80:
22:
71:
158:
414:, being bound to six oxygen ligands, including a triply bridging oxide at the center of the equilateral triangle. The compound was an early example of a molecular complex of iron that features an oxide ligand. The cation has idealized D
437:. Many different salts are known by exchanging the anion, e.g. Cl. Reduction of the cation affords the neutral mixed-valence derivative that contains one ferrous and two ferric centers. Mixed metal species are known such as .
760:
Blake, Antony B.; Yavari, Ahmad; Hatfield, William E.; Sethulekshmi, C. N. (1985). "Magnetic and spectroscopic properties of some heterotrinuclear basic acetates of chromium(III), iron(III), and divalent metal ions".
445:
Chromium(III), ruthenium(III), vanadium(III), manganese(III) and rhodium(III) form analogous compounds. Iron(III) acetate (lacking the oxo ligand) has been claimed as a red coloured compound from the reaction of
407:
Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free.
150:
262:
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524:
861:
638:
79:
43:
1269:
793:
537:
237:
609:
395:). Commonly the salt is known as "basic iron acetate". The formation of the red-brown complex was once used as a test for
411:
368:
1768:
214:
1585:
462:
Materials prepared by heating iron, acetic acid, and air, loosely described as basic iron acetates, are used as
700:
Figgis, B. N.; Robertson, G. B. (13 February 1965). "Crystal-Molecular
Structure and Magnetic Properties of Cr
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92:
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429:
The terminal aqua ligands on the trimetallic framework can be substituted with other ligands, such as
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788:, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter,
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Early work showed that the cation is trinuclear. The Fe centres are equivalent, each being
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Paul, Ram C.; Narula, Ramesh C.; Vasisht, Sham K. (December 1978). "Iron(III) acetates".
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203:
275:
coordination complex: O1(C)O6(23)()(O(C)O4)O(C)O24()(O(C)O5)O(C)O135()OC(C)O6
473:
Iron acetate is often brushed upon untreated wood to give it an aged appearance.
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347:
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169:
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70:
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Holleman, Arnold
Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.),
670:
583:
J., Burgess; M. V., Twigg (2005). R. Bruce, King; J., Wiley (eds.).
361:
Except where otherwise noted, data are given for materials in their
750:
This paper describes the isostructure chromium and iron compounds.
157:
149:
139:
654:
H. Lux (1963). "Basic Iron(III) Acetate". In Georg Brauer (ed.).
104:
basic iron(III) acetate , iron(III) oxyacetate, iron(III) Acetate
463:
843:
15:
671:"Über Salze einer Hexaacetato(formiato)-trichrombase. II"
614:. London ; New York: Longmans, Green. Archived from
246:
InChI=1/3C2H4O2.Fe/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
763:
Journal of the
Chemical Society, Dalton Transactions
202:
125:
35:Is iron (III) acetate actually soluble or not?.
675:Berichte der Deutschen Chemischen Gesellschaft
855:
8:
669:Weinland, R.; Dinkelacker, P. (July 1909).
656:Handbook of Preparative Inorganic Chemistry
31:needs attention from an expert in Chemicals
862:
848:
840:
177:
62:
222:
514:
267:
242:
892:
578:
576:
574:
46:may be able to help recruit an expert.
1558:
611:The Analysis of Steel-Works Materials
525:CRC Handbook of Chemistry and Physics
7:
882:
608:H., Brearley; F., Ibbotson (1902).
585:Encyclopedia of inorganic chemistry
249:Key: PVFSDGKDKFSOTB-DFZHHIFOAZ
193:
14:
587:(2nd ed.). New York: Wiley.
528:(87th ed.). Boca Raton, FL:
870:Acetyl halides and salts of the
78:
69:
20:
365:(at 25 °C , 100 kPa).
1:
522:Lide, David R., ed. (2006).
633:. Read Books. p. 474.
383:is the acetate salt of the
156:coordination complex:
33:. The specific problem is:
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810:Transition Metal Chemistry
894:
879:
359:
322:650.9 g/mol
283:
258:
233:
109:
101:
91:
86:
77:
68:
687:10.1002/cber.19090420318
629:W., Simon (March 2007).
403:Structure and synthesis
498:Manganese(III) acetate
503:Chromium(III) acetate
270:CC(=O).CC(=O).CC(=O).
44:WikiProject Chemicals
771:10.1039/DT9850002509
385:coordination complex
330:brownish-red powder
1769:Iron(III) compounds
786:Inorganic Chemistry
730:1965Natur.205..694F
631:Manual of Chemistry
554:"Iron(III) Acetate"
493:Rhodium(II) acetate
337:Solubility in water
65:
822:10.1007/BF01393501
488:Cobalt(II) acetate
452:iron(III) chloride
369:Infobox references
64:Iron(III) acetate
63:
1749:
1748:
1743:
1742:
765:(12): 2509–2520.
724:(4972): 694–695.
618:on 18 April 2015.
594:978-0-470-86078-6
532:. pp. 4–63.
441:Related compounds
435:dimethylformamide
377:Chemical compound
375:
374:
159:Interactive image
151:Interactive image
96:iron(III) acetate
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681:(3): 2997–3018.
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483:Iron(II) acetate
291:Chemical formula
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658:. p. 1508.
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381:Ferric acetate
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363:standard state
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795:0-12-352651-5
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539:0-8493-0487-3
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29:This article
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816:(1): 35–38.
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721:
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664:
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616:the original
610:
603:
584:
561:. Retrieved
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380:
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110:Identifiers
102:Other names
49:
41:for details.
34:
30:
352:soluble in
327:Appearance
284:Properties
52:August 2024
1758:Categories
509:References
412:octahedral
387:(OAc is CH
348:Solubility
342:Insoluble
318:Molar mass
224:CZZ8832SI5
170:ChemSpider
138:3D model (
117:CAS Number
93:IUPAC name
530:CRC Press
425:Reactions
127:1834-30-6
39:talk page
1764:Acetates
987:NaH(OAc)
830:94447648
563:18 April
477:See also
468:mordants
431:pyridine
419:symmetry
37:See the
1690:Th(OAc)
1682:Ac(OAc)
1669:Yb(OAc)
1661:Tm(OAc)
1653:Er(OAc)
1645:Ho(OAc)
1637:Dy(OAc)
1629:Tb(OAc)
1621:Gd(OAc)
1613:Eu(OAc)
1605:Sm(OAc)
1594:Nd(OAc)
1586:Pr(OAc)
1578:Ce(OAc)
1570:La(OAc)
1561:
1482:Bi(OAc)
1474:Pb(OAc)
1467:Pb(OAc)
1459:Tl(OAc)
1447:Hg(OAc)
1428:Au(OAc)
1420:Pt(OAc)
1394:Lu(OAc)
1383:Ba(OAc)
1346:Sb(OAc)
1338:Sn(OAc)
1331:Sn(OAc)
1323:In(OAc)
1315:Cd(OAc)
1302:Pd(OAc)
1282:Ru(OAc)
1259:Mo(OAc)
1248:Zr(OAc)
1230:Sr(OAc)
1200:As(OAc)
1189:Ga(OAc)
1181:Zn(OAc)
1173:Cu(OAc)
1161:Ni(OAc)
1153:Co(OAc)
1145:Fe(OAc)
1138:Fe(OAc)
1130:Mn(OAc)
1123:Mn(OAc)
1115:Cr(OAc)
1108:Cr(OAc)
1100:VO(OAc)
1092:Ti(OAc)
1084:Sc(OAc)
1074:Ca(OAc)
1014:Al(OAc)
1003:Al(OAc)
995:Mg(OAc)
908:Be(OAc)
872:acetate
746:4283321
726:Bibcode
558:EndMemo
354:ethanol
312:
191:PubChem
1365:I(OAc)
1240:Y(OAc)
1022:Al(OH)
938:O(OAc)
927:B(OAc)
919:O(OAc)
828:
792:
744:
718:Nature
712:OCl.5H
637:
591:
536:
399:ions.
397:ferric
263:SMILES
204:164887
179:144555
87:Names
1705:(OAc)
1455:TlOAc
1440:(OAc)
1378:CsOAc
1310:AgOAc
1294:(OAc)
1274:(OAc)
1225:RbOAc
1215:BrOAc
1169:CuOAc
1059:ClOAc
1038:(OAc)
1010:ALSOL
983:NaOAc
964:AcOOH
946:AcOAc
903:LiOAc
826:S2CID
742:S2CID
238:InChI
140:JSmol
1361:IOAc
1211:BrAc
1069:KOAc
1055:ClAc
973:FOAc
950:ROAc
887:AcOH
790:ISBN
716:O".
708:COO)
635:ISBN
589:ISBN
565:2015
534:ISBN
466:and
464:dyes
458:Uses
450:and
433:and
215:UNII
1739:No
1736:Md
1733:Fm
1730:Es
1727:Cf
1724:Bk
1721:Cm
1718:Am
1715:Pu
1712:Np
1697:Pa
1678:**
1601:Pm
1554:Og
1551:Ts
1548:Lv
1545:Mc
1542:Fl
1539:Nh
1536:Cn
1533:Rg
1530:Ds
1527:Mt
1524:Hs
1521:Bh
1518:Sg
1515:Db
1512:Rf
1509:Lr
1506:**
1503:Ra
1500:Fr
1495:Rn
1492:At
1489:Po
1416:Ir
1413:Os
1410:Re
1404:Ta
1401:Hf
1372:Xe
1357:IAc
1353:Te
1266:Tc
1255:Nb
1219:Kr
1207:Se
1196:Ge
1063:Ar
1045:Si
1026:OAc
977:Ne
969:FAc
959:OAc
897:He
874:ion
818:doi
767:doi
734:doi
722:205
704:(CH
683:doi
194:CID
1760::
1701:UO
1566:*
1436:Hg
1407:W
1390:*
1290:Rh
1278:Cl
1270:Ru
1051:S
1048:P
1034:SO
1030:Al
1018:OH
955:NH
915:Be
824:.
812:.
740:.
732:.
720:.
679:42
677:.
673:.
573:^
556:.
470:.
454:.
421:.
416:3h
391:CO
310:18
304:Fe
302:27
298:14
1707:2
1703:2
1692:4
1684:3
1671:3
1663:3
1655:3
1647:3
1639:3
1631:3
1623:3
1615:3
1607:3
1596:3
1588:3
1580:3
1572:3
1484:3
1476:4
1469:2
1461:3
1449:2
1442:2
1438:2
1430:3
1422:2
1396:3
1385:2
1367:3
1348:3
1340:4
1333:2
1325:3
1317:2
1304:2
1296:4
1292:2
1284:3
1276:4
1272:2
1261:2
1250:4
1242:3
1232:2
1202:3
1191:3
1183:2
1175:2
1163:2
1155:2
1147:3
1140:2
1132:3
1125:2
1117:3
1110:2
1102:3
1094:4
1086:3
1076:2
1040:4
1036:4
1032:2
1024:2
1016:2
1005:3
997:2
989:2
957:4
940:4
936:2
934:B
929:3
921:6
917:4
910:2
863:e
856:t
849:v
832:.
820::
814:3
773:.
769::
748:.
736::
728::
714:2
710:6
706:3
702:3
689:.
685::
643:.
597:.
567:.
542:.
393:2
389:3
308:O
306:3
300:H
296:C
142:)
54:)
50:(
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