40:
71:
1786:
61:
1421:
1398:
384:
255:
1519:
1016:
928:
1011:
1856:
1889:
1249:
1800:
reaction, although its practice is more technically demanding. For both reactions, the aluminium chloride, as well as other materials and the equipment, should be dry, although a trace of moisture is necessary for the reaction to proceed. Detailed procedures are available for alkylation and acylation
1014:
1489:
The anhydrous form is commercially important. It has a low melting and boiling point. It is mainly produced and consumed in the production of aluminium, but large amounts are also used in other areas of the chemical industry. The compound is often cited as a
986:
2220:. Metallic aluminium also readily dissolves in hydrochloric acid ─ releasing hydrogen gas and generating considerable heat. Heating this solid does not produce anhydrous aluminium trichloride, the hexahydrate decomposes to
936:
908:
192:
1039:
2270:
Anhydrous aluminium chloride is not found as a mineral. The hexahydrate, however, is known as the rare mineral chloraluminite. A more complex, basic and hydrated aluminium chloride mineral is
1015:
2481:
1356:
1079:
883:
982:
1262:
2518:
1017:
2910:
Rieke RD, Bales SE, Hudnall PM, Burns TP, Poindexter GS (1979). "Highly
Reactive Magnesium for the Preparation of Grignard Reagents: 1-Norbornanecarboxylic Acid".
3186:
1294:
1578:
aluminium. This change in structure is related to the lower density of the liquid phase (1.78 g/cm) versus solid aluminium trichloride (2.48 g/cm).
433:
39:
1705:
link the cation and anions. The hydrated form of aluminium chloride has an octahedral molecular geometry, with the central aluminium ion surrounded by six
70:
3659:
2694:
Nenitzescu CD, Cantuniari IP (1933). "Durch
Aluminiumchlorid Katalysierte Reaktion, VI. Mitteil.: Die Umlagerung des Cyclohexans in Metyl-cyclopentan".
184:
3255:
2020:. The anhydrous phase cannot be regained on heating the hexahydrate. Instead HCl is lost leaving aluminium hydroxide or alumina (aluminium oxide):
2001:, having a very pronounced affinity for water. It fumes in moist air and hisses when mixed with liquid water as the Cl ligands are displaced with H
5773:
5748:
3082:
2363:
60:
3018:
Nawrocki S, Cha J (September 2019). "The etiology, diagnosis, and management of hyperhidrosis: A comprehensive review: Therapeutic options".
2866:
2623:
2442:
2331:
829:
3150:
3113:
4058:
2293:, so suitable precautions are required. It can cause irritation to the eyes, skin, and the respiratory system if inhaled or on contact.
2535:
1609:
3179:
2455:
2344:
398:
1898:
Aluminium chloride combined with aluminium in the presence of an arene can be used to synthesize bis(arene) metal complexes, e.g.
3683:
1560:
adopts the same structure, as do a range of other compounds. When aluminium trichloride is in its melted state, it exists as the
1553:
5778:
2762:
Paruch K, Vyklicky L, Katz TJ (2003). "Preparation of 9,10-Dimethoxyphenanthrene and 3,6-Diacetyl-9,10-Dimethoxyphenanthrene".
1312:
2213:
In the US in 1993, approximately 21,000 tons were produced, not counting the amounts consumed in the production of aluminium.
2833:
2821:
2564:
1433:
1331:
1231:
3969:
3727:
1672:
974:
1903:
1804:
A general problem with the
Friedel-Crafts reaction is that the aluminium chloride catalyst sometimes is required in full
5768:
5763:
3172:
2731:"Synthesis of Trifluoromethyl Ketones from Carboxylic Acids: 4-(3,4-Dibromophenyl)-1,1,1-trifluoro-4-methylpentan-2-one"
2188:
964:
333:
3948:
3358:
2516:
Helmboldt O, Keith Hudson L, Misra C, Wefers K, Heck W, Stark H, et al. (2007). "Aluminum
Compounds, Inorganic".
1377:
362:
2639:
Andress KR, Carpenter C (1934). "Kristallhydrate II. Die
Struktur von Chromchlorid- und Aluminiumchloridhexahydrat".
1552:
has a sheet-like layered structure with cubic close-packed chloride ions. In this framework, the Al centres exhibit
1025:
5416:
4403:
3754:
3707:
1269:
1103:
1090:
5697:
5673:
5582:
3914:
3634:
3490:
3159:
1714:
262:
4373:
4123:
1785:
5690:
5589:
5500:
5477:
5439:
4815:
4808:
4421:
3931:
3782:
1832:
1605:
1482:. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with
5783:
5665:
5649:
5634:
5626:
5546:
5493:
5431:
5400:
4970:
4952:
4866:
4859:
4844:
4829:
4801:
4764:
4671:
4586:
4051:
3510:
3238:
1907:
1741:
1342:
978:
5050:
1416:
927:
250:
5758:
5680:
5642:
5559:
5539:
5469:
5454:
5424:
5276:
5072:
5043:
5027:
4944:
4882:
4852:
4837:
4822:
4771:
4757:
4716:
4652:
4579:
4564:
4542:
4535:
4520:
4513:
4414:
4361:
4335:
3639:
3293:
3219:
3214:
2302:
1915:
1631:
805:
5611:
5604:
5597:
5567:
5531:
5508:
5485:
5447:
5284:
5188:
5181:
5173:
5166:
5115:
5101:
5093:
5079:
5065:
5035:
4874:
4779:
4749:
4698:
4686:
4571:
4557:
4528:
4506:
4395:
4324:
4141:
3456:
3431:
3322:
3209:
2259:
1752:. These types of reactions are the major use for aluminium chloride, for example, in the preparation of
1557:
1518:
950:
920:
749:
90:
173:
5657:
5618:
5574:
5524:
5516:
5408:
5238:
5234:
5226:
5200:
5159:
5137:
5122:
5108:
5086:
5057:
4963:
4937:
4914:
4786:
4724:
4664:
4616:
4549:
4451:
4328:
4301:
4279:
4212:
4193:
4036:
3894:
3485:
3448:
3224:
2858:
1959:
1899:
1185:
990:
5462:
5269:
5215:
5144:
5130:
5001:
4978:
4907:
4793:
4709:
4679:
4656:
4636:
4624:
4609:
4484:
4433:
4290:
4249:
4171:
3590:
3522:
3477:
3472:
3440:
3423:
3407:
3301:
3195:
2371:
2221:
2192:
2113:
1813:
1809:
1499:
1393:
1180:
379:
118:
5753:
5207:
5151:
4990:
4982:
4903:
4739:
4632:
4601:
4479:
4428:
4384:
4353:
4312:
4204:
4104:
4044:
3858:
3614:
3602:
3578:
3366:
3317:
3285:
3229:
3053:
2656:
2415:
2051:
1844:
1495:
1483:
1479:
1449:
1304:
1211:
1190:
1144:
763:
46:
3998:
3147:
1816:
waste. For these and similar reasons, the use of aluminium chloride has often been displaced by
970:
5294:
5253:
5246:
4734:
4693:
4594:
4498:
4444:
4268:
4257:
4230:
4160:
4134:
4112:
4083:
3874:
3825:
3805:
3622:
3562:
3550:
3395:
3390:
3374:
3342:
3334:
3142:
3035:
3000:
2862:
2829:
2711:
2619:
2560:
2531:
2498:
2451:
2340:
2217:
2155:
1982:
1868:
1840:
1622:
1561:
1216:
1175:
1149:
856:
660:
449:
179:
5261:
5196:
5011:
4994:
4929:
4922:
4895:
4488:
4458:
4272:
4226:
4200:
4182:
4099:
3382:
3027:
2973:
2946:
2919:
2892:
2798:
2771:
2742:
2703:
2648:
2605:
2523:
2407:
2290:
2117:
2098:
2055:
1154:
715:
690:
559:
472:
349:
342:
232:
136:
5299:
5016:
4890:
4348:
4152:
3538:
3248:
3154:
2884:
2134:
1986:
1978:
1836:
1645:
1575:
1542:
281:
144:
128:
3134:
3129:
1420:
1397:
383:
254:
212:
4238:
4219:
3770:
2615:
1240:
956:
670:
616:
5742:
5318:
4644:
2854:
2825:
2660:
2494:
2419:
2271:
1927:
1876:
1805:
1769:
1753:
1702:
1409:
786:
539:
243:
1812:
strongly with the products. This complication sometimes generates a large amount of
2395:
1951:
1872:
1773:
1749:
1706:
1282:
894:
889:
732:
2527:
306:
2609:
17:
5713:
4319:
2109:
2065:
1855:
1847:
1652:
1634:
1590:
1538:
1460:
1065:
678:
513:
3160:
Government of Canada Fact Sheets and
Frequently Asked Questions: Aluminum Salts
3031:
2652:
2411:
1709:
molecules. Being coordinatively saturated, the hydrate is of little value as a
5334:
5310:
2582:
centers occupying adjacent tetrahedral holes of the close-packed framework of
2477:
2147:
1998:
1955:
1947:
1939:
1793:
1698:
1638:
1491:
1202:
666:
597:
489:
223:
3074:
2977:
2950:
2923:
2802:
2775:
2747:
2730:
2715:
2707:
2216:
Hydrated aluminium trichloride is prepared by dissolving aluminium oxides in
2991:
McConaghy JR, Fosselman D (June 2018). "Hyperhidrosis: Management
Options".
2789:
Seed AJ, Sonpatki V, Herbert MR (2002). "3-(4-Bromobenzoyl)propanoic Acid".
2447:
2336:
2151:
2095:
1895:
It is used to induce a variety of hydrocarbon couplings and rearrangements.
1797:
1745:
1710:
1298:
635:
3039:
3004:
1888:
5721:
4466:
4068:
2255:
1971:
1828:
1824:
1777:
1765:
1737:
1326:
1038:
1031:
1024:
997:
2896:
5705:
5346:
5326:
2158:
at temperatures between 650 and 750 °C (1,202 and 1,382 °F).
1911:
1880:
1817:
1761:
1618:
1507:
1503:
1349:
772:
605:
Soluble in hydrogen chloride, ethanol, chloroform, carbon tetrachloride
520:
441:
293:
263:
168:
3164:
3096:
2849:
Galatsis P (1999). "Aluminum
Chloride". In Reich HJ, Rigby JH (eds.).
2729:
Reeves JT, Tan Z, Fandrick DR, Song JJ, Yee NK, Senanayake CH (2012).
2262:(AlCl), but this is very unstable and only known in the vapour phase.
2556:
1943:
1690:
1686:
1641:
45:
Aluminium trichloride hexahydrate, pure (top), and contaminated with
1239:
Except where otherwise noted, data are given for materials in their
1926:
Topical aluminum chloride hexahydrate is used for the treatment of
1517:
317:
203:
191:
183:
172:
158:
1867:
Aluminium chloride finds a wide variety of other applications in
1032:
3746:
1116:
4040:
3168:
2696:
Berichte der
Deutschen Chemischen Gesellschaft (A and B Series)
1321:
550:
100 °C (212 °F; 373 K) (hexahydrate, decomposes)
2105:
1757:
1166:
1135:
2964:
Buchner B, Lockhart Jr LB (1951). "Phenyldichlorophosphine".
1382:
367:
69:
59:
2398:(1935). "Die Kristallstruktur der Aluminiumhalogenide II".
2146:
Aluminium chloride is manufactured on a large scale by the
547:
180 °C (356 °F; 453 K) (anhydrous, sublimes)
1863:
Other applications in organic and organometallic synthesis
1744:, both acylations and alkylations. Important products are
1009:
2937:
Shama SA, Wamser CC (1983). "Hexamethyl Dewar
Benzene".
2882:
Snider BB (1980). "Lewis-acid catalyzed ene reactions".
2641:
Zeitschrift für Kristallographie – Crystalline Materials
2400:
Zeitschrift für Kristallographie – Crystalline Materials
3135:
Index of Organic Synthesis procedures that utilize AlCl
1257:
3069:
3067:
2482:
National Institute for Occupational Safety and Health
3058:
American Society of Health System Pharmacists (ASHP)
3798:
3745:
3310:
3278:
3247:
3202:
1427:
1408:
1376:
1371:
1355:
1341:
1311:
1293:
1288:
1823:Aluminium chloride can also be used to introduce
1522:Illustration of structures of aluminium chloride
305:
1013:
143:
135:
127:
3020:Journal of the American Academy of Dermatology
2853:. Handbook of Reagents for Organic Synthesis.
2519:Ullmann's Encyclopedia of Industrial Chemistry
4052:
3180:
2364:"Properties of substance: Aluminium chloride"
1768:. In the general Friedel-Crafts reaction, an
8:
2094:Aqueous solutions behave similarly to other
1330:
1281:
2683:. Vol. 1. New York City: Interscience.
2600:
2598:
2596:
2594:
2358:
2356:
1938:Anhydrous aluminium chloride is a powerful
4059:
4045:
4037:
3742:
3244:
3187:
3173:
3165:
2674:
2672:
2670:
1651:Aluminium chloride monomer belongs to the
1537:adopts three structures, depending on the
1419:
1396:
382:
253:
231:
31:
3054:"Aluminum Chloride (Topical) (Monograph)"
2746:
2578:has a more molecular structure, with the
2064:is acidic owing to the ionization of the
1074:3311 mg/kg, rat (oral, hexahydrate)
348:
341:
5683:
3734:
3730:
2574:
2476:NIOSH Pocket Guide to Chemical Hazards.
2285:
2246:
2242:
2238:
2234:
2230:
2205:
2201:
2180:
2176:
2168:
2164:
2130:
2126:
2086:
2082:
2078:
2074:
2060:
2042:
2038:
2034:
2030:
2026:
2016:
2012:
2008:
1965:
1732:
1681:
1677:
1625:
1614:
1600:
1596:
1585:
1581:
1570:
1566:
1548:
1533:
1474:
1470:
1466:
1455:
480:
3130:International Chemical Safety Card 1125
3083:International Mineralogical Association
2314:
2187:Aluminium chloride may be formed via a
1392:
438:
403:
378:
4089:
4067:Salts and covalent derivatives of the
2471:
2469:
2467:
2435:
2433:
2431:
2429:
1796:reaction is more widely used than the
1410:
1280:
1072:380 mg/kg, rat (oral, anhydrous)
244:
5389:
2511:
2509:
2507:
2443:CRC Handbook of Chemistry and Physics
2390:
2388:
2332:CRC Handbook of Chemistry and Physics
2324:
2322:
2320:
2318:
1942:, capable of forming Lewis acid-base
1902:, from certain metal halides via the
1621:, which is structurally analogous to
1303:
410:Key: VSCWAEJMTAWNJL-UHFFFAOYSA-K
211:
7:
4079:
2681:Friedel-Crafts and Related Reactions
2005:O molecules to form the hexahydrate
893:
1871:. For example, it can catalyse the
420:Key: VSCWAEJMTAWNJL-DFZHHIFOAR
296:
1726:Alkylation and acylation of arenes
407:InChI=1S/Al.3ClH/h;3*1H/q+3;;;/p-3
25:
2559:, United Kingdom.: Oxford Press.
2446:(92nd ed.). Boca Raton, FL:
2335:(92nd ed.). Boca Raton, FL:
1918:catalyzed by aluminium chloride.
417:InChI=1/Al.3ClH/h;3*1H/q+3;;;/p-3
1997:Anhydrous aluminium chloride is
1887:
1854:
1784:
1554:octahedral coordination geometry
1247:
926:
500:241.432 g/mol (hexahydrate)
38:
1977:Aluminium chloride reacts with
1486:, giving them a yellow colour.
1243:(at 25 °C , 100 kPa).
74:Aluminium trichloride unit cell
5774:Reagents for organic chemistry
5749:Drugs not assigned an ATC code
3799:Organoaluminium(III) compounds
2822:Upper Saddle River, New Jersey
2553:Structural Inorganic Chemistry
1989:forming tetrahydroaluminates.
1593:. At higher temperatures, the
1434:Aluminium chloride (data page)
1232:Aluminium chloride (data page)
497:133.341 g/mol (anhydrous)
1:
2528:10.1002/14356007.a01_527.pub2
2254:Aluminium also forms a lower
1589:dimers are also found in the
1084:(US health exposure limits):
531:2.398 g/cm (hexahydrate)
457:hexahydrate: ()()()()...
2370:. 2007-03-19. Archived from
2189:single displacement reaction
1671:The hexahydrate consists of
1545:(solid, liquid, gas). Solid
1480:water molecules of hydration
704: = 0.591 nm,
700: = 0.591 nm,
1910:is prepared by reaction of
1831:rings, for example via the
1659:in its monomeric form and D
1054:or concentration (LD, LC):
627:13.3 kPa (151 °C)
608:Slightly soluble in benzene
64:Aluminium trichloride dimer
55:
5800:
5391:
3032:10.1016/j.jaad.2018.11.066
2653:10.1524/zkri.1934.87.1.446
2412:10.1524/zkri.1935.90.1.237
2116:upon reaction with dilute
1875:, such as the addition of
708: = 1.752 nm
646:0.26 cP (237 °C)
643:0.35 cP (197 °C)
624:133.3 Pa (99 °C)
589:490 g/L (100 °C)
528:2.48 g/cm (anhydrous)
4091:
4076:
2993:American Family Physician
2851:Acidic and Basic Reagents
2611:Chemistry of the Elements
1879:(methyl vinyl ketone) to
1715:Friedel-Crafts alkylation
1494:. It is an example of an
1432:
1237:
1230:
1225:
1127:
1078:
1050:
907:
902:
876:
779:
653:
586:486 g/L (80 °C)
583:481 g/L (60 °C)
580:473 g/L (40 °C)
577:466 g/L (30 °C)
574:458 g/L (20 °C)
571:449 g/L (10 °C)
465:
429:
394:
111:
99:
89:
84:
54:
37:
2978:10.15227/orgsyn.031.0088
2951:10.15227/orgsyn.061.0062
2924:10.15227/orgsyn.059.0085
2803:10.15227/orgsyn.079.0204
2776:10.15227/orgsyn.080.0227
2748:10.15227/orgsyn.089.0210
2708:10.1002/cber.19330660817
1904:Fischer–Hafner synthesis
1833:Gattermann-Koch reaction
1742:Friedel-Crafts reactions
1226:Supplementary data page
965:Precautionary statements
568:439 g/L (0 °C)
2522:. Weinheim: Wiley-VCH.
2440:Haynes WM, ed. (2011).
2329:Haynes WM, ed. (2011).
2289:reacts vigorously with
2154:metal with chlorine or
1908:Dichlorophenylphosphine
1808:quantities, because it
1736:is a common Lewis-acid
1717:and related reactions.
452:: Cl1(Cl)(1)(Cl)Cl
102:Aluminium(III) chloride
5779:Deliquescent materials
3143:The period 3 chlorides
3079:www.ima-mineralogy.org
2303:Aluminium monochloride
2108:, giving a gelatinous
1930:(excessive sweating).
1916:phosphorus trichloride
1523:
1020:
75:
65:
2679:Olah GA, ed. (1963).
2608:, Earnshaw A (1984).
2260:aluminium(I) chloride
2175:2 Al + 6 HCl → 2 AlCl
1970:) in the presence of
1689:centers and chloride
1663:in its dimeric form.
1558:Yttrium(III) chloride
1521:
1510:at mild temperature.
1446:aluminium trichloride
1019:
823:109.3 J/(mol·K)
757:Tetrahedral (liquid)
750:Coordination geometry
512:Colourless crystals,
104:Aluminium trichloride
73:
63:
3116:. solvaychemicals.us
2101:containing hydrated
2052:metal aquo complexes
1993:Reactions with water
1960:tetrachloroaluminate
1900:bis(benzene)chromium
1637:poorly, unlike more
1186:Indium(III) chloride
1002:(fire diamond)
799:91.1 J/(mol·K)
5769:Inorganic compounds
5764:Aluminium compounds
3196:Aluminium compounds
2897:10.1021/ar50155a007
2222:aluminium hydroxide
2193:copper(II) chloride
2114:aluminium hydroxide
1285:
1181:Gallium trichloride
987:P305+P351+P338+P310
872:−628.8 kJ/mol
850:−704.2 kJ/mol
560:Solubility in water
353: (hexahydrate)
148: (hexahydrate)
34:
33:Aluminium chloride
3153:2011-07-22 at the
3114:Aluminium Chloride
3075:"List of Minerals"
2861:. pp. 12–15.
2499:Aluminium chloride
2266:Natural occurrence
1983:magnesium hydrides
1845:copper(I) chloride
1524:
1500:reversibly changes
1496:inorganic compound
1484:iron(III) chloride
1450:inorganic compound
1442:Aluminium chloride
1283:Aluminium chloride
1270:Infobox references
1212:Iron(III) chloride
1191:Magnesium chloride
1145:Aluminium fluoride
1128:Related compounds
1119:(Immediate danger)
1021:
755:Octahedral (solid)
190:hexahydrate:
94:Aluminium chloride
76:
66:
47:iron(III) chloride
32:
5736:
5735:
5730:
5729:
4034:
4033:
4030:
4029:
3274:
3273:
3085:. March 21, 2011.
2966:Organic Syntheses
2939:Organic Syntheses
2912:Organic Syntheses
2868:978-0-471-97925-8
2818:Organic Chemistry
2791:Organic Syntheses
2764:Organic Syntheses
2735:Organic Syntheses
2625:978-0-08-022057-4
2551:Wells AF (1984).
2495:Sigma-Aldrich Co.
2218:hydrochloric acid
2156:hydrogen chloride
2129:+ 3 NaOH → Al(OH)
2081:] ⇌ [Al(OH)(H
1869:organic chemistry
1841:hydrogen chloride
1780:system as shown:
1478:, containing six
1463:with the formula
1452:with the formula
1439:
1438:
1378:CompTox Dashboard
1332:aluminum chloride
1324:
1278:Chemical compound
1276:
1275:
1217:Boron trifluoride
1176:Boron trichloride
1150:Aluminium bromide
951:Hazard statements
857:Gibbs free energy
661:Crystal structure
363:CompTox Dashboard
193:Interactive image
185:Interactive image
174:Interactive image
132: (anhydrous)
106:Trichloroaluminum
80:
79:
27:Chemical compound
18:Aluminum chloride
16:(Redirected from
5791:
5686:
4080:
4061:
4054:
4047:
4038:
3854:
3853:
3852:
3844:
3843:
3835:
3834:
3743:
3737:
3245:
3189:
3182:
3175:
3166:
3117:
3111:
3105:
3104:
3093:
3087:
3086:
3071:
3062:
3061:
3050:
3044:
3043:
3015:
3009:
3008:
2988:
2982:
2981:
2961:
2955:
2954:
2934:
2928:
2927:
2907:
2901:
2900:
2879:
2873:
2872:
2846:
2840:
2839:
2820:(5th ed.).
2816:Wade LG (2003).
2813:
2807:
2806:
2786:
2780:
2779:
2759:
2753:
2752:
2750:
2726:
2720:
2719:
2702:(8): 1097–1100.
2691:
2685:
2684:
2676:
2665:
2664:
2636:
2630:
2629:
2602:
2589:
2588:
2585:
2581:
2577:
2548:
2542:
2541:
2513:
2502:
2492:
2486:
2485:
2473:
2462:
2461:
2437:
2424:
2423:
2406:(1–6): 237–255.
2392:
2383:
2382:
2380:
2379:
2360:
2351:
2350:
2339:. p. 4.45.
2326:
2288:
2250:
2209:
2183:
2171:
2137:
2118:sodium hydroxide
2104:
2090:
2063:
2046:
2019:
1969:
1891:
1858:
1788:
1735:
1696:
1685:
1628:
1617:
1603:
1588:
1573:
1551:
1536:
1477:
1458:
1444:, also known as
1423:
1412:
1401:
1400:
1386:
1384:
1334:
1323:
1320:
1307:
1286:
1284:
1260:
1254:
1251:
1250:
1155:Aluminium iodide
1041:
1034:
1027:
1012:
992:
988:
984:
980:
976:
972:
958:
930:
897:
868:
846:
819:
795:
780:Thermochemistry
769:Trigonal planar
726:0.52996 nm
691:Lattice constant
483:
473:Chemical formula
387:
386:
371:
369:
352:
345:
309:
298:
282:Gmelin Reference
265:
257:
246:
235:
215:
195:
187:
176:
147:
139:
131:
56:
42:
35:
21:
5799:
5798:
5794:
5793:
5792:
5790:
5789:
5788:
5739:
5738:
5737:
5732:
5731:
5725:
5717:
5709:
5701:
5696:
5694:
5685:
5681:
5679:
5677:
5669:
5661:
5653:
5648:
5646:
5638:
5630:
5622:
5617:
5615:
5610:
5608:
5603:
5601:
5593:
5588:
5586:
5578:
5573:
5571:
5563:
5550:
5545:
5543:
5535:
5530:
5528:
5520:
5512:
5504:
5499:
5497:
5489:
5481:
5473:
5468:
5466:
5458:
5453:
5451:
5443:
5435:
5430:
5428:
5420:
5412:
5404:
5350:
5342:
5338:
5330:
5322:
5314:
5303:
5280:
5275:
5273:
5265:
5257:
5252:
5250:
5242:
5237:
5230:
5225:
5223:
5219:
5211:
5206:
5204:
5199:
5192:
5187:
5185:
5177:
5172:
5170:
5165:
5163:
5155:
5150:
5148:
5143:
5141:
5136:
5134:
5126:
5121:
5119:
5114:
5112:
5107:
5105:
5097:
5092:
5090:
5085:
5083:
5078:
5076:
5071:
5069:
5061:
5056:
5054:
5049:
5047:
5039:
5031:
5020:
5005:
5000:
4998:
4993:
4986:
4981:
4974:
4969:
4967:
4962:
4960:
4956:
4948:
4943:
4941:
4933:
4928:
4926:
4918:
4913:
4911:
4906:
4899:
4886:
4878:
4870:
4865:
4863:
4858:
4856:
4848:
4843:
4841:
4833:
4828:
4826:
4821:
4819:
4814:
4812:
4807:
4805:
4797:
4792:
4790:
4785:
4783:
4775:
4770:
4768:
4763:
4761:
4753:
4743:
4720:
4715:
4713:
4708:
4706:
4702:
4692:
4690:
4685:
4683:
4675:
4670:
4668:
4660:
4655:
4648:
4640:
4635:
4628:
4620:
4615:
4613:
4605:
4600:
4598:
4590:
4585:
4583:
4575:
4570:
4568:
4563:
4561:
4553:
4548:
4546:
4541:
4539:
4534:
4532:
4524:
4519:
4517:
4512:
4510:
4502:
4492:
4487:
4470:
4462:
4457:
4455:
4450:
4448:
4443:
4441:
4437:
4427:
4425:
4420:
4418:
4413:
4411:
4407:
4399:
4394:
4392:
4388:
4383:
4381:
4377:
4369:
4364:
4357:
4339:
4334:
4332:
4327:
4318:
4316:
4311:
4309:
4305:
4300:
4298:
4294:
4289:
4287:
4283:
4278:
4276:
4271:
4267:
4265:
4261:
4256:
4253:
4248:
4246:
4242:
4234:
4229:
4225:
4223:
4218:
4216:
4208:
4203:
4199:
4197:
4192:
4190:
4186:
4181:
4179:
4175:
4170:
4168:
4164:
4156:
4151:
4149:
4145:
4140:
4138:
4133:
4131:
4127:
4122:
4120:
4116:
4108:
4072:
4065:
4035:
4026:
4022:
4018:
4014:
4010:
4006:
4002:
3993:
3989:
3985:
3981:
3977:
3973:
3964:
3960:
3956:
3952:
3943:
3939:
3935:
3926:
3922:
3918:
3910:
3906:
3902:
3898:
3890:
3886:
3882:
3878:
3870:
3866:
3862:
3851:
3848:
3847:
3846:
3842:
3839:
3838:
3837:
3833:
3830:
3829:
3828:
3826:
3821:
3817:
3813:
3809:
3794:
3790:
3786:
3778:
3774:
3766:
3762:
3758:
3741:
3736:
3732:
3728:
3723:
3719:
3715:
3711:
3703:
3699:
3695:
3691:
3687:
3679:
3675:
3671:
3667:
3663:
3655:
3651:
3647:
3643:
3630:
3626:
3618:
3610:
3606:
3598:
3594:
3586:
3582:
3574:
3570:
3566:
3558:
3554:
3546:
3542:
3534:
3530:
3526:
3518:
3514:
3506:
3502:
3498:
3494:
3481:
3468:
3464:
3460:
3452:
3444:
3435:
3427:
3419:
3415:
3411:
3403:
3399:
3386:
3378:
3370:
3362:
3354:
3346:
3338:
3330:
3326:
3306:
3297:
3289:
3270:
3267:
3263:
3259:
3249:Organoaluminium
3243:
3233:
3198:
3193:
3155:Wayback Machine
3138:
3126:
3121:
3120:
3112:
3108:
3097:"Cadwaladerite"
3095:
3094:
3090:
3073:
3072:
3065:
3052:
3051:
3047:
3017:
3016:
3012:
2999:(11): 729–734.
2990:
2989:
2985:
2963:
2962:
2958:
2936:
2935:
2931:
2909:
2908:
2904:
2885:Acc. Chem. Res.
2881:
2880:
2876:
2869:
2848:
2847:
2843:
2836:
2815:
2814:
2810:
2788:
2787:
2783:
2761:
2760:
2756:
2728:
2727:
2723:
2693:
2692:
2688:
2678:
2677:
2668:
2638:
2637:
2633:
2626:
2604:
2603:
2592:
2583:
2579:
2576:
2572:
2567:
2550:
2549:
2545:
2538:
2515:
2514:
2505:
2493:
2489:
2475:
2474:
2465:
2458:
2450:. p. 5.5.
2439:
2438:
2427:
2394:
2393:
2386:
2377:
2375:
2362:
2361:
2354:
2347:
2328:
2327:
2316:
2311:
2299:
2287:
2283:
2280:
2268:
2248:
2244:
2240:
2236:
2232:
2228:
2207:
2203:
2199:
2195:and aluminium.
2182:
2178:
2174:
2170:
2166:
2162:
2144:
2132:
2128:
2124:
2102:
2088:
2084:
2080:
2076:
2072:
2062:
2058:
2044:
2040:
2036:
2032:
2028:
2024:
2018:
2014:
2010:
2006:
2004:
1995:
1987:tetrahydrofuran
1967:
1963:
1946:with even weak
1936:
1924:
1865:
1837:carbon monoxide
1776:reacts with an
1760:industry) from
1734:
1730:
1728:
1723:
1694:
1683:
1679:
1675:
1669:
1662:
1658:
1646:sodium chloride
1627:
1623:
1616:
1612:
1610:trigonal planar
1602:
1598:
1594:
1587:
1583:
1579:
1576:tetracoordinate
1572:
1568:
1564:
1550:
1546:
1535:
1531:
1529:
1516:
1476:
1472:
1468:
1464:
1457:
1453:
1404:
1380:
1367:
1344:
1337:
1279:
1272:
1267:
1266:
1265: ?)
1256:
1252:
1248:
1244:
1221:
1205:
1195:
1169:
1159:
1138:
1120:
1107:
1094:
1073:
1069:
1063:
1046:
1045:
1044:
1043:
1036:
1029:
1022:
1018:
1010:
967:
953:
939:
923:
886:
869:
863:
859:
847:
844:
838:
834:
831:
830:Std enthalpy of
820:
817:
810:
807:
796:
789:
770:
766:
764:Molecular shape
756:
752:
740:
723:
709:
693:
684:C12/m1, No. 12
681:
663:
649:
630:
611:
592:
562:
553:
534:
503:
482:
478:
475:
461:
458:
453:
445:
444:: Cl(Cl)Cl
437:
436:
425:
422:
421:
418:
412:
411:
408:
402:
401:
390:
372:
365:
356:
328:
312:
299:
284:
275:
238:
218:
198:
162:
151:
140: (hydrate)
121:
107:
105:
103:
95:
50:
43:
28:
23:
22:
15:
12:
11:
5:
5797:
5795:
5787:
5786:
5784:Acid catalysts
5781:
5776:
5771:
5766:
5761:
5756:
5751:
5741:
5740:
5734:
5733:
5728:
5727:
5723:
5719:
5715:
5711:
5707:
5703:
5699:
5692:
5688:
5675:
5671:
5667:
5663:
5659:
5655:
5651:
5644:
5640:
5636:
5632:
5628:
5624:
5620:
5613:
5606:
5599:
5595:
5591:
5584:
5580:
5576:
5569:
5565:
5561:
5557:
5553:
5552:
5548:
5541:
5537:
5533:
5526:
5522:
5518:
5514:
5510:
5506:
5502:
5495:
5491:
5487:
5483:
5479:
5475:
5471:
5464:
5460:
5456:
5449:
5445:
5441:
5437:
5433:
5426:
5422:
5418:
5414:
5410:
5406:
5402:
5398:
5394:
5393:
5390:
5387:
5386:
5383:
5380:
5377:
5374:
5371:
5368:
5365:
5362:
5359:
5356:
5353:
5348:
5344:
5340:
5336:
5332:
5328:
5324:
5320:
5316:
5312:
5308:
5305:
5301:
5297:
5291:
5290:
5287:
5282:
5278:
5271:
5267:
5263:
5259:
5255:
5248:
5244:
5240:
5232:
5228:
5221:
5217:
5213:
5209:
5202:
5194:
5190:
5183:
5179:
5175:
5168:
5161:
5157:
5153:
5146:
5139:
5132:
5128:
5124:
5117:
5110:
5103:
5099:
5095:
5088:
5081:
5074:
5067:
5063:
5059:
5052:
5045:
5041:
5037:
5033:
5029:
5025:
5022:
5018:
5014:
5008:
5007:
5003:
4996:
4988:
4984:
4976:
4972:
4965:
4958:
4954:
4950:
4946:
4939:
4935:
4931:
4924:
4920:
4916:
4909:
4901:
4897:
4893:
4888:
4884:
4880:
4876:
4872:
4868:
4861:
4854:
4850:
4846:
4839:
4835:
4831:
4824:
4817:
4810:
4803:
4799:
4795:
4788:
4781:
4777:
4773:
4766:
4759:
4755:
4751:
4747:
4745:
4741:
4737:
4731:
4730:
4727:
4722:
4718:
4711:
4704:
4700:
4696:
4688:
4681:
4677:
4673:
4666:
4662:
4658:
4650:
4646:
4642:
4638:
4630:
4626:
4622:
4618:
4611:
4607:
4603:
4596:
4592:
4588:
4581:
4577:
4573:
4566:
4559:
4555:
4551:
4544:
4537:
4530:
4526:
4522:
4515:
4508:
4504:
4500:
4496:
4494:
4490:
4482:
4476:
4475:
4472:
4468:
4464:
4460:
4453:
4446:
4439:
4435:
4431:
4423:
4416:
4409:
4405:
4401:
4397:
4390:
4386:
4379:
4375:
4371:
4367:
4359:
4355:
4351:
4345:
4344:
4341:
4337:
4330:
4322:
4314:
4307:
4303:
4296:
4292:
4285:
4281:
4274:
4263:
4259:
4251:
4244:
4240:
4236:
4232:
4221:
4214:
4210:
4206:
4195:
4188:
4184:
4177:
4173:
4166:
4162:
4158:
4154:
4147:
4143:
4136:
4129:
4125:
4118:
4114:
4110:
4106:
4102:
4096:
4095:
4092:
4090:
4088:
4086:
4078:
4077:
4074:
4073:
4066:
4064:
4063:
4056:
4049:
4041:
4032:
4031:
4028:
4027:
4025:
4024:
4020:
4016:
4012:
4008:
4004:
4000:
3996:
3991:
3987:
3983:
3979:
3975:
3971:
3967:
3962:
3958:
3954:
3950:
3946:
3941:
3937:
3933:
3929:
3924:
3920:
3916:
3912:
3908:
3904:
3900:
3896:
3892:
3888:
3884:
3880:
3876:
3872:
3868:
3864:
3860:
3856:
3849:
3840:
3831:
3823:
3819:
3815:
3811:
3807:
3802:
3800:
3796:
3795:
3793:
3792:
3788:
3784:
3780:
3776:
3772:
3768:
3764:
3760:
3756:
3751:
3749:
3740:
3739:
3725:
3721:
3717:
3713:
3709:
3705:
3701:
3697:
3693:
3689:
3685:
3681:
3677:
3673:
3669:
3665:
3661:
3657:
3653:
3649:
3645:
3641:
3637:
3632:
3628:
3624:
3620:
3616:
3612:
3608:
3604:
3600:
3596:
3592:
3588:
3584:
3580:
3576:
3572:
3568:
3564:
3560:
3556:
3552:
3548:
3544:
3540:
3536:
3532:
3528:
3524:
3520:
3516:
3512:
3508:
3504:
3500:
3496:
3492:
3488:
3483:
3479:
3475:
3470:
3466:
3462:
3458:
3454:
3450:
3446:
3442:
3438:
3433:
3429:
3425:
3421:
3417:
3413:
3409:
3405:
3401:
3397:
3393:
3388:
3384:
3380:
3376:
3372:
3368:
3364:
3360:
3356:
3352:
3348:
3344:
3340:
3336:
3332:
3328:
3324:
3320:
3314:
3312:
3308:
3307:
3305:
3304:
3299:
3295:
3291:
3287:
3282:
3280:
3276:
3275:
3272:
3271:
3265:
3261:
3257:
3254:
3252:
3242:
3241:
3236:
3231:
3227:
3222:
3217:
3212:
3206:
3204:
3200:
3199:
3194:
3192:
3191:
3184:
3177:
3169:
3163:
3162:
3157:
3145:
3140:
3136:
3132:
3125:
3124:External links
3122:
3119:
3118:
3106:
3101:www.mindat.org
3088:
3063:
3045:
3026:(3): 669–680.
3010:
2983:
2956:
2929:
2902:
2874:
2867:
2841:
2834:
2808:
2781:
2754:
2721:
2686:
2666:
2631:
2624:
2616:Pergamon Press
2590:
2565:
2543:
2537:978-3527306732
2536:
2503:
2487:
2463:
2456:
2425:
2384:
2352:
2345:
2313:
2312:
2310:
2307:
2306:
2305:
2298:
2295:
2279:
2276:
2267:
2264:
2252:
2251:
2211:
2210:
2185:
2184:
2172:
2143:
2140:
2139:
2138:
2092:
2091:
2048:
2047:
2002:
1994:
1991:
1935:
1932:
1923:
1920:
1893:
1892:
1864:
1861:
1860:
1859:
1806:stoichiometric
1790:
1789:
1727:
1724:
1722:
1719:
1703:Hydrogen bonds
1668:
1665:
1660:
1656:
1528:
1525:
1515:
1512:
1437:
1436:
1430:
1429:
1425:
1424:
1414:
1406:
1405:
1403:
1402:
1389:
1387:
1374:
1373:
1369:
1368:
1366:
1365:
1361:
1359:
1353:
1352:
1347:
1345:administration
1339:
1338:
1336:
1335:
1317:
1315:
1309:
1308:
1301:
1291:
1290:
1277:
1274:
1273:
1268:
1246:
1245:
1241:standard state
1238:
1235:
1234:
1228:
1227:
1223:
1222:
1220:
1219:
1214:
1208:
1206:
1200:
1197:
1196:
1194:
1193:
1188:
1183:
1178:
1172:
1170:
1164:
1161:
1160:
1158:
1157:
1152:
1147:
1141:
1139:
1133:
1130:
1129:
1125:
1124:
1121:
1115:
1112:
1111:
1108:
1102:
1099:
1098:
1095:
1089:
1086:
1085:
1076:
1075:
1070:
1061:
1059:
1056:
1055:
1048:
1047:
1037:
1030:
1023:
1008:
1007:
1006:
1005:
1003:
994:
993:
983:P303+P361+P353
979:P301+P330+P331
968:
963:
960:
959:
954:
949:
946:
945:
940:
935:
932:
931:
924:
919:
916:
915:
905:
904:
900:
899:
887:
882:
879:
878:
874:
873:
870:
861:
855:
852:
851:
848:
842:
836:
828:
825:
824:
821:
815:
804:
801:
800:
797:
785:
782:
781:
777:
776:
767:
762:
759:
758:
753:
748:
745:
744:
741:
731:
728:
727:
724:
716:Lattice volume
714:
711:
710:
696:
694:
689:
686:
685:
682:
677:
674:
673:
664:
659:
656:
655:
651:
650:
648:
647:
644:
640:
638:
632:
631:
629:
628:
625:
621:
619:
617:Vapor pressure
613:
612:
610:
609:
606:
602:
600:
594:
593:
591:
590:
587:
584:
581:
578:
575:
572:
569:
565:
563:
558:
555:
554:
552:
551:
548:
544:
542:
536:
535:
533:
532:
529:
525:
523:
517:
516:
510:
506:
505:
504:
502:
501:
498:
494:
492:
486:
485:
476:
471:
468:
467:
463:
462:
460:
459:
456:
454:
448:
446:
440:
432:
431:
430:
427:
426:
424:
423:
419:
416:
415:
413:
409:
406:
405:
397:
396:
395:
392:
391:
389:
388:
375:
373:
361:
358:
357:
355:
354:
346:
338:
336:
330:
329:
327:
326:
322:
320:
314:
313:
311:
310:
302:
300:
292:
289:
288:
285:
280:
277:
276:
274:
273:
269:
267:
259:
258:
248:
240:
239:
237:
236:
228:
226:
220:
219:
217:
216:
208:
206:
200:
199:
197:
196:
188:
177:
165:
163:
156:
153:
152:
150:
149:
141:
133:
124:
122:
117:
114:
113:
109:
108:
101:
97:
96:
93:
87:
86:
82:
81:
78:
77:
67:
52:
51:
44:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
5796:
5785:
5782:
5780:
5777:
5775:
5772:
5770:
5767:
5765:
5762:
5760:
5759:Metal halides
5757:
5755:
5752:
5750:
5747:
5746:
5744:
5726:
5720:
5718:
5712:
5710:
5704:
5702:
5695:
5689:
5687:
5678:
5672:
5670:
5664:
5662:
5656:
5654:
5647:
5641:
5639:
5633:
5631:
5625:
5623:
5616:
5609:
5602:
5596:
5594:
5587:
5581:
5579:
5572:
5566:
5564:
5558:
5555:
5554:
5551:
5544:
5538:
5536:
5529:
5523:
5521:
5515:
5513:
5507:
5505:
5498:
5492:
5490:
5484:
5482:
5476:
5474:
5467:
5461:
5459:
5452:
5446:
5444:
5438:
5436:
5429:
5423:
5421:
5415:
5413:
5407:
5405:
5399:
5396:
5395:
5388:
5384:
5381:
5378:
5375:
5372:
5369:
5366:
5363:
5360:
5357:
5354:
5352:
5345:
5343:
5333:
5331:
5325:
5323:
5317:
5315:
5309:
5306:
5304:
5298:
5296:
5293:
5292:
5288:
5286:
5283:
5281:
5274:
5268:
5266:
5260:
5258:
5251:
5245:
5243:
5236:
5233:
5231:
5224:
5214:
5212:
5205:
5198:
5195:
5193:
5186:
5180:
5178:
5171:
5164:
5158:
5156:
5149:
5142:
5135:
5129:
5127:
5120:
5113:
5106:
5100:
5098:
5091:
5084:
5077:
5070:
5064:
5062:
5055:
5048:
5042:
5040:
5034:
5032:
5026:
5023:
5021:
5015:
5013:
5010:
5009:
5006:
4999:
4992:
4989:
4987:
4980:
4977:
4975:
4968:
4961:
4951:
4949:
4942:
4936:
4934:
4927:
4921:
4919:
4912:
4905:
4902:
4900:
4894:
4892:
4889:
4887:
4881:
4879:
4873:
4871:
4864:
4857:
4851:
4849:
4842:
4836:
4834:
4827:
4820:
4813:
4806:
4800:
4798:
4791:
4784:
4778:
4776:
4769:
4762:
4756:
4754:
4748:
4746:
4744:
4738:
4736:
4733:
4732:
4728:
4726:
4723:
4721:
4714:
4707:
4697:
4695:
4691:
4684:
4678:
4676:
4669:
4663:
4661:
4654:
4651:
4649:
4643:
4641:
4634:
4631:
4629:
4623:
4621:
4614:
4608:
4606:
4599:
4593:
4591:
4584:
4578:
4576:
4569:
4562:
4556:
4554:
4547:
4540:
4533:
4527:
4525:
4518:
4511:
4505:
4503:
4497:
4495:
4493:
4486:
4483:
4481:
4478:
4477:
4473:
4471:
4465:
4463:
4456:
4449:
4442:
4432:
4430:
4426:
4419:
4412:
4402:
4400:
4393:
4382:
4372:
4370:
4363:
4360:
4358:
4352:
4350:
4347:
4346:
4342:
4340:
4333:
4326:
4323:
4321:
4317:
4310:
4299:
4288:
4277:
4270:
4266:
4255:
4247:
4237:
4235:
4228:
4224:
4217:
4211:
4209:
4202:
4198:
4191:
4180:
4169:
4159:
4157:
4150:
4139:
4132:
4121:
4111:
4109:
4103:
4101:
4098:
4097:
4093:
4087:
4085:
4082:
4081:
4075:
4070:
4062:
4057:
4055:
4050:
4048:
4043:
4042:
4039:
4023:
3997:
3995:
3968:
3966:
3947:
3945:
3930:
3928:
3913:
3911:
3893:
3891:
3873:
3871:
3857:
3855:
3824:
3822:
3804:
3803:
3801:
3797:
3791:
3781:
3779:
3769:
3767:
3753:
3752:
3750:
3748:
3744:
3738:
3726:
3724:
3706:
3704:
3682:
3680:
3658:
3656:
3638:
3636:
3633:
3631:
3621:
3619:
3613:
3611:
3601:
3599:
3589:
3587:
3577:
3575:
3561:
3559:
3549:
3547:
3537:
3535:
3521:
3519:
3509:
3507:
3489:
3487:
3484:
3482:
3476:
3474:
3471:
3469:
3455:
3453:
3447:
3445:
3439:
3437:
3430:
3428:
3422:
3420:
3406:
3404:
3394:
3392:
3389:
3387:
3381:
3379:
3373:
3371:
3365:
3363:
3357:
3355:
3349:
3347:
3341:
3339:
3333:
3331:
3321:
3319:
3316:
3315:
3313:
3309:
3303:
3300:
3298:
3292:
3290:
3284:
3283:
3281:
3277:
3269:
3253:
3251:(I) compounds
3250:
3246:
3240:
3237:
3235:
3228:
3226:
3223:
3221:
3218:
3216:
3213:
3211:
3208:
3207:
3205:
3201:
3197:
3190:
3185:
3183:
3178:
3176:
3171:
3170:
3167:
3161:
3158:
3156:
3152:
3149:
3146:
3144:
3141:
3139:
3133:
3131:
3128:
3127:
3123:
3115:
3110:
3107:
3102:
3098:
3092:
3089:
3084:
3080:
3076:
3070:
3068:
3064:
3059:
3055:
3049:
3046:
3041:
3037:
3033:
3029:
3025:
3021:
3014:
3011:
3006:
3002:
2998:
2994:
2987:
2984:
2979:
2975:
2971:
2967:
2960:
2957:
2952:
2948:
2944:
2940:
2933:
2930:
2925:
2921:
2917:
2913:
2906:
2903:
2898:
2894:
2890:
2887:
2886:
2878:
2875:
2870:
2864:
2860:
2856:
2855:New York City
2852:
2845:
2842:
2837:
2831:
2827:
2826:Prentice Hall
2823:
2819:
2812:
2809:
2804:
2800:
2796:
2792:
2785:
2782:
2777:
2773:
2769:
2765:
2758:
2755:
2749:
2744:
2740:
2736:
2732:
2725:
2722:
2717:
2713:
2709:
2705:
2701:
2697:
2690:
2687:
2682:
2675:
2673:
2671:
2667:
2662:
2658:
2654:
2650:
2646:
2642:
2635:
2632:
2627:
2621:
2617:
2613:
2612:
2607:
2601:
2599:
2597:
2595:
2591:
2587:
2571:In contrast,
2568:
2562:
2558:
2554:
2547:
2544:
2539:
2533:
2529:
2525:
2521:
2520:
2512:
2510:
2508:
2504:
2500:
2496:
2491:
2488:
2483:
2479:
2472:
2470:
2468:
2464:
2459:
2457:1-4398-5511-0
2453:
2449:
2445:
2444:
2436:
2434:
2432:
2430:
2426:
2421:
2417:
2413:
2409:
2405:
2401:
2397:
2391:
2389:
2385:
2374:on 2014-05-05
2373:
2369:
2365:
2359:
2357:
2353:
2348:
2346:1-4398-5511-0
2342:
2338:
2334:
2333:
2325:
2323:
2321:
2319:
2315:
2308:
2304:
2301:
2300:
2296:
2294:
2292:
2277:
2275:
2273:
2272:cadwaladerite
2265:
2263:
2261:
2257:
2245:+ 3 HCl + 3 H
2227:
2226:
2225:
2224:when heated:
2223:
2219:
2214:
2200:2 Al + 3 CuCl
2198:
2197:
2196:
2194:
2190:
2173:
2161:
2160:
2159:
2157:
2153:
2149:
2141:
2136:
2123:
2122:
2121:
2119:
2115:
2111:
2107:
2100:
2097:
2071:
2070:
2069:
2067:
2057:
2053:
2041:+ 3 HCl + 3 H
2023:
2022:
2021:
2000:
1992:
1990:
1988:
1984:
1980:
1975:
1973:
1961:
1957:
1953:
1949:
1945:
1941:
1933:
1931:
1929:
1928:hyperhidrosis
1921:
1919:
1917:
1913:
1909:
1905:
1901:
1896:
1890:
1886:
1885:
1884:
1882:
1878:
1877:3-buten-2-one
1874:
1870:
1862:
1857:
1853:
1852:
1851:
1849:
1846:
1842:
1838:
1834:
1830:
1826:
1821:
1819:
1815:
1811:
1807:
1802:
1799:
1795:
1787:
1783:
1782:
1781:
1779:
1775:
1771:
1770:acyl chloride
1767:
1763:
1759:
1756:(used in the
1755:
1754:anthraquinone
1751:
1747:
1743:
1739:
1725:
1720:
1718:
1716:
1712:
1708:
1704:
1700:
1692:
1688:
1674:
1666:
1664:
1654:
1649:
1647:
1643:
1640:
1636:
1633:
1629:
1620:
1611:
1607:
1592:
1577:
1563:
1559:
1555:
1544:
1540:
1526:
1520:
1513:
1511:
1509:
1505:
1501:
1497:
1493:
1487:
1485:
1481:
1462:
1459:. It forms a
1451:
1447:
1443:
1435:
1431:
1426:
1422:
1418:
1415:
1413:
1411:ECHA InfoCard
1407:
1399:
1395:
1394:DTXSID6029674
1391:
1390:
1388:
1379:
1375:
1370:
1363:
1362:
1360:
1358:
1354:
1351:
1348:
1346:
1340:
1333:
1328:
1319:
1318:
1316:
1314:
1310:
1306:
1302:
1300:
1296:
1292:
1289:Clinical data
1287:
1271:
1264:
1259:
1242:
1236:
1233:
1229:
1224:
1218:
1215:
1213:
1210:
1209:
1207:
1204:
1199:
1198:
1192:
1189:
1187:
1184:
1182:
1179:
1177:
1174:
1173:
1171:
1168:
1163:
1162:
1156:
1153:
1151:
1148:
1146:
1143:
1142:
1140:
1137:
1132:
1131:
1126:
1122:
1118:
1114:
1113:
1109:
1106:(Recommended)
1105:
1101:
1100:
1096:
1093:(Permissible)
1092:
1088:
1087:
1083:
1082:
1077:
1071:
1067:
1058:
1057:
1053:
1049:
1042:
1035:
1028:
1004:
1001:
1000:
996:
995:
969:
966:
962:
961:
955:
952:
948:
947:
944:
941:
938:
934:
933:
929:
925:
922:
918:
917:
913:
911:
906:
901:
896:
891:
888:
885:
881:
880:
877:Pharmacology
875:
871:
866:
858:
854:
853:
849:
841:
833:
827:
826:
822:
814:
809:
803:
802:
798:
793:
788:
787:Heat capacity
784:
783:
778:
774:
768:
765:
761:
760:
754:
751:
747:
746:
742:
738:
734:
733:Formula units
730:
729:
725:
721:
717:
713:
712:
707:
703:
699:
695:
692:
688:
687:
683:
680:
676:
675:
672:
668:
665:
662:
658:
657:
652:
645:
642:
641:
639:
637:
634:
633:
626:
623:
622:
620:
618:
615:
614:
607:
604:
603:
601:
599:
596:
595:
588:
585:
582:
579:
576:
573:
570:
567:
566:
564:
561:
557:
556:
549:
546:
545:
543:
541:
540:Melting point
538:
537:
530:
527:
526:
524:
522:
519:
518:
515:
511:
508:
507:
499:
496:
495:
493:
491:
488:
487:
477:
474:
470:
469:
464:
455:
451:
447:
443:
439:
435:
428:
414:
404:
400:
393:
385:
381:
380:DTXSID6029674
377:
376:
374:
364:
360:
359:
351:
347:
344:
340:
339:
337:
335:
332:
331:
324:
323:
321:
319:
316:
315:
308:
304:
303:
301:
295:
291:
290:
286:
283:
279:
278:
271:
270:
268:
266:
261:
260:
256:
252:
249:
247:
245:ECHA InfoCard
242:
241:
234:
230:
229:
227:
225:
222:
221:
214:
210:
209:
207:
205:
202:
201:
194:
189:
186:
181:
178:
175:
170:
167:
166:
164:
160:
155:
154:
146:
142:
138:
134:
130:
126:
125:
123:
120:
116:
115:
110:
98:
92:
88:
83:
72:
68:
62:
58:
57:
53:
48:
41:
36:
30:
19:
4365:
3350:
3109:
3100:
3091:
3078:
3060:. drugs.com.
3057:
3048:
3023:
3019:
3013:
2996:
2992:
2986:
2969:
2965:
2959:
2942:
2938:
2932:
2915:
2911:
2905:
2888:
2883:
2877:
2850:
2844:
2817:
2811:
2794:
2790:
2784:
2767:
2763:
2757:
2738:
2734:
2724:
2699:
2695:
2689:
2680:
2644:
2640:
2634:
2610:
2606:Greenwood NN
2570:
2552:
2546:
2517:
2490:
2441:
2403:
2399:
2376:. Retrieved
2372:the original
2368:Chemister.ru
2367:
2330:
2281:
2269:
2253:
2215:
2212:
2186:
2150:reaction of
2145:
2093:
2066:aquo ligands
2049:
1996:
1976:
1952:benzophenone
1937:
1925:
1897:
1894:
1873:ene reaction
1866:
1827:groups onto
1822:
1803:
1791:
1774:alkyl halide
1750:ethylbenzene
1729:
1707:water ligand
1670:
1650:
1591:vapour phase
1530:
1488:
1445:
1441:
1440:
1313:License data
1110:2 mg/m
1080:
1051:
998:
942:
909:
864:
839:
812:
791:
736:
719:
705:
701:
697:
318:RTECS number
112:Identifiers
100:Other names
29:
3441:Al(OH)(OAc)
2891:(11): 426.
2396:Ketelaar JA
2163:2 Al + 3 Cl
2110:precipitate
1999:hygroscopic
1958:. It forms
1948:Lewis bases
1848:co-catalyst
1835:which uses
1801:of arenes.
1699:counterions
1667:Hexahydrate
1653:point group
1635:electricity
1630:. The melt
1539:temperature
1461:hexahydrate
1417:100.028.371
1372:Identifiers
1203:Lewis acids
1066:median dose
1052:Lethal dose
937:Signal word
679:Space group
514:hygroscopic
509:Appearance
466:Properties
251:100.028.371
213:CHEBI:30114
5743:Categories
2835:013033832X
2614:. Oxford:
2566:0198553706
2378:2017-03-17
2309:References
2282:Anhydrous
2148:exothermic
1956:mesitylene
1940:Lewis acid
1794:alkylation
1746:detergents
1673:octahedral
1606:dissociate
1492:Lewis acid
921:Pictograms
667:Monoclinic
654:Structure
598:Solubility
490:Molar mass
350:3CYT62D3GA
343:LIF1N9568Y
224:ChemSpider
157:3D model (
137:10124-27-3
119:CAS Number
91:IUPAC name
5754:Chlorides
2716:1099-0682
2661:263857074
2448:CRC Press
2420:100796636
2337:CRC Press
2229:[Al(H
2152:aluminium
2142:Synthesis
2096:aluminium
2073:[Al(H
2025:[Al(H
2007:[Al(H
1964:[AlCl
1934:Reactions
1814:corrosive
1810:complexes
1798:acylation
1758:dyestuffs
1676:[Al(H
1527:Anhydrous
1514:Structure
1465:[Al(H
1428:Data page
1343:Routes of
1305:Monograph
1299:Drugs.com
912:labelling
832:formation
806:Std molar
773:monomeric
636:Viscosity
325:BD0530000
272:231-208-1
264:EC Number
145:7784-13-6
129:7446-70-0
4069:chloride
3151:Archived
3040:30710603
3005:30215934
2484:(NIOSH).
2297:See also
2256:chloride
2241:→ Al(OH)
2204:→ 2 AlCl
2191:between
2167:→ 2 AlCl
2037:→ Al(OH)
1972:chloride
1950:such as
1829:aromatic
1825:aldehyde
1818:zeolites
1778:aromatic
1766:phosgene
1738:catalyst
1711:catalyst
1644:such as
1632:conducts
1541:and the
1448:, is an
1357:ATC code
1327:DailyMed
1201:Related
999:NFPA 704
903:Hazards
898:)
884:ATC code
775:vapour)
49:(bottom)
5392:
4015:ClAl(CH
3783:NaAl(SO
3449:Al(OAc)
3311:Al(III)
2797:: 204.
2770:: 227.
2741:: 210.
2478:"#0024"
2056:aqueous
1979:calcium
1944:adducts
1922:Medical
1912:benzene
1881:carvone
1762:benzene
1642:halides
1619:monomer
1604:dimers
1574:, with
1508:monomer
1504:polymer
1502:from a
1350:Topical
1329::
1263:what is
1261: (
1167:cations
892: (
890:D10AX01
860:(Δ
808:entropy
521:Density
484:
442:monomer
294:PubChem
182::
171::
169:monomer
3859:(Al(CH
3771:KAl(SO
3759:)Al(SO
3640:Al(OH)
3511:Al(MnO
3432:Al(OH)
3424:Al(OH)
3359:NaAlCl
3343:Al(CN)
3279:Al(II)
3038:
3003:
2972:: 88.
2945:: 62.
2918:: 85.
2865:
2832:
2714:
2659:
2622:
2563:
2557:Oxford
2534:
2454:
2418:
2343:
2278:Safety
2208:+ 3 Cu
1974:ions.
1843:and a
1691:anions
1687:cation
1325:
1258:verify
1255:
1165:Other
1136:anions
1134:Other
943:Danger
434:SMILES
85:Names
3953:CH(CH
3949:Al(CH
3899:CH(CH
3895:Al(CH
3875:(Al(C
3747:Alums
3684:LiAlH
3660:NaAlH
3635:AlOHO
3615:AlAsO
3465:(OAc)
3396:Al(NO
3323:Al(BH
3203:Al(I)
2859:Wiley
2657:S2CID
2586:ions.
2416:S2CID
2291:bases
2179:+ 3 H
2099:salts
2089:] + H
2050:Like
1697:) as
1639:ionic
1608:into
1562:dimer
1543:state
1506:to a
1498:that
1123:N.D.
1097:None
1081:NIOSH
450:dimer
399:InChI
307:24012
287:1876
233:22445
204:ChEBI
180:dimer
159:JSmol
5722:NoCl
5714:MdCl
5706:FmCl
5698:EsCl
5691:EsCl
5682:CfCl
5674:CfCl
5666:BkCl
5658:CmCl
5650:AmCl
5643:AmCl
5635:PuCl
5627:NpCl
5590:PaCl
5583:PaCl
5575:ThCl
5568:ThCl
5560:AcCl
5547:YbCl
5540:YbCl
5532:TmCl
5525:TmCl
5517:ErCl
5509:HoCl
5501:DyCl
5494:DyCl
5486:TbCl
5478:GdCl
5470:EuCl
5463:EuCl
5455:SmCl
5448:SmCl
5440:PmCl
5432:NdCl
5425:NdCl
5417:PrCl
5409:CeCl
5401:LaCl
5327:DbCl
5319:RfCl
5311:LrCl
5300:RaCl
5295:FrCl
5285:AtCl
5277:PoCl
5270:PoCl
5262:BiCl
5254:PbCl
5247:PbCl
5239:TlCl
5235:TlCl
5227:HgCl
5208:AuCl
5201:(Au)
5197:AuCl
5189:PtCl
5182:PtCl
5174:IrCl
5167:IrCl
5160:IrCl
5152:OsCl
5145:OsCl
5138:OsCl
5131:OsCl
5123:ReCl
5116:ReCl
5109:ReCl
5102:ReCl
5058:TaCl
5051:TaCl
5044:TaCl
5036:HfCl
5028:LuCl
5017:BaCl
5012:CsCl
5002:XeCl
4995:XeCl
4991:XeCl
4971:TeCl
4964:TeCl
4945:SbCl
4938:SbCl
4930:SnCl
4923:SnCl
4915:InCl
4908:InCl
4904:InCl
4896:CdCl
4891:AgCl
4883:PdCl
4875:RhCl
4867:RuCl
4860:RuCl
4853:RuCl
4845:TcCl
4838:TcCl
4830:MoCl
4823:MoCl
4816:MoCl
4809:MoCl
4802:MoCl
4794:NbCl
4787:NbCl
4780:NbCl
4772:ZrCl
4765:ZrCl
4758:ZrCl
4740:SrCl
4735:RbCl
4725:BrCl
4717:SeCl
4710:SeCl
4687:AsCl
4680:AsCl
4672:GeCl
4665:GeCl
4657:GaCl
4653:GaCl
4645:ZnCl
4637:CuCl
4633:CuCl
4625:NiCl
4617:CoCl
4610:CoCl
4602:FeCl
4595:FeCl
4587:MnCl
4580:MnCl
4572:CrCl
4565:CrCl
4558:CrCl
4521:TiCl
4514:TiCl
4507:TiCl
4499:ScCl
4489:CaCl
4485:CaCl
4396:SiCl
4366:AlCl
4362:AlCl
4354:MgCl
4349:NaCl
4105:BeCl
4100:LiCl
3999:Ti(C
3970:Al(C
3932:Al(C
3915:Al(C
3806:Al(C
3527:(MoO
3491:Al(C
3486:AlSb
3478:AlPO
3351:AlCl
3335:AlBr
3318:AlAs
3256:Al(C
3239:AlOH
3215:AlCl
3210:AlBr
3148:MSDS
3036:PMID
3001:PMID
2863:ISBN
2830:ISBN
2712:ISSN
2620:ISBN
2573:AlBr
2561:ISBN
2532:ISBN
2452:ISBN
2341:ISBN
2284:AlCl
2135:NaCl
2133:+ 3
2125:AlCl
2106:ions
2059:AlCl
1981:and
1954:and
1914:and
1792:The
1764:and
1748:and
1740:for
1731:AlCl
1721:Uses
1613:AlCl
1547:AlCl
1532:AlCl
1454:AlCl
1364:None
1295:AHFS
1117:IDLH
991:P310
975:P280
971:P260
957:H314
671:mS16
479:AlCl
334:UNII
5619:UCl
5612:UCl
5605:UCl
5598:UCl
5556:**
5385:Og
5382:Ts
5379:Lv
5376:Mc
5373:Fl
5370:Nh
5367:Cn
5364:Rg
5361:Ds
5358:Mt
5355:Hs
5347:BhO
5335:SgO
5307:**
5289:Rn
5094:WCl
5087:WCl
5080:WCl
5073:WCl
5066:WCl
4983:ICl
4979:ICl
4750:YCl
4729:Kr
4694:+As
4550:VCl
4543:VCl
4536:VCl
4529:VCl
4480:KCl
4474:Ar
4459:+SO
4452:SCl
4445:SCl
4422:PCl
4415:PCl
4343:Ne
4336:ClF
4329:ClF
4325:ClF
4313:ClO
4273:ClO
4269:ClO
4231:+NO
4220:ClN
4213:NCl
4205:+CO
4194:CCl
4153:+BO
4135:BCl
4094:He
4084:HCl
4071:ion
3845:AlO
3755:(NH
3733:AlF
3696:OCH
3688:(OC
3672:OCH
3664:(OC
3607:SiO
3567:(SO
3473:AlP
3436:OAc
3412:(CO
3391:AlN
3383:AlI
3375:AlH
3367:AlF
3302:AlO
3294:AlB
3286:AlB
3260:(CH
3225:AlI
3220:AlF
3028:doi
2974:doi
2947:doi
2920:doi
2893:doi
2799:doi
2772:doi
2743:doi
2704:doi
2649:doi
2524:doi
2408:doi
2237:]Cl
2112:of
2033:]Cl
2015:]Cl
1985:in
1772:or
1713:in
1473:]Cl
1383:EPA
1104:REL
1091:PEL
910:GHS
895:WHO
843:298
816:298
368:EPA
297:CID
5745::
5397:*
5351:Cl
5339:Cl
5220:Cl
5216:Hg
5024:*
4957:Cl
4953:Te
4703:Cl
4699:Se
4467:Cl
4438:Cl
4429:+P
4408:Cl
4389:Cl
4385:Si
4380:12
4378:Cl
4374:Si
4320:+O
4302:Cl
4291:Cl
4280:Cl
4258:Cl
4250:Cl
4239:Cl
4227:+N
4201:+C
4187:Cl
4176:Cl
4165:Cl
4146:Cl
4130:12
4128:Cl
4126:12
4117:Cl
4011:CH
3994:Cl
3982:Cl
3944:CN
3927:Cl
3841:69
3832:36
3712:Al
3650:17
3644:CO
3623:Al
3603:Al
3595:Te
3591:Al
3583:Se
3579:Al
3563:Al
3551:Al
3539:Al
3523:Al
3461:SO
3457:Al
3408:Al
3296:12
3230:Al
3099:.
3081:.
3077:.
3066:^
3056:.
3034:.
3024:81
3022:.
2997:97
2995:.
2970:31
2968:.
2943:61
2941:.
2916:59
2914:.
2889:13
2857::
2828:.
2824::
2795:79
2793:.
2768:80
2766:.
2739:89
2737:.
2733:.
2710:.
2700:66
2698:.
2669:^
2655:.
2647:.
2645:87
2643:.
2618:.
2593:^
2584:Br
2580:Al
2569:.
2555:.
2530:.
2506:^
2501:.
2497:,
2480:.
2466:^
2428:^
2414:.
2404:90
2402:.
2387:^
2366:.
2355:^
2317:^
2274:.
2258:,
2233:O)
2120::
2103:Al
2085:O)
2077:O)
2068::
2054:,
2029:O)
2011:O)
1906:.
1883::
1850:.
1839:,
1820:.
1701:.
1695:Cl
1680:O)
1661:2h
1657:3h
1648:.
1624:BF
1599:Cl
1595:Al
1584:Cl
1580:Al
1569:Cl
1565:Al
1556:.
1469:O)
1322:US
1062:50
1060:LD
989:,
985:,
981:,
977:,
973:,
914::
835:(Δ
743:6
669:,
5724:2
5716:2
5708:2
5700:3
5693:2
5684:2
5676:3
5668:3
5660:3
5652:3
5645:2
5637:3
5629:3
5621:6
5614:5
5607:4
5600:3
5592:5
5585:4
5577:4
5570:3
5562:3
5549:3
5542:2
5534:3
5527:2
5519:3
5511:3
5503:3
5496:2
5488:3
5480:3
5472:3
5465:2
5457:3
5450:2
5442:3
5434:3
5427:2
5419:3
5411:3
5403:3
5349:3
5341:2
5337:2
5329:5
5321:4
5313:3
5302:2
5279:4
5272:2
5264:3
5256:4
5249:2
5241:3
5229:2
5222:2
5218:2
5210:3
5203:2
5191:4
5184:2
5176:4
5169:3
5162:2
5154:5
5147:4
5140:3
5133:2
5125:6
5118:5
5111:4
5104:3
5096:6
5089:5
5082:4
5075:3
5068:2
5060:5
5053:4
5046:3
5038:4
5030:3
5019:2
5004:4
4997:2
4985:3
4973:4
4966:2
4959:2
4955:3
4947:5
4940:3
4932:4
4925:2
4917:3
4910:2
4898:2
4885:2
4877:3
4869:4
4862:3
4855:2
4847:4
4840:3
4832:6
4825:5
4818:4
4811:3
4804:2
4796:5
4789:4
4782:3
4774:4
4767:3
4760:2
4752:3
4742:2
4719:4
4712:2
4705:2
4701:2
4689:5
4682:3
4674:4
4667:2
4659:3
4647:2
4639:2
4627:2
4619:3
4612:2
4604:3
4597:2
4589:3
4582:2
4574:4
4567:3
4560:2
4552:5
4545:4
4538:3
4531:2
4523:4
4516:3
4509:2
4501:3
4491:2
4469:2
4461:4
4454:4
4447:2
4440:2
4436:2
4434:S
4424:5
4417:3
4410:4
4406:2
4404:P
4398:4
4391:6
4387:2
4376:5
4368:3
4356:2
4338:5
4331:3
4315:4
4308:7
4306:O
4304:2
4297:6
4295:O
4293:2
4286:4
4284:O
4282:2
4275:2
4264:2
4262:O
4260:2
4254:O
4252:2
4245:y
4243:O
4241:x
4233:3
4222:3
4215:3
4207:3
4196:4
4189:6
4185:2
4183:C
4178:4
4174:2
4172:C
4167:2
4163:2
4161:C
4155:3
4148:4
4144:2
4142:B
4137:3
4124:B
4119:4
4115:4
4113:B
4107:2
4060:e
4053:t
4046:v
4021:2
4019:)
4017:3
4013:2
4009:2
4007:)
4005:5
4003:H
4001:5
3992:5
3990:H
3988:2
3986:C
3984:2
3980:2
3978:)
3976:5
3974:H
3972:2
3965:H
3963:2
3961:)
3959:2
3957:)
3955:3
3951:2
3942:2
3940:)
3938:5
3936:H
3934:2
3925:2
3923:)
3921:5
3919:H
3917:2
3909:3
3907:)
3905:2
3903:)
3901:3
3897:2
3889:2
3887:)
3885:3
3883:)
3881:5
3879:H
3877:2
3869:2
3867:)
3865:3
3863:)
3861:3
3850:6
3836:H
3827:C
3820:3
3818:)
3816:3
3814:O
3812:5
3810:H
3808:3
3789:2
3787:)
3785:4
3777:2
3775:)
3773:4
3765:2
3763:)
3761:4
3757:4
3735:6
3731:3
3729:K
3722:7
3720:O
3718:2
3716:B
3714:2
3710:2
3708:K
3702:2
3700:)
3698:3
3694:4
3692:H
3690:2
3686:2
3678:2
3676:)
3674:3
3670:4
3668:H
3666:2
3662:2
3654:5
3652:H
3648:C
3646:2
3642:2
3629:3
3627:C
3625:4
3617:4
3609:5
3605:2
3597:3
3593:2
3585:3
3581:2
3573:3
3571:)
3569:4
3565:2
3557:3
3555:S
3553:2
3545:3
3543:O
3541:2
3533:3
3531:)
3529:4
3525:2
3517:3
3515:)
3513:4
3505:3
3503:)
3501:2
3499:O
3497:7
3495:H
3493:5
3480:4
3467:4
3463:4
3459:2
3451:3
3443:2
3434:2
3426:3
3418:3
3416:)
3414:3
3410:2
3402:3
3400:)
3398:3
3385:3
3377:3
3369:3
3361:4
3353:3
3345:3
3337:3
3329:3
3327:)
3325:4
3288:2
3268:)
3266:5
3264:)
3262:3
3258:5
3234:O
3232:2
3188:e
3181:t
3174:v
3137:3
3103:.
3042:.
3030::
3007:.
2980:.
2976::
2953:.
2949::
2926:.
2922::
2899:.
2895::
2871:.
2838:.
2805:.
2801::
2778:.
2774::
2751:.
2745::
2718:.
2706::
2663:.
2651::
2628:.
2575:3
2540:.
2526::
2460:.
2422:.
2410::
2381:.
2349:.
2286:3
2249:O
2247:2
2243:3
2239:3
2235:6
2231:2
2206:3
2202:2
2181:2
2177:3
2169:3
2165:2
2131:3
2127:3
2087:5
2083:2
2079:6
2075:2
2061:3
2045:O
2043:2
2039:3
2035:3
2031:6
2027:2
2017:3
2013:6
2009:2
2003:2
1968:]
1966:4
1962:(
1733:3
1693:(
1684:]
1682:6
1678:2
1655:D
1626:3
1615:3
1601:6
1597:2
1586:6
1582:2
1571:6
1567:2
1549:3
1534:3
1475:3
1471:6
1467:2
1456:3
1385:)
1381:(
1297:/
1253:N
1068:)
1064:(
1040:2
1033:0
1026:3
867:)
865:G
862:f
845:)
840:H
837:f
818:)
813:S
811:(
794:)
792:C
790:(
771:(
739:)
737:Z
735:(
722:)
720:V
718:(
706:c
702:b
698:a
481:3
370:)
366:(
161:)
20:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
