446:
Schlesinger, H. I.; Brown, Herbert C.; Finholt, A. E.; Gilbreath, James R.; Hoekstra, Henry R.; Hyde, Earl K. (January 1953). "Sodium
Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen".
661:
558:
Wu, Chuan; Wu, Feng; Bai, Ying; Yi, Baolian; Zhang, Huamin (2005). "Cobalt boride catalysts for hydrogen generation from alkaline NaBH4 solution".
605:
397:
531:
Kapfenberger, C.; Albert, B.; Pottgen, R.; Huppertz, H. (January 2014). "Synthesis of cobalt boride nanoparticles using RF thermal plasma".
410:
1233:
631:
488:
2016:
1170:
1158:
654:
317:
Cobalt boride is produced under high temperature such as 1500 °C. Coatings of cobalt boride on iron are produced by
684:
170:
2011:
647:
432:
Methods for manufacturing of cobalt boride coating layer on surface of steels by using a pack cementation process
64:
1769:
1855:
1825:
1776:
243:
1915:
1862:
1832:
1784:
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1922:
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871:
759:
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1586:
1364:
1907:
1877:
1847:
1754:
1381:
1226:
1098:
597:
27:
329:. On to this iron boride coating is deposited cobalt using a pack cementation process. Cobalt boride
1802:
1746:
1485:
1400:
1148:
1106:
1090:
1058:
1030:
892:
848:
835:
811:
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1809:
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1066:
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965:
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771:
747:
739:
290:
239:
43:
1415:
478:
301:
1885:
1503:
1371:
1324:
1316:
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862:
827:
799:
779:
727:
711:
703:
619:
346:
342:
186:
1955:
1892:
1761:
1568:
1389:
1078:
791:
627:
601:
484:
406:
375:
297:
279:
219:
215:
2006:
1944:
1622:
1610:
1594:
1525:
1511:
1439:
1408:
1219:
1014:
843:
670:
615:
589:
567:
540:
513:
504:
Barnett, Clive (1969). "Hydrogenation of
Aliphatic Nitriles over Transition Metal Borides".
456:
358:
354:
286:
283:
113:
53:
1602:
1495:
1447:
1053:
1630:
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856:
164:
341:
When used as a catalyst, cobalt boride is prepared by reducing a cobalt salt, such as
2000:
370:
330:
275:
152:
96:
350:
430:
571:
322:
318:
544:
124:
402:
263:
231:
222:. For instance, studies suggest cobalt boride can increase the lifespan of
259:
255:
517:
483:(1st ed.). New York: Wiley-Interscience. pp. 25–26 & 263.
460:
1262:
1242:
506:
Industrial & Engineering
Chemistry Product Research and Development
480:
Handbook of
Heterogeneous Catalytic Hydrogenation for Organic Synthesis
227:
214:
Cobalt borides are known to be exceptionally resistant to oxidation, a
142:
83:
65:
1291:
163:
Except where otherwise noted, data are given for materials in their
639:
293:
223:
238:
resistance. These properties have been exploited in the field of
235:
1215:
1211:
643:
333:
in the size range of 18 to 22 nm have also been produced.
300:, even exceeding other cobalt containing catalysts such as
539:. Advanced Powder Technology Volume 25, Issue 1: 365–371.
282:. In one study, cobalt boride was found to be the most
357:
the salt on another material; often this material is
1186:
1141:
1118:
1046:
1023:
1002:
696:
677:
429:Yoon, Jin Kook; Man, Jung; Park, Sang Whan (2013).
622:; Murillo, Carlos A.; Bochmann, Manfred (1999),
321:, which involves first introducing a coating of
95:
289:based catalyst available for the production of
52:
626:(6th ed.), New York: Wiley-Interscience,
1227:
655:
8:
197:. The two main cobalt borides are CoB and Co
157:1,460 °C (2,660 °F; 1,730 K)
435:. Patent Publication No. US 20130260160 A1.
1234:
1220:
1212:
662:
648:
640:
15:
424:
422:
401:(91 ed.). Boca Raton, Florida, USA:
254:Cobalt boride has also been studied as a
1151:
472:
470:
449:Journal of the American Chemical Society
218:which makes them useful in the field of
387:
1275:
1728:
7:
1258:
274:Cobalt boride is also an effective
201:B. These are refractory materials.
86:
14:
398:Handbook of Chemistry and Physics
230:, imparting surfaces with higher
353:of the catalyst is maximized by
167:(at 25 °C , 100 kPa).
242:for the design of specialized
1:
624:Advanced Inorganic Chemistry
572:10.1016/j.matlet.2005.01.058
395:Haynes, William M. (2010).
189:with the general formula Co
2033:
1730:
533:Advanced Powder Technology
477:Nishimura, Shigeo (2001).
349:. Prior to reduction, the
1277:
1255:
594:Chemistry of the Elements
592:; Earnshaw, Alan (1997).
545:10.1016/j.apt.2013.06.002
161:
106:
36:
26:
21:
2017:Hydrogenation catalysts
598:Butterworth-Heinemann
590:Greenwood, Norman N.
244:drug delivery systems
226:parts when used as a
566:(14–15): 1748–1751.
129:69.744
620:Wilkinson, Geoffrey
518:10.1021/i360030a009
461:10.1021/ja01097a057
240:biomedical sciences
187:inorganic compounds
18:
347:sodium borohydride
343:cobalt(II) nitrate
171:Infobox references
16:
1994:
1993:
1988:
1987:
1209:
1208:
616:Cotton, F. Albert
607:978-0-08-037941-8
560:Materials Letters
376:Urushibara cobalt
313:Materials coating
298:nitrile reduction
280:organic synthesis
278:catalyst used in
270:Organic synthesis
220:materials science
216:chemical property
210:Materials science
179:Chemical compound
177:
176:
137:Refractory Solid
2024:
2012:Cobalt compounds
1259:
1236:
1229:
1222:
1213:
1154:
994:
993:
992:
984:
983:
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950:
942:
941:
671:Cobalt compounds
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657:
650:
641:
636:
611:
596:(2nd ed.).
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575:
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522:
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443:
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426:
417:
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412:978-1-43982077-3
392:
359:activated carbon
287:transition metal
250:Renewable energy
114:Chemical formula
99:
88:
67:
56:
19:
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2031:
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2021:
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1959:
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1114:
1110:
1102:
1094:
1086:
1082:
1074:
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1062:
1042:
1038:
1034:
1024:Cobalt(II, III)
1019:
998:
991:
988:
987:
986:
982:
979:
978:
977:
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969:
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583:Further reading
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1119:Cobalt(III,IV)
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1036:
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1027:
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1020:
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1006:
1004:
1003:Cobalt(0, III)
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996:
989:
980:
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947:
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926:
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512:(2): 145–149.
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455:(1): 215–219.
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271:
268:
266:technologies.
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183:Cobalt borides
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175:
174:
169:
165:standard state
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24:
23:
17:Cobalt boride
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2:
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633:0-471-19957-5
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371:Nickel boride
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331:nanoparticles
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276:hydrogenation
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153:Melting point
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31:Cobalt boride
29:
25:
20:
1427:
1247:
861:
623:
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559:
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532:
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509:
505:
499:
479:
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448:
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431:
396:
390:
351:surface area
340:
316:
308:Preparations
302:Raney cobalt
273:
262:storage and
253:
213:
205:Applications
182:
181:
37:Identifiers
1047:Cobalt(III)
134:Appearance
107:Properties
2001:Categories
1142:Cobalt(IV)
697:Cobalt(II)
382:References
355:supporting
147:7.25 g/cm
125:Molar mass
119:CoB
54:12006-77-8
44:CAS Number
28:IUPAC name
1187:Cobalt(V)
678:Cobalt(I)
403:CRC Press
284:selective
264:fuel cell
232:corrosion
74:235-722-7
66:EC Number
365:See also
337:Catalyst
319:boriding
260:hydrogen
256:catalyst
97:13628825
2007:Borides
1731:
1243:Borides
872:Co(SCN)
863:Co(OCN)
828:Co(OAc)
685:HCo(CO)
345:, with
323:FeB, Fe
291:primary
228:coating
143:Density
84:PubChem
1099:Co(OH)
849:Co(OH)
780:Co(HCO
760:Co(ClO
748:Co(ClO
712:Co(CN)
630:
604:
487:
409:
294:amines
22:Names
1107:LiCoO
1067:Co(NO
836:CoGeO
800:Co(NO
224:metal
1059:CoCl
1054:CoAs
1015:CoGe
1010:CoSi
913:Co(C
888:CoSe
880:CoSO
740:CoCl
720:CoCO
704:CoBr
628:ISBN
602:ISBN
485:ISBN
407:ISBN
296:via
258:for
236:wear
234:and
185:are
1984:No
1981:Md
1978:Fm
1975:Es
1972:Cf
1969:Bk
1966:Cm
1963:Am
1956:PuB
1952:Np
1941:Pa
1938:Th
1935:Ac
1932:**
1923:YbB
1916:YbB
1908:TmB
1901:TmB
1893:ErB
1886:ErB
1878:HoB
1871:HoB
1863:DyB
1856:DyB
1848:TbB
1841:TbB
1833:GdB
1826:GdB
1818:EuB
1810:SmB
1803:SmB
1799:Pm
1792:NdB
1785:NdB
1777:PrB
1770:PrB
1762:CeB
1755:CeB
1747:LaB
1740:LaB
1724:Og
1721:Ts
1718:Lv
1715:Mc
1712:Fl
1709:Nh
1706:Cn
1703:Rg
1700:Ds
1697:Mt
1694:Hs
1691:Bh
1688:Sg
1685:Db
1682:Rf
1679:Lr
1676:**
1673:Ra
1670:Fr
1665:Rn
1662:At
1659:Po
1656:Bi
1653:Pb
1650:Tl
1647:Hg
1644:Au
1641:Pt
1638:Ir
1631:OsB
1623:ReB
1603:TaB
1595:HfB
1587:LuB
1580:LuB
1569:BaB
1565:Cs
1560:Xe
1554:Te
1551:Sb
1548:Sn
1545:In
1542:Cd
1539:Ag
1536:Pd
1533:Rh
1526:RuB
1522:Tc
1519:Mo
1512:NbB
1504:ZrB
1486:SrB
1482:Rb
1477:Kr
1474:Br
1471:Se
1468:As
1465:Ge
1462:Ga
1459:Zn
1456:Cu
1409:FeB
1405:Mn
1401:CrB
1390:TiB
1382:ScB
1372:CaB
1365:CaB
1356:Ar
1353:Cl
1340:SiB
1332:AlB
1325:AlB
1317:MgB
1313:Na
1308:Ne
1288:Be
1285:Li
1280:He
1198:CoO
1171:CoC
1163:CoF
1150:CoF
1130:CoO
1091:CoF
985:CoO
952:CoO
905:CoH
857:CoS
844:CoO
816:(PO
792:CoI
772:CoF
728:CoC
568:doi
541:doi
514:doi
457:doi
87:CID
2003::
1945:UB
1736:*
1576:*
1557:I
1496:YB
1448:Ni
1440:Ni
1428:Co
1416:Fe
1397:V
1384:12
1361:K
1350:S
1347:P
1334:12
1305:F
1302:O
1299:N
1296:C
1194:Na
1177:44
1173:28
1159:Cs
1126:Na
1079:Co
1031:Co
981:70
972:36
948:48
939:24
893:Co
812:Co
618:;
600:.
564:59
562:.
537:25
535:.
508:.
469:^
453:75
451:.
421:^
405:.
361:.
304:.
246:.
1958:x
1947:2
1925:6
1918:4
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1903:4
1895:6
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1873:4
1865:6
1858:4
1850:6
1843:4
1835:6
1828:4
1820:6
1812:6
1805:4
1794:6
1787:4
1779:6
1772:4
1764:6
1757:4
1749:6
1742:4
1633:x
1625:2
1617:y
1615:B
1613:x
1611:W
1605:x
1597:2
1589:6
1582:4
1571:6
1528:x
1514:2
1506:2
1498:x
1488:6
1452:B
1450:2
1444:B
1442:3
1434:y
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1422:y
1420:B
1418:x
1411:4
1392:2
1374:6
1367:4
1342:x
1327:2
1319:2
1292:B
1269:y
1267:H
1265:x
1263:B
1248:x
1245:B
1235:e
1228:t
1221:v
1200:4
1196:3
1175:H
1165:6
1161:2
1152:4
1132:2
1128:x
1109:2
1101:3
1093:3
1085:3
1083:O
1081:2
1073:3
1071:)
1069:3
1061:3
1037:4
1035:O
1033:3
990:4
976:H
967:C
957:4
943:H
934:C
927:2
925:)
923:3
921:O
919:6
917:H
915:3
907:2
899:2
897:P
895:3
882:4
874:2
865:2
851:2
838:3
830:2
822:2
820:)
818:4
814:3
806:2
804:)
802:3
794:2
786:2
784:)
782:2
774:2
766:2
764:)
762:4
754:2
752:)
750:3
742:2
734:4
732:O
730:2
722:3
714:2
706:2
687:4
663:e
656:t
649:v
610:.
574:.
570::
547:.
543::
520:.
516::
510:8
493:.
463:.
459::
415:.
327:B
325:2
199:2
195:y
193:B
191:x
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