Knowledge (XXG)

Kelliphite

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InChI=1S/C60H72O6P2/c1-33-29-43(57(9,10)11)53-49(37(33)5)50-38(6)34(2)30-44(58(12,13)14)54(50)64-67(63-53)61-47-27-23-21-25-41(47)42-26-22-24-28-48(42)62-68-65-55-45(59(15,16)17)31-35(3)39(7)51(55)52-40(8)36(4)32-46(56(52)66-68)60(18,19)20/h21-32H,1-20H3
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Clark, Thomas P.; Landis, CR; Freed, SL; Klosin, J; Abboud, KA (2005). "Highly Active, Regioselective, and Enantioselective Hydroformylation with Rh Catalysts Ligated by Bis-3,4-diazaphospholanes".
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Cobley, Christopher J.; Klosin, Jerzy; Qin, Cheng; Whiteker, Gregory T. (2004). "Parallel Ligand Screening on Olefin Mixtures in Asymmetric Hydroformylation Reactions".
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CC1=CC(=C2C(=C1C)C3=C(C(=CC(=C3OP(O2)OC4=CC=CC=C4C5=CC=CC=C5OP6OC7=C(C=C(C(=C7C8=C(C(=CC(=C8O6)C(C)(C)C)C)C)C)C)C(C)(C)C)C(C)(C)C)C)C)C(C)(C)C
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Cobley, Christopher J.; Gardner, K; Klosin, J; Praquin, C; Hill, C; Whiteker, GT; Zanotti-Gerosa, A; Petersen, JL; Abboud, KA (2004).
206: 344: 170: 462:"Synthesis and Application of a New Bisphosphite Ligand Collection for Asymmetric Hydroformylation of Allyl Cyanide" 541: 360: 546: 424: 368: 187: 45: 429: 79: 518: 482: 442: 416: 461: 133: 510: 474: 434: 395: 384: 364: 302: 254: 89: 191: 315: 535: 466: 158: 394:. It has been shown that high substrate concentrations as well as a wide variety of 23: 32: 502: 288: 124: 388: 522: 486: 446: 380: 376: 145: 514: 478: 438: 391: 372: 314:
Except where otherwise noted, data are given for materials in their
112: 102: 175: 332: 157: 88: 8: 190: 132: 15: 428: 406: 236: 211: 186: 363:6,6'-bisdibenzodioxaphosphepin. This 218:Key: BWNYBZZRRYVGQK-UHFFFAOYSA-N 7: 50:6,6′-{-2,2′-diylbis(oxy)}bis(4,8-di- 148: 278: 14: 322: 266: 31: 22: 318:(at 25 °C , 100 kPa). 272: 260: 54:-butyl-1,2,10,11-tetramethyl-6 1: 563: 361:organophosphorus compound 312: 247: 227: 202: 72: 64: 58:-dibenzodioxaphosphepine) 44: 39: 30: 21: 371:. In one example, this 359:is an acronym for the 369:asymmetric synthesis 46:Preferred IUPAC name 303:Solubility in water 296: g·mol 18: 375:is used to form a 367:is widely used in 345:Infobox references 16: 515:10.1021/ol0487938 479:10.1021/jo040128p 439:10.1021/ja050148o 417:J. Am. Chem. Soc. 396:functional groups 353:Chemical compound 351: 350: 308:organic solvents 171:CompTox Dashboard 114:Interactive image 554: 542:Organophosphites 527: 526: 497: 491: 490: 457: 451: 450: 432: 411: 398:are tolerated. 385:hydroformylation 335: 329: 326: 325: 295: 280: 274: 268: 262: 255:Chemical formula 195: 194: 179: 177: 161: 150: 136: 116: 92: 35: 26: 19: 562: 561: 557: 556: 555: 553: 552: 551: 532: 531: 530: 509:(19): 3277–80. 499: 498: 494: 473:(12): 4031–40. 459: 458: 454: 430:10.1.1.601.7762 413: 412: 408: 404: 354: 347: 342: 341: 340:  ?) 331: 327: 323: 319: 305: 293: 283: 277: 271: 265: 257: 243: 240: 235: 234: 223: 220: 219: 216: 210: 209: 198: 188:DTXSID401336795 180: 173: 164: 151: 139: 119: 106: 95: 82: 68: 60: 59: 12: 11: 5: 560: 558: 550: 549: 544: 534: 533: 529: 528: 492: 452: 423:(14): 5040–2. 405: 403: 400: 352: 349: 348: 343: 321: 320: 316:standard state 313: 310: 309: 306: 301: 298: 297: 291: 285: 284: 281: 275: 269: 263: 258: 253: 250: 249: 245: 244: 242: 241: 238: 230: 229: 228: 225: 224: 222: 221: 217: 214: 213: 205: 204: 203: 200: 199: 197: 196: 183: 181: 169: 166: 165: 163: 162: 154: 152: 144: 141: 140: 138: 137: 129: 127: 121: 120: 118: 117: 109: 107: 100: 97: 96: 94: 93: 85: 83: 78: 75: 74: 70: 69: 66: 62: 61: 49: 48: 42: 41: 37: 36: 28: 27: 13: 10: 9: 6: 4: 3: 2: 559: 548: 547:Phenol ethers 545: 543: 540: 539: 537: 524: 520: 516: 512: 508: 505: 504: 496: 493: 488: 484: 480: 476: 472: 469: 468: 467:J. Org. Chem. 463: 456: 453: 448: 444: 440: 436: 431: 426: 422: 419: 418: 410: 407: 401: 399: 397: 393: 390: 386: 382: 378: 374: 370: 366: 365:chiral ligand 362: 358: 346: 339: 334: 317: 311: 307: 304: 300: 299: 292: 290: 287: 286: 259: 256: 252: 251: 246: 237: 233: 226: 212: 208: 201: 193: 189: 185: 184: 182: 172: 168: 167: 160: 156: 155: 153: 147: 143: 142: 135: 131: 130: 128: 126: 123: 122: 115: 111: 110: 108: 104: 99: 98: 91: 87: 86: 84: 81: 77: 76: 71: 63: 57: 53: 47: 43: 38: 34: 29: 25: 20: 506: 501: 495: 470: 465: 455: 420: 415: 409: 356: 355: 73:Identifiers 65:Other names 55: 51: 383:asymmetric 379:complex to 248:Properties 90:729572-33-2 17:Kelliphite 536:Categories 503:Org. Lett. 402:References 357:Kelliphite 289:Molar mass 125:ChemSpider 101:3D model ( 80:CAS Number 67:Kelliphite 425:CiteSeerX 389:prochiral 523:15355031 487:15176828 447:15810837 381:catalyze 159:11815482 392:olefins 377:rhodium 338:what is 336: ( 294:951.178 146:PubChem 134:9990139 521:  485:  445:  427:  373:ligand 333:verify 330:  232:SMILES 40:Names 207:InChI 103:JSmol 519:PMID 483:PMID 443:PMID 52:tert 511:doi 475:doi 435:doi 421:127 387:of 176:EPA 149:CID 538:: 517:. 481:. 471:69 464:. 441:. 433:. 270:72 264:60 525:. 513:: 507:6 489:. 477:: 449:. 437:: 328:Y 282:2 279:P 276:6 273:O 267:H 261:C 178:) 174:( 105:) 56:H

Index

Skeletal formula of kelliphite
Ball-and-stick model of the kelliphite molecule
Preferred IUPAC name
CAS Number
729572-33-2
JSmol
Interactive image
ChemSpider
9990139
PubChem
11815482
CompTox Dashboard
DTXSID401336795
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Solubility in water
standard state
verify
what is
Infobox references
organophosphorus compound
chiral ligand
asymmetric synthesis
ligand
rhodium
catalyze
hydroformylation

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