1060:
1052:
1044:
1035:
1027:
1013:
1005:
997:
993:
985:
957:
925:
921:
902:
891:
887:
876:
854:
847:
843:
836:
824:
812:
792:
785:
781:
763:
759:
755:
747:
737:
726:
722:
711:
707:
696:
649:
637:
592:
588:
550:
531:
527:
520:
512:
475:
454:
450:
432:
428:
424:
420:
409:
402:
394:
345:
341:
337:
324:
290:
279:
251:
244:
231:
227:
223:
201:
197:
193:
189:
185:
163:
159:
155:
129:
60:
54:
2285:, 2nd ed., Pearson Prentice-Hall 2005.
2133:Housectroft & Sharpe, Figure 22.15.
1973:Angewandte Chemie International Edition
1933:
1931:
1802:
2111:
1667:are well known and contain the linear
1404:molecule. (Hydrogen atoms not shown.)
2051:
2049:
1759:, formed from an original deposit of
7:
2281:Housecroft, C. E. and Sharpe, A. G.
1925:Housecroft & Sharpe, pp. 365–367
1916:Housecroft & Sharpe, pp. 329–330
1853:, 5th. edition, Part A, Wiley, 1997
1564:theory, indicating the presence of d
951:A selection of known oxohalides of
466:together by a σ bond and a π bond.
1674:moiety. Similar species exist for
180:Partial halogenation of an oxide:
134:Chromyl chloride liquid and vapour
14:
1840:Greenwood & Earnshaw, p. 996.
1831:Greenwood & Earnshaw, p. 1023
1818:Sisler, H. H. "Chromyl Chloride"
2295:Shrivr, D. F. and Atkins, P. W.
2043:Greenwood & Earnshaw p. 993.
1370:. Ru, Os form similar complexes.
700:and oxidation state +6, such as
51:. They have the general formula
2217:The American Journal of Science
1997:Housecroft & Sharpe, p. 395
1898:(6) (published 25 March 1970).
1587:(M = Ti, Zr, Hf, Mo or W; cp =
910:Transition metals and actinides
150:Partial oxidation of a halide:
2312:Structural Inorganic Chemistry
43:atoms are attached to another
1:
2149:J. Chem. Soc., Dalton Trans.
2098:J. Chem. Soc., Dalton Trans.
1937:Shriver & Atkins, p. 397
1879:Shriver & Atkins, p. 358
1792:Transition metal oxo complex
1686:Minerals and ionic compounds
574:. It is a useful reagent in
379:Many oxohalides can act as
2356:
2261:Chemistry of the Elements
2259:; Earnshaw, Alan (1997).
2225:10.2475/ajs.s4-24.141.259
1549:(M = W, Ru, Os) have two
2219:. s4-24 (139): 259–274.
376:change for the reaction
285:phosphorus pentachloride
70:. Known oxohalides have
840:with X = Cl, Br and I.
2173:Handbook of Mineralogy
1985:10.1002/anie.197800691
1695:
1435:
1371:
948:
871:xenon oxytetrafluoride
536:
518:
505:
308:chromate or dichromate
274:phosphorus oxychloride
135:
2310:Wells, A. F. (1962).
2265:Butterworth-Heinemann
2257:Greenwood, Norman N.
1693:
1521:is square pyramidal.
1377:
1357:
918:Crystal structure of
917:
882:xenon dioxydifluoride
732:thionyl tetrafluoride
674:. Only oxohalides of
601:Silicon tetrafluoride
578:for the formation of
562:, and the very toxic
524:
516:
479:
171:In this example, the
133:
2157:10.1039/DT9960000509
2106:10.1039/DT9770000978
1490:trigonal bipyramidal
1427: Tellurium (Te)
473:(LMCT) transitions.
415:trigonal bipyramidal
372:contribution to the
336:+ 4 Cl + 6 H → 2 CrO
110:, may also refer to
25:molecular oxohalides
2297:Inorganic Chemistry
2283:Inorganic Chemistry
2074:10.1021/ic00219a022
2022:10.1021/ic00229a019
1904:10.1021/ja00709a015
1820:Inorganic Synthesis
1699:Bismuth oxochloride
897:xenon oxydifluoride
831:perchloryl fluoride
509:Main group elements
445:vibrational spectra
385:coordination number
270:coordination number
209:Oxide replacement:
2243:Wells, pp. 390–392
1696:
1640:compounds such as
1436:
1415: Fluorine (F)
1372:
949:
580:carbonyl compounds
537:
519:
506:
314:with concentrated
312:potassium chloride
222:+ 2 Cl + 4 H → CrO
136:
96:rare earth element
92:transition element
33:chemical compounds
2274:978-0-08-037941-8
2068:(25): 4307–4311.
1707:crystal structure
1562:molecular orbital
1433: Silver (Ag)
1352:
1351:
953:transition metals
717:sulfuryl chloride
702:sulfuryl fluoride
576:organic chemistry
517:Sulfuryl fluoride
374:Gibbs free energy
31:) are a group of
2347:
2325:
2278:
2263:(2nd ed.).
2244:
2241:
2235:
2234:
2232:
2231:
2204:
2198:
2197:
2195:
2193:
2178:
2167:
2161:
2160:
2140:
2134:
2131:
2125:
2123:
2117:
2109:
2093:
2087:
2084:
2078:
2077:
2053:
2044:
2041:
2035:
2032:
2026:
2025:
2016:(9): 1386–1390.
2004:
1998:
1995:
1989:
1988:
1944:
1938:
1935:
1926:
1923:
1917:
1914:
1908:
1907:
1886:
1880:
1877:
1871:
1868:
1862:
1847:
1841:
1838:
1832:
1829:
1823:
1816:
1810:
1807:
1758:
1739:
1724:
1720:
1716:
1673:
1666:
1654:
1628:
1601:
1589:cyclopentadienyl
1586:
1559:
1555:
1548:
1536:
1520:
1514:. The d complex
1509:
1501:square pyramidal
1498:
1487:
1472:
1432:
1426:
1421: Oxygen (O)
1420:
1414:
1409: Carbon (C)
1408:
1403:
1369:
1348:
1337:
1320:
1313:
1303:
1293:
1280:
1273:
1257:
1248:
1239:
1228:
1215:
1202:
1189:
1180:
1171:
1158:
1151:
1140:
1133:
1124:
1116:
1097:
1088:
1079:
1070:
1063:
1056:
1048:
1040:
1030:
1017:
1009:
1000:
989:
958:
945:
939:
933:
928:
905:
894:
879:
858:are also known.
857:
850:
839:
828:
819:chloryl fluoride
816:
796:
788:
767:
740:
729:
714:
699:
691:thionyl chloride
673:
672:
671:
668:
653:
641:
596:
591:+ 2 ROH → CO(OR)
553:
546:forms oxohalides
534:
502:
496:
490:
484:
480:Boron teflate.
464:chemically bound
457:
435:
413:which forms the
412:
405:
398:
362:oxidizing agents
355:chromyl chloride
349:
335:
334:
331:
293:
282:
255:
247:
235:
221:
220:
217:
204:
166:
65:
45:chemical element
2355:
2354:
2350:
2349:
2348:
2346:
2345:
2344:
2330:
2329:
2322:
2309:
2275:
2255:
2252:
2247:
2242:
2238:
2229:
2227:
2206:
2205:
2201:
2191:
2189:
2187:
2176:
2169:
2168:
2164:
2146:
2142:
2141:
2137:
2132:
2128:
2110:
2100:(10): 978–980.
2095:
2094:
2090:
2085:
2081:
2059:
2055:
2054:
2047:
2042:
2038:
2033:
2029:
2006:
2005:
2001:
1996:
1992:
1970:
1966:
1962:
1958:
1954:
1950:
1946:
1945:
1941:
1936:
1929:
1924:
1920:
1915:
1911:
1888:
1887:
1883:
1878:
1874:
1869:
1865:
1848:
1844:
1839:
1835:
1830:
1826:
1817:
1813:
1808:
1804:
1800:
1788:
1757:
1753:
1749:
1745:
1737:
1733:
1722:
1718:
1714:
1688:
1672:
1668:
1664:
1660:
1656:
1653:
1649:
1645:
1642:uranyl chloride
1627:
1623:
1619:
1615:
1611:
1607:
1603:
1600:
1596:
1592:
1585:
1581:
1577:
1573:
1571:
1567:
1557:
1554:
1550:
1546:
1542:
1538:
1534:
1530:
1526:
1524:
1519:
1515:
1508:
1504:
1497:
1493:
1486:
1482:
1478:
1471:
1467:
1463:
1444:oxidizing agent
1434:
1430:
1428:
1424:
1422:
1418:
1416:
1412:
1410:
1406:
1402:
1398:
1394:
1390:
1386:
1382:
1378:
1367:
1363:
1359:
1347:
1343:
1339:
1336:
1332:
1328:
1319:
1315:
1310:
1305:
1300:
1295:
1291:
1287:
1282:
1279:
1275:
1270:
1265:
1255:
1250:
1246:
1241:
1238:
1234:
1230:
1226:
1222:
1217:
1213:
1209:
1204:
1200:
1196:
1191:
1187:
1182:
1178:
1173:
1169:
1165:
1160:
1157:
1153:
1150:
1146:
1142:
1139:
1135:
1131:
1126:
1122:
1118:
1114:
1110:
1105:
1095:
1090:
1086:
1081:
1077:
1072:
1069:
1065:
1062:
1058:
1054:
1050:
1046:
1042:
1037:
1032:
1029:
1025:
1015:
1011:
1007:
1002:
999:
995:
991:
987:
983:
961:Oxidation state
947:
943:
941:
937:
935:
931:
927:
923:
919:
912:
904:
900:
893:
889:
885:
878:
874:
864:
856:
852:
849:
845:
841:
838:
834:
826:
822:
814:
810:
807:
794:
790:
787:
783:
779:
765:
761:
757:
753:
749:
745:
739:
735:
728:
724:
720:
713:
709:
705:
698:
694:
684:
678:(V) are known.
669:
666:
665:
663:
651:
647:
639:
635:
617:
594:
590:
586:
582:. For example:
568:carbon monoxide
552:
548:
542:
535:(A = S, Se, Te)
533:
529:
525:
511:
504:
500:
498:
497: Tellurium
494:
492:
488:
486:
482:
471:charge transfer
456:
452:
448:
434:
430:
426:
422:
418:
411:
407:
404:
400:
396:
392:
347:
343:
339:
332:
329:
328:
326:
322:
304:oxidation state
292:
288:
281:
277:
262:
253:
249:
246:
242:
233:
229:
225:
218:
215:
214:
212:
203:
199:
195:
191:
187:
183:
173:oxidation state
165:
161:
157:
153:
128:
66:, where X is a
64:
58:
52:
17:
12:
11:
5:
2353:
2351:
2343:
2342:
2332:
2331:
2328:
2327:
2320:
2307:
2293:
2279:
2273:
2251:
2248:
2246:
2245:
2236:
2199:
2185:
2162:
2151:(4): 509–511.
2147:) complexes".
2144:
2135:
2126:
2088:
2079:
2057:
2045:
2036:
2027:
1999:
1990:
1968:
1964:
1960:
1956:
1952:
1948:
1939:
1927:
1918:
1909:
1881:
1872:
1863:
1842:
1833:
1824:
1811:
1801:
1799:
1796:
1795:
1794:
1787:
1784:
1687:
1684:
1569:
1565:
1525:The compounds
1429:
1423:
1417:
1411:
1405:
1350:
1349:
1326:
1322:
1321:
1263:
1259:
1258:
1103:
1099:
1098:
1023:
1019:
1018:
981:
977:
976:
970:
966:
965:
962:
942:
940: Chlorine
936:
934: Titanium
930:
911:
908:
863:
860:
806:
803:
769:
768:
751:
683:
680:
616:
613:
598:
597:
541:
538:
510:
507:
503: Fluorine
499:
493:
487:
481:
438:trimethylamine
436:with the base
351:
350:
294:) are neutral
261:
258:
239:
238:
237:
236:
207:
206:
205:
196:+ 3 C → 4 VOCl
178:
177:
176:
168:
167:
127:
124:
47:A in a single
35:in which both
15:
13:
10:
9:
6:
4:
3:
2:
2352:
2341:
2338:
2337:
2335:
2323:
2321:0-19-855125-8
2317:
2313:
2308:
2306:
2305:0-19-850330-X
2302:
2298:
2294:
2292:
2291:0-582-31080-6
2288:
2284:
2280:
2276:
2270:
2266:
2262:
2258:
2254:
2253:
2249:
2240:
2237:
2226:
2222:
2218:
2214:
2212:
2203:
2200:
2188:
2186:0-9622097-2-4
2182:
2175:
2174:
2166:
2163:
2158:
2154:
2150:
2139:
2136:
2130:
2127:
2121:
2115:
2107:
2103:
2099:
2092:
2089:
2083:
2080:
2075:
2071:
2067:
2063:
2052:
2050:
2046:
2040:
2037:
2031:
2028:
2023:
2019:
2015:
2011:
2003:
2000:
1994:
1991:
1986:
1982:
1978:
1974:
1943:
1940:
1934:
1932:
1928:
1922:
1919:
1913:
1910:
1905:
1901:
1897:
1893:
1885:
1882:
1876:
1873:
1867:
1864:
1860:
1859:0-471-19406-9
1856:
1852:
1846:
1843:
1837:
1834:
1828:
1825:
1821:
1815:
1812:
1806:
1803:
1797:
1793:
1790:
1789:
1785:
1783:
1781:
1777:
1773:
1769:
1766:The elements
1764:
1762:
1743:
1732:
1728:
1712:
1708:
1704:
1700:
1692:
1685:
1683:
1681:
1677:
1643:
1639:
1635:
1630:
1590:
1563:
1522:
1513:
1502:
1491:
1476:
1461:
1457:
1453:
1449:
1445:
1441:
1376:
1358:Structure of
1356:
1327:
1324:
1323:
1312:
1302:
1292:
1272:
1264:
1261:
1260:
1256:
1247:
1227:
1214:
1201:
1188:
1179:
1170:
1132:
1115:
1104:
1101:
1100:
1096:
1087:
1078:
1039:
1024:
1021:
1020:
1008:
982:
979:
978:
975:
971:
968:
967:
963:
960:
959:
956:
954:
916:
909:
907:
898:
883:
872:
868:
861:
859:
832:
820:
804:
802:
800:
777:
773:
744:
743:
742:
733:
718:
703:
692:
688:
681:
679:
677:
661:
657:
656:isoelectronic
645:
633:
629:
625:
621:
614:
612:
610:
606:
602:
585:
584:
583:
581:
577:
573:
569:
565:
561:
557:
547:
539:
523:
515:
508:
478:
474:
472:
467:
465:
461:
446:
441:
439:
416:
390:
386:
382:
377:
375:
371:
367:
363:
358:
356:
321:
320:
319:
317:
316:sulfuric acid
313:
309:
305:
301:
298:compounds of
297:
286:
275:
271:
267:
259:
257:
211:
210:
208:
182:
181:
179:
174:
170:
169:
152:
151:
149:
148:
147:
145:
141:
132:
125:
123:
121:
117:
113:
109:
105:
101:
97:
93:
89:
85:
82:(Br), and/or
81:
77:
73:
69:
63:
57:
50:
46:
42:
38:
34:
30:
26:
22:
2311:
2296:
2282:
2260:
2250:Bibliography
2239:
2228:. Retrieved
2216:
2210:
2209:"Art. XXVI.
2202:
2190:. Retrieved
2172:
2165:
2148:
2138:
2129:
2114:cite journal
2097:
2091:
2082:
2065:
2061:
2039:
2030:
2013:
2009:
2002:
1993:
1979:(1): 69–70.
1976:
1972:
1942:
1921:
1912:
1895:
1891:
1884:
1875:
1866:
1850:
1849:K. Nakamoto
1845:
1836:
1827:
1819:
1814:
1805:
1765:
1761:lead sulfide
1731:terlinguaite
1697:
1631:
1523:
1460:VSEPR theory
1442:is a strong
1437:
972:VOCl, VOBr,
950:
946: Oxygen
865:
808:
770:
685:
618:
609:-196 °C
603:reacts with
599:
543:
540:Carbon group
491: Oxygen
468:
460:double bonds
442:
378:
359:
352:
265:
263:
240:
137:
107:
103:
61:
55:
28:
24:
18:
2192:December 5,
2062:Inorg. Chem
2010:Inorg. Chem
1604:[AgOTeF
1475:tetrahedral
1379:[AgOTeF
964:oxohalides
862:Noble gases
797:, known as
485: Boron
381:Lewis acids
122:structure.
116:crystalline
102:. The term
90:element, a
2340:Oxohalides
2230:2009-05-21
1798:References
1711:tetragonal
1703:bismoclite
1512:octahedral
984:[TiOCl
754:O + 6 SOCl
682:Chalcogens
676:phosphorus
615:Pnictogens
389:Lewis base
366:hydrolyzed
302:in the +5
300:phosphorus
266:vice versa
260:Properties
114:and other
88:main group
29:oxyhalides
1780:lanthanum
1742:Mendipite
1680:plutonium
1676:neptunium
1051:[CrOF
1043:[CrOF
1012:[VOCl
776:tellurium
658:with the
393:[VOCl
310:salt and
126:Synthesis
108:oxyhalide
104:oxohalide
21:chemistry
2334:Category
1786:See also
1772:antimony
1701:(BiOCl,
1636:series,
1634:actinide
1462:. Thus,
1448:fluorine
1446:, as is
1119:[CrO
805:Halogens
772:Selenium
766:+ 12 HCl
750:·6H
620:Nitrogen
572:chlorine
564:phosgene
417:complex
370:enthalpy
296:covalent
162:→ 2 POCl
112:minerals
100:actinide
76:chlorine
72:fluorine
49:molecule
1963:, and F
1776:bismuth
1657:[UO
1632:In the
1527:[Ta
1452:Bromine
1360:[Ta
996:TiOTiCl
799:teflate
730:), and
660:nitrate
634:and 5,
595:+ 2 HCl
544:Carbon
144:halides
80:bromine
68:halogen
41:halogen
2318:
2303:
2289:
2271:
2183:
1967:TeOTeF
1959:SeOSeF
1857:
1709:has a
1655:) and
1638:uranyl
1539:[M
1456:iodine
1440:oxygen
1431:
1425:
1419:
1413:
1407:
944:
938:
932:
920:Ti(ClO
895:) and
869:forms
833:) and
762:+ 6 SO
758:→ MgCl
687:Sulfur
642:, X =
554:, X =
501:
495:
489:
483:
283:) and
200:+ 3 CO
192:+ 6 Cl
140:oxides
98:or an
84:iodine
78:(Cl),
37:oxygen
2177:(PDF)
1602:) or
1578:(OTeF
1574:M(cp)
1558:M−O−M
1516:ReOCl
1184:MoOCl
1092:NbOCl
1066:TcOCl
1059:MnOCl
974:FeOCl
867:Xenon
662:ion,
605:water
570:with
423:(N(CH
344:+ 3 H
243:POFCl
230:+ 4 H
154:2 PCl
120:ionic
106:, or
74:(F),
2316:ISBN
2301:ISBN
2287:ISBN
2269:ISBN
2194:2011
2181:ISBN
2120:link
1951:SOSF
1855:ISBN
1778:and
1768:iron
1727:Mohs
1721:and
1678:and
1537:and
1505:OsOF
1503:and
1494:XeOF
1454:and
1316:OsOF
1276:ReOF
1252:WOCl
1175:MoOF
1154:OsOF
1136:ReOX
1128:CrOF
1083:VOCl
1004:VOCl
901:XeOF
875:XeOF
851:and
784:AOAF
774:and
746:MgCl
695:SOCl
587:COCl
530:AOAF
443:The
419:VOCl
408:VOCl
401:VOCl
353:The
278:POCl
248:and
142:and
94:, a
39:and
2221:doi
2153:doi
2102:doi
2070:doi
2018:doi
1981:doi
1955:, F
1900:doi
1738:OCl
1608:-(C
1593:η-C
1568:— p
1543:OCl
1510:is
1499:is
1488:is
1479:OsO
1473:is
1464:CrO
1383:-(C
1364:OCl
1340:OsO
1329:OsO
1307:ReO
1297:ReO
1284:ReO
1267:MnO
1243:WOF
1206:MoO
1193:MoO
1162:CrO
1143:ReO
1123:Cl]
1107:CrO
1074:VOF
1026:VOX
906:).
886:XeO
880:),
853:IOF
835:XOF
821:),
795:TeO
736:SOF
715:),
654:is
549:COX
449:CrO
289:PCl
287:, (
254:FCl
250:CrO
213:CrO
184:2 V
158:+ O
19:In
2336::
2267:.
2215:.
2116:}}
2112:{{
2066:24
2064:.
2048:^
2014:25
2012:.
1977:17
1975:.
1930:^
1896:92
1894:.
1774:,
1770:,
1754:Cl
1746:Pb
1744:,
1734:Hg
1719:Bi
1717:,
1715:Cl
1682:.
1669:UO
1661:Cl
1650:Cl
1646:UO
1629:.
1616:CH
1591:,
1551:MX
1545:10
1533:10
1531:OX
1492:,
1477:,
1468:Cl
1450:.
1391:CH
1366:10
1338:,
1314:,
1311:Cl
1304:,
1294:,
1281:,
1274:,
1249:,
1240:,
1231:WO
1229:,
1223:Cl
1219:WO
1216:,
1203:,
1197:Cl
1190:,
1181:,
1172:,
1159:,
1152:,
1141:,
1134:,
1125:,
1117:,
1111:Cl
1089:,
1080:,
1071:,
1064:,
1057:,
1049:,
1041:,
1034:VO
1031:,
1010:,
1001:,
992:Cl
990:,
929:.
842:IO
823:XO
811:XO
725:Cl
721:SO
706:SO
693:,
664:NO
648:NO
636:NO
632:Br
630:,
628:Cl
626:,
560:Br
558:,
440:.
340:Cl
330:2−
323:Cr
318:.
256:.
226:Cl
216:2−
53:AO
23:,
2326:.
2324:.
2277:.
2233:.
2223::
2213:"
2196:.
2159:.
2155::
2145:5
2122:)
2108:.
2104::
2076:.
2072::
2058:5
2024:.
2020::
1987:.
1983::
1969:5
1965:5
1961:5
1957:5
1953:5
1949:5
1906:.
1902::
1756:2
1752:2
1750:O
1748:3
1736:2
1723:O
1671:2
1665:]
1663:4
1659:2
1652:2
1648:2
1644:(
1626:2
1624:]
1622:2
1620:)
1618:3
1614:5
1612:H
1610:6
1606:5
1599:5
1597:H
1595:5
1584:2
1582:)
1580:5
1576:2
1570:π
1566:π
1553:5
1547:]
1541:2
1535:]
1529:2
1518:4
1507:5
1496:4
1485:2
1483:F
1481:3
1470:2
1466:2
1401:2
1399:]
1397:2
1395:)
1393:3
1389:5
1387:H
1385:6
1381:5
1368:]
1362:2
1346:2
1344:F
1342:3
1335:4
1333:F
1331:2
1325:8
1318:5
1309:3
1301:F
1299:3
1290:3
1288:F
1286:2
1278:5
1271:F
1269:3
1262:7
1254:4
1245:4
1237:2
1235:F
1233:2
1225:2
1221:2
1212:2
1210:F
1208:2
1199:2
1195:2
1186:4
1177:4
1168:2
1166:F
1164:2
1156:4
1149:2
1147:F
1145:2
1138:4
1130:4
1121:3
1113:2
1109:2
1102:6
1094:3
1085:3
1076:3
1068:3
1061:3
1055:]
1053:5
1047:]
1045:4
1038:F
1036:2
1028:3
1022:5
1016:]
1014:4
1006:2
998:3
994:3
988:]
986:4
980:4
969:3
926:4
924:)
922:4
903:2
899:(
892:2
890:F
888:2
884:(
877:4
873:(
855:5
848:3
846:F
844:2
837:3
829:(
827:F
825:3
817:(
815:F
813:2
793:5
791:F
786:5
782:5
780:F
764:2
760:2
756:2
752:2
748:2
738:4
734:(
727:2
723:2
719:(
712:2
710:F
708:2
704:(
697:2
670:3
667:−
652:F
650:2
644:F
640:X
638:2
624:F
593:2
589:2
556:F
551:2
532:5
528:5
526:F
455:2
453:F
451:2
433:2
431:)
429:3
427:)
425:3
421:2
410:2
403:2
397:]
395:4
348:O
346:2
342:2
338:2
333:7
327:O
325:2
291:5
280:3
276:(
252:2
245:2
234:O
232:2
228:2
224:2
219:4
202:2
198:3
194:2
190:5
188:O
186:2
164:3
160:2
156:3
62:n
59:X
56:m
27:(
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