Knowledge (XXG)

Cyanoacrylate

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275: 225: 372:, etc. Cyanoacrylate is warmed to produce fumes that react with the invisible fingerprint residues and atmospheric moisture to form a white polymer (polycyanoacrylate) on the fingerprint ridges. The ridges can then be recorded. The developed fingerprints are, on most surfaces (except on white plastic or similar), visible to the naked eye. Invisible or poorly visible prints can be further enhanced by applying a luminescent or non-luminescent stain. 22: 170: 262: 141:, which in turn repackaged and distributed it under a different brand name "Loctite Quick Set 404". In 1971, Loctite developed its own manufacturing technology and introduced its own line of cyanoacrylate, called "Super Bonder". Loctite quickly gained market share, and by the late 1970s it was believed to have exceeded Eastman Kodak's share in the 800: 727:
refrigerate it. Cyanoacrylates are moisture-sensitive, and moving from a cool to a hot location will create condensation; after removing from the refrigerator, it is best to let the adhesive reach room temperature before opening. After opening, it should be used within 30 days. Open containers should not be refrigerated.
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Another manufacturer says that the maximum shelf life of 12 months is obtained for some of their cyanoacrylates if the original containers are stored at 35 to 40 °F (2 to 4 °C). User forums and some manufacturers say that an almost unlimited shelf life is attainable by storing unopened at
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Cyanoacrylate adhesives may adhere to body parts, and injuries may occur when parts of the skin are torn off. Without force, however, the glue will spontaneously separate from the skin in time (up to four days). The glue can also cause chemical burns, and exposed skin should be washed with soap and
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When kept unopened in a cool, dry location such as a refrigerator at a temperature of about 55 °F (13 °C), the shelf life of cyanoacrylate will be extended from about one year from manufacture to at least 15 months. If the adhesive is to be used within six months, it is not necessary to
490:, wood instruments, and wood furniture. Cyanoacrylate glue is also used in the finishing of pen blanks (wooden blanks for turning pens) that have been turned on a lathe by applying multiple thin layers to build up a hard, clear finish that can then be sanded and polished to a glossy finish. 736:, and allowing the contents to reach room temperature before use. Opening a container while chilled may cause moisture from the air to condense in the container; however, reports from hobbyists suggest that storing cyanoacrylate in a freezer can preserve opened cyanoacrylate indefinitely. 517:
to arrow shafts. Some special fletching glues are primarily cyanoacrylate repackaged in special fletching glue kits. Such tubes often have a long, thin metal nozzle for improved precision in applying the glue to the base of the fletching and to ensure secure bonding to the arrow shaft.
340:-butyl cyanoacrylate for medical applications) have come to be used for specific applications. Three cyanoacrylate compounds are currently available as topical skin adhesives. 2-Octyl cyanoacrylate is marketed as Dermabond, SurgiSeal, and more LiquiBand Exceed. 216:
in the air causes a thin skin to start to form within seconds, which very greatly slows the reaction; hence, cyanoacrylates are applied as thin coats to ensure that the reaction proceeds rapidly for bonding. Cyanoacrylate adhesives generally have a short
249:, and tightening pins and bolts. It is also used in conjunction with another slower, but more resilient, adhesive as a way of rapidly forming a joint, which then holds the pieces in the appropriate configuration until the second adhesive has set. 347:
The ester substituent has several effects upon the biocompatibility of the adhesive. Longer side chains result in higher flexibility of the cured adhesive allowing a better match for the flexibility of skin, and can result in a slower release of
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Cyanoacrylate-based glue has a weak bond with smooth surfaces and as such easily gives to friction; a good example of this is the fact that cyanoacrylates may be removed from human skin by means of abrasives (e.g. sugar or sandpaper).
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near, on, and around the glue. If glue gets in eyes, serious injuries can occur. In any case of adhesives getting in or around the eyes, the eye(s) should be rinsed with lukewarm water for 15 minutes and medical care obtained.
297:(FDA) did not approve its use as a medical adhesive until 1998 with Dermabond (2-octyl cyanoacrylate). A 1986 independent study suggests that cyanoacrylate can be safer and more functional for wound closure than traditional 134:, Coover and a colleague, Fred Joyner, rediscovered cyanoacrylates. The two realized the true commercial potential, and a form of the adhesive was first sold in 1958 under the title "Eastman #910" (later "Eastman 910"). 612:
have concluded that the use of ethyl cyanoacrylate is safe and that additional study is unnecessary. The compound 2-octyl cyanoacrylate degrades much more slowly due to its longer organic backbone (series of
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Cyanoacrylates are mainly used as adhesives. Thin layers bond effectively, thick layers much less so. They bond many substances, including human skin and tissues, natural fibres, cotton, wool, and leather.
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Ohara, Takashi; Sato, Takahisa; Shimizu, Noboru; Prescher, Günter; Schwind, Helmut; Weiberg, Otto; Marten, Klaus; Greim, Helmut; Shaffer, Timothy D.; Nandi, Partha (2020). "Acrylic Acid and Derivatives".
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Cyanoacrylate glue is widely used in human and veterinary medicine. It was in veterinary use for mending bone, hide, and tortoise shell by the early 1970s or before. A cyanoacrylate spray was used in the
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due to inactivity or accidents) with cyanoacrylates. While the glue is not very toxic and wears off quickly with shed skin, applying large quantities of glue and its fumes directly to the skin can cause
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Pascual, Gemma; Sotomayor, Sandra; Rodríguez, Marta; Pérez-Köhler, Bárbara; Kühnhardt, Andreé; Fernández-Gutiérrez, Mar; San Román, Julio; Bellón, Juan Manuel (20 June 2016). Passi, Alberto G (ed.).
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stumbled upon a formulation that stuck to everything with which it came in contact. The team quickly rejected the substance for the wartime application, but in 1951, while working as researchers for
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strength, which has led to its use as a temporary adhesive in cases where the piece needs to be sheared off later. Common examples include mounting a workpiece to a sacrificial glue block on a
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purchased Eastman Kodak's cyanoacrylate business and combined it with several acquisitions made throughout the 1970s forming Permabond. Other manufacturers of cyanoacrylate include LePage (a
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which must be cured to be safe. However, as a class of adhesives, traditional cyanoacrylates are classified as having "weak" resistance to both moisture and heat although the inclusion of
161:. Together, Loctite, Eastman, and Permabond accounted for approximately 75% of the industrial cyanoacrylate market. As of 2019 Permabond continued to manufacture the original 910 formula. 722:
Cyanoacrylate adhesives have a short shelf life. Date-stamped containers help to ensure that the adhesive is still viable. One manufacturer supplies the following information and advice:
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molecules) and the adhesive does not reach the threshold of tissue toxicity. Due to the toxicity issues of ethyl cyanoacrylate, the use of 2-octyl cyanoacrylate for sutures is preferred.
301:(stitches). Although cyanoacrylates are widely used for sutureless wound repair, "existing adhesives still lack sufficient adhesion strength to completely replace sutures and staples." 2179: 308:
use cyanoacrylate to repair damage to the skin on their fingertips. Similarly, stringed-instrument players can form protective finger caps (typically, when they lose their
762: 601:. There is no singular measurement of toxicity for all cyanoacrylate adhesives because of the large number of adhesives that contain various cyanoacrylate formulations. 739:
As cyanoacrylates age, they polymerize, become thicker, and cure more slowly. They can be thinned with a cyanoacrylate of the same chemical composition with lower
344:-Butyl cyanoacrylate is marketed as Histoacryl, Indermil, GluStitch, GluSeal, PeriAcryl, and LiquiBand. The compound ethyl 2-cyanoacrylate is available as Epiglu. 1963: 212:), forming long, strong chains, joining the bonded surfaces together. Because the presence of moisture causes the glue to set, exposure to normal levels of 103: 569:
of the cured polymers producing gaseous products that are highly irritating. They are immediately polymerized by the moisture in the membranes and become
1996: 1891: 952: 1457: 798:, Alan E. Ardis, "Preparation of monomeric alkyl alpha-cyano-acrylates", issued 19 April 1949, assigned to B.F. Goodrich Company. 672:
for cyanoacrylate instruct users not to wear cotton (jeans) or wool clothing, especially cotton gloves, when applying or handling cyanoacrylates.
99: 1793: 185:. Several related esters are known. To facilitate easy handling, a cyanoacrylate monomer is frequently formulated with an ingredient such as 1389: 1364: 2188: 1199:
Mizrahi, Boaz; Stefanescu, Cristina F.; Yang, Celine; Lawlor, Michael W.; Ko, Dennis; Langer, Robert; Kohane, Daniel S. (August 2011).
1134:"Cytotoxicity of Cyanoacrylate-Based Tissue Adhesives and Short-Term Preclinical In Vivo Biocompatibility in Abdominal Hernia Repair" 687:(or at hardware stores in pure form), is a widely available solvent capable of softening cured cyanoacrylate. Other solvents include 1250: 779: 294: 1087: 274: 2159: 1272: 2115:
Vinters, H. V.; Galil, K. A.; Lundie, M. J.; Kaufmann, J. C. (1985). "The histotoxicity of cyanoacrylates. A selective review".
1325: 1979: 1427: 814: 1031: 2249: 1818:
Moschos, M.; Droutsas, D.; Boussalis, P.; Tsioulias, G. (1997). "Clinical experience with cyanoacrylate tissue adhesive".
2229: 482:, may be used to control the rate at which the cyanoacrylate cures. Cyanoacrylate glue is also used in combination with 436: 293:-Butyl cyanoacrylate has been used medically since the 1970s. In the US, due to its potential to irritate the skin, the 146: 1934:
Shantha, K. L.; Krishnamurti, N.; Krishnamurti, N. (1989). "Developments and applications of cyanoacrylate adhesives".
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Singer, A. J.; McClain, S. A.; Katz, A. (2004). "A porcine epistaxis model: hemostatic effects of octylcyanoacrylate".
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after curing. Alkoxy-ethyl substituents have also been investigated and have shown some promise as a medical adhesive.
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Hayes, Sharon Caskey (11 July 2004). "Discovery of Super Glue helped land Coover in National Inventors Hall of Fame".
743:. Storing cyanoacrylates below 0 °F (−18 °C) will nearly stop the polymerization process and prevent aging. 669: 609: 605: 582: 573:. These risks can be minimized by using cyanoacrylate in well-ventilated areas. About 5% of the population can become 205: 380:
Cyanoacrylate is used in the cosmetology and beauty industry as an eyelash extension glue, or a "nail glue" for some
221:—about one year from manufacture if unopened, and one month once opened, but this can be extended by refrigeration. 78:(used in medical, veterinary and first aid applications). Cyanoacrylate adhesives are sometimes known generically as 574: 2068:
Perry, L. C. "An evaluation of acute incisional strength with Traumaseal surgical tissue adhesive wound closure".
1960: 2244: 2174: 425: 325: 2204: 1471: 1666: 2000: 1268:"Similarities in the packaging of cyanoacrylate nail glue and ophthalmic preparations: an ongoing problem" 590: 115: 75: 1405: 493:
Some hobby applications call for cyanoacrylate glue mixed with inorganic fillers such as baking soda (
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Quinn, J. & Kissack, J. (1994). "Tissue Adhesives for Laceration Repair During Sporting Events".
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Duvvi, Sham K.; Lo, Stephen; Kumar, R.; Spraggs, P. (2005). "Superglue (Cyanoacrylate) in the Nose".
1145: 1095: 56: 455:(epoxy putty) to allow the new fragment to grow out. It is safe to use directly in the tank, unlike 1786: 849: 711: 704: 684: 487: 389: 182: 174: 71: 64: 60: 37: 2031: 2224: 2140: 2094: 1916: 1843: 1691: 1053: 977: 906: 700: 696: 494: 479: 460: 365: 242: 1612: 2209: 2239: 2183: 2163: 2132: 1908: 1835: 1768: 1733: 1725: 1591: 1542: 1534: 1385: 1360: 1307: 1289: 1230: 1181: 1163: 1011: 969: 898: 775: 692: 594: 578: 1107: 2124: 2086: 2018: 1943: 1900: 1827: 1760: 1717: 1581: 1573: 1526: 1297: 1281: 1220: 1212: 1171: 1153: 961: 925: 890: 767: 570: 566: 420:. Their effectiveness in bonding metal and general versatility have made them popular among 381: 224: 157:
in 1996), the Permabond Division of National Starch and Chemical, which was a subsidiary of
2024: 1967: 1254: 1091: 1035: 432: 1721: 1247: 486:(from a saw or sanding) to fill voids and cracks. These repair methods are used on piano 1577: 1149: 1084: 1048: 320:
While standard "superglue" is 100% ethyl 2-cyanoacrylate, many custom formulations (e.g.
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of live plants to pieces of wood or stone. Thin cyanoacrylate glue has application in
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Clarke, T.F.E. (2011). "Cyanoacrylate glue burn in a child – lessons to be learned".
910: 614: 553: 498: 333: 314: 305: 209: 142: 131: 2144: 2098: 1920: 1847: 1333: 981: 21: 1637: 688: 665: 440: 349: 329: 186: 169: 127: 123: 1435: 818: 771: 1904: 1216: 1158: 965: 287:
to reduce bleeding in wounded soldiers until they could be taken to a hospital.
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An incision wound closed with Dermabond, a cyanoacrylate-based medical adhesive
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Schwade, Nathan D. (10 April 2002). "Wound Adhesives, 2-Octyl Cyanoacrylate".
1861: 1497: 1067: 661: 657: 218: 63:(ECA, commonly sold under trade names such as "Super Glue" and "Krazy Glue"), 1729: 1538: 1293: 1167: 384:
enhancements such as nail tips and nail wraps, and is sometimes mistaken for
90:. The abbreviation "CA" is commonly used for industrial grade cyanoacrylate. 2169: 1947: 740: 514: 448: 405: 385: 1912: 1772: 1595: 1546: 1311: 1234: 1185: 973: 902: 795: 2136: 1839: 1737: 1285: 1015: 471: 456: 452: 444: 361: 298: 213: 158: 33: 2128: 1831: 1502: 839:
HBS, "Loctite Corporation: Industrial Product Group," 15 July 1991, p.3
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Cyanoacrylate glue's ability to resist water has made it popular with
1201:"Elasticity and safety of alkoxyethyl cyanoacrylate tissue adhesives" 629: 617: 598: 470:
both freshwater and marine aquariums for the purpose of securing the
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as an outgrowth of a search for materials suitable for clear plastic
111: 197:, creating a more impact resistant bond. Such additives may include 36:
with industrial, medical, and household uses. They are derived from
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Clarke, TFE (March 2011). "Superglue (Cyanoacrylate) in the Nose".
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or gel-like. Formulations are available with additives to increase
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Application note on measuring cure kinetics of cyanoacrylate glues
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Nam, Sungmin; Mooney, David (2021). "Polymeric Tissue Adhesives".
633: 478:. It can be used as a fast-drying, glossy finish. An oil, such as 417: 273: 260: 246: 223: 201:, as in Loctite's "Ultra Gel", or others which are not specified. 168: 97: 41: 20: 732:−4 °F (−20 °C), the typical temperature of a domestic 653: 645: 531: 1458:"S-FIXX APX4 Ultra Strength Superglue Adhesive and Powders Kit" 1094:
from the Physical and Theoretical Chemistry Laboratory of the
993: 991: 703:. Another viable solvent for removing cured cyanoacrylate is 577:
to cyanoacrylate fumes after repeated exposure, resulting in
1980:"MASTER BOND MB SERIES CYANOACRYLATES: Technical Data Sheet" 1753:
Journal of Plastic, Reconstructive & Aesthetic Surgery
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Journal of Plastic, Reconstructive & Aesthetic Surgery
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Was Super Glue invented to seal battle wounds in Vietnam?
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Fernandez, Tania & Bliskovsky, Val (2 January 2003).
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http://www.accessdata.fda.gov/cdrh_docs/pdf10/K101276.pdf
1661: 1659: 710:. Commercial debonders are also available, many based on 628:
Applying cyanoacrylate to some natural materials such as
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Reaction with cotton, wool, and other fibrous materials
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American Conference of Governmental Industrial Hygienists
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Harry Wesley Coover Jr. shortly before being awarded the
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http://www.accessdata.fda.gov/cdrh_docs/pdf8/K083531.pdf
581:. Cyanoacrylate may also be a skin irritant, causing an 2199:
Alcohol-Catalyzed α-Cyanoacrylate Adhesive Compositions
2175:
Cyanoacrylate Adhesive / Super Glue Safety Data Sheets
1961:
Palm Labs Adhesives: Cyanoacrylate Adhesive Shelf Life
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Eiferman, Richard A.; Snyder, James W. (1 June 1983).
817:. Lemelson-MIT Program. September 2004. Archived from 552:
warm water. Separation can be accelerated by applying
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reportedly counteracts both of these characteristics.
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During the 1960s, Eastman Kodak sold cyanoacrylate to
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in the presence of water to form long, strong chains.
1498:"Leon Paul Fencing || Foil Tip Maintenance" 25:
Structure of the backbone of a cyanoacrylate polymer.
1792:. Arrowhead Forensics. 14 May 2015. pp. 4, 6. 1787:"Microsoft Word - New Si 5-5000 SDS 14MAY15.docx" 1038:. climbingaction.com. Retrieved 19 February 2011. 1000:"Non-suture closure of wound using cyanoacrylate" 926:"Harry Coover, Super Glue's Inventor, Dies at 94" 126:effort. In 1942, a team of scientists headed by 1248:Eric W. Brown "The Cyanoacrylate Fuming Method" 2059:Jueneman, F. (August 1981). "Stick it to um". 763:Ullmann's Encyclopedia of Industrial Chemistry 530:to glue the blade wire into the groove of the 466:Cyanoacrylate glue is also used frequently in 400:Cyanoacrylates are used to assemble prototype 8: 1706:"Antibacterial Effect of Cyanoacrylate Glue" 1692:Methyl Cyanoacrylate and Ethyl Cyanoacrylate 1406:"Fine Woodworking: Super Glue to the Rescue" 597:. On rare occasions, inhalation may trigger 265:A tube of "Super Glue", a cyanoacrylate glue 177:, the precursor to many commercial adhesives 998:Dalvi, A A; Faria, M M; Pinto, A A (1986). 388:causing accidental injury (adhesion and/or 204:In general, the C=C groups rapidly undergo 114:for cyanoacrylate was filed in 1947 by the 104:National Medal of Technology and Innovation 1936:Journal of Adhesion Science and Technology 1638:"7 methods to get super glue off the skin" 1068:"Document: Cyanoacrylate adhesives (GOLD)" 1585: 1301: 1224: 1175: 1157: 660:reaction. This reaction also occurs with 1997:"WEICON Contact Cyanoacrylate Adhesives" 228:Polymerization of methyl 2-cyanoacrylate 2201:, filed June 1954, issued October 1956. 1049:"The Claim: Super Glue Can Heal Wounds" 751: 208:in the presence of water (specifically 2032:"Cyanoacrylate Technology: Stay Glued" 1566:International Journal of Ophthalmology 1384:. New York: McGraw-Hill. p. 389. 1359:. New York: McGraw-Hill. p. 354. 924:Harris, Elizabeth A. (28 March 2011). 876: 874: 766:. Weinheim: Wiley-VCH. pp. 1–21. 2061:Industrial Research & Development 1607: 1605: 7: 1892:Otolaryngology–Head and Neck Surgery 1722:10.1001/archopht.1983.01040010958022 1108:"Topical skin adhesives. DermNet NZ" 953:Otolaryngology–Head and Neck Surgery 147:National Starch and Chemical Company 2205:3M Activators, Primers and Debonder 1799:from the original on 28 August 2024 1578:10.3980/j.issn.2222-3959.2012.05.18 1085:Safety data for ethyl cyanoacrylate 1047:Anahad O'Connor (4 December 2007). 850:"Permabond 910 Technical Datasheet" 368:on non-porous surfaces like glass, 32:are a family of strong fast-acting 2189:Cyanoacrylate Technical Data Sheet 2079:Clinical Journal of Sport Medicine 1382:Handbook of adhesives and sealants 1357:Handbook of adhesives and sealants 683:, commonly found as a fraction of 14: 412:, and as retention dressings for 336:, and variations on the compound 295:U.S. Food and Drug Administration 145:industrial cyanoacrylate market. 44:. The cyanoacrylate group in the 2091:10.1097/00042752-199410000-00006 2070:Dimensional Analysis Systems Inc 1273:British Journal of Ophthalmology 332:, and a small amount of organic 55:Specific cyanoacrylates include 1862:"BSI Un-Cure Safety Data Sheet" 1562:"Superglue injuries of the eye" 2180:Safety in the Home: Super Glue 815:"Inventor of the Week Archive" 656:results in a powerful, rapid, 1: 1057:. Retrieved 19 February 2011. 772:10.1002/14356007.a01_161.pub4 447:, can be glued to a piece of 241:Cyanoacrylate glue has a low 1905:10.1016/j.otohns.2004.09.090 1217:10.1016/j.actbio.2011.04.022 1159:10.1371/journal.pone.0157920 966:10.1016/j.otohns.2003.09.035 439:corals. The cut branches of 16:Type of fast-acting adhesive 2017:derma+flex QS 510k Letter: 895:10.1021/acs.chemrev.0c00798 670:Material safety data sheets 610:National Toxicology Program 606:Health and Safety Executive 360:Cyanoacrylate is used as a 206:chain-growth polymerisation 181:The most common monomer is 2266: 1765:10.1016/j.bjps.2011.03.009 1531:10.1016/j.bjps.2011.03.009 1380:Petrie, Edward M. (2000). 1355:Petrie, Edward M. (2000). 451:(harvested reef coral) or 1820:Documenta Ophthalmologica 1710:Archives of Ophthalmology 526:Cyanoacrylate is used in 509:Cyanoacrylate is used in 326:poly(methyl methacrylate) 1826:(3). Soringer: 237–245. 1667:"CA PLUS Adhesives, Inc" 1642:www.medicalnewstoday.com 1428:"Propeller Field Repair" 1090:11 February 2009 at the 1034:27 November 2010 at the 2023:LiquiBand 510k Letter: 1948:10.1163/156856189X00191 1253:20 October 2007 at the 2170:Cyanoacrylate Toxicity 1617:Missouri Poison Center 1326:"Metal adhesive guide" 1266:Needham, A. D (2001). 729: 676:Solvents and debonders 608:and the United States 593:exposure limit of 200 583:allergic skin reaction 279: 270:Medical and veterinary 266: 229: 178: 173:Chemical structure of 107: 57:methyl 2-cyanoacrylate 26: 2195:U.S. patent 2,768,109 1286:10.1136/bjo.85.4.496a 724: 604:The United Kingdom's 591:threshold limit value 277: 264: 227: 172: 116:B.F. Goodrich Company 101: 76:2-octyl cyanoacrylate 61:ethyl 2-cyanoacrylate 24: 2250:Cyanoacrylate esters 2052:Kingsport Times-News 1966:14 July 2014 at the 1560:Reddy, S.C. (2012). 1330:Adhesiveplatform.com 1096:University of Oxford 153:company acquired by 68:-butyl cyanoacrylate 2230:American inventions 1942:(1). VSP: 237–260. 1150:2016PLoSO..1157920P 889:(18): 11336–11384. 712:propylene carbonate 685:nail polish remover 390:chemical eye injury 366:latent fingerprints 183:ethyl cyanoacrylate 175:ethyl cyanoacrylate 72:octyl cyanoacrylate 38:ethyl cyanoacrylate 2235:Medical treatments 2129:10.1007/BF00339559 2036:test.pharmabiz.com 1832:10.1007/BF02569064 1438:on 31 January 2018 1205:Acta Biomaterialia 1054:The New York Times 930:The New York Times 701:methylene chloride 697:dimethyl sulfoxide 495:sodium bicarbonate 480:boiled linseed oil 461:phthalic anhydride 280: 267: 233:General properties 230: 179: 108: 27: 2184:Queensland Health 2164:The Straight Dope 2108:eMedicine article 1644:. 31 October 2018 1391:978-0-07-049888-4 1366:978-0-07-049888-4 1336:on 20 August 2020 1112:www.dermnetnz.org 857:www.permabond.com 693:dimethylformamide 615:covalently bonded 595:parts per billion 589:(ACGIH) assign a 579:flu-like symptoms 396:Niche and hobbies 2257: 2245:Synthetic resins 2197: 2148: 2111: 2102: 2073: 2064: 2055: 2046: 2044: 2042: 2005: 2004: 1999:. 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Index


adhesives
ethyl cyanoacrylate
esters
monomer
polymerizes
methyl 2-cyanoacrylate
ethyl 2-cyanoacrylate
n-butyl cyanoacrylate
octyl cyanoacrylate
2-octyl cyanoacrylate

National Medal of Technology and Innovation
patent
B.F. Goodrich Company
gun sights
the war
Harry Coover Jr.
Eastman Kodak
Loctite
North American
National Starch and Chemical Company
Canadian
Henkel
Unilever

ethyl cyanoacrylate
ethyl cyanoacrylate
fumed silica
viscous

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