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Nishino, Keitaro; Takagi, Masanobu; Kawata, Teruhisa; Murata, Ichiro; Inanaga, Junji; Nakasuji, Kazuhiro (1991). "Thiepine-iron tricarbonyl: Stabilization of thermally labile parent thiepine by transition metal complexation".
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Computational studies suggest that thiepine would eliminate a sulfur atom to form benzene. The intermediate is this process is the bicycle thianorcaradiene. In the complex with (η-C
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S is unstable and is predicted to be antiaromatic. Bulky derivatives have been isolated and shown by
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Schwan, A. L., "Thiepins" Science of
Synthesis, 2004, volume 17, 705.
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Except where otherwise noted, data are given for materials in their
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567:at the U.S. National Library of Medicine
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527:Journal of the American Chemical Society
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260:Key: BISQTCXKVNCDDA-UHFFFAOYSA-N
257:InChI=1S/C6H6S/c1-2-4-6-7-5-3-1/h1-6H
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458:is another thiepin derivative.
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569:Medical Subject Headings
559:Medical Subject Headings
513:10.1055/sos-SD-017-01065
27:Not to be confused with
650:Antiaromatic compounds
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432:, the ring is stable.
377:In organic chemistry,
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592:heterocyclic compound
590:This article about a
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411:X-ray crystallography
391:heterocyclic compound
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74:Preferred IUPAC name
539:10.1021/ja00013a051
490:2,7-Dihydrothiepine
485:2,3-Dihydrothiepine
413:to have nonplanar C
329: g·mol
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366:Infobox references
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95:Identifiers
85:Other names
18:Benzothiepin
480:Thiazepines
393:, with six
387:unsaturated
290:Properties
639:Categories
496:References
456:Damotepine
442:group and
322:Molar mass
201:5A9XLZ8CPE
147:ChemSpider
123:3D model (
102:CAS Number
645:Thiepines
448:dosulepin
35:Thiepine
555:Thiepins
474:See also
467:zotepine
452:zotepine
446:such as
428:S)Fe(CO)
417:S ring.
385:) is an
379:thiepine
181:12444286
156:13299847
112:291-72-5
78:Thiepine
29:Thiepane
440:benzene
383:thiepin
359:what is
357: (
168:PubChem
89:Thiepin
571:(MeSH)
561:(MeSH)
399:sulfur
395:carbon
354:verify
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327:110.17
274:SMILES
68:Names
594:is a
249:InChI
125:JSmol
596:stub
450:and
381:(or
192:UNII
535:doi
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218:EPA
171:CID
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349:N
315:S
312:6
309:H
306:6
303:C
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