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402:, ethylmagnesium bromide may be used as a strong base to deprotonate various substrates such as
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In this application, ethylmagnesium bromide has been supplanted by the wide availability of
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InChI=1/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1/rC2H5BrMg/c1-2-4-3/h2H2,1H3
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Ethylmagnesium bromide is commercially available, usually as a solution in
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Except where otherwise noted, data are given for materials in their
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MgBr. It is widely used in the laboratory synthesis of
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212:InChI=1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
477:"3-Alkyl-1-alkynes Synthesis: 3-Ethyle-1-hexyne"
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437:. It may be prepared in the normal manner of
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475:Quillinan, A. J.; Scheinmann, F. (1978).
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215:Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
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508:Moyer, W. W.; Marvel, C. S. (1931).
225:Key: TWTWFMUQSOFTRN-QJSJVVHYAJ
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325:(at 25 °C , 100 kPa).
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410:RC≡CH + EtMgBr → RC≡CMgBr +
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529:, vol. 2, p. 602
496:, vol. 6, p. 595
548:Organomagnesium compounds
390:Apart from acting as the
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17:Ethylmagnesium bromide
419:organolithium reagents
364:Ethylmagnesium bromide
400:nucleophilic addition
441:— by reacting
392:synthetic equivalent
510:"Triethyl Carbinol"
297: g·mol
18:
457:EtBr + Mg → EtMgBr
394:of an ethyl anion
352:Infobox references
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527:Collected Volumes
515:Organic Syntheses
494:Collected Volumes
482:Organic Syntheses
439:Grignard reagents
380:organic compounds
360:Chemical compound
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308:Safety data sheet
168:CompTox Dashboard
72:Interactive image
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368:Grignard reagent
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262:Chemical formula
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553:Ethyl compounds
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435:tetrahydrofuran
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370:with formula C
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323:standard state
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185:DTXSID80275976
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451:diethyl ether
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431:diethyl ether
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104:ECHA InfoCard
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31:Identifiers
443:bromoethane
425:Preparation
314:Oxford MSDS
255:Properties
110:100.011.935
542:Categories
462:References
290:Molar mass
156:5564378HK3
83:ChemSpider
59:3D model (
38:CAS Number
447:magnesium
386:Reactions
302:Hazards
92:10254342
48:925-90-6
404:alkynes
396:synthon
345:what is
343: (
295:133.271
123:PubChem
340:verify
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310:(SDS)
239:SMILES
136:101914
445:with
366:is a
204:InChI
61:JSmol
522:: 98
398:for
246:BrCC
147:UNII
489:: 1
449:in
433:or
412:EtH
173:EPA
126:CID
544::
524:;
520:11
518:.
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491:;
487:58
485:.
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421:.
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382:.
283:Mg
280:Br
531:.
498:.
376:5
374:H
372:2
335:Y
277:5
274:H
271:2
268:C
175:)
171:(
63:)
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