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Aluminium–air battery

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Al/air electric vehicles (EVs) can be 15% (present stage) or 20% (projected), comparable to that of internal combustion engine vehicles (ICEs) (13%). The design battery energy density is 1300 Wh/kg (present) or 2000 Wh/kg (projected). The cost of battery system chosen to evaluate is US$ 30/kW (present) or US$ 29/kW (projected). Al/air EVs life-cycle analysis was conducted and compared to lead/acid and nickel metal hydride (NiMH) EVs. Only the Al/air EVs can be projected to have a travel range comparable to ICEs. From this analysis, Al/air EVs are the most promising candidates compared to ICEs in terms of travel range, purchase price, fuel cost, and life-cycle cost.
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Another problem is the cost of materials that need to be added to the battery to avoid power dropping. Aluminium is still very cheap compared to other elements used to build batteries. Aluminium costs $ 2.51 per kilogram while lithium and nickel cost $ 12.59 and $ 17.12 per kilogram respectively.
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Technical problems remain to be solved to make Al–air batteries suitable for electric vehicles. Anodes made of pure aluminium are corroded by the electrolyte, so the aluminium is usually alloyed with tin or other elements. The hydrated alumina that is created by the cell reaction forms a gel-like
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Traditional Al–air batteries had a limited shelf life, because the aluminium reacted with the electrolyte and produced hydrogen when the battery was not in use; this is no longer the case with modern designs. The problem can be avoided by storing the electrolyte in a tank outside the battery and
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released a video demonstration of an electric car using aluminium–air cells driven 330 km using a special cathode and potassium hydroxide. On May 27, 2013, the Israeli channel 10 evening news broadcast showed a car with Phinergy battery in the back, claiming 2,000 kilometres (1,200 mi)
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The Al/air battery system can generate enough energy and power for driving ranges and acceleration similar to gasoline powered cars...the cost of aluminium as an anode can be as low as US$ 1.1/kg as long as the reaction product is recycled. The total fuel efficiency during the cycle process in
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Research and development is taking place on alternative, safer, and higher performance electrolytes such as organic solvents and ionic liquids. Others such as AlumaPower are focusing on mechanical methods to mitigate many of the historical issues with Al-air batteries. AlumaPower's patent
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substance at the anode and reduces the electricity output. This is an issue being addressed in the development work on Al–air cells. For example, additives that form the alumina as a powder rather than a gel have been developed.
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of all batteries, but they are not widely used because of problems with high anode cost and byproduct removal when using traditional electrolytes. This has restricted their use to mainly military applications. However, an
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Aluminium–air batteries may become an effective solution for marine applications due to their high energy density, low cost, and the abundance of aluminium, with no emissions at the point of use in boats and ships.
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film that prevents electrolyte leakage. The oxygen in the air passes through the PTFE then reacts with the water to create hydroxide ions. These cathodes work well, but they can be expensive.
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Aluminium-powered vehicles have been under discussion for some decades. Hybridisation mitigates the costs, and in 1989 road tests of a hybridised aluminium–air/
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However, one other element typically used in aluminium air as a catalyst in the cathode is silver, which costs about $ 922 per kilogram (2024 prices).
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The specific voltage of the cell can vary depending upon the composition of the electrolyte as well as the structure and materials of the cathode.
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and several other commercial companies are working on commercial and military applications in the marine environment.
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Aluminium as a "fuel" for vehicles has been studied by Yang and Knickle. In 2002, they concluded:
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Yang, S. (2002). "Design and analysis of aluminum/air battery system for electric vehicles".
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is used as the electrolyte. Saltwater electrolyte achieves approximately 0.7 volts per cell.
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Aluminium battery from Stanford offers safe alternative to conventional batteries
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Parish, D. W.; Fitzpatrick, N. P.; Callaghan, W. B. O'; Anderson, W. M. (1989).
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with aluminium batteries has the potential for up to eight times the range of a
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is created by these reactions and is achievable in practice when
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Aluminium battery can charge phone in one minute, scientists say
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range before replacement of the aluminium anodes is necessary.
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transferring it to the battery when it is required for use.
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in an electric vehicle were reported. An aluminium-powered
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Fitzpatrick, N. P.; Smith, F.N.; Jeffrey, P. W. (1983).
673:"Aluminum-air batteries - game changer or hype?, Home" 655:"UK Finance Guide – Loans and finance news for the UK" 1207: 1179: 1001: 877: 815: 313:Modern air cathodes consist of a reactive layer of 279:Other metals can be used in a similar way, such as 69: 55: 45: 31: 302: 793: 440: 438: 436: 132:minivan was demonstrated in Ontario in 1990. 16:High-electrical energy density storage device 8: 26: 321:-grid current collector, a catalyst (e.g., 800: 786: 778: 37:1300 (practical), 6000/8000 (theoretical) 110:with a significantly lower total weight. 675:. www.sparkanalytics.co. Archived from 432: 25: 7: 773:Simple homemade aluminum-air battery 630:"Al-air: a better battery for EVs?" 628:Brown, Richard (3 February 2020). 19:For the rechargeable battery, see 14: 868: 521:. Vol. 1. Papers.sae.org. 488:. Vol. 1. Papers.sae.org. 336:These batteries can be used as 97:. They have one of the highest 412:Metal–air electrochemical cell 1: 467:10.1016/S0378-7753(02)00370-1 325:), and a porous hydrophobic 225:The total reaction is 4Al + 113:Aluminium–air batteries are 186:reduction half-reaction is 1312: 519:SAE Technical Paper Series 486:SAE Technical Paper Series 482:"The Aluminum-Air Battery" 18: 958:Metal–air electrochemical 866: 587:Phinergy corporate video 447:Journal of Power Sources 719:"Phinergy Marine, Home" 83:Aluminium–air batteries 1260:Semipermeable membrane 1049:Lithium–iron–phosphate 307: 1281:Electrochemical cells 1131:Rechargeable alkaline 809:Electrochemical cells 607:. Greencarreports.com 417:Aluminium-ion battery 407:Potassium-ion battery 397:List of battery types 27:Aluminium–air battery 21:aluminium-ion battery 1296:Disposable batteries 1111:Nickel–metal hydride 634:Automotive Logistics 603:Edelstein, Stephen. 267:potential difference 70:Nominal cell voltage 1291:Metal–air batteries 1121:Polysulfide–bromide 963:Nickel oxyhydroxide 855:Thermogalvanic cell 661:on January 3, 2007. 459:2002JPS...112..162Y 342:telephone exchanges 271:potassium hydroxide 108:lithium-ion battery 28: 884:(non-rechargeable) 828:Concentration cell 551:2013-10-29 at the 1268: 1267: 422:Aluminium battery 338:reserve batteries 291:Commercialization 126:lead–acid battery 80: 79: 1303: 1064:Lithium–titanate 1009: 885: 872: 833:Electric battery 802: 795: 788: 779: 751: 750: 748: 747: 736: 730: 729: 727: 726: 715: 709: 708: 706: 705: 700:. AlumaPower.com 694: 688: 687: 685: 684: 669: 663: 662: 657:. Archived from 651: 645: 644: 642: 640: 625: 616: 615: 613: 612: 600: 594: 588: 583: 577: 576: 574: 573: 566:"Phinergy, Home" 562: 556: 543: 537: 536: 534: 533: 510: 504: 503: 501: 500: 477: 471: 470: 442: 402:Zinc–air battery 386: 385: 381: 265:About 1.2 volts 261: 260: 259: 249: 247: 246: 236: 235: 234: 221: 220: 219: 210: 208: 207: 197: 196: 195: 178: 177: 176: 166: 165: 164: 144:Electrochemistry 104:electric vehicle 99:energy densities 29: 1311: 1310: 1306: 1305: 1304: 1302: 1301: 1300: 1271: 1270: 1269: 1264: 1203: 1182: 1175: 1096:Nickel–hydrogen 1054:Lithium–polymer 1010: 1007: 1006: 997: 886: 883: 882: 873: 864: 811: 806: 759: 754: 745: 743: 740:"RiAlAiR, Home" 738: 737: 733: 724: 722: 717: 716: 712: 703: 701: 696: 695: 691: 682: 680: 671: 670: 666: 653: 652: 648: 638: 636: 627: 626: 619: 610: 608: 602: 601: 597: 586: 584: 580: 571: 569: 564: 563: 559: 553:Wayback Machine 546:Plug-in highway 544: 540: 531: 529: 512: 511: 507: 498: 496: 479: 478: 474: 444: 443: 434: 430: 393: 383: 379:US US10978758B2 377: 366:Log 9 Materials 362:Phinergy Marine 298: 293: 258: 255: 254: 253: 251: 245: 242: 241: 240: 238: 233: 230: 229: 228: 226: 218: 216: 215: 214: 212: 206: 203: 202: 201: 199: 194: 191: 190: 189: 187: 175: 172: 171: 170: 168: 163: 161: 160: 159: 157: 146: 135:In March 2013, 119:aluminium oxide 33:Specific energy 24: 17: 12: 11: 5: 1309: 1307: 1299: 1298: 1293: 1288: 1283: 1273: 1272: 1266: 1265: 1263: 1262: 1257: 1252: 1247: 1242: 1237: 1232: 1227: 1222: 1217: 1211: 1209: 1205: 1204: 1202: 1201: 1196: 1191: 1189:Atomic battery 1185: 1183: 1180: 1177: 1176: 1174: 1173: 1168: 1163: 1161:Vanadium redox 1158: 1153: 1148: 1143: 1138: 1136:Silver–cadmium 1133: 1128: 1123: 1118: 1113: 1108: 1106:Nickel–lithium 1103: 1098: 1093: 1091:Nickel–cadmium 1088: 1083: 1078: 1073: 1068: 1067: 1066: 1061: 1059:Lithium–sulfur 1056: 1051: 1046: 1036: 1031: 1030: 1029: 1019: 1013: 1011: 1008:(rechargeable) 1004:Secondary cell 1002: 999: 998: 996: 995: 990: 985: 980: 975: 970: 965: 960: 955: 950: 945: 940: 935: 930: 928:Edison–Lalande 925: 920: 915: 910: 905: 900: 895: 889: 887: 878: 875: 874: 867: 865: 863: 862: 857: 852: 847: 846: 845: 843:Trough battery 840: 830: 825: 819: 817: 813: 812: 807: 805: 804: 797: 790: 782: 776: 775: 770: 765: 758: 757:External links 755: 753: 752: 731: 721:. Phinergy.com 710: 689: 664: 646: 617: 595: 578: 568:. Phinergy.com 557: 538: 527:10.4271/891690 505: 494:10.4271/830290 472: 453:(1): 162–201. 431: 429: 426: 425: 424: 419: 414: 409: 404: 399: 392: 389: 297: 294: 292: 289: 256: 243: 231: 217: 204: 192: 179:+ 3e +2.31 V. 173: 162: 145: 142: 130:plug-in hybrid 78: 77: 71: 67: 66: 59: 57:Specific power 53: 52: 49: 47:Energy density 43: 42: 35: 15: 13: 10: 9: 6: 4: 3: 2: 1308: 1297: 1294: 1292: 1289: 1287: 1284: 1282: 1279: 1278: 1276: 1261: 1258: 1256: 1253: 1251: 1248: 1246: 1243: 1241: 1238: 1236: 1233: 1231: 1228: 1226: 1223: 1221: 1218: 1216: 1213: 1212: 1210: 1206: 1200: 1197: 1195: 1192: 1190: 1187: 1186: 1184: 1178: 1172: 1169: 1167: 1164: 1162: 1159: 1157: 1154: 1152: 1151:Sodium–sulfur 1149: 1147: 1144: 1142: 1139: 1137: 1134: 1132: 1129: 1127: 1126:Potassium ion 1124: 1122: 1119: 1117: 1114: 1112: 1109: 1107: 1104: 1102: 1099: 1097: 1094: 1092: 1089: 1087: 1084: 1082: 1079: 1077: 1074: 1072: 1069: 1065: 1062: 1060: 1057: 1055: 1052: 1050: 1047: 1045: 1042: 1041: 1040: 1037: 1035: 1032: 1028: 1025: 1024: 1023: 1020: 1018: 1015: 1014: 1012: 1005: 1000: 994: 991: 989: 986: 984: 981: 979: 976: 974: 971: 969: 966: 964: 961: 959: 956: 954: 951: 949: 946: 944: 943:Lithium metal 941: 939: 936: 934: 931: 929: 926: 924: 921: 919: 916: 914: 911: 909: 906: 904: 901: 899: 898:Aluminium–air 896: 894: 891: 890: 888: 881: 876: 871: 861: 858: 856: 853: 851: 848: 844: 841: 839: 836: 835: 834: 831: 829: 826: 824: 823:Galvanic cell 821: 820: 818: 814: 810: 803: 798: 796: 791: 789: 784: 783: 780: 774: 771: 769: 766: 764: 761: 760: 756: 742:. rialair.com 741: 735: 732: 720: 714: 711: 699: 693: 690: 679:on 2021-12-13 678: 674: 668: 665: 660: 656: 650: 647: 635: 631: 624: 622: 618: 606: 599: 596: 593: 589: 582: 579: 567: 561: 558: 554: 550: 547: 542: 539: 528: 524: 520: 516: 509: 506: 495: 491: 487: 483: 476: 473: 468: 464: 460: 456: 452: 448: 441: 439: 437: 433: 427: 423: 420: 418: 415: 413: 410: 408: 405: 403: 400: 398: 395: 394: 390: 388: 380: 373: 371: 367: 363: 359: 353: 349: 347: 343: 339: 334: 330: 328: 324: 320: 316: 311: 306: 301: 295: 290: 288: 286: 282: 277: 274: 272: 268: 263: 223: 185: 180: 155: 154:half-reaction 151: 143: 141: 138: 133: 131: 127: 122: 120: 116: 115:primary cells 111: 109: 105: 100: 96: 92: 88: 84: 76: 72: 68: 64: 60: 58: 54: 50: 48: 44: 40: 36: 34: 30: 22: 1166:Zinc–bromine 973:Silver oxide 908:Chromic acid 897: 880:Primary cell 860:Voltaic pile 838:Flow battery 744:. 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Index

aluminium-ion battery
Specific energy
W·h
Energy density
Specific power
W
V
oxygen
air
aluminium
energy densities
electric vehicle
lithium-ion battery
primary cells
aluminium oxide
lead–acid battery
plug-in hybrid
Phinergy
anode
half-reaction
cathode
potential difference
potassium hydroxide
lithium-air
zinc-air
carbon
nickel
cobalt
PTFE
reserve batteries

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