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118:. Normal laboratory equipment can be set up in the glovebox, and manipulated by the use of gloves that penetrate its walls. The atmosphere can be regulated to approximately atmospheric pressure and set to be pure nitrogen or other gas with which the chemicals will not react. Chemicals and equipment can be transferred in and out via an
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A Schlenk line is a vacuum and inert-gas dual-manifold that allows glassware to be evacuated and refilled with inert gas specially developed to work with air sensitive compounds. It is connected with a
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to prevent vapors from contaminating a rotary vane pump. The technique is modified from the double-tipped needle technique. These methods allow working in totally controlled and isolated environment.
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142:(chemical compounds containing at least one chemical bond between a metal and carbon atom, including alkaline earth, alkaline and
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Smith
Vosejpka, Laura J. (August 1993). "A simple and cost-effective technique for the transfer of air-sensitive solutions".
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like tin, boron and sometimes silicon encountered in chemistry, which are sensitive to oxygen and moisture.
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Air-sensitive compounds are substances that would react, explode or oxidise with air, such as
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compounds which react violently with water can be handled safely using air free techniques.
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have been developed to handle air-sensitive compounds. Two main types of equipment are
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Analysis of Carbon, Hydrogen, Nitrogen, Oxygen, and halogens including
Fluorine
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237:. Stratingh Institute for Chemistry, University of Groningen. pp. 4, 6.
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281:"Air Sensitive Sample Analysis | Reduced Oxygen Moisture-Free Handling"
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O), although reactions with the other constituents of air such as
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403:"Application of Air-sensitive Semiconductors in Nanoelectronics"
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322:"The Glassware Gallery: Schlenk Lines and Vacuum Lines"
217:"Techniques for handling air and moisture sensitivity"
367:"Air-Sensitive Chemistry - Labware | Sigma-Aldrich"
235:working with air and moisture sensitive compounds
106:. Glove boxes are sealed cabinets filled with an
263:techniques of handling air sensitivity compound
42:. Most often, reactions occur with atmospheric
200:Handling and Storage of Air-Sensitive Reagents
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161:Some semiconductors are air-sensitive.
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385:"Pyrophoric Control - FQE Chemicals"
305:"Handling air‐sensitive compounds"
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30:is a term used, particularly in
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34:, to denote the reactivity of
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341:Journal of Chemical Education
202:, Technical Bulletin AL-134,
233:W. Bouwkamp, Marco (2008).
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38:with some constituent of
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407:www.sciencenewsline.com
250:, The Glassware Gallery
134:Air-sensitive compounds
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78:) are also possible.
146:). They may include
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427:Air-free techniques
181:Ultrahydrophobicity
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290:2018-02-27
187:References
176:Hydrophile
171:Hygroscopy
156:pyrophoric
154:and other
148:metalloids
100:gloveboxes
128:cold trap
108:inert gas
32:chemistry
165:See also
116:nitrogen
110:such as
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72:nitrogen
54:vapor (H
120:airlock
70:), and
82:Method
62:(CO),
44:oxygen
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52:water
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