49:
261:
168:
65:
410:
39:
807:
415:
414:
413:
510:
416:
48:
842:
727:
Park, J. D.; Rosser, R. W.; Lacher, J. R. (1962). "Preparation of
Perfluoronitrosoalkanes. Reaction of Trifluoroacetic Anhydride with Nitrosyl Chloride".
438:
779:
Griffin, C. E.; Haszeldine, R. N. (1960). "279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers".
602:
Griffin, C. E.; Haszeldine, R. N. (1960). "279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers".
763:
549:
with a yield of up to 90% in normal pressure. A small amount of mercury is needed as catalyst. The reaction results in the creation of
827:
431:
275:
811:
700:
Taylor, C. W.; Brice, T. J.; Wear, R. L. (1962). "The
Preparation of Polyfluoronitrosoalkanes from Nitrosyl Polyfluoroacylates".
377:
458:
218:
561:
Although it is somewhat more kinetically stable due to its fluorine substituents, trifluoronitrosomethane, like other
239:
424:
832:
38:
837:
175:
582:
163:
538:
77:
506:
256:
107:
759:
784:
736:
709:
682:
673:
641:
607:
478:
303:
227:
145:
482:
260:
167:
117:
64:
522:
518:
452:
821:
486:
361:
351:
156:
542:
526:
514:
207:
328:
136:
645:
625:
502:
806:
788:
611:
546:
437:
430:
423:
396:
740:
713:
686:
562:
490:
194:
176:
501:
Trifluoronitrosomethane was synthesized for the first time in 1936 by
550:
17:
451:
Except where otherwise noted, data are given for materials in their
537:
Trifluoronitrosomethane can be produced from the reaction of
493:
group. Its distinctive deep blue color is unusual for a gas.
244:
47:
37:
573:
Trifluoronitrosoethylene is also a similar deep blue gas.
628:; Giese, Manfred (1936). "Das Trifluor-nitroso-methan, CF
408:
565:
compounds, has a weak C–N bond of only 39.9 kcal/mol.
511:
Schlesische
Friedrich-Wilhelms-Universität zu Breslau
756:Comprehensive Handbook of Chemical Bond Energies
206:
412:
116:
52:Space-filling model of trifluoronitrosomethane
356:−196.6 °C (−321.9 °F; 76.5 K)
8:
758:. Boca Raton, Fl.: CRC Press. p. 406.
42:Skeletal formula of trifluoronitrosomethane
259:
166:
144:
26:
781:Journal of the Chemical Society (Resumed)
604:Journal of the Chemical Society (Resumed)
226:
594:
366:−85 °C (−121 °F; 188 K)
280:
255:
157:
287:Key: PGOMVYSURVZIIW-UHFFFAOYSA-N
7:
197:
843:Substances discovered in the 1930s
25:
805:
318:
312:
63:
455:(at 25 °C , 100 kPa).
378:Occupational safety and health
321:
309:
1:
513:. It was created through the
729:Journal of Organic Chemistry
702:Journal of Organic Chemistry
659:Senning, Alexander (1964). "
671:-trihalomethyl compounds".
284:InChI=1S/CF3NO/c2-1(3,4)5-6
33:
859:
828:Trifluoromethyl compounds
449:
375:
370:
296:
271:
100:
93:Trifluoro-nitroso-methane
88:
82:Trifluoro(nitroso)methane
76:
71:
62:
32:
646:10.1002/cber.19360690411
91:Trifluoro-nitrosomethane
28:Trifluoronitrosomethane
812:Trifluoronitrosomethane
583:Trichloronitrosomethane
471:Trifluoronitrosomethane
95:Nitrosotrifluoromethane
473:(commonly abbreviated
419:
53:
43:
418:
51:
41:
814:at Wikimedia Commons
789:10.1039/JR9600001398
754:Luo, Yu-Ran (2007).
612:10.1039/JR9600001398
539:trifluoroiodomethane
401:(fire diamond)
78:Preferred IUPAC name
741:10.1021/jo01051a519
714:10.1021/jo01050a523
687:10.1021/cr60236a001
521:in the presence of
336: g·mol
29:
634:Ber Dtsch Chem Ges
459:Infobox references
420:
54:
44:
27:
833:Nitroso compounds
810:Media related to
765:978-0-8493-7366-4
553:as a by-product.
467:Chemical compound
465:
464:
240:CompTox Dashboard
58:
57:
16:(Redirected from
850:
838:Gases with color
809:
793:
792:
776:
770:
769:
751:
745:
744:
724:
718:
717:
708:(3): 1064–1066.
697:
691:
690:
674:Chemical Reviews
656:
650:
649:
622:
616:
615:
599:
487:covalently bound
481:consisting of a
479:organic compound
440:
433:
426:
411:
335:
323:
320:
314:
311:
304:Chemical formula
264:
263:
248:
246:
230:
210:
199:
178:
170:
159:
148:
120:
67:
34:
30:
21:
858:
857:
853:
852:
851:
849:
848:
847:
818:
817:
802:
797:
796:
778:
777:
773:
766:
753:
752:
748:
726:
725:
721:
699:
698:
694:
658:
657:
653:
631:
624:
623:
619:
601:
600:
596:
591:
579:
571:
559:
535:
499:
483:trifluoromethyl
468:
461:
456:
445:
444:
443:
442:
435:
428:
421:
417:
409:
388:
345:
333:
317:
306:
292:
289:
288:
285:
279:
278:
267:
249:
242:
233:
213:
200:
188:
151:
123:
110:
96:
94:
92:
84:
83:
23:
22:
15:
12:
11:
5:
856:
854:
846:
845:
840:
835:
830:
820:
819:
816:
815:
801:
800:External links
798:
795:
794:
771:
764:
746:
719:
692:
681:(4): 385–412.
651:
640:(4): 684–689.
629:
617:
593:
592:
590:
587:
586:
585:
578:
575:
570:
567:
558:
555:
534:
531:
523:silver nitrate
519:silver cyanide
498:
495:
466:
463:
462:
457:
453:standard state
450:
447:
446:
436:
429:
422:
407:
406:
405:
404:
402:
393:
392:
389:
386:
383:
382:
373:
372:
368:
367:
364:
358:
357:
354:
348:
347:
344:Deep blue gas
342:
338:
337:
331:
325:
324:
315:
307:
302:
299:
298:
294:
293:
291:
290:
286:
283:
282:
274:
273:
272:
269:
268:
266:
265:
252:
250:
238:
235:
234:
232:
231:
223:
221:
215:
214:
212:
211:
203:
201:
193:
190:
189:
187:
186:
182:
180:
172:
171:
161:
153:
152:
150:
149:
141:
139:
133:
132:
129:
128:Abbreviations
125:
124:
122:
121:
113:
111:
106:
103:
102:
98:
97:
90:
86:
85:
81:
80:
74:
73:
69:
68:
60:
59:
56:
55:
45:
24:
14:
13:
10:
9:
6:
4:
3:
2:
855:
844:
841:
839:
836:
834:
831:
829:
826:
825:
823:
813:
808:
804:
803:
799:
790:
786:
783:: 1398–1406.
782:
775:
772:
767:
761:
757:
750:
747:
742:
738:
734:
730:
723:
720:
715:
711:
707:
703:
696:
693:
688:
684:
680:
676:
675:
670:
666:
662:
655:
652:
647:
643:
639:
635:
632:.NO (III.)".
627:
621:
618:
613:
609:
605:
598:
595:
588:
584:
581:
580:
576:
574:
568:
566:
564:
556:
554:
552:
548:
544:
540:
532:
530:
528:
524:
520:
516:
512:
508:
507:Manfred Giese
504:
496:
494:
492:
488:
484:
480:
477:) is a toxic
476:
472:
460:
454:
448:
441:
434:
427:
403:
400:
399:
395:
394:
390:
385:
384:
380:
379:
374:
369:
365:
363:
362:Boiling point
360:
359:
355:
353:
352:Melting point
350:
349:
346:Purple solid
343:
340:
339:
332:
330:
327:
326:
308:
305:
301:
300:
295:
281:
277:
270:
262:
258:
257:DTXSID3073896
254:
253:
251:
241:
237:
236:
229:
225:
224:
222:
220:
217:
216:
209:
205:
204:
202:
196:
192:
191:
184:
183:
181:
179:
174:
173:
169:
165:
162:
160:
158:ECHA InfoCard
155:
154:
147:
143:
142:
140:
138:
135:
134:
130:
127:
126:
119:
115:
114:
112:
109:
105:
104:
99:
87:
79:
75:
70:
66:
61:
50:
46:
40:
36:
35:
31:
19:
780:
774:
755:
749:
732:
728:
722:
705:
701:
695:
678:
672:
668:
664:
660:
654:
637:
633:
620:
603:
597:
572:
560:
543:nitric oxide
536:
527:silver oxide
515:fluorination
500:
474:
470:
469:
397:
387:Main hazards
376:
101:Identifiers
89:Other names
735:(4): 1642.
381:(OHS/OSH):
341:Appearance
297:Properties
164:100.005.804
822:Categories
626:Ruff, Otto
589:References
557:Properties
533:Production
329:Molar mass
228:M9H4YRQ7XZ
137:ChemSpider
108:CAS Number
503:Otto Ruff
185:206-383-2
177:EC Number
606:: 1398.
577:See also
547:UV light
545:under a
398:NFPA 704
371:Hazards
118:334-99-6
667:-, and
569:Related
563:nitroso
509:at the
497:History
491:nitroso
195:PubChem
762:
551:iodine
485:group
391:Toxic
334:99.012
72:Names
489:to a
276:InChI
208:67630
146:60949
131:TFNM
18:CF3NO
760:ISBN
541:and
525:and
505:and
475:TFNM
219:UNII
785:doi
737:doi
710:doi
683:doi
663:-,
642:doi
608:doi
517:of
245:EPA
198:CID
824::
733:27
731:.
706:27
704:.
679:65
677:.
638:69
636:.
529:.
791:.
787::
768:.
743:.
739::
716:.
712::
689:.
685::
669:S
665:0
661:N
648:.
644::
630:3
614:.
610::
439:0
432:1
425:3
322:O
319:N
316:3
313:F
310:C
247:)
243:(
20:)
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