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Ethyl group

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45: 185: 131: 444: 1363: 329: : 1–39.) In reporting on Liebig's findings (and related work by others), Berzelius coined the names "methyl" and "ethyl" for the "radicals" CH 1368: 135: 157:
is the formation of a compound by introduction of the ethyl group. The most widely practiced example of this reaction is the ethylation of
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constituted a "radical" (a cluster of atoms that did not undergo changes during chemical reactions). (See: Justus Liebig (1834)
437: 290: 1267: 237:, the first-born Greek elemental god of air (and at that time a general term for any highly volatile compound) and " 840: 430: 1396: 877: 1350: 242: 1250: 38: 1391: 1357: 1245: 318: 1326: 771: 632: 402: 209:
is such a reagent. For good nucleophiles, less electrophilic reagents are employed, such as ethyl
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transliterated "ethyl" as "Aethyl". (See: Jöns Jacob Berzelius with Friedrich Wöhler, trans.,
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In unsymmetrical ethylated compounds, the methylene protons in the ethyl substituent are
1311: 1306: 1182: 1177: 1172: 965: 932: 716: 698: 688: 222: 1385: 1331: 1279: 1210: 1096: 1086: 1081: 1071: 1066: 1016: 1011: 927: 922: 912: 766: 721: 683: 671: 642: 520: 241:", referring to "stuff". The name "ethyl" was coined in 1835 by the Swedish chemist 194: 67: 1262: 1149: 1144: 1121: 872: 711: 637: 574: 569: 547: 503: 488: 478: 166: 28: 282: 273:
Welch, Vincent A.; Fallon, Kevin J.; Gelbke, Heinz-Peter (2005). "Ethylbenzene".
1321: 1274: 1235: 1116: 1004: 989: 984: 972: 537: 532: 498: 493: 461: 198: 174: 94: 63: 401:, … ) In his translation into German of Berzelius' report, the German chemist 1230: 1221: 1101: 1056: 952: 917: 907: 847: 783: 706: 654: 44: 1197: 1111: 1076: 1061: 1049: 892: 867: 676: 225:. Chiral reagents are known to stereoselectively modify such substituents. 177:. Approximately 24.7 million tons of ethylbenzene were produced in 1999. 17: 1205: 1159: 1126: 822: 728: 602: 557: 542: 162: 184: 146:" is used to indicate the presence of two carbon atoms in the molecule. 1167: 1091: 942: 937: 902: 887: 882: 852: 835: 659: 586: 552: 170: 158: 59: 1255: 1187: 1031: 740: 733: 627: 608: 597: 581: 527: 377:(One may then give names to ether radicals; one can call the older C 210: 112: 422: 1136: 1106: 1039: 897: 862: 857: 830: 778: 745: 649: 473: 351:"Man får då ge namn åt etherradikalerna; man kan kalla den äldre C 91: 43: 407:
Jahresbericht über die Fortschritte der physischen Wissenschaften
564: 238: 426: 319:"Ueber die Constitution des Aethers und seiner Verbindungen" 409:(Annual report on the progress of the physical sciences), 345:(Stockholm, Sweden: P.A. Norstedt & Söner, 1835), 321:(On the composition of ethers and their compounds), 1299: 1219: 1196: 1158: 1135: 1030: 951: 821: 798: 754: 697: 620: 595: 460: 193:Many ethyl-containing compounds are generated by 132:International Union of Pure and Applied Chemistry 275:Ullmann's Encyclopedia of Industrial Chemistry 438: 8: 343:Årsberättelsen om framsteg i fysik och kemi 818: 617: 445: 431: 423: 233:The name of the group is derived from the 122: 118: 107: 103: 341:, respectively. From Jacob Berzelius, 265: 54:) as part of a molecule, as the ethyl 7: 25: 203:Triethyloxonium tetrafluoroborate 142:in a molecule, while the prefix " 136:nomenclature of organic chemistry 183: 197:ethylation, i.e. treatment of 1: 283:10.1002/14356007.a10_035.pub2 305:In 1834, the German chemist 309:had argued that the group C 138:for a saturated two-carbon 1413: 173:, which is a precursor to 36: 26: 1340: 48:Ethyl group (highlighted 34:Chemical group (–CH₂–CH₃) 27:Not to be confused with 1351:chemical classification 58:, and in the compounds 75: 39:Ethyl (disambiguation) 1358:chemical nomenclature 323:Annalen der Pharmacie 201:with sources of Et. 47: 243:Jöns Jacob Berzelius 37:For other uses, see 814:not C, H or O) 1256:Hypervalent iodine 76: 72:ethyl methyl ether 1379: 1378: 1317:Sulfenyl chloride 1295: 1294: 794: 793: 613:(only C, H and O) 454:Functional groups 169:, a precursor to 80:organic chemistry 16:(Redirected from 1404: 1346: 1251:Trifluoromethoxy 819: 815: 618: 614: 467: 447: 440: 433: 424: 418: 403:Friedrich Wöhler 303: 297: 296: 270: 255:Functional group 187: 125: 110: 53: 21: 1412: 1411: 1407: 1406: 1405: 1403: 1402: 1401: 1397:Ethyl compounds 1382: 1381: 1380: 1375: 1344: 1336: 1291: 1246:Trichloromethyl 1241:Trifluoromethyl 1215: 1192: 1154: 1131: 1026: 995:Phosphine oxide 947: 813: 811: 810: 808: 806: 804: 802: 800: 790: 750: 693: 612: 611: 606: 601: 591: 465: 464: 456: 451: 421: 396: 392: 384: 380: 370: 366: 358: 354: 340: 336: 332: 316: 312: 304: 300: 293: 272: 271: 267: 263: 251: 231: 219: 217:Stereochemistry 208: 152: 130:is used in the 124: 120: 116: 111:, derived from 109: 105: 101: 49: 42: 35: 32: 23: 22: 15: 12: 11: 5: 1410: 1408: 1400: 1399: 1394: 1384: 1383: 1377: 1376: 1374: 1373: 1372: 1371: 1366: 1354: 1347: 1341: 1338: 1337: 1335: 1334: 1332:Sulfinylamines 1329: 1324: 1319: 1314: 1312:Phosphoramides 1309: 1307:Isothiocyanate 1303: 1301: 1297: 1296: 1293: 1292: 1290: 1289: 1284: 1283: 1282: 1272: 1271: 1270: 1260: 1259: 1258: 1253: 1248: 1243: 1238: 1227: 1225: 1217: 1216: 1214: 1213: 1208: 1202: 1200: 1194: 1193: 1191: 1190: 1185: 1183:Selenenic acid 1180: 1178:Seleninic acid 1175: 1173:Selenonic acid 1170: 1164: 1162: 1156: 1155: 1153: 1152: 1147: 1141: 1139: 1133: 1132: 1130: 1129: 1124: 1119: 1114: 1109: 1104: 1099: 1094: 1089: 1084: 1079: 1074: 1069: 1064: 1059: 1054: 1053: 1052: 1042: 1036: 1034: 1028: 1027: 1025: 1024: 1019: 1014: 1009: 1008: 1007: 997: 992: 987: 982: 981: 980: 970: 969: 968: 966:Phosphodiester 957: 955: 949: 948: 946: 945: 940: 935: 930: 925: 920: 915: 910: 905: 900: 895: 890: 885: 880: 875: 870: 865: 860: 855: 850: 845: 844: 843: 838: 827: 825: 816: 812:(one element, 796: 795: 792: 791: 789: 788: 787: 786: 776: 775: 774: 769: 758: 756: 752: 751: 749: 748: 743: 738: 737: 736: 726: 725: 724: 719: 714: 703: 701: 695: 694: 692: 691: 689:Methylenedioxy 686: 681: 680: 679: 674: 664: 663: 662: 657: 647: 646: 645: 635: 630: 624: 622: 615: 593: 592: 590: 589: 584: 579: 578: 577: 572: 562: 561: 560: 555: 550: 545: 540: 535: 525: 524: 523: 518: 508: 507: 506: 501: 496: 491: 486: 481: 470: 468: 466:(only C and H) 458: 457: 452: 450: 449: 442: 435: 427: 420: 419: 394: 390: 389:, the newer C 382: 378: 368: 364: 356: 352: 338: 334: 330: 314: 310: 298: 291: 264: 262: 259: 258: 257: 250: 247: 230: 227: 223:diastereotopic 218: 215: 206: 191: 190: 189: 188: 151: 148: 33: 24: 14: 13: 10: 9: 6: 4: 3: 2: 1409: 1398: 1395: 1393: 1390: 1389: 1387: 1370: 1367: 1365: 1362: 1361: 1360: 1359: 1355: 1353: 1352: 1348: 1343: 1342: 1339: 1333: 1330: 1328: 1325: 1323: 1320: 1318: 1315: 1313: 1310: 1308: 1305: 1304: 1302: 1298: 1288: 1285: 1281: 1278: 1277: 1276: 1273: 1269: 1266: 1265: 1264: 1261: 1257: 1254: 1252: 1249: 1247: 1244: 1242: 1239: 1237: 1234: 1233: 1232: 1229: 1228: 1226: 1224: 1223: 1218: 1212: 1211:Telluroketone 1209: 1207: 1204: 1203: 1201: 1199: 1195: 1189: 1186: 1184: 1181: 1179: 1176: 1174: 1171: 1169: 1166: 1165: 1163: 1161: 1157: 1151: 1148: 1146: 1143: 1142: 1140: 1138: 1134: 1128: 1125: 1123: 1120: 1118: 1115: 1113: 1110: 1108: 1105: 1103: 1100: 1098: 1097:Sulfonic acid 1095: 1093: 1090: 1088: 1087:Sulfinic acid 1085: 1083: 1082:Thiosulfonate 1080: 1078: 1075: 1073: 1072:Thiosulfinate 1070: 1068: 1067:Sulfenic acid 1065: 1063: 1060: 1058: 1055: 1051: 1048: 1047: 1046: 1043: 1041: 1038: 1037: 1035: 1033: 1029: 1023: 1022:Phosphaallene 1020: 1018: 1017:Phosphaalkyne 1015: 1013: 1012:Phosphaalkene 1010: 1006: 1003: 1002: 1001: 998: 996: 993: 991: 988: 986: 983: 979: 976: 975: 974: 971: 967: 964: 963: 962: 959: 958: 956: 954: 950: 944: 941: 939: 936: 934: 931: 929: 926: 924: 921: 919: 916: 914: 911: 909: 906: 904: 901: 899: 896: 894: 891: 889: 886: 884: 881: 879: 876: 874: 871: 869: 866: 864: 861: 859: 856: 854: 851: 849: 846: 842: 839: 837: 834: 833: 832: 829: 828: 826: 824: 820: 817: 797: 785: 782: 781: 780: 777: 773: 770: 768: 765: 764: 763: 760: 759: 757: 753: 747: 744: 742: 739: 735: 732: 731: 730: 727: 723: 720: 718: 715: 713: 710: 709: 708: 705: 704: 702: 700: 696: 690: 687: 685: 684:Ethylenedioxy 682: 678: 675: 673: 670: 669: 668: 665: 661: 658: 656: 653: 652: 651: 648: 644: 641: 640: 639: 636: 634: 631: 629: 626: 625: 623: 619: 616: 610: 604: 599: 594: 588: 585: 583: 580: 576: 573: 571: 568: 567: 566: 563: 559: 556: 554: 551: 549: 546: 544: 541: 539: 536: 534: 531: 530: 529: 526: 522: 519: 517: 514: 513: 512: 509: 505: 502: 500: 497: 495: 492: 490: 487: 485: 482: 480: 477: 476: 475: 472: 471: 469: 463: 459: 455: 448: 443: 441: 436: 434: 429: 428: 425: 416: 412: 408: 404: 400: 388: 376: 372: 363:, den nyare C 360: 348: 344: 328: 324: 320: 308: 307:Justus Liebig 302: 299: 294: 288: 284: 280: 276: 269: 266: 260: 256: 253: 252: 248: 246: 244: 240: 236: 228: 226: 224: 216: 214: 212: 204: 200: 196: 195:electrophilic 186: 182: 181: 180: 179: 178: 176: 172: 168: 164: 160: 156: 149: 147: 145: 141: 137: 133: 129: 114: 100: 96: 93: 89: 85: 81: 73: 69: 68:ethyl acetate 65: 61: 57: 52: 46: 40: 30: 19: 1392:Alkyl groups 1356: 1349: 1263:Vinyl halide 1220: 1150:Borinic acid 1145:Boronic acid 1122:Thioxanthate 483: 462:Hydrocarbons 410: 406: 398: 386: 374: 362: 350: 342: 326: 322: 301: 274: 268: 232: 220: 199:nucleophiles 192: 167:ethylbenzene 154: 153: 143: 127: 87: 83: 77: 50: 29:Methyl group 1327:Thiocyanate 1322:Sulfonamide 1287:Perchlorate 1275:Acyl halide 1236:Fluoroethyl 1117:Thionoester 1005:Phosphonium 990:Phosphinate 985:Phosphonous 973:Phosphonate 672:Hydroperoxy 494:Cyclopropyl 175:polystyrene 95:substituent 84:ethyl group 64:bromoethane 1386:Categories 1231:Haloalkane 1102:Thioketone 1057:Persulfide 953:Phosphorus 918:Isocyanate 908:Isonitrile 809:or oxygen 807:hydrogen, 803:not being 784:Orthoester 677:Dioxiranes 655:Enol ether 543:1-Propenyl 292:3527306730 261:References 155:Ethylation 150:Ethylation 18:Ethylation 1364:inorganic 1198:Tellurium 1112:Thioester 1077:Sulfoxide 1062:Disulfide 1050:Sulfonium 1000:Phosphine 978:Phosphite 961:Phosphate 893:Carbamate 868:Hydrazone 801:element, 799:Only one 772:Anhydride 511:Methylene 413: : 229:Etymology 165:to yield 97:with the 1345:See also 1280:Chloride 1206:Tellurol 1160:Selenium 1127:Xanthate 841:Ammonium 823:Nitrogen 805:carbon, 762:Carboxyl 729:Aldehyde 717:Acryloyl 699:carbonyl 603:hydrogen 558:Cumulene 249:See also 163:ethylene 90:) is an 1369:organic 1168:Selenol 1092:Sulfone 1045:Sulfide 943:NONOate 938:Nitroso 928:Nitrite 923:Nitrate 913:Cyanate 903:Nitrile 888:Amidine 883:Imidate 853:Nitrene 848:Hydrazo 836:Enamine 767:Acetoxy 755:carboxy 722:Benzoyl 660:Epoxide 643:Methoxy 633:Alcohol 587:Carbene 521:Methine 211:halides 171:styrene 159:benzene 99:formula 86:(abbr. 60:ethanol 56:radical 1268:Iodide 1188:Selone 1032:Sulfur 741:Ketone 734:Ketene 712:Acetyl 667:Peroxy 638:Alkoxy 628:Acetal 609:oxygen 598:carbon 582:Alkyne 575:Benzyl 570:Phenyl 553:Allene 548:Crotyl 528:Alkene 516:Bridge 504:Pentyl 489:Propyl 479:Methyl 399:methyl 373:methyl 347:p. 376 289:  235:Aether 140:moiety 113:ethane 70:, and 1300:Other 1137:Boron 1107:Thial 1040:Thiol 933:Nitro 898:Imide 878:Amide 863:Oxime 858:Imine 831:Amine 779:Ester 746:Ynone 650:Ether 621:R-O-R 596:Only 538:Allyl 533:Vinyl 499:Butyl 484:Ethyl 474:Alkyl 387:ethyl 375:, … " 361:ethyl 333:and C 161:with 128:Ethyl 92:alkyl 82:, an 1222:Halo 707:Acyl 607:and 565:Aryl 415:381. 287:ISBN 239:hyle 144:eth- 126:). 51:blue 873:Azo 349:: 279:doi 134:'s 102:−CH 78:In 1388:: 605:, 600:, 411:15 397:, 385:, 383:10 371:, 359:, 357:10 325:, 285:. 277:. 245:. 213:. 205:BF 106:CH 88:Et 66:, 62:, 446:e 439:t 432:v 417:) 395:6 393:H 391:2 381:H 379:4 369:6 367:H 365:2 355:H 353:4 339:5 337:H 335:2 331:3 327:9 315:5 313:H 311:2 295:. 281:: 207:4 123:6 121:H 119:2 117:C 115:( 108:3 104:2 74:. 41:. 31:. 20:)

Index

Ethylation
Methyl group
Ethyl (disambiguation)

radical
ethanol
bromoethane
ethyl acetate
ethyl methyl ether
organic chemistry
alkyl
substituent
formula
ethane
International Union of Pure and Applied Chemistry
nomenclature of organic chemistry
moiety
benzene
ethylene
ethylbenzene
styrene
polystyrene

electrophilic
nucleophiles
Triethyloxonium tetrafluoroborate
halides
diastereotopic
Aether
hyle

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