73:
27:
215:
are formed. With increasing fluorine content the colour changes from dark grey to cream white indicating the loss of the aromatic character. The fluorine atoms are located in an alternating fashion above and under the former
644:
224:
carbon-fluorine bonds. Reaction of carbon with fluorine at even higher temperature successively destroys the graphite compound to yield a mixture of gaseous
637:
475:
Radek Zboril; Frantisek
Karlicky; A.B. Bourlinos; T.A. Steriotis; A.K. Stubos; V. Georgakilas; K. Safarova; D. Jancik; C. Trapalis; Michal Otyepka (2010).
630:
394:
913:
598:
453:
841:
528:"Metal/Fluorocarbon Pyrolants: VI. Combustion Behaviour and Radiation Properties of Magnesium/Poly(Carbon Monofluoride) Pyrolant"
203:
Carbon is stable in a fluorine atmosphere up to about 400 °C, but between 420-600 °C a reaction takes place to give sub
193:
109:
653:
188:
428:
Troyanov, Sergei I.; Troshin, Pavel A.; Boltalina, Olga V.; Ioffe, Ilya N.; Sidorov, Lev N.; Kemnitz, Erhard (2001).
918:
429:
588:
302:
288:
68:
353:
477:"Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene"
229:
237:
40:
908:
726:
622:
211:
appearing dark grey. With increasing temperature and fluorine pressure stoichiometries up to CF
771:
751:
604:
594:
547:
508:
457:
390:
357:
314:
527:
384:
743:
721:
705:
697:
539:
498:
490:
449:
179:
175:
86:
565:
50:
783:
759:
713:
689:
676:
481:
349:
333:
72:
872:
867:
731:
681:
503:
476:
326:
204:
103:
902:
877:
61:
225:
825:
262:
reacts with fluorine gas to give fullerene fluorides with stoichiometries up to C
882:
815:
593:. Studies in Inorganic Chemistry Vol. 8 (First ed.). Amsterdam: Elsevier.
183:
608:
551:
367:
Carbon monofluoride is commercially available as
Carbofluor-brand materials.
887:
862:
846:
820:
341:
255:
252:
26:
543:
512:
494:
461:
454:
10.1002/1521-3773(20010618)40:12<2285::AID-ANIE2285>3.0.CO;2-Y
416:
361:
221:
217:
197:
171:
167:
163:
810:
805:
799:
329:
656:
102:
Except where otherwise noted, data are given for materials in their
345:
337:
626:
251:
In a similar fashion in 2001 it was found that the carbon
162:, is a material formed by high-temperature reaction of
313:
Graphite fluoride is a precursor for preparation of
855:
834:
792:
664:
587:Watanabe, N.; Nakajima, T.; Touhara, H. (1988).
220:plane, which is now buckled due to formation of
417:BBC – h2g2 – Carbon and its Inorganic Compounds
49:
566:"Carbofluor | Advance Research Chemicals, Inc"
638:
284:Other intercalation fluorides of carbon are:
8:
386:Metal-Fluorocarbon Based Energetic Materials
645:
631:
623:
273:A precursor of carbon monofluoride is the
71:
18:
502:
389:. John Wiley & Sons. pp. 25–27.
348:. Graphite fluoride is also used as both
275:fluorine-graphite intercalation compound
442:Angewandte Chemie International Edition
375:
325:Carbon monofluoride is used as a high-
62:
532:Propellants, Explosives, Pyrotechnics
383:Ernst-Christian Koch (3 April 2012).
344:, and weather-resistant additive for
7:
336:of the "BR" type. Other uses are a
178:powder. It is a highly hydrophobic
14:
842:Graphite intercalation compounds
194:graphite intercalation compounds
25:
317:by a liquid phase exfoliation.
106:(at 25 °C , 100 kPa).
1:
935:
914:Inorganic carbon compounds
156:poly(carbon monofluoride)
100:
79:
33:
24:
438:: An Indented Fullerene"
303:tetracarbon monofluoride
340:reduction additive for
289:poly(dicarbon fluoride)
207:carbon monofluoride, CF
144:polycarbon monofluoride
654:Inorganic compounds of
544:10.1002/prep.200500007
495:10.1002/smll.201001401
526:Koch, E.‐C. (2005).
20:Carbon monofluoride
570:www.fluoridearc.com
354:combustion modifier
238:tetrafluoroethylene
200:graphite compound.
152:polycarbon fluoride
122:Carbon monofluoride
21:
856:Oxides and related
590:Graphite Fluorides
358:rocket propellants
230:tetrafluoromethane
110:Infobox references
19:
896:
895:
489:(24): 2885–2891.
448:(12): 2285–2287.
430:"Two Isomers of C
396:978-3-527-32920-5
334:lithium batteries
315:graphene fluoride
192:. In contrast to
160:graphite fluoride
118:Chemical compound
116:
115:
16:Chemical compound
926:
919:Nonmetal halides
659:and related ions
647:
640:
633:
624:
619:
617:
615:
580:
579:
577:
576:
562:
556:
555:
523:
517:
516:
506:
472:
466:
465:
425:
419:
414:
408:
407:
405:
403:
380:
191:
180:microcrystalline
176:pyrolytic carbon
87:Chemical formula
75:
64:
53:
29:
22:
934:
933:
929:
928:
927:
925:
924:
923:
899:
898:
897:
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873:Metal carbonyls
851:
830:
788:
779:
775:
767:
763:
755:
747:
739:
735:
717:
709:
701:
693:
685:
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613:
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586:
583:
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525:
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437:
433:
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411:
401:
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382:
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350:oxidizing agent
323:
308:
298:
294:
269:
265:
261:
247:
243:
235:
214:
210:
187:
142:), also called
140:
133:
119:
112:
107:
95:
89:
56:
43:
17:
12:
11:
5:
932:
930:
922:
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916:
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894:
893:
891:
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885:
880:
875:
870:
865:
859:
857:
853:
852:
850:
849:
844:
838:
836:
835:Nanostructures
832:
831:
829:
828:
823:
818:
813:
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803:
796:
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790:
789:
787:
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737:
733:
729:
724:
719:
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621:
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582:
581:
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538:(3): 209–215.
518:
467:
435:
431:
420:
409:
395:
374:
372:
369:
327:energy-density
322:
319:
311:
310:
306:
300:
296:
292:
277:, also called
267:
263:
259:
245:
241:
233:
212:
208:
205:stoichiometric
138:
131:
117:
114:
113:
108:
104:standard state
101:
98:
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81:
77:
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66:
58:
57:
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46:
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30:
15:
13:
10:
9:
6:
4:
3:
2:
931:
920:
917:
915:
912:
910:
907:
906:
904:
889:
886:
884:
881:
879:
878:Carbonic acid
876:
874:
871:
869:
866:
864:
861:
860:
858:
854:
848:
845:
843:
840:
839:
837:
833:
827:
826:Thiofulminate
824:
822:
819:
817:
814:
812:
809:
807:
804:
801:
798:
797:
795:
791:
785:
782:
780:
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768:
758:
756:
750:
748:
742:
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730:
728:
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723:
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704:
702:
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688:
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669:
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663:
658:
655:
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643:
641:
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634:
629:
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610:
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602:
600:9780444428851
596:
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584:
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541:
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290:
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286:
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257:
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249:
239:
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227:
226:fluorocarbons
223:
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67:
65:
63:ECHA InfoCard
60:
59:
52:
48:
47:
45:
42:
38:
37:
32:
28:
23:
883:Bicarbonates
671:
612:. Retrieved
589:
573:. Retrieved
569:
560:
535:
531:
521:
486:
480:
470:
445:
441:
423:
412:
402:16 September
400:. Retrieved
385:
378:
366:
332:material in
324:
312:
283:
279:fluorine-GIC
278:
274:
272:
250:
202:
182:powder. Its
159:
155:
151:
147:
143:
136:
129:
125:
121:
120:
34:Identifiers
816:Thiocyanate
793:Carbon ions
614:23 December
321:Application
80:Properties
69:100.051.920
903:Categories
888:Carbonates
847:Fullerides
575:2018-09-13
371:References
342:lubricants
189:51311-17-2
184:CAS number
51:51311-17-2
41:CAS Number
909:Fluorides
821:Fulminate
665:Compounds
609:438996069
552:0721-3115
362:pyrolants
256:fullerene
253:allotrope
166:gas with
868:Nitrides
800:Carbides
513:21104801
462:29711847
305:(TCMF, C
228:such as
222:covalent
218:graphene
198:covalent
196:it is a
172:charcoal
168:graphite
164:fluorine
811:Cyanate
806:Cyanide
504:3020323
330:cathode
96:
863:Oxides
657:carbon
607:
597:
550:
511:
501:
460:
393:
346:paints
236:, and
158:, and
482:Small
174:, or
135:, or
802:, ,
616:2020
605:OCLC
595:ISBN
548:ISSN
509:PMID
458:PMID
404:2012
391:ISBN
360:and
352:and
338:wear
232:, CF
213:1.12
209:0.68
150:),
137:(CF)
92:(CF)
784:SiC
752:CSe
722:COS
540:doi
499:PMC
491:doi
450:doi
356:in
309:F).
291:((C
258:, C
240:, C
186:is
148:PMF
905::
744:CS
727:CS
714:CO
706:CO
698:CO
690:CO
682:CO
677:CO
672:CF
603:.
568:.
546:.
536:30
534:.
530:.
507:.
497:.
485:.
479:.
456:.
446:40
444:.
440:.
436:48
432:60
364:.
299:);
295:F)
281:.
270:.
268:48
264:60
260:60
248:.
170:,
154:,
130:CF
128:,
126:CF
778:2
776:S
774:3
772:C
766:2
764:O
762:3
760:C
754:2
746:2
738:2
736:S
734:2
732:C
716:6
708:5
700:4
692:3
684:2
646:e
639:t
632:v
618:.
578:.
554:.
542::
515:.
493::
487:6
464:.
452::
434:F
406:.
307:4
297:n
293:2
266:F
246:4
244:F
242:2
234:4
146:(
139:n
132:x
124:(
94:x
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