314:
175:
33:
24:
636:
who discovered anomalous magnetic behavior for the tris(N,N-dialkyldithiocarbamatoiron(III) complexes. The spin states of these complexes are sensitive to the nature of the amine substituents.
112:
808:
786:
719:
678:
Reflecting the strongly donating properties of dithiocarbamate ligands, iron tris(dithiocarbamate)s oxidize at relatively mild potentials to give isolable iron(IV) derivatives .
512:
722:(NIOSH) has set a recommended exposure limit (REL) of 1 mg/m over an 8-hour workday. At levels of 800 mg/m, ferbam is immediately dangerous to life and health.
862:
J. Albertsson; Å. Oskarsson (1977). "Compounds with intermediate spin. I. The crystal structure of tris(N,N-dimethyldithiocarbamato)iron(III) at 150 and 295 K".
711:
353:
104:
999:
Martin, R. L.; White, A. H. (1967). "A Novel Series of fFive-Coordinated Iron(III) Complexes with the Square-Pyramidal
Configuration and Spin, S = 3/2".
925:
846:
737:
743:
328:
461:
569:
1042:
731:
261:
941:
Fujii, S.; Yoshimura, T. (2000). "A New Trend in Iron–Dithiocarbamate
Complexes: as an Endogenous NO Trapping Agent".
292:
715:
536:
523:
1037:
182:
1047:
589:
170:
45:
585:
889:
L. Cambi; L and L. Szego (1931). "Über die magnetische
Susceptibilität der komplexen Verbindungen".
1032:
309:
69:
921:
842:
682:
1008:
981:
950:
898:
871:
834:
619:
Iron tris(dimethyldithiocarbamate) is an octahedral coordination complex of iron(III) with D
444:
381:
270:
152:
79:
718:) for ferbam exposure in the workplace as 15 mg/m over an 8-hour workday. The U.S.
313:
174:
825:
D. Coucouvanis (2007). "The
Chemistry of the Dithioacid and 1,1-Dithiolate Complexes".
629:
623:
563:
132:
954:
32:
1026:
672:
616:
Iron tris(dithiocarbamate)s are typically are prepared by salt metathesis reactions.
433:
423:
163:
645:
234:
494:
800:
875:
838:
782:
395:
143:
902:
281:
1012:
985:
413:
221:
183:
605:
562:
Except where otherwise noted, data are given for materials in their
209:
245:
123:
111:
103:
92:
23:
337:
InChI=1S/3C3H7NS2.Fe/c3*1-4(2)3(5)6;/h3*1-2H3,(H,5,6);/q;;;+3/p-3
549:
200:
361:
coordination form: CN(C)C(S1)S123(SC(S2)N(C)C)SC(S3)N(C)C
972:-Disubstituted Dithiocarbamato)iron(IV) Tetrafluoroborates".
805:
Immediately
Dangerous to Life or Health Concentrations (IDLH)
297:
809:
National
Institute for Occupational Safety and Health
787:
National
Institute for Occupational Safety and Health
740:- a related dimethyldithiocarbamate complex of nickel
720:
National
Institute for Occupational Safety and Health
746:- a related dimethyldithiocarbamate complex of iron
734:- a related dimethyldithiocarbamate complex of zinc
366:ionic form: CN(C)C(=S)..CN(C)C(=S).CN(C)C(=S)
233:
78:
918:Spin Crossover in Transition Metal Compounds I
712:Occupational Safety and Health Administration
8:
428:Decomposes above 180 °C (356 °F)
968:Pasek, E. A.; Straub, D. K. (1972). "Tris(
632:(SCO) was first observed in 1931 by Cambi
312:
173:
151:
15:
269:
820:
818:
781:NIOSH Pocket Guide to Chemical Hazards.
696:
691:
675:reaction provides a means to detect NO.
664:
659:
654:
756:
681:Iron tris(dithiocarbamate)s react with
644:Iron tris(dithiocarbamate)s react with
475:Reacts with strong oxidizers, moisture
358:
333:
308:
57:Ferric dimethyl dithiocarbamate, Ferbam
776:
774:
772:
770:
768:
766:
764:
762:
760:
685:to give the pentacoordinate chloride:
164:
340:Key: WHDGWKAJBYRJJL-UHFFFAOYSA-K
131:
7:
608:). It is marketed as a fungicide.
408:Dark brown to black, odorless solid
738:Nickel bis(dimethyldithiocarbamate)
224:
208:
17:Iron tris(dimethyldithiocarbamate)
582:Iron tris(dimethyldithiocarbamate)
14:
916:P. Gütlich; H.A. Goodwin (2004).
744:Iron tris(diethyldithiocarbamate)
49:Tris(dimethyldithiocarbamato)iron
864:Acta Crystallographica Section B
31:
22:
827:Progress in Inorganic Chemistry
566:(at 25 °C , 100 kPa).
943:Coordination Chemistry Reviews
462:Occupational safety and health
1:
955:10.1016/S0010-8545(99)00196-4
612:Synthesis, structure, bonding
517:(US health exposure limits):
503:2000 mg/kg (guinea pig, oral)
732:Zinc dimethyldithiocarbamate
648:to give a nitrosyl complex:
483:or concentration (LD, LC):
1064:
716:permissible exposure limit
714:(OSHA) has set the legal (
876:10.1107/s0567740877007237
839:10.1002/9780470166123.ch4
560:
511:
507:3400 mg/kg (mouse, oral)
501:3000 mg/kg (rabbit, oral)
479:
459:
454:
400:416.5 g/mol
374:
349:
324:
62:
54:
44:
39:
30:
21:
903:10.1002/cber.19310641002
102:coordination form:
590:dimethyldithiocarbamate
505:1130 mg/kg (rat, oral)
891:Chem. Ber. Dtsch. Ges
592:with the formula Fe(S
694:+ HCl → Fe(dtc)
586:coordination complex
1043:Iron(III) compounds
1013:10.1021/ic50050a016
1001:Inorganic Chemistry
986:10.1021/ic50108a012
974:Inorganic Chemistry
920:. Springer Berlin.
657:+ NO → Fe(dtc)
445:Solubility in water
18:
570:Infobox references
552:(Immediate danger)
16:
927:978-3-540-40396-8
848:978-0-470-16612-3
683:hydrochloric acid
673:chemical trapping
578:Chemical compound
576:
575:
293:CompTox Dashboard
113:Interactive image
110:ionic form:
105:Interactive image
1055:
1038:Dithiocarbamates
1017:
1016:
996:
990:
989:
965:
959:
958:
938:
932:
931:
913:
907:
906:
886:
880:
879:
870:(6): 1871–1877.
859:
853:
852:
822:
813:
812:
797:
791:
790:
778:
701:
667:
663:NO + 0.5 (dtc)
382:Chemical formula
317:
316:
301:
299:
273:
237:
226:
212:
185:
177:
166:
155:
135:
115:
107:
82:
35:
26:
19:
1063:
1062:
1058:
1057:
1056:
1054:
1053:
1052:
1023:
1022:
1021:
1020:
998:
997:
993:
967:
966:
962:
940:
939:
935:
928:
915:
914:
910:
888:
887:
883:
861:
860:
856:
849:
824:
823:
816:
799:
798:
794:
780:
779:
758:
753:
728:
708:
699:
698:
693:
689:
671:This efficient
666:
662:
661:
656:
652:
642:
622:
614:
603:
599:
595:
579:
572:
567:
553:
540:
527:
506:
504:
502:
498:
492:
472:
447:
389:
384:
370:
367:
362:
357:
356:
345:
342:
341:
338:
332:
331:
320:
302:
295:
276:
256:
240:
227:
215:
195:
158:
138:
118:
96:
85:
72:
58:
50:
12:
11:
5:
1061:
1059:
1051:
1050:
1048:Iron complexes
1045:
1040:
1035:
1025:
1024:
1019:
1018:
1007:(4): 712–717.
991:
980:(2): 259–263.
960:
933:
926:
908:
881:
854:
847:
814:
792:
755:
754:
752:
749:
748:
747:
741:
735:
727:
724:
707:
704:
703:
702:
695:
669:
668:
658:
641:
638:
630:Spin crossover
620:
613:
610:
601:
597:
593:
577:
574:
573:
568:
564:standard state
561:
558:
557:
554:
548:
545:
544:
541:
535:
532:
531:
528:
522:
519:
518:
509:
508:
499:
490:
488:
485:
484:
477:
476:
473:
470:
467:
466:
457:
456:
452:
451:
450:0.01% (20 °C)
448:
443:
440:
439:
436:
430:
429:
426:
420:
419:
416:
410:
409:
406:
402:
401:
398:
392:
391:
387:
385:
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371:
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321:
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305:
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291:
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284:
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205:
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148:
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128:
126:
120:
119:
117:
116:
108:
99:
97:
90:
87:
86:
84:
83:
75:
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68:
65:
64:
60:
59:
56:
52:
51:
48:
42:
41:
37:
36:
28:
27:
13:
10:
9:
6:
4:
3:
2:
1060:
1049:
1046:
1044:
1041:
1039:
1036:
1034:
1031:
1030:
1028:
1014:
1010:
1006:
1002:
995:
992:
987:
983:
979:
975:
971:
964:
961:
956:
952:
948:
944:
937:
934:
929:
923:
919:
912:
909:
904:
900:
896:
892:
885:
882:
877:
873:
869:
865:
858:
855:
850:
844:
840:
836:
832:
828:
821:
819:
815:
810:
806:
802:
796:
793:
788:
784:
777:
775:
773:
771:
769:
767:
765:
763:
761:
757:
750:
745:
742:
739:
736:
733:
730:
729:
725:
723:
721:
717:
713:
705:
688:
687:
686:
684:
679:
676:
674:
651:
650:
649:
647:
639:
637:
635:
631:
627:
625:
617:
611:
609:
607:
591:
588:of iron with
587:
583:
571:
565:
559:
555:
551:
547:
546:
542:
539:(Recommended)
538:
534:
533:
529:
526:(Permissible)
525:
521:
520:
516:
515:
510:
500:
496:
487:
486:
482:
478:
474:
469:
468:
464:
463:
458:
453:
449:
446:
442:
441:
437:
435:
434:Boiling point
432:
431:
427:
425:
424:Melting point
422:
421:
417:
415:
412:
411:
407:
404:
403:
399:
397:
394:
393:
386:
383:
379:
378:
373:
364:
359:
355:
348:
334:
330:
323:
315:
311:
310:DTXSID8020624
307:
306:
304:
294:
290:
289:
285:
283:
280:
279:
272:
268:
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263:
260:
259:
252:
251:
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244:
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236:
232:
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207:
206:
204:
202:
199:
198:
191:
190:
188:
186:
181:
180:
176:
172:
169:
167:
165:ECHA InfoCard
162:
161:
154:
150:
149:
147:
145:
142:
141:
134:
130:
129:
127:
125:
122:
121:
114:
109:
106:
101:
100:
98:
94:
89:
88:
81:
77:
76:
74:
71:
67:
66:
61:
53:
47:
43:
38:
34:
29:
25:
20:
1004:
1000:
994:
977:
973:
969:
963:
946:
942:
936:
917:
911:
897:(10): 2591.
894:
890:
884:
867:
863:
857:
830:
826:
804:
795:
709:
680:
677:
670:
646:nitric oxide
643:
633:
628:
618:
615:
581:
580:
543:TWA 10 mg/m
530:TWA 15 mg/m
513:
480:
471:Main hazards
460:
246:RTECS number
63:Identifiers
55:Other names
833:: 233–371.
700:Cl + Hdtc
495:median dose
481:Lethal dose
465:(OHS/OSH):
438:Decomposes
405:Appearance
375:Properties
286:3077, 2771
171:100.034.970
1033:Fungicides
1027:Categories
751:References
418:1.52 g/cm
396:Molar mass
271:SKM8W5154H
144:ChemSpider
133:CHEBI:5015
91:3D model (
80:14484-64-1
70:CAS Number
46:IUPAC name
949:: 89–99.
710:The U.S.
640:Reactions
556:800 mg/m
390:Fe
282:UN number
253:NO8750000
192:238-484-2
184:EC Number
811:(NIOSH).
801:"Ferbam"
789:(NIOSH).
726:See also
624:symmetry
455:Hazards
783:"#0286"
690:Fe(dtc)
653:Fe(dtc)
584:is the
414:Density
222:PubChem
924:
845:
706:Safety
634:et al.
606:methyl
604:(Me =
354:SMILES
210:C11223
40:Names
514:NIOSH
329:InChI
235:26710
153:24884
124:ChEBI
93:JSmol
922:ISBN
843:ISBN
596:CNMe
550:IDLH
262:UNII
201:KEGG
1009:doi
982:doi
970:N,N
951:doi
947:198
899:doi
872:doi
835:doi
537:REL
524:PEL
298:EPA
225:CID
1029::
1003:.
978:11
976:.
945:.
895:64
893:.
868:33
866:.
841:.
831:11
829:.
817:^
807:.
803:.
785:.
759:^
626:.
491:50
489:LD
1015:.
1011::
1005:6
988:.
984::
957:.
953::
930:.
905:.
901::
878:.
874::
851:.
837::
697:2
692:3
665:2
660:2
655:3
621:3
602:3
600:)
598:2
594:2
497:)
493:(
388:3
300:)
296:(
95:)
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