914:. Hydridocopper has acidic behavior for the same reason as normal copper hydride. However, it does not form stable aqueous solutions, due in part to its autopolymerisation, and its tendency to be oxidised by water. Copper hydride reversibly precipitates from pyridine solution, as an amorphous solid. However, repeated dissolution affords the regular crystalline form, which is insoluble. Under standard conditions, molecular copper hydride autopolymerises to form the crystalline form, including under aqueous conditions, hence the aqueous production method devised by Wurtz.
942:
it was found that the solidified diatomic substance is distinct from the
Wurtzite structure. The Wurtzite substance was insoluble and was decomposed by lithium iodide, but not the solidified diatomic species. Moreover, while the Wurtzite substance's decomposition is strongly base catalysed, whereas the solidified diatomic species is not strongly affected at all. Dilts distinguishes between the two copper hydrides as the 'insoluble-' and 'soluble copper hydrides'. The soluble hydride is susceptible to pyrolysis under vacuum and proceeds to completion under 100 °C.
229:
156:
695:. This method is faster and has a higher chemical yield than the copper sulfate based synthesis and produces nanoparticles of CuH with higher purity and a smaller size distribution. The obtained CuH can easily be converted to conducting thin films of Cu. These films are obtained by spraying the CuH nanoparticles in their synthesis medium into some insulating support. After drying, conducting Cu films protected by a layer of mixed copper oxides are spontaneously formed.
517:). In 2011, Panitat Hasin and Yiying Wu were the first to synthesise a metal hydride (copper hydride) using the technique of sonication. Copper hydride has the distinction of being the first metal hydride discovered. In 2013, it was established by Donnerer et al. that, at least up to fifty gigapascals, copper hydride cannot be synthesised by pressure alone. However, they were successful in synthesising several copper-hydrogen alloys under pressure.
357:
352:
531:
761:
744:
550:
engenders differing surface properties. The different behaviors of CuH obtained by aqueous and nonaqueous routes can be ascribed to a combination of very different particle size and dissimilar surface termination, namely, bonded hydroxyls for the aqueous routes and a coordinated donor for the nonaqueous routes.
35:
941:
This was discovered by E Wiberg and W Henle in 1952. The solution of this CuH in the pyridine is typically dark red to dark orange. A precipitate is formed if ether is added to this solution. This will redissolve in pyridine. Impurities of the reaction products remain in the product. In this study,
945:
Amorphous copper hydride is also produced by anhydrous reduction. In this process copper(I) and tetrahydroaluminate react to produce molecular copper hydride and triiodoaluminium adducts. The molecular copper hydride is precipitated into amorphous copper hydride with the addition of diethyl ether.
958:
in 2000 by
Bernath, who detected it at the University of Waterloo. It was first detected as a contaminant while attempting to generate NeH using the hollow-cathode lamp. Molecular copper hydride has the distinction of being the first metal hydride to be detected in this way. (1,0) (2,0) and (2,1)
549:
The CuH consists of a core of CuH with a shell of water and this may be largely replaced by ethanol. This offers the possibility of modifying the properties of CuH produced by aqueous routes. While all methods for the synthesis of CuH result in the same bulk product, the synthetic path taken
880:
Chiral phosphine-copper complexes catalyze hydrosilation of ketones and esters with low enantioselectivities. An enantioselective (80 to 92% ee) reduction of prochiral α,β-unsaturated esters uses Tol-BINAP complexes of copper in the presence of
981:
However, this proved to be unviable as a production method as the reaction is difficult to control. The activation barrier for the reverse reaction is virtually non-existent, which allows it to readily proceed even at 20 Kelvin.
488:
where n ~ 0.95. It is a red solid, rarely isolated as a pure composition, that decomposes to the elements. Copper hydride is mainly produced as a reducing agent in organic synthesis and as a precursor to various catalysts.
365:
332:
1818:
Appella, Daniel H.; Moritani, Yasunori; Shintani, Ryo; Ferreira, Eric M.; Buchwald, Stephen L. (1999-10-01). "Asymmetric
Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine−Copper Catalyst".
1854:
Lipshutz, Bruce H.; Noson, Kevin; Chrisman, Will; Lower, Asher (2003-07-01). "Asymmetric
Hydrosilylation of Aryl Ketones Catalyzed by Copper Hydride Complexed by Nonracemic Biphenyl Bis-phosphine Ligands".
1609:
Lousada, Cláudio M.; Fernandes, Ricardo M. F.; Tarakina, Nadezda V.; Soroka, Inna L. (2017). "Synthesis of copper hydride (CuH) from CuCO3·Cu(OH)2 – a path to electrically conductive thin films of Cu".
1984:
Miki, Yuya; Hirano, Koji; Satoh, Tetsuya; Miura, Masahiro (2013-10-04). "Copper-Catalyzed
Intermolecular Regioselective Hydroamination of Styrenes with Polymethylhydrosiloxane and Hydroxylamines".
894:
CuH species with weakly activated (e.g. styrenes, dienes) and unactivated alkenes (e.g. α-olefins) and alkynes has been recognized and has served as the basis for several copper-catalyzed formal
885:
as the reductant. Subsequently, conditions have been developed for the CuH-catalyzed hydrosilylation of ketones and imines proceeding with excellent levels of chemo- and enantioselectivity.
1066:
404:
621:
Copper does not react with hydrogen even on heating, thus copper hydrides are made indirectly from copper(I) and copper(II) precursors. Examples include the reduction of
1704:
Mahoney, Wayne S.; Stryker, Jeffrey M. (1989-11-01). "Hydride-mediated homogeneous catalysis. Catalytic reduction of .alpha.,.beta.-unsaturated ketones using 6 and H2".
1653:
Whitesides, George M.; San
Filippo, Joseph; Stredronsky, Erwin R.; Casey, Charles P. (1969-11-01). "Reaction of copper(I) hydride with organocopper(I) compounds".
2311:
Ram, R. S.; P.F. Bernath; J.W. Brault (1985). Cameron, David G; Grasselli, Jeannette G (eds.). "Infrared
Fourier Transform Emission Spectroscopy of CuH and NeH".
2213:
1391:
Bennett, Elliot L; Thomas Wilson; Patrick J Murphy; Keith Refson; Alex C Hannon; Silvia
Imberti; Samantha K Callear; Gregory A Chass; Stewart F Parker (2015).
1342:
Bennett, Elliot L; Thomas Wilson; Patrick J Murphy; Keith Refson; Alex C Hannon; Silvia
Imberti; Samantha K Callear; Gregory A Chass; Stewart F Parker (2015).
268:
3182:
2531:
1941:
Noh, Dongwan; Chea, Heesung; Ju, Junghwan; Yun, Jaesook (2009-08-03). "Highly Regio- and
Enantioselective Copper-Catalyzed Hydroboration of Styrenes".
1687:
John F. Daeuble and Jeffrey M. Stryker "Hexa-μ-hydrohexakis(triphenylphosphine)hexacopper" eEROS Encyclopedia of Reagents for Organic Synthesis, 2001.
613:
Solid copper hydride is the irreversible autopolymerisation product of the molecular form, and the molecular form cannot be isolated in concentration.
2356:"Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides: CuH & CuD, AgH & AgD, and AuH & AuD"
906:
The diatomic species CuH is a gas that has attracted the attention of spectroscopists. It polymerises upon being condensed. A well-known oligomer is
1029:
Fitzsimons, Nuala P.; Jones, William; Herley, Patrick J. (1 January 1995). "Studies of copper hydride. Part 1.—Synthesis and solid-state stability".
665:
The reactions produce a red-colored precipitate of CuH, which is generally impure and slowly decomposes to liberate hydrogen, even at 0 °C.
1530:
1473:
1441:
577:
When not cooled below −5 °C (23 °F), copper hydride decomposes, to produce hydrogen gas and a mixture containing elemental copper:
857:
Phosphine- and NHC-copper hydride species have been developed as reagents in organic synthesis, albeit of limited use. Most widely used is
683:
A new synthesis method has been published in 2017 by Lousada et al. In this synthesis high purity CuH nanoparticles have been obtained from
1080:
Jordan, Abraham J.; Lalic, Gojko; Sadighi, Joseph P. (2016-07-25). "Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity".
2866:
1898:
Lipshutz, Bruce H.; Shimizu, Hideo (2004-04-19). "Copper(I)-Catalyzed Asymmetric Hydrosilylations of Imines at Ambient Temperatures".
558:
CuH generally behaves as a source of H. For instance, Wurtz reported the double displacement reaction of CuH with hydrochloric acid:
844:
243:
782:
775:
5972:
3111:
2859:
1740:
1165:
969:
In vapour experiments, it was found that copper hydride is produced from the elements upon exposure to 310 nanometre radiation.
3175:
2524:
825:
707:. In this process, hexaaquacopper(II) and hydrogen(•) react to produce copper hydride and oxonium according to the equation:
2084:
Uehling, Mycah R.; Rucker, Richard P.; Lalic, Gojko (2014-06-18). "Catalytic Anti-Markovnikov Hydrobromination of Alkynes".
797:
3142:
461:
5962:
3191:
2748:
2788:
2451:
804:
207:
2244:
356:
3168:
735:
from the homolytic sonication of water. Reductive sonication produces molecular copper hydride as an intermediate.
539:
428:
415:
771:
5200:
2517:
959:
vibrational bands were observed along with line splitting due to the presence of two copper isotopes, Cu and Cu.
927:
163:
1546:
Warf, James C.; Feitknecht, W. (1950). "Zur Kenntnis des Kupferhydrids, insbesondere der Kinetik des Zerfalls".
1126:
Aldridge, Simon; Downs, Anthony J. (2001). "Hydrides of the Main-Group Metals: New Variations on an Old Theme".
811:
1223:
351:
5967:
5920:
5816:
5593:
946:
Amorphous copper hydride is converted into the Wurtz phase by annealing, accompanied by some decomposition.
882:
5912:
5689:
5657:
4894:
4870:
4858:
3273:
793:
151:
5904:
5848:
5681:
5649:
5617:
5601:
5561:
5338:
5317:
4930:
4918:
4906:
4882:
3006:
2890:
2828:
895:
684:
5896:
5872:
5840:
5798:
5761:
5633:
5553:
5545:
5325:
5312:
5296:
5256:
5240:
5232:
2354:
Seto, Jenning Y.; Zulfikar Morbi; Frank Charron; Sang K. Lee; Peter F. Bernath; Robert J. Le Roy (1999).
5782:
5753:
5745:
5737:
5705:
5673:
5625:
5609:
5569:
5343:
5280:
5248:
5224:
4727:
4710:
3278:
3263:
3258:
2844:
2768:
2674:
1465:
1004:
962:
The AΣ-XΣ absorption lines from CuH have been claimed to have been observed in sunspots and in the star
676:
This slow decomposition also takes place underwater, however there are reports of the material becoming
498:
379:
344:
47:
5774:
5729:
5721:
5697:
5665:
5585:
5330:
5713:
5577:
5437:
3134:
5880:
5824:
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5401:
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5304:
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5009:
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3087:
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2922:
2820:
2466:
2424:
2367:
2320:
2277:
2184:
1492:
Burtovyy, R.; Utzig, E.; Tkacz, M. (2000). "Studies of the thermal decomposition of copper hydride".
1177:
911:
862:
634:
626:
506:
5888:
4555:
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224:
5941:
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2656:
2643:
2606:
955:
79:
4543:
4059:
4047:
2173:"Über die Dämpfung der elektromagnetischen Eigenschwingungen des Systems Erde — Luft — Ionosphäre"
5505:
5500:
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5393:
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3014:
3001:
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2800:
2776:
2760:
2590:
2584:
2393:
2336:
1315:
Müller, Heinz; Bradley, Albert James (1926). "CCXVII.—Copper hydride and its crystal structure".
622:
502:
477:
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4385:
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4035:
3918:
3906:
3894:
3627:
3592:
2717:
2268:
Ram, R.S.; P.F. Bernath; J.W. Brault (1985). "Fourier transform emission spectroscopy of NeH+".
4270:
4246:
4234:
1247:
Hasin, Panitat; Wu, Yiying (1 January 2012). "Sonochemical synthesis of copper hydride (CuH)".
5864:
5856:
5422:
5385:
5288:
5179:
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2009:
2001:
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1414:
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1097:
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133:
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4825:
3703:
3347:
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2601:
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2145:
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1993:
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1907:
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481:
288:
113:
1201:
89:
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228:
155:
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2705:
2061:
2028:
1368:
1348:
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
1343:
455:
1767:
1505:
5956:
2478:
2289:
1804:
1741:"Copper(I) salt mediated 1,4-reduction of α,β-unsaturated ketones using hydrosilanes"
923:
630:
317:
144:
2397:
2340:
195:
5933:
5484:
5453:
5087:
4792:
4780:
4523:
4413:
4332:
2680:
530:
1520:
501:
synthesised copper hydride for the first time. He reduced an aqueous solution of
17:
5526:
5473:
5127:
5060:
4942:
4817:
4531:
4401:
3858:
3846:
3745:
3740:
3735:
3712:
3415:
3403:
3391:
1093:
870:
760:
397:
3160:
2415:(May 1976). "Identification of Novel Molecules in the Spectrum of 19 Piscium".
5185:
4846:
4768:
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1574:
1359:
1300:
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963:
704:
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304:
124:
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2105:
2052:
2005:
1962:
1919:
1876:
1840:
1763:
1725:
1674:
1631:
1559:
1101:
637:. Other reducing agents, including classical aluminium hydrides can be used.
393:
4701:
4666:
4393:
4364:
4210:
4140:
4080:
4023:
3834:
3750:
3557:
1791:
Brunner, Henri; Miehling, Wolfgang (1984-10-23). "Asymmetrische katalysen".
2490:
2197:
2172:
2136:
Dilts, J. A.; D. F. Shriver (1968). "Nature of soluble copper(I) hydride".
2113:
2070:
2013:
1997:
1970:
1954:
1927:
1911:
1884:
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1418:
1377:
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1197:
1147:
1109:
5117:
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4352:
4222:
4123:
4088:
3981:
3952:
3822:
3648:
3619:
3379:
1328:
1164:
Donnerer, Christian; Scheler, Thomas; Gregoryanz, Eugene (4 April 2013).
1042:
2452:"Fourier Transform Emission Spectroscopy of the AΣ-XΣ Transition of CuD"
2149:
2027:
Zhu, Shaolin; Niljianskul, Nootaree; Buchwald, Stephen L. (2013-10-23).
1717:
1666:
1434:
Nationalizing Science: Adolphe Wurtz and the Battle for French Chemistry
4956:
4619:
4340:
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4015:
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3522:
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3239:
3199:
1623:
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543:
182:
164:
2332:
2097:
2044:
1868:
1832:
1525:. Vol. 2 (2nd ed.). New York: Academic Press. p. 1004.
1409:
1392:
1344:"Structure and spectroscopy of CuH prepared via borohydride reduction"
1189:
1139:
873:
can be used as the terminal reductant, allowing a catalytic amount of
389:
4584:
4576:
3814:
3730:
3725:
3720:
3366:
2380:
2355:
2232:
2029:"Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes"
1755:
954:
Hydridocopper was discovered in the vibration-rotation emission of a
454:
Except where otherwise noted, data are given for materials in their
2509:
2436:
743:
4318:
4194:
742:
529:
112:
102:
441:
3164:
2513:
385:
754:
34:
2450:
Fernando, W. T. M. L.; L. C. O'Brien; P. F. Bernath (1990).
1393:"How the Surface Structure Determines the Properties of CuH"
865:) for the reduction of α,β-unsaturated carbonyl compounds. H
212:
2221:
Annual Reports on the Progress of Chemistry, Section C
1007:
in the reduction of copper hydride by atomic hydrogen.
1067:
National Institute for Occupational Safety and Health
1031:
Journal of the Chemical Society, Faraday Transactions
5932:
5773:
5544:
5199:
5149:
5052:
5029:
4993:
4955:
4816:
4739:
4726:
4658:
4635:
4612:
4575:
4522:
4384:
4331:
4193:
4182:
4139:
4116:
4079:
4006:
3972:
3943:
3805:
3711:
3702:
3647:
3612:
3577:
3542:
3507:
3357:
3346:
3291:
3251:
3238:
3198:
3127:
3104:
2741:
2698:
2567:
2547:
922:Molecular copper hydride can be formed by reducing
2315:. Fourier and Computerized Infrared Spectroscopy.
1166:"High-pressure synthesis of noble metal hydrides"
1024:
1022:
1020:
194:
88:
1739:Mori, Atsunori; Fujita, Akinori (1997-01-01).
1436:. Cambridge, MA: MIT Press. pp. 121–122.
1159:
1157:
877:to be used for conjugate reduction reactions.
3176:
2525:
703:Copper hydride is also produced by reductive
8:
2131:
2129:
2127:
2125:
2123:
1522:Handbook of Preparative Inorganic Chemistry
1242:
1240:
5049:
5026:
4990:
4952:
4813:
4736:
4655:
4632:
4609:
4572:
4519:
4381:
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4136:
4113:
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4003:
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3940:
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3708:
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3539:
3504:
3354:
3288:
3248:
3183:
3169:
3161:
2532:
2518:
2510:
1487:
1485:
1003:) also exists, in the form of an unstable
227:
154:
132:
26:
2379:
2196:
2060:
1590:
1575:"The crystal structure of copper hydride"
1573:Goedkoop, J. A.; Andresen, A. F. (1955).
1408:
1367:
1317:Journal of the Chemical Society (Resumed)
1299:
1284:"The crystal structure of copper hydride"
1282:Goedkoop, J. A.; Andresen, A. F. (1955).
1121:
1119:
845:Learn how and when to remove this message
2973:
2969:
2686:
2682:
2138:Journal of the American Chemical Society
2086:Journal of the American Chemical Society
2033:Journal of the American Chemical Society
1857:Journal of the American Chemical Society
1821:Journal of the American Chemical Society
1706:Journal of the American Chemical Society
1655:Journal of the American Chemical Society
1061:NIOSH Pocket Guide to Chemical Hazards.
1986:Angewandte Chemie International Edition
1943:Angewandte Chemie International Edition
1900:Angewandte Chemie International Edition
1016:
273:
248:
223:
1056:
1054:
1052:
781:Please improve this article by adding
546:), being connected by covalent bonds.
538:In copper hydride, elements adopt the
322:100 °C (212 °F; 373 K)
145:
1604:
1602:
255:Key: JJFLDSOAQUJVBF-UHFFFAOYSA-N
7:
2417:The Astrophysical Journal Supplement
1793:Journal of Organometallic Chemistry
930:in ether and pyridine. 4CuI + LiAlH
185:
2214:"6 Infrared emission spectroscopy"
25:
2459:Journal of Molecular Spectroscopy
2270:Journal of Molecular Spectroscopy
739:Applications in Organic Synthesis
2177:Zeitschrift für Naturforschung A
759:
355:
350:
297:
33:
2360:The Journal of Chemical Physics
2171:E Wiberg & W Henle (1952).
1170:The Journal of Chemical Physics
458:(at 25 °C , 100 kPa).
910:-hexacuprane(6), occurring in
294:
1:
1506:10.1016/S0040-6031(00)00594-3
783:secondary or tertiary sources
409:(US health exposure limits):
3192:Binary compounds of hydrogen
2479:10.1016/0022-2852(90)90084-4
2290:10.1016/0022-2852(85)90281-4
1805:10.1016/0022-328X(84)85066-4
497:In 1844, the French chemist
1094:10.1021/acs.chemrev.6b00366
633:, or more simply with just
5989:
540:Wurtzite crystal structure
5201:Transition metal hydrides
3763:
1693:10.1002/047084289X.rh011m
1592:10.1107/S0365110X55000480
1462:Chemistry of the Elements
1460:; Earnshaw, Alan (1997).
1360:10.1107/S2052520615015176
1301:10.1107/S0365110X55000480
1224:"Sur l'hydrure de cuivre"
928:lithium aluminium hydride
452:
403:
331:
326:
281:
264:
239:
72:
56:
46:
41:
32:
1560:10.1002/hlca.19500330327
731:Hydrogen(•) is obtained
5973:Wurtzite structure type
2212:Bernath, P. F. (2000).
1748:Chemical Communications
1432:Rocke, Alan J. (2001).
1249:Chemical Communications
5934:Exotic matter hydrides
2198:10.1515/zna-1952-3-404
1998:10.1002/anie.201304365
1955:10.1002/anie.200902015
1912:10.1002/anie.200353294
1548:Helvetica Chimica Acta
1519:Brauer, Georg (1963).
1288:Acta Crystallographica
896:hydrofunctionalization
869:(at least 80 psi) and
770:relies excessively on
752:
685:basic copper carbonate
535:
1466:Butterworth-Heinemann
1458:Greenwood, Norman N.
1226:(On copper hydride),
1005:reactive intermediate
986:Other copper hydrides
746:
533:
448:TWA 100 mg/m (as Cu)
2411:Wojslaw, Robert S.;
1329:10.1039/JR9262901669
1043:10.1039/FT9959100713
991:A binary dihydride (
723:+ 2 + 4 H
699:Reductive sonication
635:hypophosphorous acid
627:sodium hypophosphite
507:hypophosphorous acid
5963:Copper(I) compounds
5546:Lanthanide hydrides
5153:(Group 17 hydrides)
4732:(Group 16 hydrides)
4186:(Group 15) hydrides
2471:1990JMoSp.139..461F
2429:1976ApJS...31...75W
2372:1999JChPh.11011756S
2325:1985SPIE..553..374R
2282:1985JMoSp.113..451R
2189:1952ZNatA...7..250S
2150:10.1021/ja01023a020
2039:(42): 15746–15749.
1992:(41): 10830–10834.
1718:10.1021/ja00206a008
1667:10.1021/ja01051a093
1612:Dalton Transactions
1397:Inorganic Chemistry
1182:2013JChPh.138m4507D
956:hollow-cathode lamp
888:The reactivity of L
629:in the presence of
521:Chemical properties
435:TWA 1 mg/m (as Cu)
422:TWA 1 mg/m (as Cu)
312: g·mol
29:
3202:(Group 1) hydrides
1624:10.1039/C7DT00511C
1494:Thermochimica Acta
1261:10.1039/C2CC15741A
753:
623:copper(II) sulfate
562:CuH + HCl → CuCl +
554:Chemical reactions
536:
534:Wurtzite structure
503:copper(II) sulfate
478:inorganic compound
462:Infobox references
444:(Immediate danger)
27:
5950:
5949:
5775:Actinide hydrides
5151:Hydrogen halides
5113:
5078:
5077:
5048:
5047:
5025:
5024:
4989:
4988:
4951:
4950:
4812:
4811:
4718:
4684:
4683:
4654:
4653:
4631:
4630:
4608:
4607:
4571:
4570:
4518:
4517:
4380:
4379:
4327:
4326:
4178:
4177:
4135:
4134:
4112:
4111:
4075:
4074:
4002:
4001:
3968:
3967:
3939:
3938:
3801:
3800:
3759:
3758:
3704:Group 14 hydrides
3698:
3697:
3643:
3642:
3608:
3607:
3573:
3572:
3538:
3537:
3503:
3502:
3342:
3341:
3287:
3286:
3158:
3157:
2413:Benjamin F. Peery
2333:10.1117/12.970862
2144:(21): 5769–5772.
2098:10.1021/ja503944n
2092:(24): 8799–8803.
2045:10.1021/ja4092819
1949:(33): 6062–6064.
1906:(17): 2228–2230.
1869:10.1021/ja021391f
1863:(29): 8779–8789.
1833:10.1021/ja992366l
1827:(40): 9473–9474.
1750:(22): 2159–2160.
1712:(24): 8818–8823.
1661:(23): 6542–6544.
1618:(20): 6533–6543.
1532:978-0-323-16129-9
1475:978-0-08-037941-8
1443:978-0-262-26429-7
1410:10.1021/ic5027009
1234: : 702–704.
1222:Wurtz, A. (1844)
1190:10.1063/1.4798640
1140:10.1021/cr960151d
1134:(11): 3305–3366.
1088:(15): 8318–8372.
912:Stryker's reagent
863:Stryker's reagent
855:
854:
847:
829:
470:Chemical compound
468:
467:
380:Hazard statements
208:CompTox Dashboard
114:Interactive image
59:Copper(I) hydride
18:Copper(I) hydride
16:(Redirected from
5980:
5111:
5050:
5027:
4991:
4953:
4814:
4737:
4716:
4656:
4633:
4610:
4573:
4520:
4382:
4329:
4191:
4137:
4114:
4077:
4004:
3970:
3941:
3803:
3761:
3709:
3645:
3610:
3575:
3540:
3505:
3355:
3289:
3249:
3185:
3178:
3171:
3162:
3067:
3066:
3065:
3057:
3056:
3048:
3047:
2977:
2691:
2541:Copper compounds
2534:
2527:
2520:
2511:
2505:
2504:
2502:
2501:
2495:
2489:. Archived from
2456:
2447:
2441:
2440:
2408:
2402:
2401:
2383:
2381:10.1063/1.479120
2351:
2345:
2344:
2308:
2302:
2301:
2265:
2259:
2258:
2256:
2255:
2249:
2243:. Archived from
2233:10.1039/B001200I
2218:
2209:
2203:
2202:
2200:
2168:
2162:
2161:
2133:
2118:
2117:
2081:
2075:
2074:
2064:
2024:
2018:
2017:
1981:
1975:
1974:
1938:
1932:
1931:
1895:
1889:
1888:
1851:
1845:
1844:
1815:
1809:
1808:
1788:
1782:
1781:
1779:
1778:
1772:
1766:. Archived from
1756:10.1039/a706032g
1745:
1736:
1730:
1729:
1701:
1695:
1685:
1679:
1678:
1650:
1644:
1643:
1606:
1597:
1596:
1594:
1579:Acta Crystallogr
1570:
1564:
1563:
1543:
1537:
1536:
1516:
1510:
1509:
1500:(1–2): 157–163.
1489:
1480:
1479:
1464:(2nd ed.).
1454:
1448:
1447:
1429:
1423:
1422:
1412:
1403:(5): 2213–2220.
1388:
1382:
1381:
1371:
1339:
1333:
1332:
1312:
1306:
1305:
1303:
1279:
1273:
1272:
1255:(9): 1302–1304.
1244:
1235:
1220:
1214:
1213:
1211:
1209:
1200:. Archived from
1161:
1152:
1151:
1123:
1114:
1113:
1082:Chemical Reviews
1077:
1071:
1070:
1058:
1047:
1046:
1026:
1002:
1001:
1000:
850:
843:
839:
836:
830:
828:
794:"Copper hydride"
787:
763:
755:
669:2 CuH → 2 Cu + H
604:
603:
602:
573:
572:
571:
482:chemical formula
399:
395:
391:
387:
359:
354:
311:
299:
296:
289:Chemical formula
232:
231:
216:
214:
198:
187:
166:
158:
147:
136:
116:
92:
63:Hydridocopper(I)
37:
30:
21:
5988:
5987:
5983:
5982:
5981:
5979:
5978:
5977:
5953:
5952:
5951:
5946:
5928:
5924:
5916:
5908:
5900:
5892:
5884:
5876:
5868:
5860:
5852:
5844:
5836:
5828:
5820:
5813:
5809:
5802:
5794:
5786:
5769:
5765:
5757:
5749:
5741:
5733:
5725:
5717:
5709:
5701:
5693:
5685:
5677:
5669:
5661:
5653:
5645:
5637:
5629:
5621:
5613:
5605:
5597:
5589:
5581:
5573:
5565:
5557:
5540:
5530:
5521:
5513:
5509:
5496:
5488:
5457:
5443:
5428:
5413:
5405:
5397:
5389:
5381:
5368:
5360:
5347:
5334:
5321:
5308:
5300:
5292:
5284:
5276:
5268:
5260:
5252:
5244:
5236:
5228:
5220:
5212:
5195:
5152:
5145:
5140:
5131:
5108:
5099:
5091:
5074:
5064:
5044:
5040:
5021:
5017:
5013:
5004:
4985:
4981:
4977:
4968:
4947:
4938:
4934:
4926:
4922:
4914:
4910:
4902:
4898:
4890:
4886:
4878:
4874:
4866:
4862:
4854:
4850:
4842:
4838:
4829:
4808:
4800:
4796:
4788:
4784:
4776:
4772:
4764:
4760:
4751:
4731:
4729:
4722:
4714:
4705:
4692:
4680:
4670:
4650:
4646:
4627:
4623:
4604:
4600:
4596:
4588:
4567:
4563:
4559:
4551:
4547:
4539:
4535:
4514:
4505:
4501:
4493:
4489:
4481:
4477:
4469:
4465:
4457:
4453:
4445:
4441:
4433:
4429:
4421:
4417:
4409:
4405:
4397:
4376:
4372:
4368:
4360:
4356:
4348:
4344:
4323:
4314:
4310:
4302:
4298:
4290:
4286:
4278:
4274:
4266:
4262:
4254:
4250:
4242:
4238:
4230:
4226:
4218:
4214:
4206:
4185:
4174:
4170:
4162:
4131:
4127:
4108:
4104:
4100:
4092:
4071:
4067:
4063:
4055:
4051:
4043:
4039:
4031:
4027:
4019:
3998:
3989:
3985:
3964:
3960:
3956:
3935:
3926:
3922:
3914:
3910:
3902:
3898:
3890:
3886:
3878:
3874:
3866:
3862:
3854:
3850:
3842:
3838:
3830:
3826:
3818:
3797:
3792:
3784:
3776:
3755:
3694:
3690:
3682:
3678:
3670:
3639:
3635:
3631:
3623:
3604:
3600:
3596:
3588:
3569:
3565:
3561:
3553:
3534:
3530:
3526:
3518:
3499:
3495:
3491:
3483:
3479:
3471:
3467:
3459:
3455:
3447:
3443:
3435:
3431:
3423:
3419:
3411:
3407:
3399:
3395:
3387:
3383:
3370:
3349:
3338:
3334:
3326:
3318:
3310:
3302:
3283:
3243:
3241:
3234:
3201:
3194:
3189:
3159:
3154:
3150:
3146:
3138:
3123:
3119:
3115:
3100:
3096:
3083:
3079:
3075:
3064:
3061:
3060:
3059:
3055:
3052:
3051:
3050:
3046:
3043:
3042:
3041:
3039:
3034:
3030:
3026:
3018:
3010:
2997:
2989:
2975:
2971:
2966:
2962:
2958:
2950:
2946:
2942:
2934:
2930:
2926:
2918:
2914:
2906:
2898:
2894:
2886:
2882:
2874:
2870:
2863:
2856:
2848:
2840:
2836:
2832:
2824:
2816:
2812:
2808:
2804:
2796:
2792:
2784:
2780:
2772:
2764:
2756:
2752:
2737:
2733:
2729:
2725:
2721:
2713:
2709:
2694:
2688:
2684:
2679:
2669:
2660:
2652:
2638:
2630:
2626:
2622:
2614:
2610:
2563:
2558:
2543:
2538:
2508:
2499:
2497:
2493:
2454:
2449:
2448:
2444:
2410:
2409:
2405:
2353:
2352:
2348:
2310:
2309:
2305:
2267:
2266:
2262:
2253:
2251:
2247:
2216:
2211:
2210:
2206:
2170:
2169:
2165:
2135:
2134:
2121:
2083:
2082:
2078:
2026:
2025:
2021:
1983:
1982:
1978:
1940:
1939:
1935:
1897:
1896:
1892:
1853:
1852:
1848:
1817:
1816:
1812:
1790:
1789:
1785:
1776:
1774:
1770:
1743:
1738:
1737:
1733:
1703:
1702:
1698:
1686:
1682:
1652:
1651:
1647:
1608:
1607:
1600:
1572:
1571:
1567:
1545:
1544:
1540:
1533:
1518:
1517:
1513:
1491:
1490:
1483:
1476:
1456:
1455:
1451:
1444:
1431:
1430:
1426:
1390:
1389:
1385:
1341:
1340:
1336:
1314:
1313:
1309:
1281:
1280:
1276:
1246:
1245:
1238:
1221:
1217:
1207:
1205:
1204:on 24 June 2013
1163:
1162:
1155:
1125:
1124:
1117:
1079:
1078:
1074:
1060:
1059:
1050:
1028:
1027:
1018:
1014:
999:
996:
995:
994:
992:
988:
976:
952:
940:
937:CuH + LiI + AlI
936:
933:
920:
904:
902:"Hydridocopper"
893:
876:
868:
860:
851:
840:
834:
831:
788:
786:
780:
776:primary sources
764:
750:
741:
726:
722:
716:
701:
694:
690:
672:
660:
656:
653:O → 4 CuH + 6 H
652:
648:
644:
619:
601:
598:
597:
596:
594:
570:
567:
566:
565:
563:
556:
528:
523:
516:
512:
495:
487:
471:
464:
459:
445:
432:
419:
382:
368:
347:
309:
291:
277:
272:
271:
260:
257:
256:
253:
247:
246:
235:
217:
210:
201:
188:
176:
139:
119:
106:
95:
82:
68:
66:
64:
62:
61:Cuprous hydride
60:
52:
28:Copper hydride
23:
22:
15:
12:
11:
5:
5986:
5984:
5976:
5975:
5970:
5968:Metal hydrides
5965:
5955:
5954:
5948:
5947:
5945:
5944:
5938:
5936:
5930:
5929:
5927:
5926:
5922:
5918:
5914:
5910:
5906:
5902:
5898:
5894:
5890:
5886:
5882:
5878:
5874:
5870:
5866:
5862:
5858:
5854:
5850:
5846:
5842:
5838:
5834:
5830:
5826:
5822:
5818:
5814:
5811:
5807:
5804:
5800:
5796:
5792:
5788:
5784:
5779:
5777:
5771:
5770:
5768:
5767:
5763:
5759:
5755:
5751:
5747:
5743:
5739:
5735:
5731:
5727:
5723:
5719:
5715:
5711:
5707:
5703:
5699:
5695:
5691:
5687:
5683:
5679:
5675:
5671:
5667:
5663:
5659:
5655:
5651:
5647:
5643:
5639:
5635:
5631:
5627:
5623:
5619:
5615:
5611:
5607:
5603:
5599:
5595:
5591:
5587:
5583:
5579:
5575:
5571:
5567:
5563:
5559:
5555:
5550:
5548:
5542:
5541:
5539:
5538:
5528:
5523:
5519:
5515:
5511:
5507:
5503:
5498:
5494:
5490:
5486:
5482:
5470:
5465:
5455:
5450:
5439:
5435:
5424:
5420:
5415:
5411:
5407:
5403:
5399:
5395:
5391:
5387:
5383:
5379:
5375:
5370:
5366:
5362:
5358:
5354:
5349:
5345:
5341:
5336:
5332:
5328:
5323:
5319:
5315:
5310:
5306:
5302:
5298:
5294:
5290:
5286:
5282:
5278:
5274:
5270:
5266:
5262:
5258:
5254:
5250:
5246:
5242:
5238:
5234:
5230:
5226:
5222:
5218:
5214:
5210:
5205:
5203:
5197:
5196:
5194:
5182:
5177:
5172:
5167:
5162:
5157:
5155:
5147:
5146:
5144:
5143:
5138:
5134:
5129:
5125:
5120:
5115:
5106:
5101:
5097:
5093:
5089:
5085:
5079:
5076:
5075:
5073:
5072:
5062:
5056:
5054:
5046:
5045:
5043:
5042:
5038:
5033:
5031:
5023:
5022:
5020:
5019:
5015:
5011:
5007:
5002:
4997:
4995:
4987:
4986:
4984:
4983:
4979:
4975:
4971:
4966:
4961:
4959:
4949:
4948:
4946:
4945:
4940:
4936:
4932:
4928:
4924:
4920:
4916:
4912:
4908:
4904:
4900:
4896:
4892:
4888:
4884:
4880:
4876:
4872:
4868:
4864:
4860:
4856:
4852:
4848:
4844:
4840:
4836:
4832:
4827:
4822:
4820:
4810:
4809:
4807:
4802:
4798:
4794:
4790:
4786:
4782:
4778:
4774:
4770:
4766:
4762:
4758:
4754:
4749:
4745:
4743:
4734:
4730:chalcogenides
4724:
4723:
4721:
4720:
4712:
4707:
4703:
4699:
4694:
4690:
4685:
4682:
4681:
4679:
4678:
4668:
4662:
4660:
4652:
4651:
4649:
4648:
4644:
4639:
4637:
4629:
4628:
4626:
4625:
4621:
4616:
4614:
4606:
4605:
4603:
4602:
4598:
4594:
4590:
4586:
4581:
4579:
4569:
4568:
4566:
4565:
4561:
4557:
4553:
4549:
4545:
4541:
4537:
4533:
4528:
4526:
4516:
4515:
4513:
4512:
4507:
4503:
4499:
4495:
4491:
4487:
4483:
4479:
4475:
4471:
4467:
4463:
4459:
4455:
4451:
4447:
4443:
4439:
4435:
4431:
4427:
4423:
4419:
4415:
4411:
4407:
4403:
4399:
4395:
4390:
4388:
4378:
4377:
4375:
4374:
4370:
4366:
4362:
4358:
4354:
4350:
4346:
4342:
4337:
4335:
4325:
4324:
4322:
4321:
4316:
4312:
4308:
4304:
4300:
4296:
4292:
4288:
4284:
4280:
4276:
4272:
4268:
4264:
4260:
4256:
4252:
4248:
4244:
4240:
4236:
4232:
4228:
4224:
4220:
4216:
4212:
4208:
4204:
4199:
4197:
4188:
4180:
4179:
4176:
4175:
4173:
4172:
4168:
4164:
4160:
4156:
4150:
4148:
4133:
4132:
4130:
4129:
4125:
4120:
4118:
4110:
4109:
4107:
4106:
4102:
4098:
4094:
4090:
4085:
4083:
4073:
4072:
4070:
4069:
4065:
4061:
4057:
4053:
4049:
4045:
4041:
4037:
4033:
4029:
4025:
4021:
4017:
4012:
4010:
4000:
3999:
3997:
3996:
3991:
3987:
3983:
3978:
3976:
3966:
3965:
3963:
3962:
3958:
3954:
3949:
3947:
3937:
3936:
3934:
3933:
3928:
3924:
3920:
3916:
3912:
3908:
3904:
3900:
3896:
3892:
3888:
3884:
3880:
3876:
3872:
3868:
3864:
3860:
3856:
3852:
3848:
3844:
3840:
3836:
3832:
3828:
3824:
3820:
3816:
3811:
3809:
3799:
3798:
3796:
3795:
3790:
3786:
3782:
3778:
3774:
3770:
3764:
3757:
3756:
3754:
3753:
3748:
3743:
3738:
3733:
3728:
3723:
3717:
3715:
3706:
3700:
3699:
3696:
3695:
3693:
3692:
3688:
3684:
3680:
3676:
3672:
3668:
3664:
3658:
3656:
3641:
3640:
3638:
3637:
3633:
3629:
3625:
3621:
3616:
3614:
3606:
3605:
3603:
3602:
3598:
3594:
3590:
3586:
3581:
3579:
3571:
3570:
3568:
3567:
3563:
3559:
3555:
3551:
3546:
3544:
3536:
3535:
3533:
3532:
3528:
3524:
3520:
3516:
3511:
3509:
3501:
3500:
3498:
3497:
3493:
3489:
3485:
3481:
3477:
3473:
3469:
3465:
3461:
3457:
3453:
3449:
3445:
3441:
3437:
3433:
3429:
3425:
3421:
3417:
3413:
3409:
3405:
3401:
3397:
3393:
3389:
3385:
3381:
3377:
3372:
3368:
3363:
3361:
3352:
3344:
3343:
3340:
3339:
3337:
3336:
3332:
3328:
3324:
3320:
3316:
3312:
3308:
3304:
3300:
3295:
3293:
3285:
3284:
3282:
3281:
3276:
3271:
3266:
3261:
3255:
3253:
3246:
3244:earth hydrides
3236:
3235:
3233:
3232:
3227:
3222:
3217:
3212:
3206:
3204:
3196:
3195:
3190:
3188:
3187:
3180:
3173:
3165:
3156:
3155:
3153:
3152:
3148:
3144:
3140:
3136:
3131:
3129:
3125:
3124:
3122:
3121:
3117:
3113:
3108:
3106:
3102:
3101:
3099:
3098:
3094:
3090:
3085:
3081:
3077:
3073:
3069:
3062:
3053:
3044:
3036:
3032:
3028:
3024:
3020:
3016:
3012:
3008:
3004:
2999:
2995:
2991:
2987:
2983:
2978:
2964:
2960:
2956:
2952:
2948:
2944:
2940:
2936:
2932:
2928:
2924:
2920:
2916:
2912:
2908:
2904:
2900:
2896:
2892:
2888:
2884:
2880:
2876:
2872:
2868:
2861:
2854:
2850:
2846:
2842:
2838:
2834:
2830:
2826:
2822:
2818:
2814:
2810:
2806:
2802:
2798:
2794:
2790:
2786:
2782:
2778:
2774:
2770:
2766:
2762:
2758:
2754:
2750:
2745:
2743:
2739:
2738:
2736:
2735:
2731:
2727:
2723:
2719:
2715:
2711:
2707:
2702:
2700:
2696:
2695:
2693:
2692:
2677:
2672:
2667:
2663:
2658:
2654:
2650:
2646:
2641:
2636:
2632:
2628:
2624:
2620:
2616:
2612:
2608:
2604:
2599:
2594:
2587:
2582:
2577:
2571:
2569:
2565:
2564:
2562:
2561:
2556:
2551:
2549:
2545:
2544:
2539:
2537:
2536:
2529:
2522:
2514:
2507:
2506:
2465:(2): 461–464.
2442:
2437:10.1086/190375
2403:
2346:
2303:
2276:(2): 451–457.
2260:
2204:
2163:
2119:
2076:
2019:
1976:
1933:
1890:
1846:
1810:
1799:(2): c17–c21.
1783:
1731:
1696:
1680:
1645:
1598:
1585:(2): 118–119.
1565:
1554:(3): 613–639.
1538:
1531:
1511:
1481:
1474:
1449:
1442:
1424:
1383:
1354:(6): 608–612.
1334:
1307:
1294:(2): 118–119.
1274:
1236:
1228:Comptes rendus
1215:
1176:(13): 134507.
1153:
1115:
1072:
1048:
1037:(4): 713–718.
1015:
1013:
1010:
1009:
1008:
997:
987:
984:
979:
978:
974:
951:
948:
938:
934:
931:
919:
916:
903:
900:
889:
874:
866:
858:
853:
852:
767:
765:
758:
748:
740:
737:
729:
728:
724:
718:
712:
711:+ 3 H → /
700:
697:
692:
688:
674:
673:
670:
663:
662:
658:
654:
650:
646:
642:
618:
615:
611:
610:
599:
575:
574:
568:
555:
552:
527:
524:
522:
519:
514:
510:
494:
491:
485:
474:Copper hydride
469:
466:
465:
460:
456:standard state
453:
450:
449:
446:
440:
437:
436:
433:
427:
424:
423:
420:
414:
411:
410:
401:
400:
383:
378:
375:
374:
369:
364:
361:
360:
348:
343:
340:
339:
329:
328:
324:
323:
320:
314:
313:
307:
301:
300:
292:
287:
284:
283:
279:
278:
276:
275:
267:
266:
265:
262:
261:
259:
258:
254:
251:
250:
242:
241:
240:
237:
236:
234:
233:
225:DTXSID50391571
220:
218:
206:
203:
202:
200:
199:
191:
189:
181:
178:
177:
175:
174:
170:
168:
160:
159:
149:
141:
140:
138:
137:
129:
127:
121:
120:
118:
117:
109:
107:
100:
97:
96:
94:
93:
85:
83:
78:
75:
74:
70:
69:
58:
54:
53:
51:Copper hydride
50:
44:
43:
39:
38:
24:
14:
13:
10:
9:
6:
4:
3:
2:
5985:
5974:
5971:
5969:
5966:
5964:
5961:
5960:
5958:
5943:
5940:
5939:
5937:
5935:
5931:
5925:
5919:
5917:
5911:
5909:
5903:
5901:
5895:
5893:
5887:
5885:
5879:
5877:
5871:
5869:
5863:
5861:
5855:
5853:
5847:
5845:
5839:
5837:
5831:
5829:
5823:
5821:
5815:
5805:
5803:
5797:
5795:
5789:
5787:
5781:
5780:
5778:
5776:
5772:
5766:
5760:
5758:
5752:
5750:
5744:
5742:
5736:
5734:
5728:
5726:
5720:
5718:
5712:
5710:
5704:
5702:
5696:
5694:
5688:
5686:
5680:
5678:
5672:
5670:
5664:
5662:
5656:
5654:
5648:
5646:
5640:
5638:
5632:
5630:
5624:
5622:
5616:
5614:
5608:
5606:
5600:
5598:
5592:
5590:
5584:
5582:
5576:
5574:
5568:
5566:
5560:
5558:
5552:
5551:
5549:
5547:
5543:
5536:
5532:
5531:
5524:
5522:
5516:
5514:
5504:
5502:
5499:
5497:
5491:
5489:
5483:
5480:
5476:
5475:
5471:
5469:
5466:
5463:
5459:
5458:
5451:
5449:
5447:
5442:
5436:
5434:
5432:
5427:
5421:
5419:
5416:
5414:
5408:
5406:
5400:
5398:
5392:
5390:
5384:
5382:
5376:
5374:
5371:
5369:
5363:
5361:
5355:
5353:
5350:
5348:
5342:
5340:
5337:
5335:
5329:
5327:
5324:
5322:
5316:
5314:
5311:
5309:
5303:
5301:
5295:
5293:
5287:
5285:
5279:
5277:
5271:
5269:
5263:
5261:
5255:
5253:
5247:
5245:
5239:
5237:
5231:
5229:
5223:
5221:
5215:
5213:
5207:
5206:
5204:
5202:
5198:
5192:
5188:
5187:
5183:
5181:
5178:
5176:
5173:
5171:
5168:
5166:
5163:
5161:
5158:
5156:
5154:
5148:
5142:
5135:
5133:
5126:
5124:
5121:
5119:
5116:
5114:
5110:
5102:
5100:
5094:
5092:
5086:
5084:
5081:
5080:
5070:
5066:
5065:
5058:
5057:
5055:
5051:
5041:
5035:
5034:
5032:
5028:
5018:
5008:
5006:
4999:
4998:
4996:
4992:
4982:
4972:
4970:
4963:
4962:
4960:
4958:
4954:
4944:
4941:
4939:
4929:
4927:
4917:
4915:
4905:
4903:
4893:
4891:
4881:
4879:
4869:
4867:
4857:
4855:
4845:
4843:
4833:
4831:
4824:
4823:
4821:
4819:
4815:
4806:
4803:
4801:
4791:
4789:
4779:
4777:
4767:
4765:
4755:
4753:
4746:
4744:
4742:
4738:
4735:
4733:
4725:
4719:
4715:
4708:
4706:
4700:
4698:
4695:
4693:
4687:
4686:
4676:
4672:
4671:
4664:
4663:
4661:
4657:
4647:
4641:
4640:
4638:
4634:
4624:
4618:
4617:
4615:
4611:
4601:
4591:
4589:
4583:
4582:
4580:
4578:
4574:
4564:
4554:
4552:
4542:
4540:
4530:
4529:
4527:
4525:
4521:
4511:
4508:
4506:
4496:
4494:
4484:
4482:
4472:
4470:
4460:
4458:
4448:
4446:
4436:
4434:
4424:
4422:
4412:
4410:
4400:
4398:
4392:
4391:
4389:
4387:
4383:
4373:
4363:
4361:
4351:
4349:
4339:
4338:
4336:
4334:
4330:
4320:
4317:
4315:
4305:
4303:
4293:
4291:
4281:
4279:
4269:
4267:
4257:
4255:
4245:
4243:
4233:
4231:
4221:
4219:
4209:
4207:
4201:
4200:
4198:
4196:
4192:
4189:
4187:
4181:
4171:
4165:
4163:
4157:
4155:
4152:
4151:
4149:
4146:
4142:
4138:
4128:
4122:
4121:
4119:
4115:
4105:
4095:
4093:
4087:
4086:
4084:
4082:
4078:
4068:
4058:
4056:
4046:
4044:
4034:
4032:
4022:
4020:
4014:
4013:
4011:
4009:
4005:
3995:
3992:
3990:
3980:
3979:
3977:
3975:
3971:
3961:
3951:
3950:
3948:
3946:
3942:
3932:
3929:
3927:
3917:
3915:
3905:
3903:
3893:
3891:
3881:
3879:
3869:
3867:
3857:
3855:
3845:
3843:
3833:
3831:
3821:
3819:
3813:
3812:
3810:
3808:
3804:
3794:
3787:
3785:
3779:
3777:
3771:
3769:
3766:
3765:
3762:
3752:
3749:
3747:
3744:
3742:
3739:
3737:
3734:
3732:
3729:
3727:
3724:
3722:
3719:
3718:
3716:
3714:
3710:
3707:
3705:
3701:
3691:
3685:
3683:
3673:
3671:
3665:
3663:
3660:
3659:
3657:
3654:
3650:
3646:
3636:
3626:
3624:
3618:
3617:
3615:
3611:
3601:
3591:
3589:
3583:
3582:
3580:
3576:
3566:
3556:
3554:
3548:
3547:
3545:
3541:
3531:
3521:
3519:
3513:
3512:
3510:
3506:
3496:
3486:
3484:
3474:
3472:
3462:
3460:
3450:
3448:
3438:
3436:
3426:
3424:
3414:
3412:
3402:
3400:
3390:
3388:
3378:
3376:
3373:
3371:
3365:
3364:
3362:
3360:
3356:
3353:
3351:
3345:
3335:
3329:
3327:
3321:
3319:
3313:
3311:
3305:
3303:
3297:
3296:
3294:
3290:
3280:
3277:
3275:
3272:
3270:
3267:
3265:
3262:
3260:
3257:
3256:
3254:
3250:
3247:
3245:
3237:
3231:
3228:
3226:
3223:
3221:
3218:
3216:
3213:
3211:
3208:
3207:
3205:
3203:
3200:Alkali metal
3197:
3193:
3186:
3181:
3179:
3174:
3172:
3167:
3166:
3163:
3151:
3141:
3139:
3133:
3132:
3130:
3126:
3120:
3110:
3109:
3107:
3103:
3097:
3091:
3089:
3086:
3084:
3070:
3068:
3037:
3035:
3021:
3019:
3013:
3011:
3005:
3003:
3000:
2998:
2992:
2990:
2984:
2982:
2979:
2976:
2965:
2963:
2953:
2951:
2937:
2935:
2921:
2919:
2909:
2907:
2901:
2899:
2889:
2887:
2877:
2875:
2864:
2857:
2851:
2849:
2843:
2841:
2827:
2825:
2819:
2817:
2799:
2797:
2787:
2785:
2775:
2773:
2767:
2765:
2759:
2757:
2747:
2746:
2744:
2740:
2734:
2716:
2714:
2704:
2703:
2701:
2697:
2690:
2678:
2676:
2673:
2671:
2664:
2662:
2655:
2653:
2647:
2645:
2642:
2640:
2633:
2631:
2617:
2615:
2605:
2603:
2600:
2598:
2595:
2593:
2592:
2588:
2586:
2583:
2581:
2578:
2576:
2573:
2572:
2570:
2566:
2560:
2553:
2552:
2550:
2546:
2542:
2535:
2530:
2528:
2523:
2521:
2516:
2515:
2512:
2496:on 2005-03-10
2492:
2488:
2484:
2480:
2476:
2472:
2468:
2464:
2460:
2453:
2446:
2443:
2438:
2434:
2430:
2426:
2422:
2418:
2414:
2407:
2404:
2399:
2395:
2391:
2387:
2382:
2377:
2373:
2369:
2366:(24): 11756.
2365:
2361:
2357:
2350:
2347:
2342:
2338:
2334:
2330:
2326:
2322:
2318:
2314:
2307:
2304:
2299:
2295:
2291:
2287:
2283:
2279:
2275:
2271:
2264:
2261:
2250:on 2015-04-02
2246:
2242:
2238:
2234:
2230:
2226:
2222:
2215:
2208:
2205:
2199:
2194:
2190:
2186:
2182:
2178:
2174:
2167:
2164:
2159:
2155:
2151:
2147:
2143:
2139:
2132:
2130:
2128:
2126:
2124:
2120:
2115:
2111:
2107:
2103:
2099:
2095:
2091:
2087:
2080:
2077:
2072:
2068:
2063:
2058:
2054:
2050:
2046:
2042:
2038:
2034:
2030:
2023:
2020:
2015:
2011:
2007:
2003:
1999:
1995:
1991:
1987:
1980:
1977:
1972:
1968:
1964:
1960:
1956:
1952:
1948:
1944:
1937:
1934:
1929:
1925:
1921:
1917:
1913:
1909:
1905:
1901:
1894:
1891:
1886:
1882:
1878:
1874:
1870:
1866:
1862:
1858:
1850:
1847:
1842:
1838:
1834:
1830:
1826:
1822:
1814:
1811:
1806:
1802:
1798:
1794:
1787:
1784:
1773:on 2022-05-14
1769:
1765:
1761:
1757:
1753:
1749:
1742:
1735:
1732:
1727:
1723:
1719:
1715:
1711:
1707:
1700:
1697:
1694:
1690:
1684:
1681:
1676:
1672:
1668:
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1370:
1365:
1361:
1357:
1353:
1349:
1345:
1338:
1335:
1330:
1326:
1323:: 1669–1673.
1322:
1318:
1311:
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1302:
1297:
1293:
1289:
1285:
1278:
1275:
1270:
1266:
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1199:
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1187:
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1175:
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1129:
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1120:
1116:
1111:
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1103:
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1073:
1068:
1064:
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972:
971:
970:
967:
965:
960:
957:
949:
947:
943:
929:
925:
924:copper iodide
917:
915:
913:
909:
901:
899:
897:
892:
886:
884:
878:
872:
864:
849:
846:
838:
827:
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820:
817:
813:
810:
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803:
799:
796: –
795:
791:
790:Find sources:
784:
778:
777:
773:
768:This article
766:
762:
757:
756:
747:Structure of
745:
738:
736:
734:
721:
715:
710:
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698:
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686:
681:
679:
668:
667:
666:
640:
639:
638:
636:
632:
631:sulfuric acid
628:
624:
616:
614:
608:
592:
588:
584:
581:2 CuH →
580:
579:
578:
561:
560:
559:
553:
551:
547:
545:
541:
532:
525:
520:
518:
508:
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500:
499:Adolphe Wurtz
492:
490:
483:
479:
475:
463:
457:
451:
447:
443:
439:
438:
434:
431:(Recommended)
430:
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418:(Permissible)
417:
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384:
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318:Melting point
316:
315:
308:
306:
303:
302:
293:
290:
286:
285:
280:
274:
270:
263:
252:InChI=1S/Cu.H
249:
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150:
148:
146:ECHA InfoCard
143:
142:
135:
131:
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128:
126:
123:
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115:
111:
110:
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104:
99:
98:
91:
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71:
55:
49:
45:
40:
36:
31:
19:
5534:
5525:
5478:
5472:
5467:
5461:
5452:
5445:
5440:
5430:
5425:
5190:
5184:
5103:
5068:
5059:
5053:Livermoranes
4818:Polysulfanes
4741:Polyoxidanes
4709:
4674:
4665:
4166:
4158:
4153:
4144:
3746:Cycloalkynes
3741:Cycloalkenes
3736:Cycloalkanes
3713:Hydrocarbons
3686:
3674:
3666:
3661:
3652:
3252:Monohydrides
2596:
2589:
2498:. Retrieved
2491:the original
2462:
2458:
2445:
2420:
2416:
2406:
2363:
2359:
2349:
2316:
2312:
2306:
2273:
2269:
2263:
2252:. Retrieved
2245:the original
2224:
2220:
2207:
2183:(3–4): 250.
2180:
2176:
2166:
2141:
2137:
2089:
2085:
2079:
2036:
2032:
2022:
1989:
1985:
1979:
1946:
1942:
1936:
1903:
1899:
1893:
1860:
1856:
1849:
1824:
1820:
1813:
1796:
1792:
1786:
1775:. Retrieved
1768:the original
1747:
1734:
1709:
1705:
1699:
1683:
1658:
1654:
1648:
1615:
1611:
1582:
1578:
1568:
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1433:
1427:
1400:
1396:
1386:
1351:
1347:
1337:
1320:
1316:
1310:
1291:
1287:
1277:
1252:
1248:
1231:
1227:
1218:
1206:. Retrieved
1202:the original
1173:
1169:
1131:
1127:
1085:
1081:
1075:
1034:
1030:
980:
968:
961:
953:
944:
921:
907:
905:
890:
887:
879:
871:hydrosilanes
856:
841:
832:
822:
815:
808:
801:
789:
769:
732:
730:
719:
713:
702:
682:
675:
664:
620:
612:
606:
590:
586:
582:
576:
557:
548:
537:
496:
473:
472:
405:
371:
333:
73:Identifiers
57:Other names
4636:Bismuthanes
2319:: 774–775.
898:reactions.
717: (CuH)
366:Signal word
282:Properties
152:100.229.864
5957:Categories
4659:Moscovanes
4524:Phosphenes
4386:Phosphanes
4184:Pnictogen
4141:Flerovanes
3292:Dihydrides
3242:(Group 2)
2500:2013-02-20
2313:Proc. SPIE
2254:2013-02-23
2227:(1): 202.
1777:2019-12-19
1012:References
964:19 Piscium
918:Production
805:newspapers
772:references
705:sonication
680:if dried.
678:pyrophoric
641:4 Cu + 6 H
617:Production
345:Pictograms
305:Molar mass
125:ChemSpider
101:3D model (
90:13517-00-5
80:CAS Number
48:IUPAC name
5535:predicted
5479:predicted
5462:predicted
5191:predicted
5069:predicted
4728:Hydrogen
4675:predicted
4145:predicted
4117:Plumbanes
4081:Stannanes
3751:Annulenes
3653:predicted
3649:Nihonanes
3613:Thallanes
3578:Indiganes
3348:Group 13
3240:Alkaline
2487:0022-2852
2423:: 75–92.
2390:0021-9606
2298:0022-2852
2241:0260-1826
2158:0002-7863
2106:0002-7863
2053:0002-7863
2006:1521-3773
1963:1521-3773
1920:1521-3773
1877:0002-7863
1841:0002-7863
1764:1364-548X
1726:0002-7863
1675:0002-7863
1632:1477-9226
1128:Chem. Rev
1102:0009-2665
977:↔ CuH + H
908:octahedro
835:July 2021
544:polymeric
526:Structure
480:with the
336:labelling
173:803-023-1
165:EC Number
5448:< 1)
4994:Tellanes
4613:Stibanes
4008:Germanes
3543:Gallanes
3350:hydrides
2699:Cu(I,II)
2398:43929297
2341:93779370
2114:24896663
2071:24106781
2014:24038866
1971:19591178
1928:15108129
1885:12862472
1640:28379275
1419:25671787
1378:26634717
1269:22179137
1198:23574244
1148:11840988
1110:27454444
1069:(NIOSH).
605:(0 <
589:)CuH + ½
327:Hazards
5433:< 1)
5030:Polanes
4957:Selanes
4943:more...
4805:more...
4577:Arsanes
4510:more...
4319:more...
3974:Silynes
3945:Silenes
3931:more...
3807:Silanes
3731:alkynes
3726:alkenes
3721:alkanes
3359:Boranes
3105:Cu(III)
3007:Cu(SCN)
2548:Cu(0,I)
2467:Bibcode
2425:Bibcode
2368:Bibcode
2321:Bibcode
2278:Bibcode
2185:Bibcode
2062:3874865
1369:4669994
1208:20 June
1178:Bibcode
1063:"#0150"
950:History
819:scholar
733:in situ
691:·Cu(OH)
609:< 2)
493:History
372:Warning
196:3335333
183:PubChem
134:2582262
65:Cuprane
4333:Azenes
4195:Azanes
3508:Alanes
3128:Cu(IV)
2994:Cu(OH)
2891:Cu(ClO
2879:Cu(ClO
2845:Cu(CN)
2742:Cu(II)
2485:
2396:
2388:
2339:
2296:
2239:
2156:
2112:
2104:
2069:
2059:
2051:
2012:
2004:
1969:
1961:
1926:
1918:
1883:
1875:
1839:
1762:
1724:
1673:
1638:
1630:
1529:
1472:
1440:
1417:
1376:
1366:
1267:
1196:
1146:
1108:
1100:
973:Cu + H
821:
814:
807:
800:
792:
687:, CuCO
593:
585:Cu•(2-
476:is an
310:64.554
269:SMILES
42:Names
2911:Cu(NO
2860:KCuCl
2789:Cu(CF
2777:Cu(CH
2749:Cu(BF
2675:CuSCN
2568:Cu(I)
2494:(PDF)
2455:(PDF)
2394:S2CID
2337:S2CID
2248:(PDF)
2217:(PDF)
1771:(PDF)
1744:(PDF)
926:with
826:JSTOR
812:books
661:+ 8 H
649:+ 6 H
625:with
505:with
406:NIOSH
244:InChI
103:JSmol
3093:CuTe
3088:CuTe
3080:COO)
3072:Cu(C
3058:COO)
3040:Cu(C
3027:(AsO
3015:CuSO
2955:Cu(N
2871:CuCl
2853:CuCl
2837:(OH)
2821:CuCO
2801:Cu(C
2793:COO)
2781:COO)
2761:CuBr
2649:CuNO
2644:CuOH
2585:CuCl
2580:CuCN
2575:CuBr
2483:ISSN
2386:ISSN
2294:ISSN
2237:ISSN
2154:ISSN
2110:PMID
2102:ISSN
2067:PMID
2049:ISSN
2010:PMID
2002:ISSN
1967:PMID
1959:ISSN
1924:PMID
1916:ISSN
1881:PMID
1873:ISSN
1837:ISSN
1760:ISSN
1722:ISSN
1671:ISSN
1636:PMID
1628:ISSN
1527:ISBN
1470:ISBN
1438:ISBN
1415:PMID
1374:PMID
1265:PMID
1210:2013
1194:PMID
1144:PMID
1106:PMID
1098:ISSN
883:PMHS
798:news
442:IDLH
398:H335
394:H319
390:H315
386:H228
67:poly
5942:PsH
5921:CfH
5913:CfH
5905:BkH
5897:BkH
5889:CmH
5881:AmH
5873:AmH
5865:PuH
5857:PuH
5849:NpH
5841:NpH
5817:PaH
5799:ThH
5791:ThH
5783:AcH
5762:LuH
5754:LuH
5746:YbH
5738:TmH
5730:TmH
5722:ErH
5714:ErH
5706:HoH
5698:HoH
5690:DyH
5682:DyH
5674:TbH
5666:TbH
5658:GdH
5650:GdH
5642:EuH
5634:SmH
5626:SmH
5618:NdH
5610:NdH
5602:PrH
5594:PrH
5586:CeH
5578:CeH
5570:LaH
5562:LaH
5554:LaH
5527:CnH
5518:HgH
5501:HgH
5493:CdH
5485:ZnH
5474:RgH
5468:CuH
5454:DsH
5438:PtH
5423:PdH
5418:NiH
5410:IrH
5402:RhH
5394:CoH
5386:FeH
5378:FeH
5373:FeH
5365:CrH
5357:CrH
5352:CrH
5344:TaH
5339:TaH
5331:NbH
5326:NbH
5305:HfH
5297:HfH
5289:ZrH
5281:ZrH
5273:TiH
5265:TiH
5257:LuH
5249:LuH
5209:ScH
5186:HTs
5180:HAt
5170:HBr
5165:HCl
5123:HDO
5112:(?)
5109:O–O
5061:LvH
5037:PoH
4717:(?)
4667:McH
4643:BiH
4620:SbH
4585:AsH
4167:FlH
4159:FlH
4154:FlH
4124:PbH
4089:SnH
4016:GeH
3994:SiH
3815:SiH
3687:NhH
3667:NhH
3662:NhH
3620:TlH
3585:InH
3550:GaH
3515:AlH
3331:BaH
3323:SrH
3315:CaH
3307:MgH
3299:BeH
3279:BaH
3274:SrH
3269:CaH
3264:MgH
3259:BeH
3230:CsH
3225:RbH
3215:NaH
3210:LiH
3147:CuF
3135:CuO
3116:CuF
3002:CuS
2986:CuO
2981:CuO
2968:CuC
2943:(BO
2927:(PO
2903:CuF
2769:CuC
2602:CuI
2597:CuH
2591:CuF
2475:doi
2463:139
2433:doi
2376:doi
2364:110
2329:doi
2317:553
2286:doi
2274:113
2229:doi
2193:doi
2146:doi
2094:doi
2090:136
2057:PMC
2041:doi
2037:135
1994:doi
1951:doi
1908:doi
1865:doi
1861:125
1829:doi
1825:121
1801:doi
1797:275
1752:doi
1714:doi
1710:111
1689:doi
1663:doi
1620:doi
1587:doi
1556:doi
1502:doi
1498:363
1405:doi
1364:PMC
1356:doi
1325:doi
1321:129
1296:doi
1257:doi
1186:doi
1174:138
1136:doi
1132:101
1090:doi
1086:116
1039:doi
993:CuH
774:to
484:CuH
429:REL
416:PEL
334:GHS
213:EPA
186:CID
5959::
5833:UH
5825:UH
5812:15
5806:Th
5572:10
5506:Hg
5318:VH
5313:VH
5241:YH
5233:YH
5225:YH
5217:YH
5175:HI
5160:HF
5118:HS
5096:HO
5088:HO
5083:HO
5014:Te
5005:Te
4978:Se
4969:Se
4937:10
4711:NH
4702:HN
4697:NH
4689:HN
4593:As
4504:12
4500:10
4492:11
4480:10
4394:PH
4313:12
4309:10
4301:11
4289:10
4203:NH
4097:Sn
4066:12
4060:Ge
4054:10
4048:Ge
4036:Ge
4024:Ge
3982:Si
3953:Si
3925:22
3921:10
3919:Si
3913:20
3907:Si
3901:18
3895:Si
3889:16
3883:Si
3877:14
3871:Si
3865:12
3859:Si
3853:10
3847:Si
3835:Si
3823:Si
3781:CH
3773:CH
3768:CH
3675:Nh
3628:Tl
3593:In
3558:Ga
3523:Al
3494:22
3490:18
3482:14
3478:10
3470:12
3458:10
3446:11
3422:10
3375:BH
3367:BH
3220:KH
3143:Cs
3078:35
3074:17
3054:23
3045:11
3023:Cu
2939:Cu
2923:Cu
2865:/
2858:/
2833:CO
2829:Cu
2718:Cu
2706:Cu
2689:Cu
2666:Cu
2657:Cu
2635:Cu
2623:Cr
2619:Cu
2607:Cu
2559:Si
2555:Cu
2481:.
2473:.
2461:.
2457:.
2431:.
2421:31
2419:.
2392:.
2384:.
2374:.
2362:.
2358:.
2335:.
2327:.
2292:.
2284:.
2272:.
2235:.
2225:96
2223:.
2219:.
2191:.
2179:.
2175:.
2152:.
2142:90
2140:.
2122:^
2108:.
2100:.
2088:.
2065:.
2055:.
2047:.
2035:.
2031:.
2008:.
2000:.
1990:52
1988:.
1965:.
1957:.
1947:48
1945:.
1922:.
1914:.
1904:43
1902:.
1879:.
1871:.
1859:.
1835:.
1823:.
1795:.
1758:.
1746:.
1720:.
1708:.
1669:.
1659:91
1657:.
1634:.
1626:.
1616:46
1614:.
1601:^
1581:.
1577:.
1552:33
1550:.
1496:.
1484:^
1468:.
1413:.
1401:54
1399:.
1395:.
1372:.
1362:.
1352:71
1350:.
1346:.
1319:.
1290:.
1286:.
1263:.
1253:48
1251:.
1239:^
1232:18
1230:,
1192:.
1184:.
1172:.
1168:.
1156:^
1142:.
1130:.
1118:^
1104:.
1096:.
1084:.
1065:.
1051:^
1035:91
1033:.
1019:^
966:.
785:.
657:PO
645:PO
513:PO
509:(H
396:,
392:,
388:,
338::
295:Cu
5923:3
5915:2
5907:3
5899:2
5891:2
5883:3
5875:2
5867:3
5859:2
5851:3
5843:2
5835:4
5827:3
5819:3
5810:H
5808:4
5801:4
5793:2
5785:2
5764:3
5756:2
5748:2
5740:3
5732:2
5724:3
5716:2
5708:3
5700:2
5692:3
5684:2
5676:3
5668:2
5660:3
5652:2
5644:2
5636:3
5628:2
5620:3
5612:2
5604:3
5596:2
5588:3
5580:2
5564:3
5556:2
5537:)
5533:(
5529:2
5520:2
5512:2
5510:H
5508:2
5495:2
5487:2
5481:)
5477:(
5464:)
5460:(
5456:2
5446:x
5444:(
5441:x
5431:x
5429:(
5426:x
5412:3
5404:2
5396:2
5388:5
5380:2
5367:x
5359:2
5346:2
5333:2
5320:2
5307:4
5299:2
5291:4
5283:2
5275:4
5267:2
5259:3
5251:2
5243:9
5235:6
5227:3
5219:2
5211:2
5193:)
5189:(
5141:O
5139:2
5137:T
5132:O
5130:2
5128:D
5107:2
5105:H
5098:3
5090:2
5071:)
5067:(
5063:2
5039:2
5016:2
5012:2
5010:H
5003:2
5001:H
4980:2
4976:2
4974:H
4967:2
4965:H
4935:S
4933:2
4931:H
4925:9
4923:S
4921:2
4919:H
4913:8
4911:S
4909:2
4907:H
4901:7
4899:S
4897:2
4895:H
4889:6
4887:S
4885:2
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