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Peroxycarbonate

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Electrolysis of a solution of lithium carbonate at -30° to -40 °C yields a solution of the Lithium percarbonate, which can liberate iodine from potassium iodide instantaneously. The crystalline salt has not been isolated.
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Chen, Li-Jiang; Lin, Chang-Jian; Zuo, Juan; Song, Ling-Chun; Huang, Chao-Ming (2004). "First Spectroscopic Observation of Peroxocarbonate/ Peroxodicarbonate in Molten Carbonate".
799: 181: 646:"Darstellung und strukturelle Charakterisierung neuer Alkali- bzw. Erdalkalimetallperoxide, -hydrogenperoxide, -peroxocarbonate und -peroxohydrate" 645: 792: 694: 574:
Firsova, T. P.; Kvlividze, V. I.; Molodkina, A. N.; Morozova, T. G. (1975). "Synthesis and some properties of lithium peroxocarbonate".
833: 630: 156: 785: 318:). or the real hydroperoxyformic acid, HO-O-CO-OH (a.k.a. percarbonic acid, carbonoperoxoic acid, hydroxycarbonic acid). 828: 97: 466: 241: 405: 358: 487:"Die Existenz echter Percarbonate und ihre Unterscheidung von Carbonaten mit Krystall-Wasserstoffsuperoxyd" 444: 310: 48: 36: 392:
The peroxycarbonate anion has been proposed as an intermediate to explain the catalytic effect of CO
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10.1002/(SICI)1521-3773(19980605)37:10<1387::AID-ANIE1387>3.0.CO;2-3
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
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Except where otherwise noted, data are given for materials in their
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as an oxidant and current understanding on its role",
403:The potassium and rubidium salts of the monovalent 321:The peroxycarbonate anion is formed, together with 681:—An Oxygen-Rich Salt of Monoperoxocarbonic Acid". 655:. Doctoral Thesis, University of Köln. 115 pages. 409:anion (aka. hydroxycarbonate, biperoxycarbonate) 141: 522:Berichte der Deutschen Chemischen Gesellschaft 491:Berichte der Deutschen Chemischen Gesellschaft 793: 8: 605:chemistry – Recent advances in utilizing CO 601:Park, Sang-Eon; Yoo, Jin S. (2004), "New CO 800: 786: 665:Adam, Arnold; Mehta, Mathias (1998). "KH(O 396:on the oxidation of organic compounds by O 308:. It would be the anion of a hypothetical 116: 15: 740:, Suppl. Issue 15 p. 46. Cited by Gjikaj. 727:, Suppl. Issue 15 p. 53. Cited by Gjikaj. 165:InChI=1S/CH2O4/c2-1(3)5-4/h4H,(H,2,3)/p-2 611:Studies in Surface Science and Catalysis 485:Riesenfeld, E. H.; Reinhold, B. (1909). 683:Angewandte Chemie International Edition 477: 186: 161: 168:Key: MMCOUVMKNAHQOY-UHFFFAOYSA-L 7: 751: 749: 549:The Journal of Physical Chemistry B 516:Riesenfeld, E. H.; Mau, W. (1911). 132: 361:can be produced also by combining 14: 753: 22: 238:(at 25 °C , 100 kPa). 213: 210: 1: 736:M. Mehta and A. Adam (1998), 723:M. Mehta and A. Adam (1998), 623:10.1016/s0167-2991(04)80269-6 772:. You can help Knowledge by 850: 748: 467:Dipropyl peroxydicarbonate 534:10.1002/cber.191104403244 421:have also been obtained. 232: 228:76.01 g/mol 197: 177: 152: 78: 73:Dioxidan-2-idecarboxylate 59: 47: 35: 30: 21: 834:Inorganic compound stubs 503:10.1002/cber.19090420428 300:that consists solely of 406:hydrogenperoxycarbonate 359:Lithium peroxycarbonate 768:–related article is a 644:Mimoza Gjikaj (2001), 518:"Isomere Percarbonate" 445:Sodium peroxycarbonate 314:HO–CO–O–OH (sometimes 617:, Elsevier: 303–314, 49:Systematic IUPAC name 37:Preferred IUPAC name 431:Sodium percarbonate 316:peroxocarbonic acid 311:peroxycarbonic acid 69:Peroxidocarboxylate 18: 829:Physical chemistry 651:2012-02-25 at the 588:10.1007/BF00922073 345:, at the negative 242:Infobox references 17:α-Peroxycarbonate 16: 781: 780: 689:(10): 1387–1388. 561:10.1021/jp035749l 555:(23): 7553–7556. 375:hydrogen peroxide 371:lithium hydroxide 355:lithium carbonate 323:peroxydicarbonate 250:Chemical compound 248: 247: 98:Interactive image 64:(Peroxocarbonate) 841: 802: 795: 788: 757: 750: 741: 734: 728: 721: 715: 714: 662: 656: 642: 636: 635: 598: 592: 591: 582:(6): 1318–1319. 571: 565: 564: 544: 538: 537: 528:(3): 3595–3605. 513: 507: 506: 497:(4): 4377–4383. 482: 463: 462: 461: 439:sodium carbonate 420: 419: 418: 385:at −10 °C. 373:in concentrated 344: 343: 342: 334: 333: 295: 294: 293: 215: 212: 205:Chemical formula 145: 134: 120: 100: 62:Peroxycarbonate 26: 19: 849: 848: 844: 843: 842: 840: 839: 838: 809: 808: 807: 806: 746: 744: 738:Z. Kristallogr. 735: 731: 725:Z. Kristallogr. 722: 718: 680: 676: 672: 668: 664: 663: 659: 653:Wayback Machine 643: 639: 633: 608: 604: 600: 599: 595: 573: 572: 568: 546: 545: 541: 515: 514: 510: 484: 483: 479: 475: 460: 457: 456: 455: 453: 427: 417: 414: 413: 412: 410: 399: 395: 384: 380: 368: 341: 338: 337: 336: 332: 329: 328: 327: 325: 298:oxocarbon anion 292: 289: 288: 287: 285: 263:peroxocarbonate 259:peroxycarbonate 251: 244: 239: 218: 207: 193: 190: 185: 184: 173: 170: 169: 166: 160: 159: 148: 135: 123: 103: 90: 74: 72: 71:Peroxidoformate 70: 68: 66: 55: 54: 43: 42: 12: 11: 5: 847: 845: 837: 836: 831: 826: 821: 811: 810: 805: 804: 797: 790: 782: 779: 778: 758: 743: 742: 729: 716: 678: 674: 670: 666: 657: 637: 631: 606: 602: 593: 566: 539: 508: 476: 474: 471: 470: 469: 464: 458: 450:Orthocarbonate 447: 442: 426: 423: 415: 397: 393: 382: 378: 366: 363:carbon dioxide 339: 330: 290: 271:oxidocarbonate 265:, IUPAC name: 249: 246: 245: 240: 236:standard state 233: 230: 229: 226: 220: 219: 216: 208: 203: 200: 199: 195: 194: 192: 191: 188: 180: 179: 178: 175: 174: 172: 171: 167: 164: 163: 155: 154: 153: 150: 149: 147: 146: 138: 136: 128: 125: 124: 122: 121: 113: 111: 105: 104: 102: 101: 93: 91: 84: 81: 80: 76: 75: 61: 57: 56: 52: 51: 45: 44: 41:Oxidocarbonate 40: 39: 33: 32: 28: 27: 13: 10: 9: 6: 4: 3: 2: 846: 835: 832: 830: 827: 825: 822: 820: 817: 816: 814: 803: 798: 796: 791: 789: 784: 783: 777: 775: 771: 767: 764: 759: 756: 752: 747: 739: 733: 730: 726: 720: 717: 712: 708: 704: 700: 696: 692: 688: 684: 661: 658: 654: 650: 647: 641: 638: 634: 632:9780444516008 628: 624: 620: 616: 612: 597: 594: 589: 585: 581: 577: 570: 567: 562: 558: 554: 550: 543: 540: 535: 531: 527: 523: 519: 512: 509: 504: 500: 496: 492: 488: 481: 478: 472: 468: 465: 451: 448: 446: 443: 440: 436: 433:, actually a 432: 429: 428: 424: 422: 408: 407: 401: 390: 386: 376: 372: 364: 360: 356: 352: 348: 324: 319: 317: 313: 312: 307: 303: 299: 284:with formula 283: 280: 276: 272: 268: 264: 260: 256: 243: 237: 231: 227: 225: 222: 221: 209: 206: 202: 201: 196: 187: 183: 176: 162: 158: 151: 144: 140: 139: 137: 131: 127: 126: 119: 115: 114: 112: 110: 107: 106: 99: 95: 94: 92: 88: 83: 82: 77: 65: 58: 50: 46: 38: 34: 29: 25: 20: 774:expanding it 760: 745: 737: 732: 724: 719: 686: 682: 660: 640: 614: 610: 596: 579: 575: 569: 552: 548: 542: 525: 521: 511: 494: 490: 480: 404: 402: 391: 387: 351:electrolysis 320: 315: 309: 275:percarbonate 274: 270: 267:oxocarbonate 266: 262: 258: 252: 79:Identifiers 67:Percarbonate 63: 60:Other names 53:Oxocarbonate 296:. It is an 261:(sometimes 198:Properties 824:Oxocarbons 813:Categories 473:References 435:perhydrate 353:of molten 224:Molar mass 109:ChemSpider 85:3D model ( 819:Oxyanions 763:inorganic 703:1521-3773 347:electrode 255:chemistry 766:compound 711:29710903 649:Archived 425:See also 411:H–O–O–CO 279:divalent 189:C(=O)()O 143:15793132 118:23255841 349:during 130:PubChem 709:  701:  629:  452:anion 306:oxygen 302:carbon 182:SMILES 31:Names 761:This 369:with 282:anion 277:is a 273:) or 157:InChI 87:JSmol 770:stub 707:PMID 699:ISSN 627:ISBN 304:and 691:doi 669:)CO 619:doi 615:153 584:doi 557:doi 553:108 530:doi 499:doi 437:of 269:or 253:In 133:CID 815:: 705:. 697:. 687:37 685:. 673:·H 625:, 580:24 578:. 551:. 526:44 524:. 520:. 495:42 493:. 489:. 454:CO 400:. 365:CO 357:. 286:CO 257:, 801:e 794:t 787:v 776:. 713:. 693:: 679:2 677:O 675:2 671:2 667:2 621:: 607:2 603:2 590:. 586:: 563:. 559:: 536:. 532:: 505:. 501:: 459:4 441:. 416:2 398:2 394:2 383:2 381:O 379:2 377:H 367:2 340:6 335:O 331:2 326:C 291:4 217:4 214:O 211:C 89:)

Index


Preferred IUPAC name
Systematic IUPAC name
JSmol
Interactive image
ChemSpider
23255841
PubChem
15793132
InChI
SMILES
Chemical formula
Molar mass
standard state
Infobox references
chemistry
divalent
anion
oxocarbon anion
carbon
oxygen
peroxycarbonic acid
peroxydicarbonate
electrode
electrolysis
lithium carbonate
Lithium peroxycarbonate
carbon dioxide
lithium hydroxide
hydrogen peroxide

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