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Amphibole

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263: 2062: 157: 179:. The chief differences from pyroxenes are that (i) amphiboles contain essential hydroxyl (OH) or halogen (F, Cl) and (ii) the basic structure is a double chain of tetrahedra (as opposed to the single chain structure of pyroxene). Most apparent, in hand specimens, is that amphiboles form oblique cleavage planes (at around 120 degrees), whereas pyroxenes have cleavage angles of approximately 90 degrees. Amphiboles are also specifically less dense than the corresponding pyroxenes. Amphiboles are the primary constituent of 231: 207: 247: 219: 2147: 1437: 1763: 46: 389:. The group was so named by Haüy in allusion to the protean variety, in composition and appearance, assumed by its minerals. This term has since been applied to the whole group. Numerous sub-species and varieties are distinguished, the more important of which are tabulated below in two series. The formulae of each will be seen to be built on the general double-chain 255: 1242:). In addition, titanium, manganese, or chromium can substitute for some of the cations and oxygen, fluorine, or chlorine for some of the hydroxide. The different chemical types are almost impossible to distinguish even by optical or X-ray methods, and detailed chemical analysis using an electron microprobe is required. 1103:
Certain amphibole minerals form solid solution series, at least at elevated temperature. Ferrous iron usually substitutes freely for magnesium in amphiboles to form continuous solid solution series between magnesium-rich and iron-rich endmembers. These include the cummington (magnesium) to grunerite
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a continuous series between calcic clinoamphiboles, such as hornblende, and low-calcium amphiboles, such as orthoamphiboles or the cummingtonite-grunerite series. Compositions intermediate in calcium are almost nonexistent in nature. However, there is a solid solution series between hornblende and
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Like pyroxenes, amphiboles are classified as inosilicate (chain silicate) minerals. However, the pyroxene structure is built around single chains of silica tetrahedra while amphiboles are built around double chains of silica tetrahedra. In other words, as with almost all silicate minerals, each
200:. Each I-beam is bonded to its neighbor by additional metal ions to form the complete crystal structure. Large gaps in the structure may be empty or partially filled by large metal ions, such as sodium, but remain points of weakness that help define the cleavage planes of the crystal. 1107:
In addition, the orthoamphiboles, anthophyllite and gedrite, which differ in their aluminium content, form a continuous solid solution at elevated temperature. As the amphibole cools, the two end members exsolve to form very thin layers (lamellae).
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silicon ion is surrounded by four oxygen ions. In amphiboles, some of the oxygen ions are shared between silicon ions to form a double chain structure as depicted below. These chains extend along the axis of the crystal. One side of each chain has
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and crocidolite (blue asbestos) in ironstone formations, both resulting from dynamo-metamorphic processes. The latter two are dark green minerals, which occur as original constituents of igneous rocks rich in sodium, such as
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oxygen ions, shared by only one silicon ion, and pairs of double chains are bound to each other by metal ions that connect apical oxygen ions. The pairs of double chains have been likened to
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is known as crocidolite or "blue asbestos". These are generally called amphibole asbestos. Mining, manufacture and prolonged use of these minerals can cause serious illnesses.
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On account of the wide variations in chemical composition, the different members vary considerably in properties and general appearance.
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Hornblende is highly variable in composition, and includes at least five solid solution series: magnesiohornblende-ferrohornblende (
314:. Calcium is sometimes a constituent of naturally occurring amphiboles. Amphilotes of metamorphic origin include those developed in 95: 163:
of a thin section containing an amphibole crystal; under cross-polarized light on the left, and plane-polarized light on the right.
1971: 322:) and those formed by the alteration of other ferromagnesian minerals (such as hornblende as an alteration product of pyroxene). 1568: 1633:
Peters, Stefan T. M.; Troll, Valentin R.; Weis, Franz A.; Dallai, Luigi; Chadwick, Jane P.; Schulz, Bernhard (2017-03-16).
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form a somewhat special group of alkali-amphiboles. The first two are blue fibrous minerals, with glaucophane occurring in
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Glaucophane to riebeckite form yet another solid solution series, which also extends towards hornblende and arfvedsonite.
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magmas favors formation of amphiboles rather than pyroxenes. The highest amphibole content, around 20%, is found in
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Amphibole structure looking along the axis. Silicon ions are emphasized. Two "I-beams" are outlined in green.
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exists at lower temperatures, and, as a result, hornblende often contains exsolution lamellae of grunerite.
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currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
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Double-chain inosilicate structure looking up the axis. Silicon ions are hidden by apical oxygen ions.
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One or more of the preceding sentences incorporates text from a publication now in the
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crystals of a bright green or greyish-green color. It occurs frequently as a constituent of
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is an important constituent of many igneous rocks. It is also an important constituent of
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Side view (along ) of double chain inosilicate backbone. Apical oxygens are at the bottom.
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is an important and common member of the monoclinic series, forming radiating groups of
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is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The
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is widespread in igneous and metamorphic rocks and is particularly common in
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The more common amphiboles are classified as shown in the following table:
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Amphibolite from Warrensburg, Adirondack Mountains, New York State, USA
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and some other localities. An aluminous related species is known as
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occurs as brownish, fibrous or lamellar masses with hornblende in
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This article is about the mineral. For the logical fallacy, see
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is a rare magnesium-rich variety of hornblende with essential
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Hornblende diorite from the Henry Mountains, Utah, US
96: 75: 87: 81: 2125: 2069: 2025: 1559:Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). 404:Four of the amphibole minerals are commonly called 72: 66: 125:, linked at the vertices and generally containing 38:. For the study of amphibians (amphibiology), see 34:. For the ambiguous grammatical construction, see 1561:Manual of mineralogy : (after James D. Dana) 167:Amphiboles crystallize into two crystal systems, 1832:Agency for Toxic Substances and Disease Registry 1253:tremolite-actinolite at elevated temperature. A 1834:. Centers for Disease Control. 10 December 2018 1563:(21st ed.). New York: Wiley. p. 491. 2003: 8: 1930: 1906: 1724: 1595: 1583: 430:Amphibole classification (After Nesse 2000) 374: 373:), implying ambiguity. The name was used by 1399:rocks. For instance, it occurs in uncommon 358: 2010: 1996: 1988: 1756: 1754: 1752: 1750: 1639:Contributions to Mineralogy and Petrology 1524: 1342:, a 'stone') is a translation of the old 326:of amphibole after pyroxene are known as 1238: 1234: 1230: 1226: 1222: 1218: 1215:) and magnesiohastingstite-hastingsite ( 1211: 1207: 1203: 1199: 1195: 1191: 1184: 1180: 1176: 1172: 1168: 1161: 1157: 1153: 1149: 1145: 1141: 1137: 1130: 1126: 1122: 1118: 1114: 957: 953: 949: 940: 932: 905: 901: 897: 889: 885: 877: 857: 853: 849: 840: 812: 808: 804: 796: 768: 764: 760: 756: 747: 739: 719: 715: 711: 703: 695: 687: 665: 661: 657: 649: 641: 611: 607: 603: 595: 587: 570: 566: 562: 558: 550: 546: 538: 515: 511: 507: 499: 491: 467: 463: 459: 451: 443: 426: 294:and dissolved water content of the more 1467: 1410:. It is hard, dense, black and usually 202: 146:International Mineralogical Association 278:origin. Amphiboles are more common in 1942: 1918: 1894: 1882: 1870: 1855: 1814: 1741: 1687: 7: 1501:"IMA-CNMNC approved mineral symbols" 1456:Classification of silicate minerals 1134:), tschermakite-ferrotschermakite ( 250:Mineral assemblage of igneous rocks 290:igneous rocks, because the higher 270:Amphiboles are minerals of either 25: 2145: 2060: 1972:Mineralogical Society of America 1761: 1435: 229: 217: 205: 62: 1: 1586:, pp. 474–475, 478, 491. 1336:ἀκτίς, ἀκτῖνος/aktís, aktînos 1188:), pargasite-ferropargasite ( 27:Group of inosilicate minerals 1828:"Health Effects of Asbestos" 1548:Mindat, Amphibole Supergroup 347: 2193: 1610:Introduction to mineralogy 1608:Nesse, William D. (2000). 1313:formed by metamorphism of 1295:variety containing little 352: 29: 2141: 2058: 1700:Levin, Harold L. (2010). 1659:10.1007/s00410-017-1338-0 1165:), edenite-ferroedenite ( 919: 869: 822: 780: 679: 633: 625: 528: 525: 483: 429: 412:or "brown asbestos", and 375: 318:by contact metamorphism ( 137:in their structures. Its 1931:Klein & Hurlbut 1993 1907:Klein & Hurlbut 1993 1805:, accessed 20 July 2015. 1725:Klein & Hurlbut 1993 1596:Klein & Hurlbut 1993 1584:Klein & Hurlbut 1993 629:Low-Ca-clinoamphibolite 1788:Encyclopædia Britannica 1964:Handbook of Mineralogy 1801:US Geological Survey, 1775:Spencer, Leonard James 1702:The earth through time 1505:Mineralogical Magazine 823:Na-Ca-clinonamphibole 381:to include tremolite, 286:igneous rocks than in 267: 259: 251: 164: 54: 1480:Dictionary of Geology 334:History and etymology 265: 257: 249: 159: 48: 2152:Minerals portal 1945:, pp. 287–289. 1933:, pp. 495–496. 1873:, pp. 277–290. 1651:2017CoMP..172...16P 1526:10.1180/mgm.2021.43 1517:2021MinM...85..291W 1499:Warr, L.N. (2021). 1414:, with a red-brown 1395:, usually found in 981:Orthorhombic series 2133:Industrial mineral 1727:, p. 496-497. 1690:, p. 279–280. 1350:(radiated stone). 920:Na-clinoamphibole 680:Ca-clinoamphibole 268: 260: 252: 165: 55: 2159: 2158: 1331:. The name (from 1291:and a deep green 1017:Monoclinic series 973: 972: 529:Orthoamphibolite 16:(Redirected from 2184: 2150: 2149: 2148: 2064: 2012: 2005: 1998: 1989: 1982: 1981: 1979: 1978: 1969: 1960: 1952: 1946: 1940: 1934: 1928: 1922: 1916: 1910: 1904: 1898: 1892: 1886: 1880: 1874: 1868: 1859: 1853: 1844: 1843: 1841: 1839: 1824: 1818: 1812: 1806: 1799: 1793: 1792: 1767: 1765: 1764: 1758: 1745: 1739: 1728: 1722: 1716: 1715: 1697: 1691: 1685: 1679: 1678: 1630: 1624: 1623: 1605: 1599: 1593: 1587: 1581: 1575: 1574: 1556: 1550: 1545: 1539: 1538: 1528: 1496: 1490: 1489: 1487: 1486: 1472: 1451:List of minerals 1445: 1440: 1439: 1438: 1406:, carried up by 1241: 1214: 1187: 1164: 1133: 960: 944: 935: 927: 908: 892: 880: 860: 844: 835: 830: 815: 799: 791: 786: 771: 751: 742: 734: 722: 706: 698: 690: 668: 652: 644: 614: 598: 590: 573: 553: 541: 518: 502: 494: 470: 454: 446: 427: 380: 379: 372: 369: 366: 363: 360: 356: 350: 233: 221: 209: 161:Photomicrographs 121: 120: 119: 103:) is a group of 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781:Sodic-calcic 779: 776: 773: 753: 744: 736: 731: 730: 727: 724: 708: 702:(Mg,Fe,Fe,Al) 700: 692: 684: 683: 677: 673: 670: 654: 646: 638: 636: 632: 628: 623: 619: 618:Cummingtonite 616: 600: 592: 584: 582: 581: 578: 575: 555: 543: 535: 533: 532: 526:Orthorhombic 523: 522:Anthophyllite 520: 504: 496: 488: 486: 482: 478: 475: 472: 456: 448: 440: 437: 434: 433: 428: 425: 419: 417: 415: 411: 407: 402: 392: 388: 384: 378: 355: 349: 345: 342:derives from 341: 333: 331: 329: 325: 321: 317: 313: 309: 305: 301: 297: 293: 289: 285: 281: 277: 273: 264: 256: 248: 241: 232: 227: 220: 215: 208: 203: 201: 199: 195: 186: 184: 182: 178: 174: 170: 162: 158: 151: 149: 147: 143: 140: 136: 132: 128: 124: 109: 106: 102: 101: 92: 59: 52: 47: 41: 37: 33: 19: 2172:Inosilicates 2143: 2076: 1975:. 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Retrieved 1479: 1470: 1423:thin section 1420:petrographic 1387: 1366:arfvedsonite 1352: 1347: 1340:λίθος/líthos 1339: 1335: 1329:greenschists 1319: 1311:amphibolites 1305: 1267: 1264: 1261:Descriptions 1249: 1247: 1244: 1221:[(Mg,Fe) 1194:[(Mg,Fe) 1140:[(Mg,Fe) 1117:[(Mg,Fe) 1110: 1106: 1102: 1016: 1015: 987:Holmquistite 980: 979: 968:arfvedsonite 423: 403: 339: 337: 324:Pseudomorphs 280:intermediate 269: 193: 190: 181:amphibolites 173:orthorhombic 166: 57: 56: 32:equivocation 2102:Plagioclase 2082:Bridgmanite 1956:"Pargasite" 1476:"Amphibole" 1416:pleochroism 1412:automorphic 1370:blueschists 1358:crocidolite 1354:Glaucophane 1348:Strahlstein 964:Eckermanite 912:Glaucophane 864:Katophorite 626:Monoclinic 393:formula RSi 276:metamorphic 105:inosilicate 49:Amphibole ( 36:amphibology 2166:Categories 2087:K-feldspar 2045:Mineralogy 1977:2012-12-17 1943:Nesse 2000 1919:Nesse 2000 1895:Nesse 2000 1883:Nesse 2000 1871:Nesse 2000 1856:Nesse 2000 1838:6 November 1815:Nesse 2000 1742:Nesse 2000 1688:Nesse 2000 1570:047157452X 1485:2013-01-21 1462:References 1408:kimberlite 1397:ultramafic 1362:riebeckite 1321:Actinolite 1307:Hornblende 1301:kupfferite 1054:, (CaNa)Mg 916:riebeckite 819:Richterite 775:Kaersutite 726:Hornblende 676:actinolite 414:riebeckite 387:hornblende 383:actinolite 348:amphíbolos 316:limestones 304:Hornblende 169:monoclinic 152:Mineralogy 123:tetrahedra 18:Amphiboles 2077:Amphibole 1779:Amphibole 1777:(1911). " 1675:132014026 1667:1432-0967 1645:(4): 16. 1535:235729616 1404:xenoliths 1389:Pargasite 1383:phonolite 1375:nepheline 1281:Kongsberg 1248:There is 1058:(Al,Fe)Si 1023:Pargasite 672:Tremolite 622:Grunerite 476:Symmetry 354:ἀμφίβολος 340:amphibole 338:The name 320:tremolite 300:andesites 187:Structure 177:pyroxenes 135:magnesium 58:Amphibole 51:tremolite 40:amphibian 2177:Asbestos 2107:Pyroxene 2026:Overview 2019:Minerals 1803:Asbestos 1429:See also 1325:acicular 1052:Winchite 479:Comment 473:Mineral 406:asbestos 391:silicate 312:diorites 308:syenites 242:In rocks 108:minerals 100:-fə-bohl 2126:Related 2097:Olivine 2050:History 2033:Mineral 1785:(ed.). 1772::  1647:Bibcode 1513:Bibcode 1379:syenite 1293:Russian 1289:gedrite 1171:(Mg,Fe) 1073:Edenite 943:(Al,Fe) 939:(Mg,Fe) 888:(Al,Fe) 884:(Mg,Fe) 839:(Mg,Fe) 795:(Mg,Fe) 746:(Mg,Fe) 710:(Si,Al) 648:(Mg,Fe) 634:Calcic 594:(Mg,Fe) 586:(Mg,Fe) 577:Gedrite 545:(Mg,Fe) 537:(Mg,Fe) 498:(Mg,Fe) 490:(Mg,Fe) 410:amosite 362:  328:uralite 296:evolved 272:igneous 198:I-beams 133:and/or 2117:Spinel 2112:Quartz 1781:". In 1766:  1708:  1673:  1665:  1616:  1567:  1533:  1401:mantle 1393:sodium 1344:German 1315:basalt 1285:Norway 1277:schist 1099:Series 1075:, NaCa 1025:, NaCa 870:Sodic 686:(Na,K) 435:Group 292:silica 284:felsic 194:apical 142:symbol 1968:(pdf) 1959:(PDF) 1671:S2CID 1531:S2CID 1346:word 1333:Greek 1225:Fe]Si 1198:Al]Si 1121:Al]Si 344:Greek 288:mafic 2092:Mica 2038:List 1840:2020 1706:ISBN 1663:ISSN 1614:ISBN 1565:ISBN 1381:and 1364:and 1297:iron 1273:mica 1237:(OH) 1217:NaCa 1210:(OH) 1190:NaCa 1183:(OH) 1167:NaCa 1160:(OH) 1129:(OH) 1091:(OH) 1087:Al)O 1066:(OH) 1045:(OH) 1033:FeSi 1009:(OH) 989:, Li 956:(OH) 904:(OH) 856:(OH) 834:NaCa 811:(OH) 790:NaCa 767:(OH) 718:(OH) 664:(OH) 610:(OH) 569:(OH) 514:(OH) 466:(OH) 385:and 359:lit. 310:and 171:and 131:iron 127:ions 1655:doi 1643:172 1521:doi 1418:in 1299:as 1283:in 1279:at 1250:not 1179:AlO 1148:]Si 1125:AlO 1083:(Si 852:AlO 688:0−1 282:to 274:or 139:IMA 129:of 112:SiO 2168:: 1970:. 1961:. 1863:^ 1848:^ 1830:. 1749:^ 1732:^ 1669:. 1661:. 1653:. 1641:. 1637:. 1529:. 1519:. 1509:85 1507:. 1503:. 1478:. 1425:. 1385:. 1360:, 1356:, 1317:. 1303:. 1235:22 1229:Al 1227:67 1208:22 1202:Al 1181:22 1175:Si 1158:22 1152:Al 1144:Al 1136:Ca 1127:22 1113:Ca 1089:22 1079:Mg 1064:22 1043:22 1037:Al 1029:Mg 1007:22 1001:Si 997:Al 993:Mg 954:22 948:Si 931:Na 926:Na 902:22 896:Si 876:Na 854:22 848:Si 843:Fe 829:Na 809:22 803:Si 785:Na 765:22 759:Al 755:Si 750:Ti 738:Ca 733:Na 716:22 694:Ca 662:22 656:Si 640:Ca 608:22 602:Si 567:22 561:Si 557:Al 549:Al 512:22 506:Si 464:22 438:W 401:. 399:11 357:, 330:. 302:. 183:. 98:AM 85:oʊ 2011:e 2004:t 1997:v 1980:. 1842:. 1714:. 1677:. 1657:: 1649:: 1622:. 1573:. 1537:. 1523:: 1515:: 1488:. 1377:- 1275:- 1239:2 1233:O 1231:2 1223:4 1219:2 1212:2 1206:O 1204:2 1200:6 1196:4 1192:2 1185:2 1177:7 1173:5 1169:2 1162:2 1156:O 1154:2 1150:6 1146:2 1142:3 1138:2 1131:2 1123:7 1119:4 1115:2 1093:2 1085:7 1081:5 1077:2 1068:2 1062:O 1060:8 1056:4 1047:2 1041:O 1039:3 1035:6 1031:3 1027:2 1011:2 1005:O 1003:8 999:2 995:3 991:2 966:- 958:2 952:O 950:8 941:4 933:2 914:- 906:2 900:O 898:8 890:2 886:3 878:2 858:2 850:7 841:4 813:2 807:O 805:8 797:5 769:2 763:O 761:2 757:6 748:4 740:2 720:2 714:O 712:8 704:5 696:2 674:- 666:2 660:O 658:8 650:5 642:2 620:- 612:2 606:O 604:8 596:5 588:2 571:2 565:O 563:6 559:2 551:2 547:3 539:2 516:2 510:O 508:8 500:5 492:2 468:2 462:O 460:8 458:Z 452:5 450:Y 444:2 442:X 397:O 395:4 371:' 365:' 351:( 117:4 91:/ 88:l 82:b 79:ə 76:f 73:m 70:æ 67:ˈ 64:/ 60:( 53:) 42:. 20:)

Index

Amphiboles
equivocation
amphibology
amphibian

tremolite
/ˈæmfəbl/
AM-fə-bohl
inosilicate
minerals
tetrahedra
ions
iron
magnesium
IMA
symbol
International Mineralogical Association

Photomicrographs
monoclinic
orthorhombic
pyroxenes
amphibolites
I-beams
Double-chain inosilicate structure looking up the  axis. Silicon ions are hidden by apical oxygen ions.
Side view (along ) of double chain inosilicate backbone. Apical oxygens are at the bottom.
Amphibole structure looking along the  axis. Silicon ions are emphasized. Two "I-beams" are outlined in green.


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