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Cathode

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negative ionised dopants near the junction. These layers of fixed positive and negative charges are collectively known as the depletion layer because they are depleted of free electrons and holes. The depletion layer at the junction is at the origin of the diode's rectifying properties. This is due to the resulting internal field and corresponding potential barrier which inhibit current flow in reverse applied bias which increases the internal depletion layer field. Conversely, they allow it in forwards applied bias where the applied bias reduces the built in potential barrier.
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inappropriate, whereas "cathode" meaning 'West electrode' would have remained correct with respect to the unchanged direction of the actual phenomenon underlying the current, then unknown but, he thought, unambiguously defined by the magnetic reference. In retrospect the name change was unfortunate, not only because the Greek roots alone do not reveal the cathode's function any more, but more importantly because, as we now know, the Earth's magnetic field direction on which the "cathode" term is based is subject to
366: 610:. Treated cathodes require less surface area, lower temperatures and less power to supply the same cathode current. The untreated tungsten filaments used in early tubes (called "bright emitters") had to be heated to 1,400 Â°C (2,550 Â°F), white-hot, to produce sufficient thermionic emission for use, while modern coated cathodes produce far more electrons at a given temperature so they only have to be heated to 425–600 Â°C (797–1,112 Â°F) There are two main types of treated cathodes: 519: 486: 498: 754:
diffusing into the N-doped layer become minority carriers and tend to recombine with electrons. In equilibrium, with no applied bias, thermally assisted diffusion of electrons and holes in opposite directions across the depletion layer ensure a zero net current with electrons flowing from cathode to anode and recombining, and holes flowing from anode to cathode across the junction or depletion layer and recombining.
589:: In this type, the filament is not the cathode but rather heats the cathode which then emits electrons. Indirectly heated cathodes are used in most devices today. For example, in most vacuum tubes the cathode is a nickel tube with the filament inside it, and the heat from the filament causes the outside surface of the tube to emit electrons. The filament of an indirectly heated cathode is usually called the 1279: 33: 614: 724: 327:, the cathode is where the negative polarity is applied to drive the cell. Common results of reduction at the cathode are hydrogen gas or pure metal from metal ions. When discussing the relative reducing power of two redox agents, the couple for generating the more reducing species is said to be more "cathodic" with respect to the more easily reduced reagent. 753:
Electrons which diffuse from the cathode into the P-doped layer, or anode, become what are termed "minority carriers" and tend to recombine there with the majority carriers, which are holes, on a timescale characteristic of the material which is the p-type minority carrier lifetime. Similarly, holes
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The use of 'West' to mean the 'out' direction (actually 'out' → 'West' → 'sunset' → 'down', i.e. 'out of view') may appear unnecessarily contrived. Previously, as related in the first reference cited above, Faraday had used the more straightforward term "exode" (the doorway where the current exits).
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move towards the anode, although cathode polarity depends on the device type, and can even vary according to the operating mode. Whether the cathode is negatively polarized (such as recharging a battery) or positively polarized (such as a battery in use), the cathode will draw electrons into it from
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occurs. The cathode can be negative like when the cell is electrolytic (where electrical energy provided to the cell is being used for decomposing chemical compounds); or positive as when the cell is galvanic (where chemical reactions are used for generating electrical energy). The cathode supplies
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When P and N-doped layers are created adjacent to each other, diffusion ensures that electrons flow from high to low density areas: That is, from the N to the P side. They leave behind the fixed positively charged dopants near the junction. Similarly, holes diffuse from P to N leaving behind fixed
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with a high density of free electrons due to doping, and an equal density of fixed positive charges, which are the dopants that have been thermally ionized. In the anode, the converse applies: It features a high density of free "holes" and consequently fixed negative dopants which have captured an
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from the filament surface would affect the movement of the electrons and introduce hum into the tube output. It also allows the filaments in all the tubes in an electronic device to be tied together and supplied from the same current source, even though the cathodes they heat may be at different
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over some new names needed to complete a paper on the recently discovered process of electrolysis. In that paper Faraday explained that when an electrolytic cell is oriented so that electric current traverses the "decomposing body" (electrolyte) in a direction "from East to West, or, which will
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In a vacuum tube or electronic vacuum system, the cathode is a metal surface which emits free electrons into the evacuated space. Since the electrons are attracted to the positive nuclei of the metal atoms, they normally stay inside the metal and require energy to leave it; this is called the
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field oriented like the Earth's. This made the internal current East to West as previously mentioned, but in the event of a later convention change it would have become West to East, so that the West electrode would not have been the 'way out' any more. Therefore, "exode" would have become
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occurs. For example, in some fluorescent tubes a momentary high voltage is applied to the electrodes to start the current through the tube; after starting the electrodes are heated enough by the current to keep emitting electrons to sustain the discharge.
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can be applied to the surface by placing an electrode with a high positive voltage near the cathode. The positively charged electrode attracts the electrons, causing some electrons to leave the cathode's surface. This process is used in
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electrons to the positively charged cations which flow to it from the electrolyte (even if the cell is galvanic, i.e., when the cathode is positive and therefore would be expected to repel the positively charged cations; this is due to
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direction, which at that time was believed to be invariant. He fundamentally defined his arbitrary orientation for the cell as being that in which the internal current would run parallel to and in the same direction as a hypothetical
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performing electrolysis has its cathode as the negative terminal, from which current exits the device and returns to the external generator as charge enters the battery/ cell. For example, reversing the current direction in a
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Like a typical diode, there is a fixed anode and cathode in a Zener diode, but it will conduct current in the reverse direction (electrons flow from anode to cathode) if its breakdown voltage or "Zener voltage" is exceeded.
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His motivation for changing it to something meaning 'the West electrode' (other candidates had been "westode", "occiode" and "dysiode") was to make it immune to a possible later change in the direction convention for
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to the positive cathode (chemical energy is responsible for this "uphill" motion). It is continued externally by electrons moving into the battery which constitutes positive current flowing outwards. For example, the
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When metal ions are reduced from ionic solution, they form a pure metal surface on the cathode. Items to be plated with pure metal are attached to and become part of the cathode in the electrolytic solution.
393:: The cathode can be heated. The increased thermal motion of the metal atoms "knocks" electrons out of the surface, an effect called thermionic emission. This technique is used in most vacuum tubes. 137:
in use has a cathode that is the positive terminal since that is where conventional current flows out of the device. This outward current is carried internally by positive ions moving from the
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is used. The layer of thorium on the surface which reduces the work function of the cathode is continually replenished as it is lost by diffusion of thorium from the interior of the metal.
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Conventional current flows from cathode to anode outside the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode.
79:. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the 579:: In this type, the filament itself is the cathode and emits the electrons directly. Directly heated cathodes were used in the first vacuum tubes, but today they are only used in 1089: 648:
bombardment can destroy the coating on a coated cathode. In these tubes a directly heated cathode consisting of a filament made of tungsten incorporating a small amount of
593:. The main reason for using an indirectly heated cathode is to isolate the rest of the vacuum tube from the electric potential across the filament. Many vacuum tubes use 343:
is connected to allow the circuit to be completed: as the anode of the galvanic cell gives off electrons, they return from the circuit into the cell through the cathode.
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heated red-hot by an electric current passing through it. Before the advent of transistors in the 1960s, virtually all electronic equipment used hot-cathode
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strengthen this help to the memory, that in which the sun appears to move", the cathode is where the current leaves the electrolyte, on the West side: "
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greater than the threshold frequency falls on it. This effect is called photoelectric emission, and the electrons produced are called
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the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode.
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can be positive or negative depending on how the device is being operated. Inside a device or a cell, positively charged
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In order to improve electron emission, cathodes are treated with chemicals, usually compounds of metals with a low
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relative to the electrolyte solution being different for the anode and cathode metal/electrolyte systems in a
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Ross, S (1 November 1961). "Faraday consults the scholars: the origins of the terms of electrochemistry".
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converts it into an electrolytic cell where the copper electrode is the positive terminal and also the
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The electrode through which conventional current flows the other way, into the device, is termed an
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direction convention on which the "exode" term was based has no reason to change in the future.
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to heat the filament. In a tube in which the filament itself was the cathode, the alternating
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This is a cathode that is not heated by a filament. They may emit electrons by
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Two indirectly-heated cathodes (orange heater strip) in ECC83 dual triode tube
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of the metal. Cathodes are induced to emit electrons by several mechanisms:
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tube in a radio transmitter. The cathode filament is not directly visible.
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is the flow of electrons into the anode from a species in solution.
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Coated cathode – In these the cathode is covered with a coating of
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around the local line of latitude which would induce a magnetic
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Encyclopedic Dictionary of Condensed Matter Physics, Vol. 1
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Glow from the directly heated cathode of a 1 kW power
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from the cathode interface to a species in solution. The
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where the current of interest is the reverse current. In
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Light and Light Sources: High-Intensity Discharge Lamps
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always move towards the cathode and negatively charged
1616: 1588: 1410: 1286: 1224: 1047:Ferris, Clifford "Electron tube fundamentals" in 557:(CRT) type televisions and computer monitors, in 920:A Textbook Of Engineering Physics For B.E., B.Sc 891:. Vol. 1. London: The University of London. 849:Notes and Records of the Royal Society of London 1145:Microwave Active Devices Vacuum and Solid State 1114:A Practical Introduction to Electronic Circuits 1088:. Radio-Electronics.com, Adrio Communications. 533:A hot cathode is a cathode that is heated by a 126:outside, as well as attract positively charged 68:. This definition can be recalled by using the 64:leaves a polarized electrical device such as a 507:vacuum tube with an indirectly-heated cathode 1202: 8: 912: 910: 908: 906: 904: 902: 900: 898: 347:Electroplating metal cathode (electrolysis) 1209: 1195: 1187: 1043: 1041: 1039: 917:Avadhanulu, M.N.; P.G. Kshirsagar (1992). 746:electron (hence the origin of the holes). 644:Thoriated tungsten – In high-power tubes, 1117:. UK: Cambridge Univ. Press. p. 49. 699:Cold cathodes may also emit electrons by 641:oxide. These are used in low-power tubes. 442:: Electrons can also be emitted from the 466:Cathodes can be divided into two types: 976: 974: 821: 683:(CCFLs) used as backlights in laptops, 1148:. New Age International. p. 2.5. 1032:from the original on 24 December 2017. 1001:from the original on 24 December 2017. 955:. Encyclopædia Britannica, Inc. 2014. 888:Experimental Researches In Electricity 414:, and in microelectronics fabrication, 572:There are two types of hot cathodes: 193:The word was coined in 1834 from the 27:Electrode where reduction takes place 7: 1162:from the original on 2 January 2014. 1131:from the original on 2 January 2014. 1092:from the original on 4 November 2013 1069:from the original on 2 January 2014. 959:from the original on 2 December 2013 937:from the original on 2 January 2014. 715:tubes used in night vision goggles. 541:. The filament is a thin wire of a 339:, the cathode is where the positive 218:a way; the way which the sun sets". 711:used in scientific instruments and 511:, showing the heater element inside 149:A battery that is recharging or an 1086:Vacuum Tube Theory Basics Tutorial 675:. Some examples are electrodes in 25: 251:Since the later discovery of the 83:flow. Consequently, the mnemonic 1277: 1052:The Electronics Handbook, 2nd Ed 529:for vacuum tube, showing cathode 496: 484: 446:of certain metals when light of 1182:How to define anode and cathode 1055:. CRC Press. pp. 354–356. 987:. Academic Press. p. 468. 201:), 'descent' or 'way down', by 87:also means that electrons flow 1111:Jones, Martin Hartley (1995). 1018:. Springer. pp. 102–103. 981:Poole, Charles P. Jr. (2004). 953:Encyclopædia Britannica online 923:. S. Chand. pp. 345–348. 681:cold-cathode fluorescent lamps 1: 671:, and in gas-filled tubes by 426:. This mechanism is used in 205:, who had been consulted by 1049:Whitaker, Jerry C. (2013). 48:to flow out of the cathode. 1706: 660: 473: 454:. This effect is used in 1367:Metal–air electrochemical 1275: 1177:The Cathode Ray Tube site 1012:Flesch, Peter G. (2007). 703:. These are often called 587:Indirectly heated cathode 1082:"Vacuum tube electrodes" 537:to produce electrons by 233:magnetizing current loop 1142:Sisodia, M. L. (2006). 669:field electron emission 577:Directly heated cathode 398:Field electron emission 85:cathode current departs 77:Cathode Current Departs 1669:Semipermeable membrane 1458:Lithium–iron–phosphate 861:10.1098/rsnr.1961.0038 727: 701:photoelectric emission 625: 530: 439:Photoelectric emission 374: 228:Earth's magnetic field 49: 1540:Rechargeable alkaline 1218:Electrochemical cells 737:, the cathode is the 726: 616: 521: 368: 156:Daniell galvanic cell 144:Daniell galvanic cell 35: 1520:Nickel–metal hydride 619:(lefthand electrode) 563:electron microscopes 412:electron microscopes 281:electrochemical cell 113:with respect to the 81:conventional current 62:conventional current 1530:Polysulfide–bromide 1372:Nickel oxyhydroxide 1264:Thermogalvanic cell 1080:Poole, Ian (2012). 833:4 June 2011 at the 799:Oxidation-reduction 779:Cathodic protection 693:thermionic emission 595:alternating current 539:thermionic emission 428:gas-discharge lamps 424:secondary electrons 390:Thermionic emission 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184: 180: 176: 172: 168: 163: 161: 157: 152: 147: 145: 140: 136: 135:galvanic cell 133:A battery or 131: 130:from inside. 129: 124: 120: 116: 112: 107: 101: 99: 97: 92: 90: 86: 82: 78: 74: 71: 67: 63: 60:from which a 59: 55: 47: 43: 42:galvanic cell 40:cathode in a 39: 36:Diagram of a 34: 30: 19: 1638: 1575:Zinc–bromine 1382:Silver oxide 1317:Chromic acid 1289:Primary cell 1269:Voltaic pile 1247:Flow battery 1144: 1137: 1113: 1106: 1094:. 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Retrieved 952: 943: 919: 887: 877: 852: 848: 842: 824: 784:Electrolysis 774:Cathode bias 756: 752: 748: 743:p–n junction 729: 704: 698: 666: 663:Cold cathode 657:Cold cathode 631:alkali metal 618: 605: 590: 586: 576: 571: 551:vacuum tubes 532: 508: 465: 451: 437: 423: 417: 396: 388: 379: 376: 361:Vacuum tubes 350: 334: 322: 312: 300: 298: 272: 266: 263:In chemistry 256: 250: 244:whereas the 220: 215: 211: 198: 192: 179:vacuum tubes 171:Zener diodes 164: 148: 132: 108: 105: 93: 88: 84: 76: 72: 53: 51: 45: 29: 1664:Salt bridge 1649:Electrolyte 1580:Zinc–cerium 1565:Solid state 1550:Silver–zinc 1525:Nickel–zinc 1510:Nickel–iron 1485:Molten salt 1453:Dual carbon 1448:Lithium ion 1443:Lithium–air 1402:Zinc–carbon 1377:Silicon–air 1357:Lithium–air 809:Vacuum tube 687:tubes, and 677:neon lights 602:potentials. 476:Hot cathode 470:Hot cathode 401:: A strong 214:downwards, 181:(including 175:solar cells 139:electrolyte 102:Charge flow 1690:Electrodes 1617:Cell parts 1608:Solar cell 1590:Other cell 1555:Sodium ion 1426:Automotive 816:References 709:phototubes 456:phototubes 444:electrodes 432:neon lamps 1654:Half-cell 1644:Electrode 1603:Fuel cell 1480:Metal–air 1431:Lead–acid 1347:LeclanchĂ© 1259:Fuel cell 1096:3 October 869:145600326 685:thyratron 639:strontium 623:neon lamp 448:frequency 309:electrons 285:reduction 283:at which 277:electrode 269:chemistry 242:reversals 197:κάθοδος ( 189:Etymology 58:electrode 1684:Category 1634:Catalyst 1495:Nanowire 1490:Nanopore 1436:gel–VRLA 1397:Zinc–air 1302:Alkaline 1160:Archived 1129:Archived 1090:Archived 1067:Archived 1030:Archived 999:Archived 963:15 March 957:Archived 935:Archived 885:(1849). 831:Archived 762:See also 547:tungsten 535:filament 525:used in 430:such as 410:in some 257:kathodos 253:electron 199:kathodos 111:polarity 109:Cathode 70:mnemonic 18:Cathodes 1639:Cathode 1392:Zamboni 1362:Mercury 1327:Daniell 769:Battery 739:N–doped 650:thorium 371:tetrode 275:is the 273:cathode 246:current 224:current 128:cations 119:cations 56:is the 54:cathode 1629:Binder 1387:Weston 1312:Bunsen 1152:  1121:  1059:  1022:  991:  927:  867:  719:Diodes 635:barium 591:heater 565:, and 505:triode 462:tubes. 323:In an 279:of an 237:dipole 123:anions 38:copper 1624:Anode 1342:Grove 1322:Clark 1225:Types 865:S2CID 804:PEDOT 735:diode 730:In a 545:like 335:In a 303:, in 216:`odos 195:Greek 167:diode 165:In a 160:anode 115:anode 96:anode 1659:Ions 1150:ISBN 1119:ISBN 1098:2013 1057:ISBN 1020:ISBN 989:ISBN 965:2014 925:ISBN 637:and 458:and 341:pole 299:The 271:, a 212:kata 89:into 75:for 1332:Dry 857:doi 646:ion 621:in 296:). 267:In 173:or 73:CCD 1686:: 1158:. 1127:. 1084:. 1065:. 1038:^ 1028:. 997:. 973:^ 951:. 933:. 897:^ 863:. 853:16 851:. 679:, 569:. 561:, 162:. 98:. 52:A 1210:e 1203:t 1196:v 1100:. 967:. 871:. 859:: 434:. 46:i 20:)

Index

Cathodes

copper
galvanic cell
electrode
conventional current
lead-acid battery
mnemonic
conventional current
anode
polarity
anode
cations
anions
cations
galvanic cell
electrolyte
Daniell galvanic cell
electrolytic cell
Daniell galvanic cell
anode
diode
Zener diodes
solar cells
vacuum tubes
cathode-ray tubes
Greek
William Whewell
Michael Faraday
current

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