Knowledge (XXG)

Arumugam Manthiram

Source 📝

208:; born March 15, 1951) is an Indian-American materials scientist and engineer, best known for his identification of the polyanion class of lithium-ion battery cathodes, understanding of how chemical instability limits the capacity of layered oxide cathodes, and technological advances in lithium sulfur batteries. He is a Cockrell Family Regents Chair in engineering, Director of the Texas Materials Institute, the Director of the 316:
electrolyte-to-capacity ratio of <5 μL (mA h), and negative-to-positive capacity ratio of <5 in pouch-type cells. Key technological advances for lithium sulfur batteries developed by Manthiram include the use of microporous carbon interlayers and the use of doped graphene sponge electrodes.
311:
Manthiram discovered that the capacity limitations of layered oxide cathodes is a result of chemical instability that can be understood based on the relative positions of the metal 3d band relative to the top of the oxygen 2p band. This discovery represents the theoretical underpinnings of the
315:
He has identified the critical parameters needed for transitioning lithium sulfur batteries towards commercial use. Specifically, lithium sulfur batteries need to achieve a sulfur loading of >5 mg cm, a carbon content of <5%, electrolyte-to-sulfur ratio of <5 μL mg,
961: 376: 312:
anion-redox energy storage mechanism and has had significant implications for the practically accessible compositional space of lithium-ion batteries, as well as their stability from a safety perspective.
99: 580:
Masquelier, Christian; Croguennec, Laurence (2013). "Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries".
615:
Chebiam, R. V.; Kannan, A. M.; Prado, F.; Manthiram, A. (2001). "Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries".
981: 941: 986: 1001: 951: 134: 866:"Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur codoped graphene sponge" 996: 946: 245: 127: 72: 991: 419: 209: 200: 926: 780:
Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng; Zu, Chenxi; Su, Yu-Sheng (2014). "Rechargeable Lithium–Sulfur Batteries".
966: 273: 269: 213: 172: 333: 356: 956: 448: 257: 241: 217: 164: 120: 57: 338: 642:
Chebiam, R. V.; Prado, F.; Manthiram, A. (2001). "Soft Chemistry Synthesis and Characterization of Layered Li
361: 113: 106: 976: 289: 237: 45: 285: 460: 184: 971: 877: 828: 698: 552: 501: 168: 77: 401: 89: 62: 305: 261: 225: 429: 381: 396: 905: 846: 797: 726: 597: 265: 154: 66: 895: 885: 836: 789: 760: 716: 706: 667: 624: 589: 560: 509: 301: 240:, a small village in southern India. He completed his B.S. and M.S. degrees in chemistry at 179: 444:
Arumugam Manthiram, Challenges and Opportunities of Electrical Energy Storage Technologies)
881: 832: 817:"Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer" 702: 556: 505: 900: 865: 721: 686: 628: 935: 565: 528: 513: 221: 288:, which are widely used in commercial applications. This is a class which includes 765: 748: 465: 377:"Three Indian American Professors Named 2016 Materials Research Society Fellows" 711: 442: 424: 293: 909: 850: 801: 730: 601: 114:
Henry B. Linford Award for Distinguished Teaching, Electrochemical Society
864:
Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong; Manthiram, Arumugam (2015).
890: 841: 816: 297: 793: 671: 593: 16:
Indian-American material scientist, solid-state chemist, and professor
480:
Manthiram, A.; Goodenough, J. B. (1989). "Lithium insertion into Fe
962:
Fellows of the American Association for the Advancement of Science
284:
Manthiram identified the polyanion class of cathode materials for
128:
Distinguished Alumnus Award, Indian Institute of Technology Madras
420:"Professor Arumugam Manthiram Delivered the Nobel Prize Lecture" 304:
of the polyanion. These polyanion cathodes are also used in
100:
Fellow, American Association for the Advancement of Science
749:"Lithium-Sulfur Batteries: Attaining the Critical Metrics" 687:"A reflection on lithium-ion battery cathode chemistry" 292:. He demonstrated that positive electrodes containing 201: 244:. He then received his Ph.D. in chemistry from the 178: 160: 150: 95: 85: 53: 28: 21: 300:, produce higher voltages than oxides due to the 334:"Arumugam Manthiram Elected as a Fellow of AAAS" 357:"Manthiram Presents Goodenough's Nobel Lecture" 224:in Chemistry on behalf of Chemistry Laureate 8: 541:frameworks: Comparison of M = W with M = Mo" 815:Su, Yu-Sheng; Manthiram, Arumugam (2012). 18: 899: 889: 840: 764: 742: 740: 720: 710: 564: 527:Manthiram, A.; Goodenough, J. B. (1987). 264:'s lab as a Research Associate, first at 325: 414: 412: 272:. Manthiram joined the faculty of the 246:Indian Institute of Technology, Madras 73:Indian Institute of Technology, Madras 982:Indian emigrants to the United States 942:University of Texas at Austin faculty 351: 349: 7: 987:American academics of Indian descent 927:Arumugam Manthiram at Google Scholar 747:Bhargav, Amruth; Jiarui, He (2020). 461:"John B. Goodenough Nobel Lecture" 135:Fellow, Royal Society of Chemistry 121:Fellow, Materials Research Society 14: 210:Materials Science and Engineering 1002:People from Thoothukudi district 545:Journal of Solid State Chemistry 952:21st-century American engineers 617:Electrochemistry Communications 256:After working as a lecturer at 220:. Manthiram delivered the 2019 107:Fellow, Electrochemical Society 1: 997:21st-century Indian engineers 947:American materials scientists 629:10.1016/S1388-2481(01)00232-6 274:University of Texas at Austin 270:University of Texas at Austin 214:University of Texas at Austin 173:University of Texas at Austin 685:Manthiram, Arumugam (2020). 658:(0 ≤ x ≤ 1 and 0 ≤ y ≤ 1)". 566:10.1016/0022-4596(87)90242-8 514:10.1016/0378-7753(89)80153-3 992:Indian materials scientists 766:10.1016/j.joule.2020.01.001 216:, and a former lecturer of 1018: 712:10.1038/s41467-020-15355-0 529:"Lithium insertion into Fe 260:for four years, he joined 258:Madurai Kamaraj University 218:Madurai Kamaraj University 165:Madurai Kamaraj University 339:Texas Materials Institute 190: 143: 494:Journal of Power Sources 232:Early life and education 362:Electrochemical Society 660:Chemistry of Materials 290:lithium iron phosphate 238:Amarapuram, Tamil Nadu 236:Manthiram was born in 46:Amarapuram, Tamil Nadu 870:Nature Communications 821:Nature Communications 691:Nature Communications 286:lithium ion batteries 967:Solid state chemists 397:"Arumugam Manthiram" 306:sodium ion batteries 169:University of Oxford 882:2015NatCo...6.7760Z 833:2012NatCo...3.1166S 788:(23): 11751–11787. 703:2020NatCo..11.1550M 557:1987JSSCh..71..349M 506:1989JPS....26..403M 365:. 13 December 2019. 90:Lithium ion battery 891:10.1038/ncomms8760 842:10.1038/ncomms2163 262:John B. Goodenough 242:Madurai University 226:John B. Goodenough 197:Arumugam Manthiram 58:Madurai University 23:Arumugam Manthiram 957:IIT Madras alumni 794:10.1021/cr500062v 672:10.1021/cm0102537 594:10.1021/cr3001862 266:Oxford University 194: 193: 185:J. Gopalakrishnan 155:Materials Science 145:Scientific career 1009: 914: 913: 903: 893: 861: 855: 854: 844: 812: 806: 805: 782:Chemical Reviews 777: 771: 770: 768: 744: 735: 734: 724: 714: 682: 676: 675: 639: 633: 632: 612: 606: 605: 588:(8): 6552–6591. 582:Chemical Reviews 577: 571: 570: 568: 524: 518: 517: 500:(3–4): 403–408. 477: 471: 470: 457: 451: 445: 440: 434: 433: 432:on May 24, 2022. 428:. Archived from 416: 407: 406: 393: 387: 386: 373: 367: 366: 353: 344: 343: 330: 302:inductive effect 268:and then at the 204: 180:Doctoral advisor 139: 132: 125: 118: 111: 104: 81: 70: 42: 38: 36: 19: 1017: 1016: 1012: 1011: 1010: 1008: 1007: 1006: 932: 931: 923: 918: 917: 863: 862: 858: 814: 813: 809: 779: 778: 774: 746: 745: 738: 684: 683: 679: 657: 653: 649: 645: 641: 640: 636: 623:(11): 624–627. 614: 613: 609: 579: 578: 574: 540: 536: 532: 526: 525: 521: 491: 487: 483: 479: 478: 474: 459: 458: 454: 443: 441: 437: 418: 417: 410: 395: 394: 390: 375: 374: 370: 355: 354: 347: 332: 331: 327: 322: 282: 254: 234: 212:Program at the 202: 171: 167: 137: 133: 130: 126: 123: 119: 116: 112: 109: 105: 102: 75: 71: 60: 49: 43: 40: 34: 32: 24: 17: 12: 11: 5: 1015: 1013: 1005: 1004: 999: 994: 989: 984: 979: 974: 969: 964: 959: 954: 949: 944: 934: 933: 930: 929: 922: 921:External links 919: 916: 915: 856: 807: 772: 759:(2): 285–291. 736: 677: 655: 651: 647: 643: 634: 607: 572: 551:(2): 349–360. 538: 534: 530: 519: 489: 485: 481: 472: 452: 435: 408: 402:Chemistry Tree 388: 368: 345: 324: 323: 321: 318: 281: 278: 253: 250: 233: 230: 192: 191: 188: 187: 182: 176: 175: 162: 158: 157: 152: 148: 147: 141: 140: 97: 93: 92: 87: 86:Known for 83: 82: 55: 51: 50: 44: 39:March 15, 1951 30: 26: 25: 22: 15: 13: 10: 9: 6: 4: 3: 2: 1014: 1003: 1000: 998: 995: 993: 990: 988: 985: 983: 980: 978: 977:Living people 975: 973: 970: 968: 965: 963: 960: 958: 955: 953: 950: 948: 945: 943: 940: 939: 937: 928: 925: 924: 920: 911: 907: 902: 897: 892: 887: 883: 879: 875: 871: 867: 860: 857: 852: 848: 843: 838: 834: 830: 826: 822: 818: 811: 808: 803: 799: 795: 791: 787: 783: 776: 773: 767: 762: 758: 754: 750: 743: 741: 737: 732: 728: 723: 718: 713: 708: 704: 700: 696: 692: 688: 681: 678: 673: 669: 666:: 2951–2957. 665: 661: 638: 635: 630: 626: 622: 618: 611: 608: 603: 599: 595: 591: 587: 583: 576: 573: 567: 562: 558: 554: 550: 546: 542: 523: 520: 515: 511: 507: 503: 499: 495: 492:frameworks". 476: 473: 468: 467: 462: 456: 453: 450: 446: 439: 436: 431: 427: 426: 421: 415: 413: 409: 404: 403: 398: 392: 389: 384: 383: 378: 372: 369: 364: 363: 358: 352: 350: 346: 341: 340: 335: 329: 326: 319: 317: 313: 309: 307: 303: 299: 295: 291: 287: 279: 277: 275: 271: 267: 263: 259: 251: 249: 247: 243: 239: 231: 229: 227: 223: 222:Nobel Lecture 219: 215: 211: 207: 206: 198: 189: 186: 183: 181: 177: 174: 170: 166: 163: 159: 156: 153: 149: 146: 142: 136: 129: 122: 115: 108: 101: 98: 94: 91: 88: 84: 79: 74: 68: 64: 59: 56: 52: 47: 41:(age 73) 31: 27: 20: 873: 869: 859: 824: 820: 810: 785: 781: 775: 756: 752: 694: 690: 680: 663: 659: 637: 620: 616: 610: 585: 581: 575: 548: 544: 522: 497: 493: 475: 464: 455: 438: 430:the original 423: 400: 391: 380: 371: 360: 337: 328: 314: 310: 283: 255: 235: 196: 195: 161:Institutions 144: 972:1951 births 697:(1): 1550. 466:Nobel Prize 936:Categories 382:India West 320:References 294:polyanions 35:1951-03-15 425:Dinamalar 276:in 1991. 205:-thee-rum 54:Education 910:26182892 876:: 7760. 851:23132016 827:: 1166. 802:25026475 731:32214093 602:23742145 298:sulfates 296:, e.g., 280:Research 901:4518288 878:Bibcode 829:Bibcode 722:7096394 699:Bibcode 553:Bibcode 502:Bibcode 449:YouTube 48:, India 908:  898:  849:  800:  729:  719:  600:  252:Career 151:Fields 138:(2015) 131:(2015) 124:(2016) 117:(2020) 110:(2011) 103:(2014) 96:Awards 753:Joule 906:PMID 847:PMID 798:PMID 727:PMID 598:PMID 29:Born 896:PMC 886:doi 837:doi 790:doi 786:114 761:doi 717:PMC 707:doi 668:doi 656:2−δ 648:1−y 644:1−x 625:doi 590:doi 586:113 561:doi 533:(MO 510:doi 484:(SO 447:on 203:MUN 78:PhD 938:: 904:. 894:. 884:. 872:. 868:. 845:. 835:. 823:. 819:. 796:. 784:. 755:. 751:. 739:^ 725:. 715:. 705:. 695:11 693:. 689:. 664:13 662:. 650:Co 646:Ni 619:. 596:. 584:. 559:. 549:71 547:. 543:. 508:. 498:26 496:. 463:. 422:. 411:^ 399:. 379:. 359:. 348:^ 336:. 308:. 248:. 228:. 67:MS 65:, 63:BS 37:) 912:. 888:: 880:: 874:6 853:. 839:: 831:: 825:3 804:. 792:: 769:. 763:: 757:4 733:. 709:: 701:: 674:. 670:: 654:O 652:y 631:. 627:: 621:3 604:. 592:: 569:. 563:: 555:: 539:3 537:) 535:4 531:2 516:. 512:: 504:: 490:3 488:) 486:4 482:2 469:. 405:. 385:. 342:. 199:( 80:) 76:( 69:) 61:( 33:(

Index

Amarapuram, Tamil Nadu
Madurai University
BS
MS
Indian Institute of Technology, Madras
PhD
Lithium ion battery
Fellow, American Association for the Advancement of Science
Fellow, Electrochemical Society
Henry B. Linford Award for Distinguished Teaching, Electrochemical Society
Fellow, Materials Research Society
Distinguished Alumnus Award, Indian Institute of Technology Madras
Fellow, Royal Society of Chemistry
Materials Science
Madurai Kamaraj University
University of Oxford
University of Texas at Austin
Doctoral advisor
J. Gopalakrishnan
MUN-thee-rum
Materials Science and Engineering
University of Texas at Austin
Madurai Kamaraj University
Nobel Lecture
John B. Goodenough
Amarapuram, Tamil Nadu
Madurai University
Indian Institute of Technology, Madras
Madurai Kamaraj University
John B. Goodenough

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.