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Refractory

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dimension of 9 in × 4.5 in × 2.5 in (229 mm × 114 mm × 64 mm) and this dimension is called a "one brick equivalent". "Brick equivalents" are used in estimating how many refractory bricks it takes to make an installation into an industrial furnace. There are ranges of standard shapes of different sizes manufactured to produce walls, roofs, arches, tubes and circular apertures etc. Special shapes are specifically made for specific locations within furnaces and for particular kilns or furnaces. Special shapes are usually less dense and therefore less hard wearing than standard shapes.
504:). They are acidic, have high resistance to thermal shock, flux and slag resistance, and high spalling resistance. Silica bricks are often used in the iron and steel industry as furnace materials. An important property of silica brick is its ability to maintain hardness under high loads until its fusion point. Silica refractories are usually cheaper hence easily disposable. New technologies that provide higher strength and more casting duration with less silicon oxide (90%) when mixed with organic resins have been developed. 38: 388: 836:
Insulating refractories are used to reduce the rate of heat loss through furnace walls. These refractories have low thermal conductivity due to a high degree of porosity, with a desired porous structure of small, uniform pores evenly distributed throughout the refractory brick in order to minimize
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Refractory objects are manufactured in standard shapes and special shapes. Standard shapes have dimensions that conform to conventions used by refractory manufacturers and are generally applicable to kilns or furnaces of the same types. Standard shapes are usually bricks that have a standard
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linings are also monolithic, and sold and transported as a dry powder, usually with a magnesia/alumina composition with additions of other chemicals for altering specific properties. They are also finding more applications in blast furnace linings, although this use is still rare.
370:. Refractories have other high temperature applications such as fired heaters, hydrogen reformers, ammonia primary and secondary reformers, cracking furnaces, utility boilers, catalytic cracking units, air heaters, and sulfur furnaces. They are used for surfacing 518:). They are often used for glass furnaces because they have low thermal conductivity, are not easily wetted by molten glass and have low reactivity with molten glass. These refractories are also useful for applications in high temperature construction materials. 178:
C71 as "non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above 1,000 °F (811 K; 538 °C)". Refractory materials are used in
561:). The main raw materials belong to the RO group, of which magnesia (MgO) is a common example. Other examples include dolomite and chrome-magnesia. For the first half of the twentieth century, the steel making process used artificial 365:
Refractories have multiple useful applications. In the metallurgy industry, refractories are used for lining furnaces, kilns, reactors, and other vessels which hold and transport hot media such as metal and
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Acidic refractories are generally impervious to acidic materials but easily attacked by basic materials, and are thus used with acidic slag in acidic environments. They include substances such as
580:(MgO). They have high slag resistance to lime and iron-rich slags, strong abrasion and corrosion resistance, and high refractoriness under load, and are typically used in metallurgical furnaces. 617:
These are used in areas where slags and atmosphere are either acidic or basic and are chemically stable to both acids and bases. The main raw materials belong to, but are not confined to, the R
1058: 660:. These refractories are often used in highly reducing environments, and their properties of high refractoriness allow them excellent thermal stability and resistance to slags. 549:
Basic refractories are used in areas where slags and atmosphere are basic. They are stable to alkaline materials but can react to acids, which is important e. g. when removing
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These are without prescribed form and are only given shape upon application. These types are known as monolithic refractories. Common examples include plastic masses,
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Refractoriness is the property of a refractory's multiphase to reach a specific softening degree at high temperature without load, and is measured with a
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brick refractories. Notable reagents that can attack both alumina and silica are hydrofluoric acid, phosphoric acid, and fluorinated gases (e.g. HF, F
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Refractory materials must be chemically and physically stable at high temperatures. Depending on the operating environment, they must be resistant to
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are composed of sintered magnesia and chromia. They have constant volume at high temperatures, high refractoriness, and high resistance to slags.
1147: 1095: 262:) are the most important materials used in the manufacturing of refractories. Another oxide usually found in refractories is the oxide of 1068: 1008: 427: 1291: 1224:"Refractory Materials for Flame Deflector Protection System Corrosion Control: Similar Industries and/or Launch Facilities Survey" 1178: 293:) are two other refractory materials used in some very severe temperature conditions, but they cannot be used in contact with 1341: 409: 277:
Refractories must be chosen according to the conditions they face. Some applications require special refractory materials.
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McGraw-Hill encyclopedia of science and technology: an international reference work in fifteen volumes including an index
558: 1384: 1203: 587: 405: 31: 1394: 192: 398: 1120: 327: 825:(ZrC), whereas examples of nonconducting refractories are silica and alumina. Insulating refractories include 923: 540:). Aluminosilicate refractories can be semiacidic, fireclay composite, or high alumina content composite. 1223: 1037: 333: 180: 66: 1000: 814: 224: 724: 702:
Un-formed (monolithic-plastic, ramming and gunning mass, castables, mortars, dry vibrating cements.)
608:). These refractories have high refractoriness and have a high tolerance for corrosive environments. 638: 597: 316: 1379: 1271: 744: 204: 175: 102: 74: 37: 1143: 1091: 1085: 1064: 1004: 960: 822: 731: 511: 228: 200: 159: 50: 1024:
Sonntag, Kiss, Banhidi, Weber (2009). "New Kiln Furniture Solutions for Technical Ceramics".
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as either conducting, nonconducting, or insulating. Examples of conducting refractories are
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Withstanding physical stresses and preventing erosion of vessel walls due to the hot medium
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thermal conductivity. Insulating refractories can be further classified into four types:
489:). At high temperatures, acidic refractories may also react with limes and basic oxides. 626: 267: 1373: 1087:
Handbook of chemical vapor deposition (CVD): principles, technology, and applications
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Serving as a thermal barrier between a hot medium and the wall of a containing vessel
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and metal casting sectors use approximately 70% of all refractories produced.
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has one of the highest melting points of all known compounds (4215 °C).
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Fundamentals of Modern Manufacturing: Materials, Processes, and Systems
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are not considered refractory. Refractories are distinguished from the
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The Journal of the Southern African Institute of Mining and Metallurgy
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is used when the material must withstand extremely high temperatures.
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or chemical attack and that retains its strength and rigidity at high
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insulating materials with application temperatures ≤ 2000 °C
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insulating materials with application temperatures ≤ 1700 °C
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insulating materials with application temperatures ≤ 1400 °C
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insulating materials with application temperatures ≤ 1100 °C
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have a fusion temperature of 1580–1780 °C (e.g. fire clay)
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have a fusion temperature of > 2000 °C (e.g. zirconia)
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have a fusion temperature of 1780–2000 °C (e.g. chromite)
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Refractory materials are classified into three types based on
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Refractory materials are useful for the following functions:
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Materials resistant to decomposition under high temperatures
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has a high melting point of 2030 °C and is often used as a
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This article is about heat resistance. For other uses, see
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Vysokoglinozemistye keramicheskie i ogneupornye materialy
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are also widely used in the manufacture of refractories.
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Refractories are classified in multiple ways, based on:
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equivalent (PCE) test. Refractories are classified as:
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is the most refractory binary compound known, with a
949:Refractories; Activated Carbon, Advanced Ceramics 924:"Refractories and Classification of Refractories" 625:group. Common examples of these materials are 8: 1317:"Dolomite brick and magnesia dolomite brick" 1042:: CS1 maint: multiple names: authors list ( 901:. Oxford Paperbacks Oxford University Press. 596:mainly consist of magnesium oxide (MgO) and 918: 916: 914: 912: 910: 908: 699:Formed (normal, fired or chemically bonded) 1276:: CS1 maint: location missing publisher ( 1197: 1195: 496:are refractories containing more than 93% 428:Learn how and when to remove this message 1241:Aluminum Oxide, Al2O3 Ceramic Properties 897:Ailsa Allaby and Michael Allaby (1996). 889: 510:are refractories primarily composed of 1269: 1035: 378:Classification of refractory materials 993:Groover, Mikell P. (7 January 2010). 195:. Refractories are also used to make 171:that have high melting temperatures. 7: 961:"How cool are refractory materials?" 899:Concise Dictionary of Earth Sciences 730:Dry vibration linings often used in 410:adding citations to reliable sources 153:are not, and some ceramics such as 1142:. McGraw-Hill. 1977. p. 360. 813:Refractories may be classified by 203:for casting glass and metals. The 25: 1090:. William Andrew. pp. 206–. 672:are composed of ≥ 50% alumina (Al 223:, and/or have specific ranges of 105:. They are typically composed of 1127:, Los Alamos National Laboratory 569:) as a furnace lining material. 386: 1211:University of Technology - Iraq 397:needs additional citations for 1204:"Introduction to Refractories" 1063:. The Rosen Publishing Group. 374:in rocket launch structures. 1: 1262:Poluboiarinov, D. N. (1960). 1179:Encyclopædia Britannica, Inc. 654:Carbon graphite refractories 594:Magnesia-chrome refractories 522:Aluminosilicate refractories 361:Providing thermal insulation 358:Protecting against corrosion 174:Refractories are defined by 45:used for hauling molten iron 1026:Ceramic Forum International 705:Un-formed dry refractories. 588:calcium magnesium carbonate 117:of the following elements: 89:varies widely: they may be 32:Refractory (disambiguation) 1411: 227:and of the coefficient of 29: 1296:www.termorefractories.com 85:or non-porous, and their 1321:www.ruizhirefractory.com 1292:"Magnesite Refractories" 1084:Hugh O. Pierson (1992). 559:Gilchrist–Thomas process 328:tantalum hafnium carbide 315:can be very refractory. 145:. Many refractories are 1342:"Chromite Refractories" 1175:Encyclopædia Britannica 974:(September): 1–16. 2008 205:iron and steel industry 41:Refractory bricks in a 1123:11 August 2017 at the 576:are composed of ≥ 85% 574:Magnesite refractories 163:, which are elemental 81:compounds that may be 46: 1346:termorefractories.com 1001:John Wiley & Sons 860:Ultra-high refractory 719:Unshaped (monolithic) 685:Method of manufacture 664:Chromite refractories 584:Dolomite refractories 508:Zirconia refractories 447:Method of manufacture 334:Molybdenum disilicide 323:of 3890 °C. The 67:decomposition by heat 65:that is resistant to 40: 1390:Refractory materials 1226:. NASA, January 2009 815:thermal conductivity 809:Thermal conductivity 804:: PCE value of 19–28 798:: PCE value of 28–30 670:Alumina refractories 613:Neutral refractories 464:Chemical composition 459:Thermal conductivity 444:Chemical composition 406:improve this article 225:thermal conductivity 211:Refractory materials 1385:Chemical properties 1057:Roza, Greg (2009). 752:Normal refractories 494:Silica refractories 469:Acidic refractories 149:, but some such as 59:refractory material 947:ASTM Volume 15.01 792:PCE value of 30–33 786:PCE value of 33–38 764:Super refractories 745:fusion temperature 739:Fusion temperature 656:mainly consist of 586:mainly consist of 545:Basic refractories 524:mainly consist of 453:Fusion temperature 47: 18:Refractory ceramic 1395:Ceramic materials 1149:978-0-07-079590-7 1097:978-0-8155-1300-1 823:zirconium carbide 796:Intermediate duty 758:High refractories 747:(melting point). 732:induction furnace 690:Dry press process 536:) and silica (SiO 438: 437: 430: 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They are 43:torpedo car 1374:Categories 1182:Retrieved 884:References 873:Fire brick 848:Refractory 821:(SiC) and 790:High duty: 693:Fused cast 551:phosphorus 301:and burn. 272:Fire clays 167:and their 55:refractory 1380:Materials 1272:cite book 1266:. Moscow. 1171:"Hafnium" 1060:Zirconium 928:IspatGuru 567:magnesite 565:(roasted 563:periclase 483:fire clay 256:magnesium 240:aluminium 197:crucibles 143:zirconium 127:magnesium 123:aluminium 103:composite 99:amorphous 75:inorganic 1155:22 April 1121:Archived 1103:22 April 978:22 April 867:See also 802:Low duty 555:pig iron 307:such as 291:graphite 279:Zirconia 260:magnesia 193:reactors 181:furnaces 151:graphite 147:ceramics 139:chromium 115:nitrides 111:carbides 63:material 1351:6 March 1326:6 March 1301:6 March 1118:Hafnium 933:6 March 639:chromia 627:alumina 526:alumina 479:alumina 299:oxidize 264:calcium 248:silicon 244:alumina 131:calcium 119:silicon 61:) is a 1243:. 2013 1146:  1094:  1067:  1007:  831:kaolin 658:carbon 481:, and 475:silica 295:oxygen 287:carbon 254:) and 252:silica 236:oxides 191:, and 169:alloys 165:metals 107:oxides 83:porous 1207:(PDF) 964:(PDF) 557:(see 553:from 219:, be 201:molds 185:kilns 135:boron 101:, or 1353:2020 1328:2020 1303:2020 1278:link 1249:2014 1186:2010 1157:2011 1144:ISBN 1105:2011 1092:ISBN 1065:ISBN 1044:link 1005:ISBN 980:2016 935:2020 514:(ZrO 500:(SiO 368:slag 344:Uses 285:and 268:lime 234:The 199:and 176:ASTM 141:and 57:(or 53:, a 972:106 641:(Cr 637:), 629:(Al 600:(Cr 528:(Al 408:by 311:or 270:). 246:), 238:of 113:or 49:In 1376:: 1344:. 1319:. 1294:. 1274:}} 1270:{{ 1239:. 1209:. 1194:^ 1177:. 1173:. 1040:}} 1036:{{ 1030:86 1028:. 1003:. 999:. 970:. 966:. 926:. 907:^ 680:). 477:, 340:. 231:. 187:, 183:, 137:, 133:, 129:, 125:, 121:, 109:, 97:, 93:, 77:, 1355:. 1330:. 1305:. 1280:) 1251:. 1213:. 1188:. 1159:. 1107:. 1073:. 1046:) 1013:. 982:. 937:. 678:3 676:O 674:2 647:3 645:O 643:2 635:3 633:O 631:2 623:3 621:O 619:2 606:3 604:O 602:2 538:2 534:3 532:O 530:2 516:2 502:2 487:2 431:) 425:( 420:) 416:( 402:. 289:( 266:( 258:( 250:( 242:( 34:. 20:)

Index

Refractory ceramic
Refractory (disambiguation)

torpedo car
materials science
material
decomposition by heat
temperatures
inorganic
non-metallic
porous
crystallinity
crystalline
polycrystalline
amorphous
composite
oxides
carbides
nitrides
silicon
aluminium
magnesium
calcium
boron
chromium
zirconium
ceramics
graphite
clay pottery
refractory metals

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