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181:(PVDF) is applied onto the coated water droplet. The doubly-coated water droplet is then cast into the hexane/water mixture and eventually settled at the hexane/water interface to form the interfacial water marble. During this process, the PVDF coating quickly diffused into hexane to balance the hydrophobic interaction between hexane and the water droplet, while the nanomaterials quickly self-assembled into a nanostructured protective layer on the droplet surface through the
138:
107:
coating on their surface to prevent the contact between water and the solid ground (Figure 1). Liquid marbles provide a new approach to transport liquid mass on the solid surface, which sufficiently transform the inconvenient glass containers into flexible, user-specified hydrophobic coating composed
133:
into the reservoir, the combination or summary of these self-similar coalescence processes is called coalescence cascade. The underlying mechanism of coalescence cascade has been studied in detail but there has been mere attempt to control and make use of it. Until recently, Liu et al. has filled
196:. The interfacial water marbles can also realize a series of stimuli-responsive motions by integrating the functional materials into the surface coating layer. Due to their uniqueness in both form and behavior, the interfacial water marbles are speculated to have remarkable applications in
121:
161:(Figure 2). To realize interfacial water marbles at hexane/water interface, the individual particle size of the surface coating layer should be as small as possible, so that the contact line between the particles and the water reservoir can be minimized; special wettability with mixed
116:
have been extensively investigated. However, liquid marbles only reflect the water behavior at the solid-air interface, while there is no report on the water behavior at the liquid-liquid interface, as a result of the so-called coalescence cascade phenomenon.
128:
When a water droplet is in contact with a water reservoir, it will quickly pinch off from the reservoir and form a smaller daughter droplet, while this daughter droplet will continue to go through a similar contact-pinch off-splitting process until completed
742:
Li, Xiaoguang(李晓光 ); Wang, Yiqi(王义琪 ); Huang, Junchao(黄俊超 ); Yang, Yao(杨瑶 ); Wang, Renxian(王仁贤 ); Geng, Xingguo(耿兴国 ); Zang, Duyang(臧渡洋 ) (2017-12-25). "Monolayer nanoparticle-covered liquid marbles derived from a sol-gel coating".
1288:
Liu, Yang; Zhang, Xinyu; Poyraz, Selcuk; Zhang, Chao; Xin, John (15 March 2018). "One-step synthesis of multifunctional zinc-iron-oxide hybrid carbon nanowires by chemical fusion for supercapacitors and interfacial water marbles".
1058:
Sarvi, Fatemeh; Jain, Kanika; Arbatan, Tina; Verma, Paul J.; Hourigan, Kerry; Thompson, Mark C.; Shen, Wei; Chan, Peggy P.Y. (7 January 2015). "Cardiogenesis of embryonic stem cells with liquid marble micro-bioreactor".
442:
Bormashenko, Edward; Bormashenko, Yelena; Grynyov, Roman; Aharoni, Hadas; Whyman, Gene; Binks, Bernard P (2015). "Self-Propulsion of Liquid
Marbles: Leidenfrost-like Levitation Driven by Marangoni Flow".
828:
Ooi, Chin Hong; Bormashenko, Edward; Nguyen, Anh V.; Evans, Geoffrey M.; Dao, Dzung V.; Nguyen, Nam-Trung (2016-06-21). "Evaporation of
Ethanol–Water Binary Mixture Sessile Liquid Marbles".
966:
Zhao, Yan; Fang, Jian; Wang, Hongxia; Wang, Xungai; Lin, Tong (9 February 2010). "Magnetic liquid marbles: manipulation of liquid droplets using highly hydrophobic Fe3O4 nanoparticles".
67:
convert honeydew droplets into marbles. A variety of non-organic and organic liquids may be converted into liquid marbles. Liquid marbles demonstrate elastic properties and do not
538:
Draper, Thomas C.; Fullarton, Claire; Phillips, Neil; Costello, Ben P.J. de Lacy; Adamatzky, Andrew (2017). "Liquid marble interaction gate for collision-based computing".
652:
79:. Liquid marbles remain stable on solid and liquid surfaces. Statics and dynamics of rolling and bouncing of liquid marbles were reported. Liquid marbles coated with
134:
this void by proposing a new method to control coalescence cascade by using nanostructured coating at the liquid-liquid interface, —the interfacial liquid marbles.
169:
is also preferred for the interfacial water marble formation. The interfacial water marble can be fabricated by firstly coating a water droplet with
87:
particles have been reported. Liquid marbles are not hermetically coated by solid particles but connected to the gaseous phase. Kinetics of the
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71:
when bounced or pressed lightly. Liquid marbles demonstrate a potential as micro-reactors, micro-containers for growing micro-organisms and
16:
591:
Wong, Cl.Y. H. M. Adda-Bedia M., Vella, D. (2017). "Non-wetting drops at liquid interfaces: from liquid marbles to
Leidenfrost drops".
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Fullarton, Claire; Draper, Thomas C.; Phillips, Neil; Mayne, Richard; Costello, Ben P. J. de Lacy; Adamatzky, Andrew (2018-02-06).
63:, etc.); representing a platform for a diversity of chemical and biological applications. Liquid marbles are also found naturally;
881:
Dandan, Merve; Erbil, H. Yildirim (2009-07-21). "Evaporation Rate of
Graphite Liquid Marbles: Comparison with Water Droplets".
99:
Liquid marbles were first reported by P. Aussillous and D. Quere in 2001, who described a new method to construct portable
924:
Karokine, Nikita; Anyfantakis, Manos; Morel, Mathieu; Rudiuk, Sergii; Bickel, Thomas; Baigl, Damien (5 September 2016).
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cascade and exist nearly permanently at the hexane/water interface, providing that the hexane phase is not depleted by
925:
1340:
503:
Bormashenko, Edward (2016). "Liquid
Marbles, Elastic Nonstick Droplets: From Minireactors to Self-Propulsion".
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of powders of hydrophobic materials. Since then, the applications of liquid marbles in no-loss mass transport,
76:
178:
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Similar to liquid marbles at the solid-air interface, the interfacial liquid marbles are constructed on the
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Klyuzhin, Ivan S.; Lenna, Federico; Roeder, Brandon; Wexler, Adam; Pollack, Gerald H (11 November 2010).
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Society A: Mathematical, Physical and Engineering Sciences
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Thoroddsen, S. T.; Takehara, K. (June 2000). "The coalescence cascade of a drop".
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Figure 2. An interfacial water marble sitting on the hexane-water interface.
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926:"Light-driven transport of a liquid marble with and against surface flows"
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de Gennes, Pierre-Gilles; Brochard-Wyart, Françoise; Quéré, David (2004).
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Quéré, David; Aussillous, Pascale (2006). "Properties of liquid marbles".
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343:"Liquid marbles: Topical context within soft matter and recent progress"
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Arbatan, Tina; Li, Lizi; Tian, Junfei; Shen, Wei (11 January 2012).
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Supakar, T. (2017). "Impact dynamics of particle-coated droplets".
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interface using water droplets with a surface coating composed of
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1019:"Liquid marbles as micro-bioreactors for rapid blood typing"
244:
Aussillous, Pascale; Quéré, David (2001). "Liquid marbles".
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Blanchette, François; Bigioni, Terry P. (1 April 2006).
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with special wettability, e.g. hybrid carbon nanowires,
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Proceedings of the Royal
Society B: Biological Sciences
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Pike, N; Richard, D; Foster, W; Mahadevan, L (2002).
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Figure 1. A liquid marble sitting on the glass slide.
75:, micro-fluidics devices, and have even been used in
1104:"Partial coalescence of drops at liquid interfaces"
188:The interfacial water marble can completely resist
20:20 μL liquid marble coated with the Teflon powder
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668:Capillarity and Wetting Phenomena | SpringerLink
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103:in the atmospheric environment with
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445:The Journal of Physical Chemistry C
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27:are non-stick droplets (normally
341:McHale, G; Newton, M. I (2015).
1194:Journal of Physical Chemistry B
392:"How aphids lose their marbles"
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1023:Advanced Healthcare Materials
842:10.1021/acs.langmuir.6b01272
807:10.1021/acs.langmuir.7b04196
570:10.1016/j.mattod.2017.09.004
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676:10.1007/978-0-387-21656-0
95:Interfacial water marbles
475:10.1021/acs.jpcc.5b01307
77:unconventional computing
745:Applied Physics Letters
179:polyvinylidene fluoride
157:materials with special
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359:2015SMat...11.2530M
309:2006RSPSA.462..973A
258:2001Natur.411..924A
45:colloidal particles
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593:Soft Matter
347:Soft Matter
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159:wettability
131:coalescence
105:hydrophobic
89:evaporation
41:hydrophobic
1325:Categories
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226:References
1004:205234566
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155:nanoscale
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274:11418851
208:See also
69:coalesce
1331:Liquids
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