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Rubidium superoxide

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Labhart, M.; Raoux, D.; Känzig, W.; Bösch, M. A. (1979-07-01). "Magnetic order in 2p-electron systems: Electron paramagnetic resonance and antiferromagnetic resonance in the alkali hyperoxides KO
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Astuti, Fahmi; Miyajima, Mizuki; Fukuda, Takahito; Kodani, Masashi; Nakano, Takehito; Kambe, Takashi; Watanabe, Isao (2019). "Synthesis and Characterization of Magnetic Rubidium Superoxide, RbO
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Kováčik, Roman; Werner, Philipp; Dymkowski, Krzysztof; Ederer, Claude (2012-08-17). "Rubidium superoxide: A p-electron Mott insulator".
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Vol'nov, I. I.; Dobrolyubova, M. S.; Tsentsiper, A. B. (1966). "Synthesis of rubidium ozonide via rubidium superoxide".
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Kováčik, Roman; Ederer, Claude (2009-10-26). "Correlation effects in p-electron magnets: Electronic structure of RbO
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Busch, G.; Strässler, S., eds. (1974). "Magnetische und kalorische Eigenschaften von Alkali-Hyperoxid-Kristallen".
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Kraus, D. L.; Petrocelli, A. W. (1962). "The Thermal Decomposition of Rubidium Superoxide".
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The compound has been studied as an example of magnetism arising intrinsically from the
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Bulletin of the Academy of Sciences, USSR Division of Chemical Science
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Except where otherwise noted, data are given for materials in their
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and positively charged rubidium give it a structural formula of
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Between 280 and 360 Â°C, Rubidium superoxide will
415:hyperoxides, crystals can also be grown in liquid 705:(7). American Chemical Society (ACS): 1225–1227. 812:(14). American Physical Society (APS): 140411. 385:It can be created by slowly exposing elemental 50: 857:(7). American Physical Society (APS): 075130. 515:has a crystal structure similar to tetragonal 906: 665:(1). American Physical Society (APS): 53–70. 640: 638: 636: 634: 8: 692: 690: 688: 482:An even more oxygen rich compound, that of 913: 899: 891: 611:. Trans Tech Publications, Ltd.: 237–242. 107: 15: 862: 817: 557:. At low temperatures, it transitions to 1186: 1182: 546: 528: 511: 496: 489: 474: 470: 466: 462: 452: 448: 437: 433: 403: 399: 372: 357: 225: 179: 591: 532:is stable in dry air, but is extremely 153: 128: 103: 617:10.4028/www.scientific.net/msf.966.237 519:, but is rather distorted due to the 135:Key: AFEOXRVICKHWAE-UHFFFAOYSA-N 7: 14: 699:The Journal of Physical Chemistry 325:(at 25 Â°C , 100 kPa). 1: 734:Physics of Condensed Matter 550:has been predicted to be a 132:InChI=1S/O2.Rb/c1-2;/q-1;+1 1231: 873:10.1103/physrevb.86.075130 828:10.1103/physrevb.80.140411 928: 742:10.1007/978-3-662-39595-0 365:, the negatively charged 319: 234: 208: 164: 144: 119: 34: 26: 21: 804:from first principles". 605:Materials Science Forum 493:) can be created using 671:10.1103/physrevb.20.53 575:Rubidium sesquioxide 428:rubidium sesquioxide 301:Rubidium sesquioxide 262:Potassium superoxide 17:Rubidium superoxide 711:10.1021/j100813a003 345:rubidium hyperoxide 341:Rubidium superoxide 196: g·mol 29:Rubidium hyperoxide 18: 1210:Rubidium compounds 922:Rubidium compounds 779:10.1007/bf00848934 521:Jahn–Teller effect 508:Roughly speaking, 329:Infobox references 267:Caesium superoxide 252:Lithium superoxide 235:Related compounds 16: 1197: 1196: 851:Physical Review B 806:Physical Review B 751:978-3-662-38713-9 659:Physical Review B 559:antiferromagnetic 443:rubidium peroxide 349:chemical compound 337:Chemical compound 335: 334: 306:Rubidium peroxide 291:Rubidium suboxide 257:Sodium superoxide 216:Crystal structure 88:CompTox Dashboard 76:Interactive image 1222: 1189: 915: 908: 901: 892: 885: 884: 866: 846: 840: 839: 821: 797: 791: 790: 762: 756: 755: 729: 723: 722: 694: 683: 682: 642: 629: 628: 596: 563:Neel temperature 549: 531: 514: 499: 492: 484:rubidium ozonide 478: 455: 440: 407: 376: 363:oxidation states 360: 353:chemical formula 311:Rubidium ozonide 228: 195: 182: 172:Chemical formula 112: 111: 96: 94: 78: 54: 19: 1230: 1229: 1225: 1224: 1223: 1221: 1220: 1219: 1200: 1199: 1198: 1193: 1188: 1184: 1180: 1175: 1167: 1163: 1155: 1151: 1143: 1139: 1135: 1127: 1119: 1110: 1101: 1092: 1084: 1080: 1072: 1064: 1060: 1051: 1043: 1039: 1035: 1027: 1023: 1010: 1002: 994: 981: 963: 940: 936: 924: 919: 889: 888: 848: 847: 843: 803: 799: 798: 794: 764: 763: 759: 752: 731: 730: 726: 696: 695: 686: 656: 652: 648: 644: 643: 632: 602: 598: 597: 593: 588: 571: 548: 544: 530: 526: 517:calcium carbide 513: 509: 506: 498: 494: 491: 487: 476: 472: 468: 464: 460: 454: 450: 446: 439: 435: 431: 405: 401: 397: 383: 374: 370: 359: 355: 338: 331: 326: 315: 284: 271: 245: 227: 223: 218: 193: 181: 177: 174: 160: 157: 152: 151: 140: 137: 136: 133: 127: 126: 115: 105:DTXSID201315494 97: 90: 81: 68: 57: 44: 30: 12: 11: 5: 1228: 1226: 1218: 1217: 1212: 1202: 1201: 1195: 1194: 1192: 1191: 1177: 1173: 1169: 1165: 1161: 1157: 1153: 1149: 1145: 1141: 1137: 1133: 1129: 1125: 1121: 1117: 1113: 1108: 1104: 1099: 1095: 1090: 1086: 1082: 1078: 1074: 1070: 1066: 1062: 1058: 1054: 1049: 1045: 1041: 1037: 1033: 1029: 1025: 1021: 1017: 1012: 1008: 1004: 1000: 996: 992: 988: 983: 979: 975: 970: 965: 961: 957: 952: 947: 942: 938: 934: 929: 926: 925: 920: 918: 917: 910: 903: 895: 887: 886: 841: 801: 792: 757: 750: 724: 684: 654: 650: 646: 630: 600: 590: 589: 587: 584: 583: 582: 580:Rubidium oxide 577: 570: 567: 561:order, with a 555:Mott insulator 505: 502: 480: 479: 441:), but rather 426:, leaving not 409: 408: 382: 379: 361:. In terms of 336: 333: 332: 327: 323:standard state 320: 317: 316: 314: 313: 308: 303: 298: 296:Rubidium oxide 293: 287: 285: 276: 273: 272: 270: 269: 264: 259: 254: 248: 246: 240: 237: 236: 232: 231: 219: 214: 211: 210: 206: 205: 204:Bright yellow 202: 198: 197: 191: 185: 184: 175: 170: 167: 166: 162: 161: 159: 158: 155: 147: 146: 145: 142: 141: 139: 138: 134: 131: 130: 122: 121: 120: 117: 116: 114: 113: 100: 98: 86: 83: 82: 80: 79: 71: 69: 62: 59: 58: 56: 55: 47: 45: 40: 37: 36: 32: 31: 28: 24: 23: 13: 10: 9: 6: 4: 3: 2: 1227: 1216: 1213: 1211: 1208: 1207: 1205: 1190: 1178: 1176: 1170: 1168: 1158: 1156: 1146: 1144: 1130: 1128: 1122: 1120: 1114: 1112: 1105: 1103: 1096: 1094: 1087: 1085: 1075: 1073: 1067: 1065: 1055: 1053: 1046: 1044: 1030: 1028: 1018: 1016: 1013: 1011: 1005: 1003: 997: 995: 989: 987: 984: 982: 976: 974: 971: 969: 966: 964: 958: 956: 953: 951: 948: 946: 943: 941: 931: 930: 927: 923: 916: 911: 909: 904: 902: 897: 896: 893: 882: 878: 874: 870: 865: 860: 856: 852: 845: 842: 837: 833: 829: 825: 820: 815: 811: 807: 796: 793: 788: 784: 780: 776: 772: 768: 761: 758: 753: 747: 743: 739: 735: 728: 725: 720: 716: 712: 708: 704: 700: 693: 691: 689: 685: 680: 676: 672: 668: 664: 660: 641: 639: 637: 635: 631: 626: 622: 618: 614: 610: 606: 595: 592: 585: 581: 578: 576: 573: 572: 568: 566: 564: 560: 556: 553: 542: 537: 535: 524: 522: 518: 503: 501: 485: 459: 458: 457: 444: 429: 425: 420: 418: 414: 396: 395: 394: 392: 388: 380: 378: 368: 364: 354: 350: 346: 342: 330: 324: 318: 312: 309: 307: 304: 302: 299: 297: 294: 292: 289: 288: 286: 283: 280: 275: 274: 268: 265: 263: 260: 258: 255: 253: 250: 249: 247: 244: 239: 238: 233: 229: 220: 217: 213: 212: 207: 203: 200: 199: 192: 190: 187: 186: 176: 173: 169: 168: 163: 154: 150: 143: 129: 125: 118: 110: 106: 102: 101: 99: 89: 85: 84: 77: 73: 72: 70: 66: 61: 60: 53: 49: 48: 46: 43: 39: 38: 33: 25: 20: 1068: 854: 850: 844: 809: 805: 795: 770: 766: 760: 733: 727: 702: 698: 662: 658: 608: 604: 594: 552:paramagnetic 538: 525: 507: 481: 421: 413:alkali metal 410: 384: 344: 340: 339: 35:Identifiers 27:Other names 1215:Superoxides 534:hygroscopic 411:Like other 201:Appearance 165:Properties 1204:Categories 586:References 504:Properties 367:superoxide 230:structure 221:Distorted 209:Structure 189:Molar mass 63:3D model ( 52:12137-25-6 42:CAS Number 881:1098-0121 864:1206.1423 836:1098-0121 819:0905.3721 787:0568-5230 719:0022-3654 679:0163-1829 653:, and CsO 625:1662-9752 565:of 15 K. 424:decompose 402:(g) → RbO 398:Rb(s) + O 381:Chemistry 351:with the 569:See also 465:(s) → Rb 387:rubidium 371:Rb[O 279:rubidium 277:Related 541:p-shell 473:(s) + O 417:ammonia 243:cations 194:117.466 183: 879:  834:  785:  748:  717:  677:  623:  391:oxygen 282:oxides 241:Other 149:SMILES 22:Names 1172:RbGeI 1124:RbTcO 1116:RbMnO 978:RbHSO 960:RbClO 859:arXiv 814:arXiv 649:, RbO 461:2 RbO 393:gas: 347:is a 124:InChI 65:JSmol 1015:RbOH 1007:RbNO 955:RbCN 950:RbCl 945:RbBr 933:RbAg 877:ISSN 832:ISSN 783:ISSN 746:ISBN 715:ISSN 675:ISSN 621:ISSN 1185:TiF 1164:SeO 1152:AsO 1132:RbC 1069:RbO 999:RbN 991:RbI 986:RbI 973:RbH 968:RbF 869:doi 824:doi 775:doi 738:doi 707:doi 667:doi 657:". 613:doi 609:966 603:". 545:RbO 527:RbO 510:RbO 495:RbO 488:RbO 477:(g) 456:). 406:(s) 389:to 356:RbO 343:or 224:CaC 178:RbO 156:O=. 93:EPA 1206:: 1181:Rb 1160:Rb 1148:Rb 1111:Te 1107:Rb 1102:Se 1098:Rb 1089:Rb 1081:SO 1077:Rb 1057:Rb 1048:Rb 1032:Rb 1024:CO 1020:Rb 875:. 867:. 855:86 853:. 830:. 822:. 810:80 808:. 781:. 771:15 769:. 744:. 713:. 703:66 701:. 687:^ 673:. 663:20 661:. 633:^ 619:. 607:. 543:. 536:. 500:. 447:Rb 432:Rb 419:. 377:. 1187:6 1183:2 1174:3 1166:4 1162:2 1154:4 1150:3 1142:2 1140:O 1138:3 1136:H 1134:2 1126:4 1118:4 1109:2 1100:2 1093:S 1091:2 1083:4 1079:2 1071:2 1063:2 1061:O 1059:2 1052:O 1050:2 1042:4 1040:O 1038:2 1036:C 1034:2 1026:3 1022:2 1009:3 1001:3 993:3 980:4 962:4 939:5 937:I 935:4 914:e 907:t 900:v 883:. 871:: 861:: 838:. 826:: 816:: 802:2 789:. 777:: 754:. 740:: 721:. 709:: 681:. 669:: 655:2 651:2 647:2 627:. 615:: 601:2 547:2 529:2 512:2 497:2 490:3 486:( 475:2 471:2 469:O 467:2 463:2 453:2 451:O 449:2 445:( 438:3 436:O 434:2 430:( 404:2 400:2 375:] 373:2 358:2 226:2 180:2 95:) 91:( 67:)

Index

CAS Number
12137-25-6
JSmol
Interactive image
CompTox Dashboard
DTXSID201315494
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InChI
SMILES
Chemical formula
Molar mass
Crystal structure
CaC2
cations
Lithium superoxide
Sodium superoxide
Potassium superoxide
Caesium superoxide
rubidium
oxides
Rubidium suboxide
Rubidium oxide
Rubidium sesquioxide
Rubidium peroxide
Rubidium ozonide
standard state
Infobox references
chemical compound
chemical formula
oxidation states

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