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Directive 2001/59/EC of 6 August 2001 adapting to technical progress for the 28th time Council Directive 67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous
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These risk phrases are used internationally, not just in Europe, and there is an ongoing effort towards complete international harmonization using the
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48:. The list was consolidated and republished in Directive 2001/59/EC, where translations into other EU languages may be found.
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Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
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Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
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Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
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Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
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Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
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Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
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Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
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Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
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Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
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Harmful: possible risk of irreversible effects through inhalation and in contact with skin
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Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
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Missing R-numbers indicate phrases that have been deleted or replaced by other phrases.
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Harmful: danger of serious damage to health by prolonged exposure in contact with skin
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Toxic: danger of very serious irreversible effects through inhalation and if swallowed
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Harmful: possible risk of irreversible effects in contact with skin and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure in contact with skin
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Harmful: danger of serious damage to health by prolonged exposure through inhalation
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Harmful: possible risk of irreversible effects through inhalation and if swallowed
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Toxic: danger of serious damage to health by prolonged exposure through inhalation
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Extreme risk of explosion by shock, friction, fire, or other sources of ignition
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Harmful: danger of serious damage to health by prolonged exposure if swallowed
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Toxic: danger of serious damage to health by prolonged exposure if swallowed
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Very Toxic: danger of very serious irreversible effects in contact with skin
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Very Toxic: danger of very serious irreversible effects through inhalation
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Nature of special risks attributed to dangerous substances and preparations
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Reacts violently with water, liberating toxic, extremely flammable gases
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Risk of explosion by shock, friction, fire, or other sources of ignition
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Toxic: danger of very serious irreversible effects in contact with skin
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Globally
Harmonized System of Classification and Labelling of Chemicals
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Toxic: danger of very serious irreversible effects through inhalation
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Very Toxic: danger of very serious irreversible effects if swallowed
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Harmful: possible risk of irreversible effects in contact with skin
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Harmful: possible risk of irreversible effects through inhalation
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Reacts violently with water, liberating extremely flammable gases
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Toxic: danger of very serious irreversible effects if swallowed
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Very toxic by inhalation, in contact with skin and if swallowed
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Standardised phrases specifying risks associated with substances
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May cause long-term adverse effects in the aquatic environment
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Contact with water liberates toxic, extremely flammable gases
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Harmful by inhalation, in contact with skin and if swallowed
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Chemical Risk & Safety
Phrases. in 23 European Languages
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Harmful: possible risk of irreversible effects if swallowed
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Toxic by inhalation, in contact with skin and if swallowed
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Danger of serious damage to health by prolonged exposure
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In use, may form flammable/explosive vapour-air mixture
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May cause sensitization by inhalation and skin contact
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May cause long-term adverse effects in the environment
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Contact with water liberates extremely flammable gases
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Repeated exposure may cause skin dryness or cracking
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104:Forms very sensitive explosive metallic compounds
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136:Contact with combustible material may cause fire
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649:Harmful by inhalation and in contact with skin
192:Explosive when mixed with oxidising substances
144:Explosive when mixed with combustible material
897:May cause cancer and heritable genetic damage
673:Harmful in contact with skin and if swallowed
416:Risk of explosion if heated under confinement
1191:Regulation of chemicals in the European Union
681:Toxic by inhalation and in contact with skin
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705:Toxic in contact with skin and if swallowed
576:Harmful: may cause lung damage if swallowed
376:Danger of very serious irreversible effects
320:Contact with acids liberates very toxic gas
592:Vapours may cause drowsiness and dizziness
120:Explosive with or without contact with air
769:Irritating to respiratory system and skin
745:Irritating to eyes and respiratory system
721:Very toxic by inhalation and if swallowed
560:Possible risk of harm to the unborn child
384:Limited evidence of a carcinogenic effect
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600:Possible risk of irreversible effects
400:May cause sensitisation by inhalation
689:Toxic by inhalation and if swallowed
7:
1104:: Extremely flammable liquefied gas.
552:Possible risk of impaired fertility
432:May cause heritable genetic damage.
568:May cause harm to breastfed babies
544:May cause harm to the unborn child
304:Can become highly flammable in use
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360:Irritating to respiratory system
456:Very toxic to aquatic organisms
280:Very toxic in contact with skin
448:May cause cancer by inhalation
392:Risk of serious damage to eyes
200:Spontaneously flammable in air
112:Heating may cause an explosion
1181:Occupational safety and health
528:Dangerous for the ozone layer
37:) are defined in Annex III of
1:
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328:Danger of cumulative effects
232:Harmful in contact with skin
216:May form explosive peroxides
753:Irritating to eyes and skin
176:Reacts violently with water
464:Toxic to aquatic organisms
256:Toxic in contact with skin
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1126:Material safety data sheet
1110:: May cause birth defects.
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168:Extremely flammable
42:Directive 67/548/EEC
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80:Explosive when dry
18:R7: May cause fire
1121:List of S-phrases
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1151:substances
1137:References
1078:R68/21/22
1070:R68/20/22
1062:R68/20/21
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617:Statement
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1115:See also
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