49:
408:
255:
65:
39:
761:
766:
756:
873:
878:
1140:
1394:
on people of breathing high levels are not known, but animal studies with short-term exposures to high levels caused depression and collapse, indicating effects on the brain. Changes in the brain and behavior were also seen in young rats whose male parents had breathed 1,2-dibromoethane, and birth
876:
1766:
774:
736:
48:
1383:
and severe destruction of living tissues. The known empirical LD50 values for 1,2-dibromoethane are 140 mg kg (oral, rat), and 300.0 mg kg (dermal, rabbit). 1,2-Dibromoethane is a known
852:
1340:
1,2-Dibromoethane has wider applications in the preparation of other organic compounds including those carrying modified diazocine rings and vinyl bromide that is a precursor to some
877:
1501:
1476:
1022:
1232:, substantial amounts are produced industrially. It is a dense colorless liquid with a faint, sweet odor, detectable at 10 ppm. It is a widely used and sometimes-controversial
1153:
879:
447:
1520:
Yoffe, David; Frim, Ron; Ukeles, Shmuel D.; Dagani, Michael J.; Barda, Henry J.; Benya, Theodore J.; Sanders, David C. (2013). "Bromine
Compounds".
901:
1292:
in leaded fuels. It reacts with lead residues to generate volatile lead bromides, thereby preventing fouling of the engine with lead deposits.
685:
1537:
1440:
1761:
1803:
1572:
64:
2097:
2102:
2087:
422:
38:
1927:
1704:
717:
1720:
1629:
2062:
844:
1660:
Hamada, Y.; Mukai. S. (1996). "Synthesis of ethano-Tröger's base, configurationally stable substitute of Tröger's base".
1998:
1932:
1395:
defects were observed in the young of animals that were exposed while pregnant. 1,2-Dibromoethane is not known to cause
848:
830:
355:
765:
760:
1309:
386:
887:
1922:
1894:
1424:
1289:
1160:
1046:
1033:
2082:
1257:
306:
262:
1907:
1796:
300:
2092:
2013:
1957:
1937:
250:
1864:
1771:
1184:
661:
212:
2072:
2067:
1119:
788:
755:
748:
571:
1329:
77:
1789:
1421:
Nomenclature of
Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book)
403:
118:
1371:, which are innocuous, exposing a more active portion of the magnesium particle to the substrate.
2077:
1917:
1387:, with pre-1977 exposure levels ranking it as the most carcinogenic substance on the HERP Index.
1114:
1109:
836:
172:
822:
1972:
1952:
1700:
1533:
1436:
1368:
1348:
1099:
1094:
2036:
1854:
1744:
1692:
1669:
1608:
1525:
1428:
1360:
1237:
1188:
1104:
617:
560:
470:
364:
2041:
2023:
1947:
1599:
232:
152:
128:
407:
254:
192:
1967:
1884:
1391:
1341:
1312:(DBCP). Most of these uses have been stopped in the U.S. It continues to be used as a
1131:
1084:
595:
584:
1308:
and on various crops. The applications were initiated after the forced retirement of
2056:
1812:
1673:
642:
549:
539:
243:
1962:
1902:
1879:
1396:
1529:
17:
1636:
840:
328:
2003:
1844:
1834:
1727:
1432:
1008:
988:
937:
913:
814:
1993:
1776:
1472:
1384:
1380:
498:
223:
1696:
1493:
806:
2031:
1988:
1839:
1363:. In the latter process, 1,2-dibromoethane reacts with magnesium, producing
1356:
1352:
1301:
1089:
375:
798:
2008:
1869:
1859:
1849:
1829:
1767:
Congressional
Research Service (CRS) Reports regarding Ethylene Dibromide
1364:
1313:
1249:
1233:
900:
893:
886:
859:
1942:
1874:
1317:
1253:
529:
315:
263:
52:
Skeletal formula of 1,2-dibromoethane with all explicit hydrogens added
1612:
1288:
Historically, 1,2-dibromoethane was used as a component in anti-knock
802:
1321:
203:
1130:
Except where otherwise noted, data are given for materials in their
1687:
Maynard, G. D. (2004). "1,2-Dibromoethane". In
Paquette, L. (ed.).
289:
1225:
1221:
794:
339:
183:
151:
141:
894:
544:
9.4 to 10.2 °C; 48.8 to 50.3 °F; 282.5 to 283.3 K
1815:
1325:
1305:
1229:
1059:
818:
810:
519:
280:
1785:
1597:
1558:
1781:
1498:
Immediately
Dangerous to Life or Health Concentrations (IDLH)
391:
47:
37:
1559:"Safety Data Sheet for CAS-No.:106-93-4 Ethylene dibromide"
554:
129 to 133 °C; 264 to 271 °F; 402 to 406 K
1762:
National
Pollutant Inventory 1,2-Dibromoethane Fact Sheet
1721:"Ranking Possible Cancer Hazards from Rodent Carcinogens"
871:
1148:
1399:
in humans. Swallowing has caused death at 40ml doses.
1502:
National
Institute for Occupational Safety and Health
1477:
National
Institute for Occupational Safety and Health
2022:
1981:
1893:
1822:
1624:
1622:
1573:"Preparation and purification of 1,2-dibromoethane"
1220:. Although trace amounts occur naturally in the
327:
1236:. The combustion of 1,2-dibromoethane produces
875:
127:
1689:Encyclopedia of Reagents for Organic Synthesis
1522:Ullmann's Encyclopedia of Industrial Chemistry
1797:
1745:"Toxic Substances Portal – 1,2-Dibromoethane"
1630:"Toxicological Profile for 1,2-Dibromoethane"
8:
1777:CDC – NIOSH Pocket Guide to Chemical Hazards
1414:
1412:
1804:
1790:
1782:
406:
253:
231:
26:
1515:
1513:
1511:
1351:, 1,2-dibromoethane is used to brominate
363:
1471:NIOSH Pocket Guide to Chemical Hazards.
1379:1,2-Dibromoethane causes changes in the
1408:
452:
427:
402:
305:
1488:
1486:
1466:
1464:
1462:
1460:
1458:
1456:
1454:
1452:
918:104 °C (219 °F; 377 K)
244:
1240:gas that is significantly corrosive.
434:Key: PAAZPARNPHGIKF-UHFFFAOYSA-N
211:
191:
42:Skeletal formula of 1,2-dibromoethane
7:
1553:
1551:
1549:
318:
288:
1248:It is produced by the reaction of
25:
1691:. New York: J. Wiley & Sons.
1224:, where it is probably formed by
1138:
764:
759:
754:
482:
431:InChI=1S/C2H4Br2/c3-1-2-4/h1-2H2
63:
1928:2,4-Dimethyl-6-tert-butylphenol
1134:(at 25 °C , 100 kPa).
488:
1425:The Royal Society of Chemistry
718:Occupational safety and health
476:
1:
1530:10.1002/14356007.a04_405.pub2
1053:Ca TWA 0.045 ppm C 0.13 ppm
1027:(US health exposure limits):
1999:Automatic transmission fluid
1933:Dinonylnaphthylsulfonic acid
1885:Racing fuel (Tetraethyllead)
1674:10.1016/0957-4166(96)00343-6
1040:TWA 20 ppm C 30 ppm 50 ppm
1433:10.1039/9781849733069-FP001
1310:1,2-dibromo-3-chloropropane
1017:400 ppm (guinea pig, 3 hr)
926:or concentration (LD, LC):
33:
2119:
1923:Dimethyl methylphosphonate
1316:for treatment of logs for
2098:IARC Group 2A carcinogens
1258:halogen addition reaction
1128:
1070:
1021:
922:
735:
715:
710:
635:
463:
443:
418:
111:
88:
76:
71:
62:
32:
2103:Sweet-smelling chemicals
2088:Hazardous air pollutants
1908:Butylated hydroxytoluene
1697:10.1002/047084289X.rd039
831:Precautionary statements
2014:Windshield washer fluid
1958:Methyl tert-butyl ether
1938:2,6-Di-tert-butylphenol
1850:Lead Replacement Petrol
706:−1.2419–−1.2387 MJ mol
1865:Compressed natural gas
1300:It has been used as a
1185:organobromine compound
995:1831 ppm (rat, 30 min)
882:
53:
43:
1662:Tetrahedron Asymmetry
1427:. 2014. p. 657.
1324:, and for control of
1120:1,2,3-Tribromopropane
881:
51:
41:
2063:Endocrine disruptors
1494:"Ethylene dibromide"
997:691 ppm (rat, 1 hr)
989:median concentration
864:(fire diamond)
78:Preferred IUPAC name
1244:Preparation and use
1015:200 ppm (rat, 8 hr)
561:Solubility in water
506: g·mol
173:Beilstein Reference
29:
1918:1,2-Dichloroethane
1177:ethylene dibromide
1161:Infobox references
1115:1,3-Dibromopropane
1110:1,2-Dibromopropane
1071:Related compounds
1062:(Immediate danger)
961:(oral, guinea pig)
883:
566:0.4% (20 °C)
307:Ethylene+Dibromide
94:Ethylene dibromide
54:
44:
28:1,2-Dibromoethane
27:
18:Ethylene dibromide
2050:
2049:
1973:Tetranitromethane
1953:Metal deactivator
1913:1,2-Dibromoethane
1613:10.1021/om030621b
1607:(25): 5154–5178.
1539:978-3-527-30385-4
1524:. pp. 1–31.
1442:978-0-85404-182-4
1369:magnesium bromide
1361:Grignard reagents
1349:organic synthesis
1173:1,2-Dibromoethane
1169:Chemical compound
1167:
1166:
1100:1,1-Dibromoethane
1095:Tetrabromomethane
974:
968:
962:
956:
950:
789:Hazard statements
514:Colorless liquid
387:CompTox Dashboard
153:Interactive image
82:1,2-Dibromoethane
58:
57:
16:(Redirected from
2110:
2083:Flame retardants
2037:MTBE controversy
1806:
1799:
1792:
1783:
1749:
1748:
1741:
1735:
1734:
1732:
1726:. Archived from
1725:
1717:
1711:
1710:
1684:
1678:
1677:
1668:(9): 2671–2674.
1657:
1651:
1650:
1648:
1647:
1641:
1635:. Archived from
1634:
1626:
1617:
1616:
1594:
1588:
1587:
1577:
1569:
1563:
1562:
1555:
1544:
1543:
1517:
1506:
1505:
1490:
1481:
1480:
1468:
1447:
1446:
1419:"Front Matter".
1416:
1355:and to activate
1238:hydrogen bromide
1219:
1218:
1217:
1209:
1208:
1200:
1199:
1189:chemical formula
1175:, also known as
1151:
1145:
1142:
1141:
1105:Tetrabromoethane
1009:lowest published
973:(dermal, rabbit)
972:
966:
960:
954:
948:
903:
896:
889:
874:
854:
850:
846:
842:
838:
824:
820:
816:
812:
808:
804:
800:
796:
768:
763:
758:
702:
675:
651:
636:Thermochemistry
618:Refractive index
505:
490:
484:
478:
471:Chemical formula
411:
410:
395:
393:
367:
331:
320:
309:
292:
265:
257:
246:
235:
215:
195:
155:
131:
97:Ethylene bromide
67:
34:
30:
21:
2118:
2117:
2113:
2112:
2111:
2109:
2108:
2107:
2053:
2052:
2051:
2046:
2042:Pay at the pump
2018:
1977:
1948:Ethylenediamine
1889:
1830:Gasoline/petrol
1818:
1810:
1758:
1753:
1752:
1743:
1742:
1738:
1730:
1723:
1719:
1718:
1714:
1707:
1686:
1685:
1681:
1659:
1658:
1654:
1645:
1643:
1639:
1632:
1628:
1627:
1620:
1600:Organometallics
1596:
1595:
1591:
1575:
1571:
1570:
1566:
1557:
1556:
1547:
1540:
1519:
1518:
1509:
1492:
1491:
1484:
1470:
1469:
1450:
1443:
1418:
1417:
1410:
1405:
1377:
1342:fire retardants
1338:
1298:
1283:
1279:
1275:
1271:
1267:
1256:, in a classic
1246:
1216:
1213:
1212:
1211:
1207:
1204:
1203:
1202:
1198:
1195:
1194:
1193:
1191:
1170:
1163:
1158:
1157:
1156: ?)
1147:
1143:
1139:
1135:
1124:
1078:
1077:Related alkanes
1063:
1050:
1037:
1016:
1012:
1006:
996:
992:
986:
977:
955:(oral, chicken)
941:
935:
908:
907:
906:
905:
898:
891:
884:
880:
872:
833:
791:
777:
751:
728:
703:
700:
694:
690:
687:
686:Std enthalpy of
679:223.30 J K mol
676:
673:
666:
663:
652:
645:
628:
626:
608:
606:
597:
563:
503:
493:
487:
481:
473:
459:
456:
451:
450:
439:
436:
435:
432:
426:
425:
414:
396:
389:
370:
350:
334:
321:
295:
275:
238:
218:
198:
175:
158:
145:
134:
121:
107:
106:
103:Di(bromomethyl)
84:
83:
23:
22:
15:
12:
11:
5:
2116:
2114:
2106:
2105:
2100:
2095:
2093:Fuel additives
2090:
2085:
2080:
2075:
2070:
2065:
2055:
2054:
2048:
2047:
2045:
2044:
2039:
2034:
2028:
2026:
2020:
2019:
2017:
2016:
2011:
2006:
2001:
1996:
1991:
1985:
1983:
1979:
1978:
1976:
1975:
1970:
1968:Tetraethyllead
1965:
1960:
1955:
1950:
1945:
1940:
1935:
1930:
1925:
1920:
1915:
1910:
1905:
1899:
1897:
1895:Fuel additives
1891:
1890:
1888:
1887:
1882:
1877:
1872:
1867:
1862:
1857:
1852:
1847:
1842:
1837:
1832:
1826:
1824:
1820:
1819:
1811:
1809:
1808:
1801:
1794:
1786:
1780:
1779:
1774:
1769:
1764:
1757:
1756:External links
1754:
1751:
1750:
1736:
1733:on 2019-06-29.
1712:
1705:
1679:
1652:
1618:
1589:
1586:: 49–51. 2017.
1564:
1545:
1538:
1507:
1482:
1448:
1441:
1407:
1406:
1404:
1401:
1376:
1375:Health effects
1373:
1337:
1334:
1297:
1294:
1286:
1285:
1281:
1277:
1273:
1269:
1265:
1245:
1242:
1214:
1205:
1196:
1168:
1165:
1164:
1159:
1137:
1136:
1132:standard state
1129:
1126:
1125:
1123:
1122:
1117:
1112:
1107:
1102:
1097:
1092:
1087:
1085:Dibromomethane
1081:
1079:
1076:
1073:
1072:
1068:
1067:
1064:
1058:
1055:
1054:
1051:
1045:
1042:
1041:
1038:
1032:
1029:
1028:
1019:
1018:
1013:
1004:
1002:
999:
998:
993:
984:
982:
979:
978:
976:
975:
969:
963:
957:
951:
949:(oral, rabbit)
944:
942:
933:
931:
928:
927:
920:
919:
916:
910:
909:
899:
892:
885:
870:
869:
868:
867:
865:
856:
855:
853:P305+P351+P338
834:
829:
826:
825:
792:
787:
784:
783:
778:
773:
770:
769:
752:
747:
744:
743:
733:
732:
729:
726:
723:
722:
713:
712:
708:
707:
704:
698:
692:
684:
681:
680:
677:
671:
660:
657:
656:
655:134.7 J K mol
653:
641:
638:
637:
633:
632:
629:
624:
616:
613:
612:
611:14 μmol Pa kg
609:
604:
594:
591:
590:
587:
585:Vapor pressure
581:
580:
577:
568:
567:
564:
559:
556:
555:
552:
546:
545:
542:
536:
535:
532:
526:
525:
524:faintly sweet
522:
516:
515:
512:
508:
507:
501:
495:
494:
491:
485:
479:
474:
469:
466:
465:
461:
460:
458:
457:
454:
446:
445:
444:
441:
440:
438:
437:
433:
430:
429:
421:
420:
419:
416:
415:
413:
412:
399:
397:
385:
382:
381:
378:
372:
371:
369:
368:
360:
358:
352:
351:
349:
348:
344:
342:
336:
335:
333:
332:
324:
322:
314:
311:
310:
303:
297:
296:
294:
293:
285:
283:
277:
276:
274:
273:
269:
267:
259:
258:
248:
240:
239:
237:
236:
228:
226:
220:
219:
217:
216:
208:
206:
200:
199:
197:
196:
188:
186:
180:
179:
176:
171:
168:
167:
164:
163:Abbreviations
160:
159:
157:
156:
148:
146:
139:
136:
135:
133:
132:
124:
122:
117:
114:
113:
109:
108:
105:
104:
101:
100:Glycol bromide
98:
95:
91:
90:
86:
85:
81:
80:
74:
73:
69:
68:
60:
59:
56:
55:
45:
24:
14:
13:
10:
9:
6:
4:
3:
2:
2115:
2104:
2101:
2099:
2096:
2094:
2091:
2089:
2086:
2084:
2081:
2079:
2076:
2074:
2071:
2069:
2066:
2064:
2061:
2060:
2058:
2043:
2040:
2038:
2035:
2033:
2030:
2029:
2027:
2025:
2021:
2015:
2012:
2010:
2007:
2005:
2002:
2000:
1997:
1995:
1992:
1990:
1987:
1986:
1984:
1980:
1974:
1971:
1969:
1966:
1964:
1961:
1959:
1956:
1954:
1951:
1949:
1946:
1944:
1941:
1939:
1936:
1934:
1931:
1929:
1926:
1924:
1921:
1919:
1916:
1914:
1911:
1909:
1906:
1904:
1901:
1900:
1898:
1896:
1892:
1886:
1883:
1881:
1878:
1876:
1873:
1871:
1868:
1866:
1863:
1861:
1858:
1856:
1853:
1851:
1848:
1846:
1843:
1841:
1838:
1836:
1833:
1831:
1828:
1827:
1825:
1821:
1817:
1814:
1807:
1802:
1800:
1795:
1793:
1788:
1787:
1784:
1778:
1775:
1773:
1772:ATSDR ToxFAQs
1770:
1768:
1765:
1763:
1760:
1759:
1755:
1746:
1740:
1737:
1729:
1722:
1716:
1713:
1708:
1702:
1698:
1694:
1690:
1683:
1680:
1675:
1671:
1667:
1663:
1656:
1653:
1642:on 2009-11-22
1638:
1631:
1625:
1623:
1619:
1614:
1610:
1606:
1602:
1601:
1593:
1590:
1585:
1581:
1574:
1568:
1565:
1560:
1554:
1552:
1550:
1546:
1541:
1535:
1531:
1527:
1523:
1516:
1514:
1512:
1508:
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1430:
1426:
1423:. Cambridge:
1422:
1415:
1413:
1409:
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1400:
1398:
1397:birth defects
1393:
1388:
1386:
1382:
1374:
1372:
1370:
1366:
1362:
1358:
1354:
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1086:
1083:
1082:
1080:
1075:
1074:
1069:
1065:
1061:
1057:
1056:
1052:
1049:(Recommended)
1048:
1044:
1043:
1039:
1036:(Permissible)
1035:
1031:
1030:
1026:
1025:
1020:
1014:
1010:
1001:
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981:
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967:(oral, quail)
964:
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643:Heat capacity
640:
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623:
619:
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550:Boiling point
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540:Melting point
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404:DTXSID3020415
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245:ECHA InfoCard
242:
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210:
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19:
2073:Bromoalkanes
2068:Insecticides
1963:Nitromethane
1912:
1903:Butyl rubber
1880:Butanol fuel
1739:
1728:the original
1715:
1688:
1682:
1665:
1661:
1655:
1644:. Retrieved
1637:the original
1604:
1598:
1592:
1583:
1579:
1567:
1521:
1497:
1420:
1389:
1378:
1359:for certain
1346:
1339:
1299:
1287:
1247:
1180:
1176:
1172:
1171:
1023:
971:300.0 mg kg
965:130.0 mg kg
959:110.0 mg kg
923:
860:
780:
737:
727:Main hazards
716:
695:
668:
647:
621:
601:
573:
340:RTECS number
213:ChEMBL452370
112:Identifiers
89:Other names
2004:Brake fluid
1855:Electricity
1845:Biogasoline
953:79.0 mg kg
947:55.0 mg kg
938:median dose
924:Lethal dose
914:Flash point
775:Signal word
731:carcinogen
721:(OHS/OSH):
596:Henry's law
511:Appearance
464:Properties
251:100.003.132
193:CHEBI:28534
2057:Categories
1994:Antifreeze
1823:Fuel types
1706:0471936235
1646:2009-11-22
1403:References
1385:carcinogen
1381:metabolism
1353:carbanions
749:Pictograms
688:combustion
534:2.18 g mL
499:Molar mass
365:1N41638RNO
224:ChemSpider
140:3D model (
119:CAS Number
2078:Fumigants
2032:Fuel card
1989:Motor oil
1840:Biodiesel
1357:magnesium
1302:pesticide
1296:Pesticide
1290:additives
1252:gas with
1187:with the
1183:), is an
1090:Bromoform
849:P301+P310
740:labelling
662:Std molar
589:1.56 kPa
376:UN number
347:KH9275000
272:203-444-5
264:EC Number
2009:Gear oil
1870:Hydrogen
1860:Kerosene
1504:(NIOSH).
1479:(NIOSH).
1365:ethylene
1330:beehives
1318:termites
1314:fumigant
1250:ethylene
1234:fumigant
861:NFPA 704
711:Hazards
598:constant
129:106-93-4
1943:Ecalene
1875:Ethanol
1580:Synlett
1473:"#0270"
1392:effects
1336:Reagent
1322:beetles
1254:bromine
1154:what is
1152: (
664:entropy
600: (
530:Density
504:187.862
316:PubChem
178:605266
2024:Retail
1982:Fluids
1835:Diesel
1703:
1536:
1439:
1276:→ BrCH
1149:verify
1146:
781:Danger
631:1.539
579:2.024
455:BrCCBr
448:SMILES
290:C11088
204:ChEMBL
72:Names
1816:fuels
1813:Motor
1731:(PDF)
1724:(PDF)
1640:(PDF)
1633:(PDF)
1576:(PDF)
1326:moths
1226:algae
1222:ocean
1024:NIOSH
423:InChI
380:1605
184:ChEBI
142:JSmol
1701:ISBN
1534:ISBN
1437:ISBN
1390:The
1367:and
1320:and
1306:soil
1272:+ Br
1230:kelp
1228:and
1066:Ca
1060:IDLH
845:P280
841:P273
837:P261
823:H411
819:H350
815:H335
811:H331
807:H319
803:H315
799:H311
795:H301
572:log
520:Odor
356:UNII
329:7839
301:MeSH
281:KEGG
233:7551
166:EDB
1693:doi
1670:doi
1609:doi
1526:doi
1429:doi
1347:In
1328:in
1304:in
1280:–CH
1268:=CH
1181:EDB
1047:REL
1034:PEL
738:GHS
699:298
672:298
392:EPA
319:CID
2059::
1699:.
1664:.
1621:^
1605:22
1603:.
1584:28
1582:.
1578:.
1548:^
1532:.
1510:^
1500:.
1496:.
1485:^
1475:.
1451:^
1435:.
1411:^
1344:.
1332:.
1284:Br
1264:CH
1260::
1210:Br
1005:Lo
1003:LC
985:50
983:LC
934:50
932:LD
851:,
847:,
843:,
839:,
821:,
817:,
813:,
809:,
805:,
801:,
797:,
742::
691:(Δ
489:Br
1805:e
1798:t
1791:v
1747:.
1709:.
1695::
1676:.
1672::
1666:7
1649:.
1615:.
1611::
1561:.
1542:.
1528::
1445:.
1431::
1282:2
1278:2
1274:2
1270:2
1266:2
1215:2
1206:4
1201:H
1197:2
1192:C
1179:(
1144:N
1011:)
1007:(
991:)
987:(
940:)
936:(
902:0
895:0
888:3
701:)
696:H
693:c
674:)
669:S
667:(
650:)
648:C
646:(
627:)
625:D
622:n
620:(
607:)
605:H
602:k
574:P
492:2
486:4
483:H
480:2
477:C
394:)
390:(
144:)
20:)
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