259:
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439:
24:
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752:, N-alkyl pyrrolidinones are obtained. Carbonylation of allyl halides in the presence of primary amines and a rhodium compound affords the same products....If allyl derivatives are carbonylated in the presence of acetylene by means of Ni(CO)
447:
414:
533:
525:
673:. Allyl iodide dissolved in hexane can be stored for up to three months in a dark freezer at −5 °C (23 °F) before decomposition into free iodine becomes apparent.
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Disubstitution of barbituric acids at the 5-position is only possible with highly reactive halides, such as allyl halides.
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Halogen-containing allyl complexes can often be prepared simply from reactions of allyl halides with metal compounds.
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and water or methanol at 20 °C, the acetylene adds onto the allyl halide and 2-
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847:
A Comprehensive Guide to the
Hazardous Properties of Chemical Substances 3rd Ed
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489:
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808:
Behr, Arno (2000). "Organometallic
Compounds and Homogeneous Catalysis".
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Except where otherwise noted, data are given for materials in their
682:
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760:-5-dienoic acids or esters or sorbic acid esters are obtained.
744:
When unsaturated amines are carbonylated in the presence of Co
242:
404:
101 to 103 °C (214 to 217 °F; 374 to 376 K)
991:
850:. New Jersey: John Wiley & Sons. pp. 141–142.
622:
used in synthesis of other organic compounds such as
877:. New York: John Wiley & Sons, Inc. p. 22.
891:A manual of the chemistry of the carbon compounds
661:on allyl halides, or by the action of elemental
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713:
81:
810:Ullmann's Encyclopedia of Industrial Chemistry
774:Ullmann's Encyclopedia of Industrial Chemistry
722:Ullmann's Encyclopedia of Industrial Chemistry
1011:
8:
943:Armarego, Wilfred; Chai. Christina (2012).
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1004:
720:Bertleff, Werner (2000). "Carbonylation".
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15:
772:Wollweber, Hartmund (2000). "Hypnotics".
214:
911:Journal of the American Chemical Society
894:. London: Macmillan and Co. p. 262.
709:
645:. Allyl iodide can be synthesized from
394:−99 °C (−146 °F; 174 K)
310:
278:
253:
145:
949:. Kidlington: Elsevier. p. 114.
285:Key: BHELZAPQIKSEDF-UHFFFAOYSA-N
7:
972:
970:
946:Purification of Laboratory Chemicals
573:18 °C (64 °F; 291 K)
185:
14:
907:"The Preparation of Allyl Iodide"
282:InChI=1S/C3H5I/c1-2-3-4/h2H,1,3H2
974:
437:
432:
345:
292:InChI=1/C3H5I/c1-2-3-4/h2H,1,3H2
22:
905:Datta, Rasek Lal (March 1914).
596:(at 25 °C , 100 kPa).
351:
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990:. You can help Knowledge by
874:Organic Reactions, Volume II
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844:Patnaik, Pradyot (2007).
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888:Schorlemmer, C. (1874).
818:10.1002/14356007.a18_215
782:10.1002/14356007.a13_533
730:10.1002/14356007.a05_217
643:organometallic catalysts
480:Precautionary statements
982:This article about an
871:Adams, Rodger (1944).
724:. pp. 9, 14–15.
585:MSDS at Sigma Aldrich
659:Finkelstein reaction
637:, 5,5-disubstituted
37:Preferred IUPAC name
923:10.1021/ja02182a023
655:triphenyl phosphite
374:Pale yellow liquid
366: g·mol
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1047:Organohalide stubs
600:Infobox references
16:
999:
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608:Chemical compound
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605:
579:Safety data sheet
462:Hazard statements
238:CompTox Dashboard
114:Interactive image
107:Interactive image
60:2-Propenyl iodide
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56:3-Iodo-1-propene
41:3-Iodoprop-1-ene
26:
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651:methyl iodide
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616:3-iodopropene
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52:3-Iodopropene
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17:Allyl iodide
992:expanding it
981:
966:
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938:
926:. Retrieved
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612:Allyl iodide
611:
610:
453:
415:
66:Identifiers
58:Iodoallylene
50:Allyl iodide
48:Other names
928:15 December
632:sorbic acid
569:Flash point
448:Signal word
384:1.837 g/cm
371:Appearance
327:Properties
152:100.008.302
1031:Categories
704:References
663:phosphorus
427:Pictograms
359:Molar mass
216:46830QOA4D
125:ChemSpider
94:3D model (
73:CAS Number
554:P403+P235
550:P370+P378
530:P304+P340
418:labelling
227:UN number
173:209-130-4
165:EC Number
677:See also
671:glycerol
618:) is an
409:Hazards
134:21171407
83:556-56-9
626:-alkyl-
380:Density
364:167.977
183:PubChem
953:
854:
824:
788:
736:
667:iodine
641:, and
635:esters
581:(SDS)
454:Danger
306:SMILES
31:Names
986:is a
683:Allyl
318:C=CCI
313:ICC=C
274:InChI
231:1723
196:11166
96:JSmol
988:stub
951:ISBN
930:2013
852:ISBN
822:ISBN
786:ISBN
748:(CO)
734:ISBN
665:and
649:and
562:P501
558:P405
546:P363
542:P321
538:P310
518:P280
514:P264
510:P260
506:P243
502:P242
498:P241
494:P240
490:P233
486:P210
472:H314
468:H225
207:UNII
919:doi
814:doi
778:doi
758:cis
726:doi
669:on
653:on
416:GHS
243:EPA
186:CID
1033::
915:36
913:.
909:.
830:.
820:.
794:.
784:.
742:.
732:.
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