Knowledge (XXG)

Peroxydisulfate

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Wacławek, Stanisław; Lutze, Holger V.; Grübel, Klaudiusz; Padil, Vinod V.T.; Černík, Miroslav; Dionysiou, Dionysios.D. (2017). "Chemistry of persulfates in water and wastewater treatment: A review".
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It has also been used to produce hair lighteners and bleaches, medical drugs, cellophane, rubber, soaps, detergents, adhesive papers, dyes for textiles, and in photography.
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In addition to its major commercial applications, peroxydisulfate participates in reactions of interest in the laboratory:
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Peroxydisulfate is a centrosymmetric anion. The O-O distance is 1.48 Å. The sulfur centers are tetrahedral.
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Harald Jakob, Stefan Leininger, Thomas Lehmann, Sylvia Jacobi, Sven Gutewort. "Peroxo Compounds, Inorganic".
728: 471: 378:. Approximately 500,000 tons of salts containing this anion are produced annually. Important salts include 741: 459: 351: 292: 681: 1337: 887: 689: 395: 1281: 782: 411: 71: 558: 1284: 845: 815: 591: 455: 379: 359: 1288: 665: 634: 583: 548: 252: 190: 145: 81: 35: 1273: 125: 451: 301: 287: 1331: 562: 447: 438:
Salts of peroxydisulfate are mainly used to initiate the polymerization of various
170: 587: 26: 430:). These salts are colourless, water-soluble solids that are strong oxidants. 713: 670: 653: 638: 518: 355: 274: 136: 474:, water and wastewater treatment, and etching of copper on circuit boards. 553: 537:"Electroreduction of Peroxodisulfate: A Review of a Complicated Reaction" 347: 443: 439: 157: 535:
Shafiee, Saiful Arifin; Aarons, Jolyon; Hamzah, Hairul Hisham (2018).
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Except where otherwise noted, data are given for materials in their
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InChI=1S/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6)/p-2
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Moreover, sodium peroxydisulfate can be used for soil and
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Ion containing sulfur and oxygen with a charge of 2-
489:Oxidation of Ag to Ag, such as the preparation of 169: 80: 579:Ullmann's Encyclopedia of Industrial Chemistry 1312: 697: 8: 610:: CS1 maint: multiple names: authors list ( 491:tetrakis(pyridine)silver(II) peroxydisulfate 1319: 1305: 704: 690: 682: 144: 18: 669: 552: 189: 1011: 1007: 1003: 999: 995: 898: 894: 890: 881: 862: 858: 848: 826: 822: 818: 797: 793: 789: 785: 752: 748: 744: 735: 731: 510: 234: 209: 760: 712:Salts and covalent derivatives of the 603: 541:Journal of the Electrochemical Society 1158: 216:Key: JRKICGRDRMAZLK-UHFFFAOYSA-L 124: 7: 1270: 1268: 724: 530: 528: 526: 358:, but this term also refers to the 160: 1291:. You can help Knowledge (XXG) by 14: 1272: 658:Acta Crystallographica Section E 354:. It is commonly referred to as 34: 25: 304:(at 25 °C , 100 kPa). 264: 258: 1: 588:10.1002/14356007.a19_177.pub2 627:Chemical Engineering Journal 1364: 1267: 1160: 762: 721: 671:10.1107/S1600536806004302 639:10.1016/j.cej.2017.07.132 485:Elbs persulfate oxidation 298: 245: 225: 200: 64: 47: 42: 33: 24: 1348:Inorganic compound stubs 654:"Sodium Peroxodisulfate" 652:Allan, David R. (2006). 462:of the peroxydisulfate: 582:. Weinheim: Wiley-VCH. 472:groundwater remediation 1287:–related article is a 450:, and fluoroalkenes. 352:peroxydisulfuric acid 293:Peroxydisulfuric acid 554:10.1149/2.1161811jes 396:potassium persulfate 374:. It is also called 237:S(=O)(=O)OOS()(=O)=O 412:ammonium persulfate 282: g·mol 21: 308:Infobox references 19: 1300: 1299: 1265: 1264: 1259: 1258: 606:cite encyclopedia 547:(13): H785–H798. 380:sodium persulfate 360:peroxomonosulfate 316:Chemical compound 314: 313: 106:Interactive image 1355: 1343:Sulfur oxyanions 1321: 1314: 1307: 1276: 1269: 1014: 901: 884: 866: 852: 829: 800: 755: 738: 725: 706: 699: 692: 683: 676: 675: 673: 649: 643: 642: 622: 616: 615: 609: 601: 573: 567: 566: 556: 532: 521: 515: 373: 372: 371: 344: 343: 342: 334: 333: 281: 266: 260: 253:Chemical formula 193: 173: 162: 148: 128: 108: 84: 38: 29: 22: 20:Peroxydisulfate 1363: 1362: 1358: 1357: 1356: 1354: 1353: 1352: 1328: 1327: 1326: 1325: 1266: 1261: 1260: 1013: 1009: 1005: 1001: 997: 993: 900: 896: 892: 888: 886: 883: 879: 864: 860: 856: 854: 850: 846: 828: 824: 820: 816: 799: 795: 791: 787: 783: 754: 750: 746: 742: 740: 737: 733: 729: 717: 710: 680: 679: 651: 650: 646: 624: 623: 619: 602: 598: 575: 574: 570: 534: 533: 524: 516: 512: 507: 499: 436: 429: 425: 421: 417: 409: 405: 401: 393: 389: 385: 376:peroxodisulfate 370: 367: 366: 365: 363: 350:, the anion of 341: 338: 337: 336: 332: 329: 328: 327: 325: 321:peroxydisulfate 317: 310: 305: 279: 269: 263: 255: 241: 238: 233: 232: 221: 218: 217: 214: 208: 207: 196: 176: 163: 151: 131: 111: 98: 87: 74: 60: 59: 53:Peroxodisulfate 17: 12: 11: 5: 1361: 1359: 1351: 1350: 1345: 1340: 1330: 1329: 1324: 1323: 1316: 1309: 1301: 1298: 1297: 1277: 1263: 1262: 1257: 1256: 1253: 1250: 1247: 1244: 1241: 1238: 1235: 1232: 1229: 1226: 1223: 1220: 1217: 1214: 1210: 1209: 1206: 1203: 1200: 1197: 1194: 1191: 1188: 1185: 1182: 1179: 1176: 1173: 1170: 1167: 1163: 1162: 1159: 1156: 1155: 1152: 1149: 1146: 1143: 1140: 1137: 1134: 1131: 1128: 1125: 1122: 1119: 1116: 1113: 1110: 1107: 1104: 1101: 1097: 1096: 1093: 1090: 1087: 1084: 1081: 1078: 1075: 1072: 1069: 1066: 1063: 1060: 1057: 1054: 1051: 1048: 1045: 1042: 1038: 1037: 1034: 1031: 1028: 1025: 1022: 1019: 1016: 990: 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126:CHEBI:29267 1332:Categories 714:persulfate 519:persulfate 505:References 356:persulfate 275:Molar mass 191:1SQ1481FEQ 137:ChemSpider 93:3D model ( 82:15092-81-6 72:CAS Number 56:Persulfate 1282:inorganic 633:: 44–62. 563:106396614 497:Structure 460:homolysis 456:initiated 1285:compound 348:oxyanion 346:, is an 1161:  458:by the 444:styrene 440:alkenes 410:), and 158:PubChem 594:  561:  280:192.11 230:SMILES 171:107879 43:Names 1280:This 559:S2CID 362:ion, 323:ion, 205:InChI 146:97014 117:ChEBI 95:JSmol 1289:stub 880:KHSO 612:link 592:ISBN 466:⇌ 2 414:((NH 319:The 182:UNII 1255:No 1252:Md 1249:Fm 1246:Es 1243:Cf 1240:Bk 1237:Cm 1234:Am 1231:Pu 1228:Np 1222:Pa 1219:Th 1216:Ac 1213:** 1208:Yb 1205:Tm 1202:Er 1199:Ho 1196:Dy 1193:Tb 1190:Gd 1187:Eu 1184:Sm 1181:Pm 1178:Nd 1175:Pr 1172:Ce 1169:La 1154:Og 1151:Ts 1148:Lv 1145:Mc 1142:Fl 1139:Nh 1136:Cn 1133:Rg 1130:Ds 1127:Mt 1124:Hs 1121:Bh 1118:Sg 1115:Db 1112:Rf 1109:Lr 1106:** 1103:Ra 1100:Fr 1095:Rn 1092:At 1089:Po 1086:Bi 1083:Pb 1080:Tl 1077:Hg 1074:Au 1071:Pt 1068:Ir 1065:Os 1062:Re 1056:Ta 1053:Hf 1050:Lu 1044:Ba 1041:Cs 1036:Xe 1030:Te 1027:Sb 1024:Sn 1021:In 1018:Cd 1006:AgS 989:Pd 986:Rh 983:Ru 980:Tc 977:Mo 974:Nb 971:Zr 963:Sr 960:Rb 955:Kr 952:Br 949:Se 946:As 943:Ge 940:Ga 937:Zn 934:Cu 931:Ni 928:Co 925:Fe 922:Mn 919:Cr 913:Ti 910:Sc 905:Ca 873:Ar 870:Cl 847:(SO 839:Si 836:Al 833:Mg 810:Ne 784:(NH 773:Be 770:Li 765:He 716:ion 666:doi 635:doi 631:330 584:doi 549:doi 545:165 454:is 394:), 382:(Na 161:CID 1334:: 1225:U 1166:* 1059:W 1047:* 1033:I 1000:20 996:20 968:Y 916:V 857:(S 842:P 817:Na 807:F 804:O 779:C 776:B 734:SO 662:62 660:. 656:. 629:. 608:}} 604:{{ 590:. 557:. 543:. 539:. 525:^ 446:, 398:(K 364:SO 1320:e 1313:t 1306:v 1295:. 1012:8 1010:O 1008:2 1004:4 1002:N 998:H 994:C 899:8 897:O 895:2 893:S 891:2 889:K 882:5 865:) 863:8 861:O 859:2 851:) 849:5 827:8 825:O 823:2 821:S 819:2 798:8 796:O 794:2 792:S 790:2 788:) 786:4 753:8 751:O 749:2 747:S 745:2 743:H 736:5 732:2 730:H 705:e 698:t 691:v 674:. 668:: 641:. 637:: 614:) 600:. 586:: 565:. 551:: 428:8 426:O 424:2 422:S 420:2 418:) 416:4 408:8 406:O 404:2 402:S 400:2 392:8 390:O 388:2 386:S 384:2 369:5 340:8 335:O 331:2 326:S 268:2 265:S 262:8 259:O 97:)

Index



CAS Number
15092-81-6
JSmol
Interactive image
ChEBI
CHEBI:29267
ChemSpider
97014
PubChem
107879
UNII
1SQ1481FEQ
InChI
SMILES
Chemical formula
Molar mass
Conjugate acid
Peroxydisulfuric acid
standard state
Infobox references
oxyanion
peroxydisulfuric acid
persulfate
peroxomonosulfate
sodium persulfate
potassium persulfate
ammonium persulfate
alkenes

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