24:
230:
137:
23:
269:
997:
1092:
1077:
1006:
244:
795:"Trimethylgallium adsorbed on silica and its reaction with phosphine, arsine, and hydrogen chloride: an infrared and Raman study"
757:"The Dissociation Pressures of Ammonium- and Tetramethylammonium Halides and of Phosphonium Iodide and Phosphorus Pentachloride"
1082:
961:
Sequeira, A.; Hamilton, Walter C. (September 1967). "Hydrogen
Bonding in Phosphonium Iodide: A Neutron-Diffraction Study".
187:
208:
430:
144:
838:
Complexes, Heterocycles, and
Depolymerizable Polymers. Made from Building Blocks with Low-coordinated Phosphorus
883:
610:
487:
132:
707:
Phosphonium iodide is a powerful substitution reagent in organic chemistry; for example, it can convert a
94:
36:
1037:
970:
836:
225:
648:
60:
1053:
999:
Design and optimization of luminescent semiconductor nanocrystals for optoelectronic applications
814:
563:
353:
1087:
1045:
978:
943:
912:
850:
842:
806:
768:
618:
571:
389:
368:
336:
292:
114:
196:
70:
720:
614:
647:
Phosphine gas may be devolved from phosphonium iodide by mixing an aqueous solution with
229:
136:
1041:
974:
424:
511:) with elemental phosphorus and water at 80 °C and allowing the salt to sublime.
1071:
1057:
570:
crystal structure; the unit cell has approximate dimensions 634×634×462 pm. The
325:
125:
1049:
907:
Work, J. B.; Mattern, J. A.; Antonucci, R. (5 January 2007). "Phosphonium Iodide".
794:
756:
406:
176:
712:
622:
459:
916:
854:
626:
606:
559:
359:
315:
105:
1028:
Osadchenko, Ivan M; Tomilov, Andrei P (30 June 1969). "Phosphorus
Hydrides".
846:
818:
475:
708:
947:
810:
772:
678:
163:
145:
982:
674:
478:
and as a reagent for substituting phosphorus into organic molecules.
931:
423:
Except where otherwise noted, data are given for materials in their
93:
83:
681:
in a nonpolar solution to give phosphorus halides; for example:
586:
cations to orient such that the hydrogen atoms point toward the
715:
via substitution. In 1951, Glenn
Halstead Brown found that PH
213:
605:
At 62 °C and atmospheric pressure, phosphonium iodide
458:. It is an example of a salt containing an unsubstituted
755:
Smith, Alexander.; Calvert, Robert Peyton. (July 1914).
562:
space group P4/nmm, which is a distorted version of the
474:). Phosphonium iodide is commonly used as storage for
723:
to produce an unknown phosphine derivative, possibly
617:(HI). It oxidizes slowly in air to give iodine and
793:Morrow, B. A.; McFarlane, Richard A. (July 1986).
175:
69:
330:62 °C (144 °F; 335 K) Sublimes
932:"The Crystal Structure of Phosphonium Iodide"
885:Reactions of phosphine and phosphonium iodide
8:
750:
748:
228:
135:
113:
15:
486:Phosphonium iodide is prepared by mixing
195:
936:Journal of the American Chemical Society
761:Journal of the American Chemical Society
730:
726:
699:
695:
691:
687:
665:
661:
657:
639:
635:
541:
537:
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445:is a chemical compound with the formula
830:
828:
744:
274:
249:
224:
877:
875:
873:
871:
126:
256:Key: LSMAIBOZUPTNBR-UHFFFAOYSA-N
7:
166:
930:Dickinson, Roscoe G. (July 1922).
841:(Thesis). ETH Zurich. p. 18.
14:
799:The Journal of Physical Chemistry
1007:University of Erlangen–Nuremberg
320:161.910 g/mol
22:
1050:10.1070/RC1969v038n06ABEH001756
963:The Journal of Chemical Physics
427:(at 25 °C , 100 kPa).
1093:Reagents for organic chemistry
1078:Inorganic phosphorus compounds
882:Brown, Glenn Halstead (1951).
613:reversibly into phosphine and
558:Its crystal structure has the
1:
1109:
917:10.1002/9780470132333.ch41
378: = 6.34 Å,
888:(PhD). Iowa State College
673:It reacts with elemental
574:in the system causes the
421:
346:
285:
265:
240:
53:
45:
35:
30:
21:
1030:Russian Chemical Reviews
996:Levchuk, Ievgen (2017).
847:10.3929/ethz-b-000431853
488:diphosphorus tetraiodide
382: = 4.62 Å
629:into phosphine and HI:
253:InChI=1S/HI.H3P/h1H;1H3
1083:Phosphonium compounds
1042:1969RuCRv..38..495O
975:1967JChPh..47.1818S
948:10.1021/ja01428a015
909:Inorganic Syntheses
855:20.500.11850/431853
835:Mei, Yanbo (2020).
811:10.1021/j100405a029
773:10.1021/ja02184a003
649:potassium hydroxide
337:Solubility in water
18:
17:Phosphonium iodide
443:Phosphonium iodide
431:Infobox references
40:Phosphanium iodide
16:
983:10.1063/1.1712171
805:(14): 3192–3197.
619:phosphorus oxides
439:Chemical compound
437:
436:
354:Crystal structure
209:CompTox Dashboard
95:Interactive image
1100:
1062:
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1025:
1019:
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1016:
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969:(5): 1818–1822.
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767:(7): 1363–1382.
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572:hydrogen bonding
544:
510:
509:
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369:Lattice constant
309:
307:
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293:Chemical formula
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179:
168:
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139:
128:
117:
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73:
48:Iodine phosphide
26:
19:
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721:acetyl chloride
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615:hydrogen iodide
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1036:(6): 495–504.
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824:
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719:I reacts with
716:
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660:I + KOH → PH
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390:Lattice volume
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1009:. p. 140
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407:Formula units
404:
403:
400:185.7 Å
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1011:. Retrieved
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890:. Retrieved
884:
858:. Retrieved
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788:
776:. Retrieved
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379:
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54:Identifiers
46:Other names
1005:(faculty).
911:: 141–144.
713:phosphinine
623:hygroscopic
611:dissociates
532:O → 40 PH
482:Preparation
460:phosphonium
342:decomposes
286:Properties
133:100.031.978
1072:Categories
739:References
627:hydrolyzed
607:sublimates
560:tetragonal
549:Properties
360:Tetragonal
347:Structure
316:Molar mass
197:70782D13AF
106:ChemSpider
82:3D model (
71:12125-09-6
61:CAS Number
37:IUPAC name
1058:250872306
860:6 October
819:0022-3654
778:6 October
554:Structure
476:phosphine
362:(P4/nmm)
154:235-189-0
146:EC Number
733:·HI
729:C(=PH)PH
709:pyrilium
664:+ KI + H
638:I ⇌ PH
621:; it is
601:Chemical
597:anions.
536:I + 32 H
462:cation (
1088:Iodides
1038:Bibcode
971:Bibcode
711:into a
679:bromine
625:and is
528:+ 128 H
310:
164:PubChem
1056:
817:
690:I + 5I
675:iodine
524:+ 13 P
270:SMILES
177:166618
115:145802
31:Names
1054:S2CID
1013:6 Oct
1003:(PDF)
892:5 Oct
702:+ 8HI
245:InChI
84:JSmol
1015:2020
894:2020
862:2020
815:ISSN
780:2020
694:→ P
677:and
642:+ HI
609:and
516:10 P
188:UNII
1046:doi
979:doi
944:doi
913:doi
851:hdl
843:doi
807:doi
769:doi
686:2PH
214:EPA
167:CID
1074::
1052:.
1044:.
1034:38
1032:.
977:.
967:47
965:.
940:44
938:.
934:.
870:^
849:.
827:^
813:.
803:90
801:.
797:.
765:36
763:.
759:.
747:^
735:.
725:CH
656:PH
651::
634:PH
576:PH
568:Cl
564:NH
540:PO
464:PH
447:PH
417:2
299:PH
1060:.
1048::
1040::
1017:.
985:.
981::
973::
950:.
946::
919:.
915::
896:.
864:.
853::
845::
821:.
809::
782:.
771::
731:2
727:3
717:4
700:4
698:I
696:2
692:2
688:4
668:O
666:2
662:3
658:4
640:3
636:4
588:I
581:4
566:4
542:4
538:3
534:4
530:2
526:4
522:4
520:I
518:2
506:4
501:I
497:2
492:P
490:(
469:4
456:I
452:4
413:)
411:Z
409:(
396:)
394:V
392:(
380:c
376:a
308:I
304:4
277:.
216:)
212:(
86:)
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