1040:
1294:
1315:
1231:
1138:
994:
1372:
1333:
563:
249:
500:
301:
177:
122:
733:
465:
667:
356:
1269:
1214:
1183:
1156:
1058:
1012:
969:
918:
887:
856:
1417:
1445:
1438:
1431:
1424:
1121:
808:
1452:
41:
are included within the GHS: one for the labelling of containers and for workplace hazard warnings, and a second for use during the transport of dangerous goods. Either one or the other is chosen, depending on the target audience, but the two are not used together for the same hazard. The two sets of
1170:– Solids which, under conditions encountered in transport, are readily combustible or may cause or contribute to fire through friction; self-reactive substances which are liable to undergo a strongly exothermic reaction; solid desensitized explosives which may explode if not diluted sufficiently
1578:"Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006"
42:
pictograms use the same symbols for the same hazards, although certain symbols are not required for transport pictograms. Transport pictograms come in wider variety of colors and may contain additional information such as a subcategory number.
34:
1488:
91:
1195:– Substances which are liable to spontaneous heating under normal conditions encountered in transport, or to heating up in contact with air, and being then liable to catch fire
79:
The GHS chemical hazard pictograms are intended to provide the basis for or to replace national systems of hazard pictograms. It has still to be implemented by the
1281:– Substances which, while in themselves not necessarily combustible, may, generally by yielding oxygen, cause, or contribute to, the combustion of other material
1582:
836:: Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard
1409:
The following pictograms are included in the UN Model
Regulations but have not been incorporated into the GHS because of the nature of the hazards.
1226:– Substances which, by interaction with water, are liable to become spontaneously flammable or to give off flammable gases in dangerous quantities
95:
1031:
are oxidizing – gases which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does; or
1602:
1656:
72:, indicating how the product should be handled to minimize risks to the user (as well as to other people and the general environment)
1623:
684:
422:
69:
1577:
1391:
exhibit a corrosion rate of more than 6.25 mm per year on either steel or aluminium surfaces at 55 °C
1039:
1613:
1314:
1293:
1133:– Liquids which have a flash point of less than 60 °C and which are capable of sustaining combustion
283:
988:
have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit.
45:
Hazard pictograms are one of the key elements for the labelling of containers under the GHS, along with:
1564:
63:
1230:
1137:
993:
1592:
1306:– Organic substances which contain the bivalent –O–O– structure and may be considered derivatives of
868:– Substances and articles which are classified as explosives but which present no significant hazard
1661:
1199:
645:
479:
371:
146:
1388:
cause full thickness destruction of intact skin tissue on exposure time of less than 4 hours; or
1640:
1619:
1598:
1307:
275:
217:
Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
1371:
1332:
1086:
690:
428:
380:
159:
151:
1508:
562:
332:
270:
1028:
are asphyxiant – gases which dilute or replace the oxygen normally in the atmosphere; or
830:: Substances and articles which have a projection hazard but not a mass explosion hazard
1498:
311:
248:
84:
80:
1650:
1493:
1357:
391:
384:
340:
336:
326:
316:
163:
1615:
UN Recommendations on the
Transport of Dangerous Goods. Manual of Tests and Criteria
499:
300:
176:
121:
1570:. 2021. Annex 3: Codification of Statements and Pictograms (pp 268–385).
732:
483:
464:
225:
666:
355:
1310:, where one or both of the hydrogen atoms have been replaced by organic radicals
1074:
are known to be so toxic or corrosive to humans as to pose a hazard to health; or
376:
287:
321:
17:
1168:
Flammable solids, self-reactive substances and solid desensitized explosives
985:
are ignitable when in a mixture of 13 percent or less by volume with air; or
576:
388:
38:
591:
Specific target organ toxicity following repeated exposure, categories 1, 2
547:
the "health hazard" pictogram is used to indicate respiratory sensitization
1594:
UN Recommendations on the
Transport of Dangerous Goods. Model Regulations
1565:"Globally Harmonized System of Classification and Labelling of Chemicals"
1513:
598:
588:
Specific target organ toxicity following single exposure, categories 1, 2
234:
843:: The asterisks are replaced by the class number and compatibility code
1503:
1077:
are presumed to be toxic or corrosive to humans because they have an LC
279:
230:
35:
Globally
Harmonized System of Classification and Labelling of Chemicals
1618:(Fourth revised ed.), New York and Geneva: United Nations, 2002,
1489:
Globally
Harmonized System of Classification and Labeling of Chemicals
90:
The GHS transport pictograms are the same as those recommended in the
75:
the identity of the supplier (who might be a manufacturer or importer)
522:
Specific target organ toxicity following single exposure, category 3
1349:
value ≤ 300 mg/kg (oral) or ≤ 1000 mg/kg (dermal) or an LC
66:, indicating the nature and degree of the risks posed by the product
1416:
1268:
1213:
1182:
1155:
1057:
1011:
968:
917:
886:
855:
98:(49 U.S.C. 5101–5128) and D.O.T. regulations at 49 C.F.R. 100–185.
1444:
1437:
1430:
1423:
981:– Gases which at 20 °C and a standard pressure of 101.3 kPa:
1597:(Fifteenth ed.), New York and Geneva: United Nations, 2007,
899:– Very insensitive substances which have a mass explosion hazard
1451:
1120:
807:
155:
94:, widely implemented in national regulations such as the U.S.
475:
Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
824:: Substances and articles which have a mass explosion hazard
1224:
Substances which in contact with water emit flammable gases
769:
Chronic hazards to the aquatic environment, categories 3, 4
746:
Chronic hazards to the aquatic environment, categories 1, 2
199:
Self-reactive substances and mixtures, types B, C, D, E, F
766:
Acute hazards to the aquatic environment, categories 2, 3
1643:
from the United
Nations Economic Commission for Europe
1153:
92:
UN Recommendations on the
Transport of Dangerous Goods
936:: The asterisk is replaced by the compatibility code
905:: The asterisk is replaced by the compatibility code
874:: The asterisk is replaced by the compatibility code
620:
Acute toxicity (oral, dermal, inhalation), category 5
510:
Acute toxicity (oral, dermal, inhalation), category 4
214:
Self-heating substances and mixtures, categories 1, 2
743:
Acute hazards to the aquatic environment, category 1
683:
Self-reactive substances and mixtures, type G (see
421:
Self-reactive substances and mixtures, type G (see
626:
Reproductive toxicity – effects on or via lactation
135:Explosives, divisions 1.1, 1.2, 1.3, 1.4, 1.5, 1.6
1353:value ≤ 4000 ml/m (inhalation of dusts or mists)
138:Self-reactive substances and mixtures, types A, B
1476:Miscellaneous dangerous substances and articles
556:GHS07: Health Hazard/Hazardous to Ozone Layer
96:Federal Hazardous Materials Transportation Act
1101:Classes 3 and 4: Flammable liquids and solids
8:
1081:value equal to or less than 5000 ml/m (ppm).
1193:Substances liable to spontaneous combustion
585:Reproductive toxicity, categories 1A, 1B, 2
1369:
1330:
1291:
1266:
1211:
1180:
1118:
1055:
1009:
966:
915:
884:
853:
805:
757:
730:
663:
611:
560:
497:
462:
406:
353:
298:
246:
174:
119:
1630:("UN Manual of Tests and Criteria Rev.4")
538:with the "skull and crossbones" pictogram
1472:
1411:
1252:
1104:
952:
791:
716:
649:
448:
193:Flammable liquids, categories 1, 2, 3, 4
105:
1550:Part 1, section 1.4.10.5.3.1, GHS Rev.2
1525:
1376:
1337:
1298:
1273:
1218:
1187:
1160:
1125:
1062:
1034:do not come under the other divisions.
1016:
973:
922:
891:
860:
812:
760:
737:
671:
614:
567:
544:the "corrosion" pictogram also appears
504:
469:
409:
360:
305:
253:
220:Organic peroxides, types B, C, D, E, F
181:
126:
1541:Part 1, section 1.4.10.5.2, GHS Rev.2
1532:Part 1, section 1.4.10.5.1, GHS Rev.2
1356:e.g. nearly everything that contains
696:Skin corrosion, categories 1A, 1B, 1C
640:Physical and health hazard pictograms
582:Carcinogenicity, categories 1A, 1B, 2
573:Respiratory sensitization, category 1
262:Oxidizing liquids, categories 1, 2, 3
27:Standard set of hazard warning images
7:
753:GHS09: Hazardous to the Environment
265:Oxidizing solids, categories 1, 2, 3
190:Flammable aerosols, categories 1, 2
594:Aspiration hazard, categories 1, 2
579:mutagenicity, categories 1A, 1B, 2
25:
196:Flammable solids, categories 1, 2
49:an identification of the product;
1450:
1443:
1436:
1429:
1422:
1415:
1370:
1331:
1313:
1292:
1267:
1229:
1212:
1181:
1154:
1136:
1119:
1056:
1038:
1010:
992:
967:
916:
885:
854:
806:
731:
713:Environmental hazards pictograms
665:
561:
513:Skin irritation, categories 2, 3
498:
463:
354:
299:
247:
175:
120:
1609:("UN Model Regulations Rev.15")
685:HAZMAT Class 4 Flammable solids
541:for skin or eye irritation if:
423:HAZMAT Class 4 Flammable solids
366:Corrosive to metals, category 1
211:Combustible liquids, category 3
33:form part of the international
699:Serious eye damage, category 1
677:Explosives, divisions 1.5, 1.6
519:Skin sensitization, category 1
415:Explosives, divisions 1.5, 1.6
208:Combustible solids, category 3
202:Pyrophoric liquids, category 1
1:
1022:Non-flammable non-toxic gases
607:GHS08: Serious Health hazard
486:rating at health hazard is 4)
205:Pyrophoric solids, category 1
141:Organic peroxides, types A, B
1475:
1469:
1405:Non-GHS transport pictograms
775:
632:
525:Respiratory tract irritation
437:
322:Refrigerated liquefied gases
1249:Other GHS transport classes
680:Flammable gases, category 2
623:Eye irritation, category 2B
516:Eye irritation, category 2A
418:Flammable gases, category 2
259:Oxidizing gases, category 1
237:, generally most solvents.
187:Flammable gases, category 1
102:Physical hazards pictograms
1678:
1657:Globally Harmonized System
1586:(L353): 1–1355, 2008-12-31
1449:
1442:
1435:
1428:
1421:
1414:
643:
369:
268:
223:
144:
1461:
1379:
1340:
1301:
1276:
1221:
1190:
1165:
1128:
1065:
1019:
976:
925:
894:
863:
815:
763:
740:
674:
617:
570:
507:
472:
445:Health hazards pictograms
412:
363:
308:
256:
184:
129:
70:precautionary statements
1345:– Substances with an LD
52:a signal word – either
1628:, ST/SG/AC.10/11/Rev.4
1607:, ST/SG/AC.10/1/Rev.15
1588:(the "CLP Regulation")
1470:Infectious substances
930:– No hazard statement
776:no pictogram required
633:no pictogram required
438:no pictogram required
349:GHS04: Compressed Gas
284:potassium permanganate
1641:GHS pictogram gallery
1473:Radioactive material
644:Further information:
370:Further information:
269:Further information:
224:Further information:
145:Further information:
1384:– Substances which:
1382:Corrosive substances
1279:Oxidizing substances
783:Transport pictograms
375:Strong acids/bases (
1200:manganese heptoxide
788:Class 1: Explosives
646:Corrosive substance
480:manganese heptoxide
372:Corrosive substance
132:Unstable explosives
37:(GHS). Two sets of
849:Divisions 1.1–1.3
147:Explosive material
1604:978-92-1-139120-6
1480:
1479:
1402:
1401:
1320:
1308:hydrogen peroxide
1304:Organic peroxides
1246:
1245:
1236:
1143:
1131:Flammable liquids
1098:
1097:
1045:
999:
946:
945:
780:
779:
710:
709:
706:GHS05: Corrosive
691:Organic peroxides
637:
636:
442:
441:
429:Organic peroxides
402:GHS05: Corrosive
294:GHS03: Oxidizing
276:hydrogen peroxide
242:GHS02: Flammable
170:GHS01: Explosive
64:hazard statements
60:– where necessary
31:Hazard pictograms
16:(Redirected from
1669:
1629:
1608:
1587:
1571:
1569:
1551:
1548:
1542:
1539:
1533:
1530:
1454:
1447:
1440:
1433:
1426:
1419:
1412:
1374:
1343:Toxic substances
1335:
1319:Alternative sign
1318:
1317:
1296:
1271:
1253:
1235:Alternative sign
1234:
1233:
1216:
1185:
1158:
1142:Alternative sign
1141:
1140:
1123:
1105:
1087:hydrogen cyanide
1060:
1044:Alternative sign
1043:
1042:
1014:
998:Alternative sign
997:
996:
971:
953:
920:
889:
858:
810:
792:
735:
717:
669:
650:
565:
528:Narcotic effects
502:
467:
449:
381:sodium hydroxide
358:
312:Compressed gases
303:
251:
179:
160:chromyl chloride
152:azidoazide azide
124:
106:
21:
1677:
1676:
1672:
1671:
1670:
1668:
1667:
1666:
1647:
1646:
1637:
1626:
1612:
1605:
1591:
1576:
1567:
1563:
1560:
1555:
1554:
1549:
1545:
1540:
1536:
1531:
1527:
1522:
1485:
1407:
1352:
1348:
1251:
1103:
1080:
1070:– Gases which:
1024:– Gases which:
979:Flammable gases
951:
790:
785:
715:
648:
642:
447:
374:
333:liquid nitrogen
327:Dissolved gases
317:Liquefied gases
273:
271:Oxidizing agent
228:
149:
104:
28:
23:
22:
15:
12:
11:
5:
1675:
1673:
1665:
1664:
1659:
1649:
1648:
1645:
1644:
1636:
1635:External links
1633:
1632:
1631:
1624:
1610:
1603:
1589:
1573:
1572:
1559:
1556:
1553:
1552:
1543:
1534:
1524:
1523:
1521:
1518:
1517:
1516:
1511:
1506:
1501:
1499:HMIS Color Bar
1496:
1491:
1484:
1481:
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1474:
1471:
1467:
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1463:
1460:
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1395:
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1362:
1361:
1358:cyanide groups
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1327:
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1322:
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1015:
1007:
1006:
1002:
1001:
990:
989:
986:
975:
972:
964:
963:
960:
957:
950:
949:Class 2: Gases
947:
944:
943:
939:
938:
924:
921:
913:
912:
908:
907:
893:
890:
882:
881:
877:
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862:
859:
851:
850:
846:
845:
838:
837:
831:
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819:
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724:
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673:
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267:
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197:
194:
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188:
183:
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172:
171:
167:
166:
143:
142:
139:
136:
133:
128:
125:
117:
116:
113:
110:
103:
100:
85:CLP regulation
81:European Union
77:
76:
73:
67:
61:
50:
26:
24:
18:GHS pictograms
14:
13:
10:
9:
6:
4:
3:
2:
1674:
1663:
1660:
1658:
1655:
1654:
1652:
1642:
1639:
1638:
1634:
1627:
1625:92-1-139087-7
1621:
1617:
1616:
1611:
1606:
1600:
1596:
1595:
1590:
1585:
1584:
1579:
1575:
1574:
1566:
1562:
1561:
1557:
1547:
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1538:
1535:
1529:
1526:
1519:
1515:
1512:
1510:
1507:
1505:
1502:
1500:
1497:
1495:
1494:Hazard symbol
1492:
1490:
1487:
1486:
1482:
1468:
1464:
1458:
1457:
1453:
1446:
1439:
1432:
1425:
1418:
1413:
1410:
1404:
1397:
1396:
1390:
1387:
1386:
1385:
1383:
1373:
1368:
1365:Division 6.1
1364:
1363:
1360:
1359:
1354:
1344:
1334:
1329:
1326:Division 5.2
1325:
1324:
1321:
1316:
1311:
1309:
1305:
1295:
1290:
1287:Division 5.1
1286:
1285:
1282:
1280:
1270:
1265:
1261:
1258:
1255:
1254:
1248:
1242:Division 4.3
1241:
1240:
1237:
1232:
1227:
1225:
1215:
1210:
1207:Division 4.2
1206:
1205:
1202:
1201:
1196:
1194:
1184:
1179:
1176:Division 4.1
1175:
1174:
1171:
1169:
1164:
1157:
1152:
1148:
1147:
1144:
1139:
1134:
1132:
1122:
1117:
1113:
1110:
1107:
1106:
1100:
1094:Division 2.3
1093:
1092:
1089:
1088:
1076:
1073:
1072:
1071:
1069:
1059:
1054:
1051:Division 2.2
1050:
1049:
1046:
1041:
1033:
1030:
1027:
1026:
1025:
1023:
1013:
1008:
1005:Division 2.1
1004:
1003:
1000:
995:
987:
984:
983:
982:
980:
970:
965:
961:
958:
955:
954:
948:
942:Division 1.6
941:
940:
937:
935:
931:
929:
919:
914:
911:Division 1.5
910:
909:
906:
904:
900:
898:
888:
883:
880:Division 1.4
879:
878:
875:
873:
869:
867:
857:
852:
848:
847:
844:
842:
835:
832:
829:
826:
823:
820:
817:
816:
809:
804:
800:
797:
794:
793:
787:
782:
774:
768:
765:
764:
756:
752:
751:
745:
742:
741:
734:
729:
725:
722:
719:
718:
712:
705:
704:
698:
695:
692:
689:
686:
682:
679:
676:
675:
668:
662:
658:
655:
652:
651:
647:
639:
631:
625:
622:
619:
618:
610:
606:
605:
600:
596:
593:
590:
587:
584:
581:
578:
575:
572:
571:
564:
559:
555:
554:
546:
543:
542:
540:
537:
536:
535:
527:
524:
523:
521:
518:
515:
512:
509:
508:
501:
496:
493:GHS06: Toxic
492:
491:
485:
481:
477:
474:
473:
466:
461:
457:
454:
451:
450:
444:
436:
430:
427:
424:
420:
417:
414:
413:
405:
401:
400:
397:be corrosive
396:
393:
392:zinc chloride
390:
386:
385:calcium oxide
382:
378:
373:
365:
364:
357:
352:
348:
347:
342:
341:liquid helium
338:
337:liquid oxygen
334:
330:
328:
325:
323:
320:
318:
315:
313:
310:
309:
302:
297:
293:
292:
289:
285:
281:
277:
272:
264:
261:
258:
257:
250:
245:
241:
240:
236:
232:
227:
219:
216:
213:
210:
207:
204:
201:
198:
195:
192:
189:
186:
185:
178:
173:
169:
168:
165:
164:nitroglycerin
161:
157:
153:
148:
140:
137:
134:
131:
130:
123:
118:
114:
111:
108:
107:
101:
99:
97:
93:
88:
86:
82:
74:
71:
68:
65:
62:
59:
55:
51:
48:
47:
46:
43:
40:
36:
32:
19:
1614:
1593:
1581:
1546:
1537:
1528:
1408:
1381:
1380:
1355:
1342:
1341:
1312:
1303:
1302:
1278:
1277:
1228:
1223:
1222:
1197:
1192:
1191:
1167:
1166:
1135:
1130:
1129:
1084:
1067:
1066:
1037:
1021:
1020:
991:
978:
977:
933:
932:
927:
926:
902:
901:
896:
895:
871:
870:
865:
864:
840:
839:
834:Division 1.3
833:
828:Division 1.2
827:
822:Division 1.1
821:
533:
484:fire diamond
394:
226:Flammability
89:
78:
57:
53:
44:
30:
29:
1068:Toxic gases
377:nitric acid
288:nitric acid
87:) in 2009.
1662:Pictograms
1651:Categories
1558:References
1459:Class 6.2
1256:Pictogram
1108:Pictogram
956:Pictogram
928:Explosives
897:Explosives
866:Explosives
818:Explosives
795:Pictogram
720:Pictogram
653:Pictogram
452:Pictogram
109:Pictogram
39:pictograms
577:Germ cell
534:Not used
389:anhydrous
1514:NFPA 704
1483:See also
1465:Class 9
1462:Class 7
1398:Class 8
1149:Class 3
693:, type G
599:chromium
431:, type G
280:halogens
235:methanol
1504:Hazchem
1377:
1338:
1299:
1274:
1259:
1219:
1188:
1161:
1126:
1111:
1063:
1017:
974:
959:
923:
892:
861:
813:
798:
761:
758:
738:
723:
672:
664:
656:
615:
612:
568:
505:
470:
455:
410:
407:
361:
306:
278:, most
254:
231:acetone
182:
127:
112:
58:Warning
1622:
1601:
1509:Hazmat
1262:Usage
1114:Usage
962:Usage
801:Usage
726:Usage
659:Usage
458:Usage
115:Usage
54:Danger
1568:(pdf)
1520:Notes
1198:e.g.
1085:e.g.
597:e.g.
478:e.g.
331:e.g.
274:e.g.
229:e.g.
150:e.g.
1620:ISBN
1599:ISBN
1583:OJCE
934:Note
903:Note
872:Note
841:Note
395:can
383:),
156:TNT
56:or
1653::
1580:,
1351:50
1347:50
1079:50
387:,
379:,
339:,
335:,
286:,
282:,
233:,
162:,
158:,
154:,
687:)
482:(
425:)
83:(
20:)
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