363:
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47:
56:
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34:
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787:
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623:
590:
803:
1420:
Prasenjit Saha, Md Ashif Ali, and
Tharmalingam Punniyamurthy "Ligand-free Copper(ii) Oxide Nanoparticles Catalyzed Synthesis Of Substituted Benzoxazoles" Org. Synth. 2011, volume 88, pp. 398.
725:
903:
713:
1303:
412:
721:
810:
1551:
1465:
Fujita, M.; Hiyama, T. (1990). "Directed
Reduction of a beta-keto Amide: Erythro-1-(3-hydroxy-2-methyl-3-phenylpropanoyl)piperidine".
377:
701:
1320:
717:
567:
697:
910:
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341:
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33:
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219:
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134:
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55:
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100:
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1316:
1226:
1222:
1127:
868:
841:
582:
537:
1199:
and related derivatives. With carbanions, it serves again as a source of the benzoyl cation
1474:
1447:
1421:
1403:
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1218:
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161:
110:
1115:
993:
881:
651:
1535:
1165:
1088:
961:
519:
509:
212:
1091:, it can be generated from the parent acid and standard chlorinating agents such as
761:
1196:
1131:
1104:
1013:
872:
864:
681:
655:
283:
969:
945:. It is a colourless, fuming liquid with an irritating odour, and consists of a
847:
831:
1505:(Technical report). Joint FAO/WHO Expert Committee on Food Additives. p. 1
1381:
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192:
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1200:
989:
946:
499:
270:
232:
172:
880:
Except where otherwise noted, data are given for materials in their
643:
1301:
Maki, Takao; Takeda, Kazuo (2000). "Benzoic Acid and
Derivatives".
258:
1181:
1177:
1173:
997:
659:
541:
294:
152:
140:
133:
123:
1428:. (an illustrative reaction of an amine with benzoyl chloride).
981:
757:
489:
249:
1492:
El-Samragy, Yehia (2004). "Chemical and
Technical Assessment".
985:
1225:, is produced industrially by treating benzoyl chloride with
1110:
An early method for production of benzoyl chloride involved
745:
346:
54:
45:
1394:
Marvel, C. S.; Lazier, W. A. (1929). "Benzoyl
Piperidine".
1343:(1832). "Untersuchungen über das Radikal der Benzoesäure".
780:
898:
1438:Minnis, Wesley (1932). "Phenyl Thienyl Ketone".
282:
784:
109:
1304:Ullmann's Encyclopedia of Industrial Chemistry
8:
524:197.2 °C (387.0 °F; 470.3 K)
386:InChI=1S/C7H5ClO/c8-7(9)6-4-2-1-3-5-6/h1-5H
1291:Benzoyl chloride: toxicity and precautions
396:InChI=1/C7H5ClO/c8-7(9)6-4-2-1-3-5-6/h1-5H
361:
222:
200:
25:
1366:
318:
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1251:
1247:
1243:
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1210:
1206:
1156:
1152:
1148:
1144:
1140:
1103:. It was first prepared by treatment of
1079:
1075:
1071:
1067:
1063:
1059:
1055:
1051:
1042:
1038:
1034:
1030:
1026:
1022:
956:
952:
940:
936:
1527:International Chemical Safety Card 1015
1284:
417:
382:
357:
213:
836:72 °C (162 °F; 345 K)
389:Key: PASDCCFISLVPSO-UHFFFAOYSA-N
180:
160:
7:
581:Maybe harmful by ingestion and skin
514:−1 °C (30 °F; 272 K)
494:Benzaldehyde like but more pungent
399:Key: PASDCCFISLVPSO-UHFFFAOYAL
273:
257:
1008:Benzoyl chloride is produced from
14:
980:but is generally useful in other
16:Organochlorine compound (C7H5ClO)
1126:It reacts with water to produce
888:
613:
608:
458:
452:
32:
884:(at 25 °C , 100 kPa).
1164:Benzoyl chloride is a typical
984:such as in the preparation of
972:. It is mainly useful for the
568:Occupational safety and health
461:
446:
1:
1176:. Similarly, it reacts with
88:Benzoic acid chloride (1:1)
41:
1568:
1195:to give the corresponding
1172:to give the corresponding
18:
1552:IARC Group 2A carcinogens
878:
853:
589:
565:
560:
433:
408:
373:
93:
85:
73:
68:
40:
31:
1479:10.15227/orgsyn.069.0044
1452:10.15227/orgsyn.012.0062
1426:10.15227/orgsyn.088.0398
1408:10.15227/orgsyn.009.0016
1359:10.1002/jlac.18320030302
1313:10.1002/14356007.a03_555
1189:Friedel-Crafts acylation
1093:phosphorus pentachloride
927:benzenecarbonyl chloride
668:Precautionary statements
19:Not to be confused with
1307:. Weinheim: Wiley-VCH.
931:organochlorine compound
550:Magnetic susceptibility
1221:, a common reagent in
1012:using either water or
848:Fisher Scientific MSDS
791:
585:; possible carcinogen
59:
50:
1346:Annalen der Pharmacie
790:
58:
49:
773:(fire diamond)
75:Preferred IUPAC name
1547:Benzene derivatives
531:Solubility in water
476: g·mol
28:
1254:+ 2 NaOH → (C
1193:aromatic compounds
911:Infobox references
854:Related compounds
792:
504:1.21 g/mL, liquid
60:
51:
26:
1467:Organic Syntheses
1440:Organic Syntheses
1396:Organic Syntheses
1341:Justus von Liebig
1270:+ 2 NaCl + 2 H
1227:hydrogen peroxide
1223:polymer chemistry
1187:It undergoes the
1168:. It reacts with
1128:hydrochloric acid
933:with the formula
919:Chemical compound
917:
916:
869:benzoic anhydride
860:Related compounds
842:Safety data sheet
638:Hazard statements
538:hydrogen chloride
484:colorless liquid
425:c1ccc(cc1)C(=O)Cl
342:CompTox Dashboard
142:Interactive image
135:Interactive image
64:
63:
27:Benzoyl chloride
1559:
1515:
1514:
1512:
1510:
1500:
1495:Benzoyl Peroxide
1489:
1483:
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1370:
1337:Friedrich Wöhler
1333:
1327:
1326:
1298:
1292:
1289:
1275:
1231:sodium hydroxide
1219:Benzoyl peroxide
1214:
1160:
1097:thionyl chloride
1083:
1046:
1010:benzotrichloride
967:
959:
944:
925:, also known as
923:Benzoyl chloride
901:
895:
892:
891:
821:
820:
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556:-75.8·10 cm/mol
540:on contact with
475:
463:
460:
454:
448:
441:Chemical formula
366:
365:
350:
348:
322:
286:
275:
261:
234:
226:
215:
204:
184:
164:
144:
137:
113:
79:Benzoyl chloride
42:
36:
29:
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1558:
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1531:
1523:
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1506:
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1419:
1415:
1393:
1392:
1388:
1384:, 29 March 1932
1380:
1376:
1368:2027/hvd.hxdg3f
1335:
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1204:
1158:
1154:
1150:
1146:
1142:
1138:
1124:
1107:with chlorine.
1101:oxalyl chloride
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994:pharmaceuticals
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906: ?)
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426:
421:
420:ClC(=O)c1ccccc1
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24:
21:benzyl chloride
17:
12:
11:
5:
1565:
1563:
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1554:
1549:
1544:
1542:Acyl chlorides
1534:
1533:
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1529:
1522:
1521:External links
1519:
1517:
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1353:(3): 262–266.
1328:
1321:
1293:
1283:
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1161:
1123:
1120:
1116:benzyl alcohol
1089:acyl chlorides
1087:As with other
1085:
1084:
1047:
1045:COCl + 2 HCl
1005:
1002:
918:
915:
914:
909:
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886:
882:standard state
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726:P305+P351+P338
714:P303+P361+P353
706:P301+P330+P331
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1234:
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1224:
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1216:
1202:
1198:
1197:benzophenones
1194:
1190:
1185:
1183:
1179:
1175:
1171:
1167:
1166:acyl chloride
1137:
1136:
1135:
1133:
1129:
1121:
1119:
1117:
1113:
1108:
1106:
1102:
1098:
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1048:
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1015:
1011:
1003:
1001:
999:
995:
991:
987:
983:
979:
975:
971:
963:
962:acyl chloride
948:
932:
928:
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912:
905:
900:
883:
877:
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551:
547:
546:
543:
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535:
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528:
527:
523:
521:
520:Boiling point
518:
517:
513:
511:
510:Melting point
508:
507:
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497:
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359:DTXSID9026631
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221:
218:
216:
214:ECHA InfoCard
211:
210:
203:
199:
198:
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191:
190:
183:
182:ChEMBL2260719
179:
178:
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35:
30:
22:
1507:. Retrieved
1502:
1494:
1487:
1470:
1466:
1460:
1443:
1439:
1433:
1416:
1399:
1395:
1389:
1377:
1350:
1344:
1331:
1302:
1296:
1287:
1217:
1186:
1180:to give the
1163:
1159:COOH + HCl
1132:benzoic acid
1125:
1112:chlorination
1109:
1105:benzaldehyde
1086:
1082:COCl + HCl
1014:benzoic acid
1007:
926:
922:
921:
873:benzaldehyde
865:benzoic acid
769:
629:
591:
577:Main hazards
566:
295:RTECS number
94:Identifiers
86:Other names
1004:Preparation
970:substituent
832:Flash point
624:Signal word
571:(OHS/OSH):
481:Appearance
434:Properties
220:100.002.464
162:CHEBI:82275
1536:Categories
1509:31 October
1503:61st JECFA
1322:3527306730
1280:References
1246:COCl + H
1147:COCl + H
974:production
960:) with an
603:Pictograms
583:absorption
469:Molar mass
320:VTY8706W36
193:ChemSpider
122:3D model (
101:CAS Number
1382:US1851832
1151:O → C
1122:Reactions
1074:H → 2 C
978:peroxides
750:P333+P313
722:P304+P340
718:P304+P312
710:P302+P352
702:P301+P312
594:labelling
331:UN number
302:DM6600000
241:202-710-8
233:EC Number
1170:alcohols
990:perfumes
966:−C(=O)Cl
929:, is an
770:NFPA 704
561:Hazards
552:(χ)
1201:synthon
1037:O → C
947:benzene
904:what is
902: (
500:Density
271:PubChem
111:98-88-4
1473:: 44.
1446:: 62.
1402:: 16.
1319:
1178:amines
1174:esters
1099:, and
998:resins
996:, and
949:ring (
899:verify
896:
844:(SDS)
630:Danger
474:140.57
413:SMILES
259:C19168
173:ChEMBL
69:Names
1499:(PDF)
1191:with
1182:amide
982:areas
542:water
378:InChI
335:1736
153:ChEBI
124:JSmol
1511:2013
1317:ISBN
1229:and
1130:and
1062:+ C
1033:+ H
986:dyes
762:P501
758:P405
754:P363
746:P330
742:P322
738:P321
734:P312
730:P310
698:P280
694:P272
690:P271
686:P270
682:P264
678:P261
674:P260
660:H332
656:H317
652:H314
648:H312
644:H302
490:Odor
311:UNII
284:7412
250:KEGG
202:7134
1475:doi
1448:doi
1422:doi
1404:doi
1363:hdl
1355:doi
1309:doi
1262:CO)
1238:2 C
1114:of
1058:CCl
1029:CCl
976:of
943:ClO
592:GHS
347:EPA
274:CID
1538::
1501:.
1471:69
1469:.
1444:12
1442:.
1398:.
1361:.
1349:.
1339:,
1315:.
1233::
1215:.
1213:CO
1203:,
1184:.
1134::
1118:.
1095:,
1070:CO
1016::
1000:.
992:,
988:,
968:)
871:,
867:,
760:,
756:,
752:,
748:,
744:,
740:,
736:,
732:,
728:,
724:,
720:,
716:,
712:,
708:,
704:,
700:,
696:,
692:,
688:,
684:,
680:,
676:,
658:,
654:,
650:,
646:,
596::
459:Cl
1513:.
1481:.
1477::
1454:.
1450::
1424::
1410:.
1406::
1400:9
1371:.
1365::
1357::
1351:3
1325:.
1311::
1274:O
1272:2
1268:2
1266:O
1264:2
1260:5
1258:H
1256:6
1252:2
1250:O
1248:2
1244:5
1242:H
1240:6
1211:5
1209:H
1207:6
1205:C
1157:5
1155:H
1153:6
1149:2
1145:5
1143:H
1141:6
1139:C
1080:5
1078:H
1076:6
1072:2
1068:5
1066:H
1064:6
1060:3
1056:5
1054:H
1052:6
1050:C
1043:5
1041:H
1039:6
1035:2
1031:3
1027:5
1025:H
1023:6
1021:C
964:(
957:6
955:H
953:6
951:C
941:5
939:H
937:7
935:C
894:Y
819:W
811:0
804:2
797:3
462:O
456:5
453:H
450:7
447:C
349:)
345:(
126:)
23:.
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