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Anode

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inappropriate, whereas "anode" meaning 'East electrode' would have remained correct with respect to the unchanged direction of the actual phenomenon underlying the current, then unknown but, he thought, unambiguously defined by the magnetic reference. In retrospect the name change was unfortunate, not only because the Greek roots alone do not reveal the anode's function any more, but more importantly because as we now know, the Earth's magnetic field direction on which the "anode" term is based is subject to
366: 170:. The names of the electrodes do not change in cases where reverse current flows through the device. Similarly, in a vacuum tube only one electrode can emit electrons into the evacuated tube due to being heated by a filament, so electrons can only enter the device from the external circuit through the heated electrode. Therefore, this electrode is permanently named the cathode, and the electrode through which the electrons exit the tube is named the anode. 410: 1106: 436: 472: 33: 342:: LEO Red Cat (Loss of Electrons is Oxidation, Reduction occurs at the Cathode), or AnOx Red Cat (Anode Oxidation, Reduction Cathode), or OIL RIG (Oxidation is Loss, Reduction is Gain of electrons), or Roman Catholic and Orthodox (Reduction – Cathode, anode – Oxidation), or LEO the lion says GER (Losing electrons is Oxidation, Gaining electrons is Reduction). 453:
charge-carrier ions). This creates a base negative charge on the anode. When a positive voltage is applied to anode of the diode from the circuit, more holes are able to be transferred to the depleted region, and this causes the diode to become conductive, allowing current to flow through the circuit. The terms anode and cathode should not be applied to a
282:, whose exact nature was not known at the time. The reference he used to this effect was the Earth's magnetic field direction, which at that time was believed to be invariant. He fundamentally defined his arbitrary orientation for the cell as being that in which the internal current would run parallel to and in the same direction as a hypothetical 266:. In that paper Faraday explained that when an electrolytic cell is oriented so that electric current traverses the "decomposing body" (electrolyte) in a direction "from East to West, or, which will strengthen this help to the memory, that in which the sun appears to move", the anode is where the current enters the electrolyte, on the East side: " 223:, the anode is the terminal represented by the tail of the arrow symbol (flat side of the triangle), where conventional current flows into the device. Note the electrode naming for diodes is always based on the direction of the forward current (that of the arrow, in which the current flows "most easily"), even for types such as 212:, the anode is the positive terminal imposed by an external source of potential difference. The current through a recharging battery is opposite to the direction of current during discharge; in other words, the electrode which was the cathode during battery discharge becomes the anode while the battery is recharging. 390: 215:
In battery engineering, it is common to designate one electrode of a rechargeable battery the anode and the other the cathode according to the roles the electrodes play when the battery is discharged. This is despite the fact that the roles are reversed when the battery is charged. When this is done,
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where the electrode naming is fixed and does not depend on the actual charge flow (current). These devices usually allow substantial current flow in one direction but negligible current in the other direction. Therefore, the electrodes are named based on the direction of this "forward" current. In
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metal. As long as the zinc remains intact, the iron is protected from the effects of corrosion. Inevitably, the zinc coating becomes breached, either by cracking or physical damage. Once this occurs, corrosive elements act as an electrolyte and the zinc/iron combination as electrodes. The resultant
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Battery manufacturers may regard the negative electrode as the anode, particularly in their technical literature. Though from an electrochemical viewpoint incorrect, it does resolve the problem of which electrode is the anode in a secondary (or rechargeable) cell. Using the traditional definition,
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The use of 'East' to mean the 'in' direction (actually 'in' → 'East' → 'sunrise' → 'up') may appear contrived. Previously, as related in the first reference cited above, Faraday had used the more straightforward term "eisode" (the doorway where the current enters). His motivation for changing it to
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Historically, when non-reactive anodes were desired for electrolysis, graphite (called plumbago in Faraday's time) or platinum were chosen. They were found to be some of the least reactive materials for anodes. Platinum erodes very slowly compared to other materials, and graphite crumbles and can
544:. Unlike the sacrificial anode rod, the impressed current anode does not sacrifice its structure. This technology uses an external current provided by a DC source to create the cathodic protection. Impressed current anodes are used in larger structures like pipelines, boats, city water tower, 452:
to the junction. In the junction region, the holes supplied by the anode combine with electrons supplied from the N-doped region, creating a depleted zone. As the P-doped layer supplies holes to the depleted region, negative dopant ions are left behind in the P-doped layer ('P' for positive
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field oriented like the Earth's. This made the internal current East to West as previously mentioned, but in the event of a later convention change it would have become West to East, so that the East electrode would not have been the 'way in' any more. Therefore, "eisode" would have become
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relative to the electrolyte solution being different for the anode and cathode metal/electrolyte systems); but, external to the cell in the circuit, electrons are being pushed out through the negative contact and thus through the circuit by the voltage potential as would be expected.
179: 381:, the anode is the negative electrode from which electrons flow out towards the external part of the circuit. Internally the positively charged cations are flowing away from the anode (even though it is negative and therefore would be expected to attract them, this is due to 516:
developed the first and still most widely used marine electrolysis protection system. Davy installed sacrificial anodes made from a more electrically reactive (less noble) metal attached to the vessel hull and electrically connected to form a cathodic protection circuit.
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in a metal conductor. Since electrons have a negative charge, the direction of electron flow is opposite to the direction of conventional current. Consequently, electrons leave the device through the anode and enter the device through the cathode.
134:(positive charge) flows into the device from an external circuit, while a cathode is an electrode through which conventional current flows out of the device. If the current through the electrodes reverses direction, as occurs for example in a 529:
current ensures that the zinc coating is sacrificed but that the base iron does not corrode. Such a coating can protect an iron structure for a few decades, but once the protecting coating is consumed, the iron rapidly corrodes.
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is the positively charged electron collector. In a tube, the anode is a charged positive plate that collects the electrons emitted by the cathode through electric attraction. It also accelerates the flow of these electrons.
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switch functions, so the anode becomes the cathode and the cathode becomes anode, as long as the reversed current is applied. The exception is diodes where electrode naming is always based on the forward current direction.
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This process is widely used in metals refining. For example, in copper refining, copper anodes, an intermediate product from the furnaces, are electrolysed in an appropriate solution (such as
486:, a metal anode that is more reactive to the corrosive environment than the metal system to be protected is electrically linked to the protected system. As a result, the metal anode partially 194:
varies depending on the device type and on its operating mode. In the following examples, the anode is negative in a device that provides power, and positive in a device that consumes power:
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something meaning 'the East electrode' (other candidates had been "eastode", "oriode" and "anatolode") was to make it immune to a possible later change in the direction convention for
205:(diagram on left), the anode is the negative terminal: it is where conventional current flows into the cell. This inward current is carried externally by electrons moving outwards. 111:
is the wire or plate upon which excess positive charge is imposed. As a result of this, anions will tend to move towards the anode where they will undergo oxidation.
338:(negative ions) are forced by the electrical potential to react chemically and give off electrons (oxidation) which then flow up and into the driving circuit. 80:, into an outside or external circuit connected to the cell. For example, the end of a household battery marked with a "+" is the cathode (while discharging). 130:
are not defined by the voltage polarity of electrodes but the direction of current through the electrode. An anode is an electrode of a device through which
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is ACID, for "anode current into device". The direction of conventional current (the flow of positive charges) in a circuit is opposite to the direction of
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is generated by the action of flowing liquids, such as pipelines and watercraft. Sacrificial anodes are also generally used in tank-type water heaters.
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In 1824 to reduce the impact of this destructive electrolytic action on ships hulls, their fastenings and underwater equipment, the scientist-engineer
1035: 505:, which will dissolve into the seawater and prevent the hull from being corroded. Sacrificial anodes are particularly needed for systems where a 166:
a diode the anode is the terminal through which current enters and the cathode is the terminal through which current leaves, when the diode is
306:, an easier to remember and more durably correct technically although historically false, etymology has been suggested: anode, from the Greek 876: 1306: 1193: 651: 1346: 1356: 532:
If, conversely, tin is used to coat steel, when a breach of the coating occurs it actually accelerates oxidation of the iron.
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Another cathodic protection is used on the impressed current anode. It is made from titanium and covered with
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the anode is the wire or plate having excess negative charge as a result of the oxidation reaction. In an
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direction convention on which the "eisode" term was based has no reason to change in the future.
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produce carbon dioxide in aqueous solutions but otherwise does not participate in the reaction.
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Ross, S (1961). "Faraday Consults the Scholars: The Origins of the Terms of Electrochemistry".
435: 1455: 1173: 1143: 872: 657: 647: 541: 502: 498: 475: 466: 394: 331: 209: 183: 104: 88: 68:, an electrode of the device through which conventional current leaves the device. A common 1321: 1316: 1128: 1068: 864: 836: 759: 712: 418: 374: 319: 296: 279: 198: 896: 178: 1188: 1115: 892: 584: 422: 259: 255: 235: 146: 138:
when it is being charged, the roles of the electrodes as anode and cathode are reversed.
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over some new names needed to complete a paper on the recently discovered process of
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Electrode through which conventional current flows into a polarized electrical device
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The definition of anode and cathode is different for electrical devices such as
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iron. This process coats iron structures (such as fencing) with a coating of
840: 1480: 1470: 1460: 1429: 1085: 868: 782: 574: 561: 521: 487: 327: 310:, 'way up', 'the way (up) out of the cell (or other device) for electrons'. 92: 57: 763: 716: 661: 32: 1158: 303: 283: 150: 73: 69: 1013: 830: 739: 1465: 792: 557: 191: 127: 65: 992:"Powered Anode Rod Advantages | #1 Anode Rod | Corro-Protec" 978:"What is an Impressed Current Anode? - Definition from Corrosionpedia" 17: 804: 287: 227:
or solar cells where the current of interest is the reverse current.
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A less obvious example of this type of protection is the process of
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mounted "on the fly" for corrosion protection of a metal structure
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Cutaway diagram of a triode vacuum tube, showing the plate (anode)
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The polarity of voltage on an anode with respect to an associated
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Historically, the anode of a galvanic cell was also known as the
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flow, so (negatively charged) electrons flow from the anode of a
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around the local line of latitude which would induce a magnetic
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the anode switches ends between charge and discharge cycles.
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or dissolves instead of the metal system. As an example, an
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Positive and negative electrode vs. anode and cathode for a
964:"Impressed Current Protection Anodes - Specialist Castings" 863:(2nd ed.). Oxford: Blackwell Scientific Publications. 238:, the anode is the terminal where current enters the tube. 141:
Conventional current depends not only on the direction the
448:, the anode is the P-doped layer which initially supplies 149:. The currents outside the device are usually carried by 740:"Experimental Researches in Electricity. Seventh Series" 560:. When the current through the device is reversed, the 1443: 1415: 1237: 1113: 1051: 44:. Note how electrons move out of the cell, and the 639: 330:occurs and is the positive polarity contact in an 901:. Vol. 1. London: The University of London. 705:Notes and Records of the Royal Society of London 182:Electric current and electrons directions for a 744:Philosophical Transactions of the Royal Society 60:of a polarized electrical device through which 1029: 913:"What is the anode, cathode and electrolyte?" 8: 698: 696: 1036: 1022: 1014: 938:"Anode vs Cathode: What's the difference?" 64:enters the device. This contrasts with a 118:because it was usually composed of zinc. 917:Duracell Frequently Asked Questions page 861:IUPAC Compendium of Chemical Terminology 177: 48:moves into it in the opposite direction. 859:McNaught, A. D.; Wilkinson, A. (1997). 638:Pauling, Linus; Pauling, Peter (1975). 607: 417:In electronic vacuum devices such as a 898:Experimental Researches in Electricity 832:Experimental Researches in Electricity 780:in which Faraday introduces the words 847:from the original on 9 December 2017. 778:from the original on 9 December 2017. 274:a way; the way which the sun rises". 246:The word was coined in 1834 from the 7: 25: 738:Faraday, Michael (January 1834). 617:"How to Define Anode and Cathode" 302:Since the later discovery of the 1104: 646:. San Francisco: W. H. Freeman. 434: 1009:How to define anode and cathode 208:In a recharging battery, or an 556:The opposite of an anode is a 361:Battery or galvanic cell anode 1: 145:move, but also the carriers' 258:, who had been consulted by 186:during discharge and charge. 501:may be protected by a zinc 1533: 464: 1194:Metal–air electrochemical 1102: 829:Faraday, Michael (1849). 284:magnetizing current loop 869:10.1351/goldbook.A00370 835:. Vol. 1. Taylor. 536:Impressed current anode 1496:Semipermeable membrane 1285:Lithium–iron–phosphate 764:10.1098/rstl.1834.0008 717:10.1098/rsnr.1961.0038 479: 414: 397: 370: 187: 49: 1367:Rechargeable alkaline 1045:Electrochemical cells 680:collinsdictionary.com 615:Denker, John (2004). 597:(reduction–oxidation) 474: 412: 392: 368: 181: 35: 1347:Nickel–metal hydride 136:rechargeable battery 132:conventional current 126:The terms anode and 62:conventional current 46:conventional current 1357:Polysulfide–bromide 1199:Nickel oxyhydroxide 1091:Thermogalvanic cell 756:1834RSPT..124...77F 484:cathodic protection 383:electrode potential 351:electrolytic copper 91:, the anode is the 1120:(non-rechargeable) 1064:Concentration cell 966:. 16 January 2020. 480: 476:Sacrificial anodes 415: 398: 371: 314:Electrolytic anode 188: 97:oxidation reaction 50: 1504: 1503: 944:. 10 October 2023 878:978-0-9678550-9-7 841:2027/uc1.b4484853 627:on 28 March 2006. 542:mixed metal oxide 503:sacrificial anode 467:Sacrificial anode 461:Sacrificial anode 405:Vacuum tube anode 395:secondary battery 332:electrolytic cell 210:electrolytic cell 197:In a discharging 184:secondary battery 105:electrolytic cell 89:electrolytic cell 16:(Redirected from 1524: 1300:Lithium–titanate 1245: 1121: 1108: 1069:Electric battery 1038: 1031: 1024: 1015: 996: 995: 994:. 13 March 2019. 988: 982: 981: 974: 968: 967: 960: 954: 953: 951: 949: 934: 928: 927: 925: 923: 909: 903: 902: 893:Faraday, Michael 889: 883: 882: 856: 850: 848: 826: 820: 779: 735: 729: 728: 700: 691: 690: 688: 686: 672: 666: 665: 645: 635: 629: 628: 623:. 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At the anode, 320:electrochemistry 254:), 'ascent', by 236:gas-filled tubes 21: 1532: 1531: 1527: 1526: 1525: 1523: 1522: 1521: 1507: 1506: 1505: 1500: 1439: 1418: 1411: 1332:Nickel–hydrogen 1290:Lithium–polymer 1246: 1243: 1242: 1233: 1122: 1119: 1118: 1109: 1100: 1047: 1042: 1005: 1000: 999: 990: 989: 985: 976: 975: 971: 962: 961: 957: 947: 945: 936: 935: 931: 921: 919: 911: 910: 906: 891: 890: 886: 879: 858: 857: 853: 828: 827: 823: 737: 736: 732: 702: 701: 694: 684: 682: 674: 673: 669: 654: 637: 636: 632: 614: 613: 609: 604: 585:Gas-filled tube 571: 554: 552:Related antonym 538: 469: 463: 432: 407: 363: 316: 260:Michael Faraday 256:William Whewell 244: 176: 147:electric charge 143:charge carriers 124: 28: 23: 22: 15: 12: 11: 5: 1530: 1528: 1520: 1519: 1509: 1508: 1502: 1501: 1499: 1498: 1493: 1488: 1483: 1478: 1473: 1468: 1463: 1458: 1453: 1447: 1445: 1441: 1440: 1438: 1437: 1432: 1427: 1425:Atomic battery 1421: 1419: 1416: 1413: 1412: 1410: 1409: 1404: 1399: 1397:Vanadium redox 1394: 1389: 1384: 1379: 1374: 1372:Silver–cadmium 1369: 1364: 1359: 1354: 1349: 1344: 1342:Nickel–lithium 1339: 1334: 1329: 1327:Nickel–cadmium 1324: 1319: 1314: 1309: 1304: 1303: 1302: 1297: 1295:Lithium–sulfur 1292: 1287: 1282: 1272: 1267: 1266: 1265: 1255: 1249: 1247: 1244:(rechargeable) 1240:Secondary cell 1238: 1235: 1234: 1232: 1231: 1226: 1221: 1216: 1211: 1206: 1201: 1196: 1191: 1186: 1181: 1176: 1171: 1166: 1164:Edison–Lalande 1161: 1156: 1151: 1146: 1141: 1136: 1131: 1125: 1123: 1114: 1111: 1110: 1103: 1101: 1099: 1098: 1093: 1088: 1083: 1082: 1081: 1079:Trough battery 1076: 1066: 1061: 1055: 1053: 1049: 1048: 1043: 1041: 1040: 1033: 1026: 1018: 1012: 1011: 1004: 1003:External links 1001: 998: 997: 983: 969: 955: 929: 904: 884: 877: 851: 821: 730: 711:(2): 187–220. 692: 667: 653:978-0716701767 652: 630: 606: 605: 603: 600: 599: 598: 592: 587: 582: 580:Galvanic anode 577: 570: 567: 553: 550: 537: 534: 465:Main article: 462: 459: 431: 428: 406: 403: 362: 359: 315: 312: 243: 240: 175: 172: 168:forward biased 123: 120: 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 1529: 1518: 1515: 1514: 1512: 1497: 1494: 1492: 1489: 1487: 1484: 1482: 1479: 1477: 1474: 1472: 1469: 1467: 1464: 1462: 1459: 1457: 1454: 1452: 1449: 1448: 1446: 1442: 1436: 1433: 1431: 1428: 1426: 1423: 1422: 1420: 1414: 1408: 1405: 1403: 1400: 1398: 1395: 1393: 1390: 1388: 1387:Sodium–sulfur 1385: 1383: 1380: 1378: 1375: 1373: 1370: 1368: 1365: 1363: 1362:Potassium ion 1360: 1358: 1355: 1353: 1350: 1348: 1345: 1343: 1340: 1338: 1335: 1333: 1330: 1328: 1325: 1323: 1320: 1318: 1315: 1313: 1310: 1308: 1305: 1301: 1298: 1296: 1293: 1291: 1288: 1286: 1283: 1281: 1278: 1277: 1276: 1273: 1271: 1268: 1264: 1261: 1260: 1259: 1256: 1254: 1251: 1250: 1248: 1241: 1236: 1230: 1227: 1225: 1222: 1220: 1217: 1215: 1212: 1210: 1207: 1205: 1202: 1200: 1197: 1195: 1192: 1190: 1187: 1185: 1182: 1180: 1179:Lithium metal 1177: 1175: 1172: 1170: 1167: 1165: 1162: 1160: 1157: 1155: 1152: 1150: 1147: 1145: 1142: 1140: 1137: 1135: 1134:Aluminium–air 1132: 1130: 1127: 1126: 1124: 1117: 1112: 1107: 1097: 1094: 1092: 1089: 1087: 1084: 1080: 1077: 1075: 1072: 1071: 1070: 1067: 1065: 1062: 1060: 1059:Galvanic cell 1057: 1056: 1054: 1050: 1046: 1039: 1034: 1032: 1027: 1025: 1020: 1019: 1016: 1010: 1007: 1006: 1002: 993: 987: 984: 979: 973: 970: 965: 959: 956: 943: 939: 933: 930: 918: 914: 908: 905: 900: 899: 894: 888: 885: 880: 874: 870: 866: 862: 855: 852: 846: 842: 838: 834: 833: 825: 822: 819: 818: 813: 812: 807: 806: 801: 800: 795: 794: 789: 785: 784: 777: 773: 769: 765: 761: 757: 753: 749: 745: 741: 734: 731: 726: 722: 718: 714: 710: 706: 699: 697: 693: 681: 677: 671: 668: 663: 659: 655: 649: 644: 643: 634: 631: 626: 622: 618: 611: 608: 601: 596: 593: 591: 588: 586: 583: 581: 578: 576: 573: 572: 568: 566: 563: 559: 551: 549: 547: 546:water heaters 543: 535: 533: 530: 527: 523: 518: 515: 510: 508: 507:static charge 504: 500: 497: 493: 489: 485: 477: 473: 468: 460: 458: 456: 451: 447: 444: 443:semiconductor 439: 437: 429: 427: 424: 420: 411: 404: 402: 396: 391: 387: 384: 380: 379:galvanic cell 376: 369:Galvanic cell 367: 360: 358: 354: 352: 348: 347:sulfuric acid 343: 341: 337: 333: 329: 325: 321: 313: 311: 309: 305: 300: 298: 294: 289: 285: 281: 275: 273: 269: 265: 261: 257: 253: 249: 241: 239: 237: 233: 228: 226: 222: 217: 213: 211: 206: 204: 203:galvanic cell 200: 195: 193: 185: 180: 173: 171: 169: 164: 160: 155: 152: 148: 144: 139: 137: 133: 129: 121: 119: 117: 112: 110: 106: 102: 101:galvanic cell 99:occurs. In a 98: 95:at which the 94: 90: 86: 85:galvanic cell 81: 79: 78:galvanic cell 75: 71: 67: 63: 59: 55: 47: 43: 42:galvanic cell 39: 36:Diagram of a 34: 30: 19: 1450: 1402:Zinc–bromine 1209:Silver oxide 1144:Chromic acid 1116:Primary cell 1096:Voltaic pile 1074:Flow battery 986: 972: 958: 946:. Retrieved 941: 932: 920:. Retrieved 916: 907: 897: 887: 860: 854: 831: 824: 815: 809: 803: 797: 791: 787: 781: 747: 743: 733: 708: 704: 683:. 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Index

Anodes

zinc
galvanic cell
conventional current
electrode
conventional current
cathode
mnemonic
electron
galvanic cell
galvanic cell
electrolytic cell
electrode
oxidation reaction
galvanic cell
electrolytic cell
cathode
conventional current
rechargeable battery
charge carriers
electric charge
electrons
diodes
vacuum tubes
forward biased

secondary battery
cathode
battery

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