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751:
Gilli, Paola; Bertolasi, Valerio; Ferretti, Valeria; Gilli, Gastone (2000). "Evidence for
Intramolecular N−H···O Resonance-Assisted Hydrogen Bonding in β-Enaminones and Related Heterodienes. A Combined Crystal-Structural, IR and NMR Spectroscopic, and Quantum-Mechanical Investigation".
440:
407:
650:. It is a white solid that is poorly soluble in water. This chemical and many related compounds (prepared from various aniline derivatives) are used in the production of organic
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InChI=1S/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)
289:
InChI=1/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)
679:
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171:
779:
Williams, Jonathan W.; Krynitsky, John A. (1941). "Acetoacetanilide".
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608:
Except where otherwise noted, data are given for materials in their
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538:
239:
859:
Lauer, W. M.; Kaslow, C. E. (1944). "4-Methylcarbostyril".
700:
Acetoacetylation with diketene followed by diazo coupling.
565:
385:
83 to 88 °C (181 to 190 °F; 356 to 361 K)
658:. Acetoacetanilides usually exist as the keto-amide
685:To make the dyes, acetoacetanilides are coupled to
201:
808:Kirk-Othmer Encyclopedia of Chemical Technology
569:
75:
840:Ullmann's Encyclopedia of Industrial Chemistry
816:10.1002/0471238961.151807011001060605.a01.pub2
806:Jaffe, Edward E. (2004). "Pigments, Organic".
708:, acetoacetanilide dehydrates to give 4-methyl
8:
838:K. Hunger. W. Herbst "Pigments, Organic" in
646:. It is the acetoacetamide derivative of
630:is an organic compound with the formula CH
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161:
139:
15:
221:
754:Journal of the American Chemical Society
682:. Many analogues have been prepared.
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282:Key: DYRDKSSFIWVSNM-UHFFFAOYSA-N
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7:
292:Key: DYRDKSSFIWVSNM-UHFFFAOYAR
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14:
674:Acetoacetanilide is prepared by
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612:(at 25 °C , 100 kPa).
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334:
1:
842:, Wiley-VCH, Weinheim, 2012.
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670:Preparation and reactions
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21:
873:10.15227/orgsyn.024.0068
848:10.1002/14356007.a20_371
793:10.15227/orgsyn.021.0004
481:Precautionary statements
313:CC(=O)CC(=O)NC1=CC=CC=C1
54:Acetoacetylaminobenzene
701:
576:
699:
664:X-ray crystallography
575:
558:(fire diamond)
37:Preferred IUPAC name
704:In the presence of
392:Solubility in water
367: g·mol
18:
702:
616:Infobox references
577:
16:
861:Organic Syntheses
825:978-0-471-48494-3
781:Organic Syntheses
766:10.1021/ja000921+
678:of aniline using
624:Chemical compound
622:
621:
455:Hazard statements
375:Colourless solid
235:CompTox Dashboard
101:Interactive image
45:-phenylbutanamide
17:Acetoacetanilide
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676:acetoacetylation
628:Acetoacetanilide
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329:Chemical formula
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687:diazonium salts
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656:arylide yellows
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706:sulfuric acid
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662:according to
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381:Melting point
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153:ECHA InfoCard
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121:ChEMBL1604429
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746:
710:-2-quinolone
703:
691:azo coupling
684:
673:
627:
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554:
446:
408:
60:Identifiers
52:Other names
42:
441:Signal word
372:Appearance
322:Properties
159:100.002.725
739:References
420:Pictograms
360:Molar mass
223:W35JB9PY3X
132:ChemSpider
88:3D model (
67:CAS Number
523:P304+P340
519:P304+P312
515:P302+P352
511:P301+P312
411:labelling
180:202-996-4
172:EC Number
892:Anilides
886:Category
716:See also
680:diketene
660:tautomer
652:pigments
555:NFPA 704
402:Hazards
77:102-01-2
654:called
648:aniline
638:C(O)NHC
447:Warning
365:177.203
190:PubChem
867:: 68.
822:
760:(42).
634:C(O)CH
306:SMILES
112:ChEMBL
41:3-Oxo-
31:Names
787:: 4.
271:InChI
90:JSmol
820:ISBN
547:P501
543:P363
539:P330
535:P322
531:P314
527:P312
507:P280
503:P271
499:P270
495:P264
491:P261
487:P260
473:H373
469:H332
465:H312
461:H302
397:low
214:UNII
203:7592
141:7311
869:doi
844:doi
812:doi
789:doi
762:doi
758:122
693:".
689:, "
409:GHS
240:EPA
193:CID
888::
865:24
863:.
818:.
810:.
785:21
783:.
756:.
730:NO
728:11
724:10
712:.
666:.
545:,
541:,
537:,
533:,
529:,
525:,
521:,
517:,
513:,
509:,
505:,
501:,
497:,
493:,
489:,
471:,
467:,
463:,
413::
344:11
338:10
875:.
871::
846::
828:.
814::
795:.
791::
768:.
764::
732:2
726:H
722:C
644:5
642:H
640:6
636:2
632:3
596:0
589:1
582:2
353:2
350:O
347:N
341:H
335:C
242:)
238:(
92:)
43:N
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