62:
1709:
53:
1470:
names, are determined according to the substitutive and additive nomenclatures, respectively. The name sulfide is also used in compositional IUPAC nomenclature which does not take the nature of bonding involved. Examples of such naming include
712:
materials and most generally causes mass loss, cracking of the sewer pipes and ultimately, structural collapse. This kind of deterioration is a major process affecting sewer systems worldwide and leading to very high rehabilitation costs.
531:
sulfides typically have very low solubility in water, and many are related to minerals with the same composition (see below). One famous example is the bright yellow species CdS or "
674:
S, HS and S) are very aggressive species for the corrosion of many metals such as steel, stainless steel, and copper. Sulfides present in aqueous solution are responsible for
1741:
1467:
258:
543:
properties, which in turn is related to the deep colors. Several have practical applications as pigments, in solar cells, and as catalysts. The fungus
662:) of their surrounding environment during their formation. Scientists use these minerals to study environments in the deep sea or in the Earth's past.
539:
S. Such species are sometimes referred to as salts. In fact, the bonding in transition metal sulfides is highly covalent, which gives rise to their
1734:
708:
producing sulfide that is emitted in the air and oxidized in sulfuric acid by sulfur oxidizing bacteria. Biogenic sulfuric acid reacts with
1420:
Many metal sulfides are so insoluble in water that they are probably not very toxic. Some metal sulfides, when exposed to a strong mineral
1259:. The presence of the highly toxic selenium in healthcare and cosmetics products represents a general health and environmental concern.
1727:
1635:
1615:
745:
of steel and stainless steel while the medium is also acidified by the production of sulfuric acid when oxidation is more advanced.
233:
1046:, is used as a catalyst to remove sulfur from fossil fuels; also as lubricant for high-temperature and high-pressure applications.
87:
Sulfanediide (substitutive), not common, rarely used, sometimes generated by automated nomenclature software in organic chemistry
861:). Most often in sulfur chemistry and in biochemistry, the disulfide term is commonly ascribed to the sulfur analogue of the
1517:
360:
210:
394:
with the chemical formula S or a compound containing one or more S ions. Solutions of sulfide salts are corrosive.
2062:
701:
705:
675:
35:
1630:
Vaughan, D. J.; Craig, J. R. “Mineral chemistry of metal sulfides" Cambridge
University Press, Cambridge: 1978.
1224:
is a polymer commonly called "Sulfar". Its repeating units are bonded together by sulfide (thioether) linkages.
1191:. ZnS-doped with silver is used in alpha detectors while zinc sulfide with traces of copper has applications in
1188:
1446:
Hydrogen sulfide, some of its salts, and almost all organic sulfides have a strong and putrid stench; rotting
464:
of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur,
682:. Corrosion is a major concern in many industrial installations processing sulfides: sulfide ore mills, deep
679:
1965:
1252:
1221:
1150:
1085:
841:, or S–S dianion, in association with divalent iron in the formal +2 oxidation state (ferrous ion: Fe).
774:
399:
345:
80:
1235:
1231:
1125:
2067:
1713:
1292:
1267:
1203:
1162:
1053:
1039:
1026:
948:
923:
810:
1577:
Meyer, B; Ward, K; Koshlap, K; Peter, L (1983). "Second dissociation constant of hydrogen sulfide".
1097:
1001:
697:
384:
100:
469:
2052:
1472:
1248:
30:
This article is about sulfur anion in general. For the organic compound also called sulfide, see
2057:
1671:
1631:
1611:
1605:
1559:
1192:
842:
754:
742:
583:
545:
513:
1804:
1811:
1661:
1586:
1551:
1476:
1429:
989:
911:
854:
786:
762:
443:
407:
403:
278:
134:
219:
174:
110:
2047:
1542:
May, P.M.; Batka, D.; Hefter, G.; Könignberger, E.; Rowland, D. (2018). "Goodbye to S2-".
933:
818:
558:
380:
817:) consists of separated sulfide centers, in association with molybdenum in the formal +4
1499:
154:
1753:
1436:
1139:
1111:
1081:
532:
354:
312:
2041:
1750:
1176:
1143:
540:
1934:
1829:
1425:
1172:
1011:
914:
is a very toxic and corrosive gas characterised by a typical odour of "rotten egg".
643:
199:
1781:
1521:
1256:
1043:
961:
717:
691:
603:
595:
465:
1919:
1912:
627:
599:
299:
165:
1675:
1930:
1898:
1877:
1852:
1797:
1719:
1666:
1649:
1015:
969:
965:
937:
866:
806:
758:
571:
528:
415:
317:
31:
17:
1563:
1708:
785:
S. Occasionally, the term sulfide refers to molecules containing the –SH
2025:
2004:
1997:
1972:
1958:
1905:
1881:
1866:
1859:
1845:
1818:
1761:
1184:
862:
709:
683:
623:
619:
579:
341:
1590:
1435:
Organic sulfides are highly flammable. When a sulfide burns it produces
61:
2011:
1983:
1891:
1838:
1770:
1555:
1447:
957:
870:
659:
655:
615:
611:
516:
481:
477:
473:
186:
1088:(thioether) that was used as a chemical weapon in the First World War.
52:
2018:
1987:
1790:
1281:
1180:
1115:
874:
822:
651:
635:
607:
587:
575:
485:
391:
353:
Except where otherwise noted, data are given for materials in their
757:, "sulfide" usually refers to the linkage C–S–C, although the term
426:
The sulfide ion does not exist in aqueous alkaline solutions of Na
1944:
1146:
794:
793:–SH. The preferred descriptor for such SH-containing compounds is
564:
461:
337:
145:
133:
123:
1650:"Microbial Life Deep Under the Seafloor—A Story of Not Giving Up"
1421:
647:
639:
631:
591:
1723:
1693:(5th ed.). New York: W. H. Freeman & Co. p. 413.
741:), an intermediate species responsible for severe problems of
687:
567:
387:
331:
1305:
Sulfide compounds can be prepared in several different ways:
549:
plays a role in the solubilization of heavy metal sulfides.
60:
51:
1494:
1492:
857:
has no S–S bond, being S=C=S (linear molecule analog to CO
805:
Confusion arises from the different meanings of the term "
1195:
strips for emergency lighting and luminous watch dials.
869:
bond (–S–S–) plays a major role in the conformation of
797:
or mercaptan, i.e. methanethiol, or methyl mercaptan.
442:
Upon treatment with an acid, sulfide salts convert to
535:". The black tarnish formed on sterling silver is Ag
1982:
1929:
1876:
1828:
1780:
1760:
1504:Chemical Entities of Biological Interest (ChEBI)
198:
398:also refers to large families of inorganic and
109:
761:is less ambiguous. For example, the thioether
430:S. Instead sulfide converts to hydrosulfide:
1735:
1648:Tsang, Man-Yin; Inagaki, Fumio (2020-05-29).
8:
1255:used in anti-dandruff preparations, such as
1142:, as the hydrate, is used in manufacture of
570:are sulfides. Significant examples include:
1742:
1728:
1720:
884:
173:
40:
1665:
992:is a precursor to organosulfur compounds.
821:(that is, Mo and two S). Iron disulfide (
789:. For example, methyl sulfide can mean CH
418:(SH) are the conjugate acids of sulfide.
218:
1518:"SULFIDE English Definition and Meaning"
1506:. UK: European Bioinformatics Institute.
1405:
527:S) to precipitate solid sulfides. Such
85:Sulfide(2−) (additive), recommended name
1488:
1379:Precipitation of an insoluble sulfide:
777:(see below) has the empirical formula C
263:
238:
1610:. John Wiley & Sons. p. 509.
1607:Mycoremediation: Fungal Bioremediation
678:(SCC) of steel, and is also known as
245:Key: UCKMPCXJQFINFW-UHFFFAOYSA-N
153:
27:Ion, and compounds containing the ion
7:
1604:Harbhajan Singh (17 November 2006).
716:Oxidation of sulfide can also form
189:
25:
1479:, which contain no sulfide ions.
873:and in the catalytic activity of
1707:
1309:Direct combination of elements:
829:) on the other hand consists of
686:, pipelines transporting soured
1389:
1370:
357:(at 25 °C , 100 kPa).
1:
1397:
1362:
1354:
1346:
1331:
1323:
1315:
698:Microbially-induced corrosion
519:react with sulfide sources (H
1520:. Lexico.com. Archived from
666:Corrosion induced by sulfide
480:. Metal sulfides react with
1500:"sulfide(2−) (CHEBI:15138)"
845:has the chemical binding CH
658:recorded information (like
47:
2084:
702:biogenic sulfide corrosion
670:Dissolved free sulfides (H
556:
29:
1654:Frontiers for Young Minds
706:sulfate reducing bacteria
676:stress corrosion cracking
351:
323:
271:
254:
229:
93:
79:
74:
46:
36:Sulphide (disambiguation)
1689:Atkins; Shriver (2010).
1340:Reduction of a sulfate:
1280:Known as "fool's gold",
402:, e.g. lead sulfide and
1667:10.3389/frym.2020.00070
680:sulfide stress cracking
654:sulfide). This sulfide
1284:, is a common mineral.
1151:organosulfur compounds
1149:and as a precursor to
65:
56:
34:. For other uses, see
1458:The systematic names
1428:, will release toxic
1222:Polyphenylene sulfide
1086:organosulfur compound
775:Polyphenylene sulfide
512:Aqueous solutions of
492:8 MgS + 8 I
81:Systematic IUPAC name
64:
55:
1716:at Wikimedia Commons
1084:(mustard gas) is an
1040:Molybdenum disulfide
964:") is a traditional
811:Molybdenum disulfide
1691:Inorganic Chemistry
1591:10.1021/ic00158a027
1579:Inorganic Chemistry
704:are also caused by
422:Chemical properties
307: g·mol
43:
1556:10.1039/c8cc00187a
1473:selenium disulfide
1249:Selenium disulfide
1114:is a component of
896:Boiling point (°C)
893:Melting point (°C)
361:Infobox references
324:Related compounds
66:
57:
41:
2063:Functional groups
2035:
2034:
1712:Media related to
1550:(16): 1980–1983.
1524:on August 2, 2019
1298:
1297:
843:Dimethyldisulfide
755:organic chemistry
749:Organic chemistry
743:pitting corrosion
546:Aspergillus niger
514:transition metals
508:Metal derivatives
488:and metal salts.
400:organic compounds
369:Chemical compound
367:
366:
135:Interactive image
70:
69:
16:(Redirected from
2075:
2028:
2021:
2014:
2007:
2000:
1975:
1968:
1961:
1954:
1947:
1922:
1915:
1908:
1901:
1894:
1869:
1862:
1855:
1848:
1841:
1821:
1814:
1807:
1800:
1793:
1773:
1744:
1737:
1730:
1721:
1711:
1695:
1694:
1686:
1680:
1679:
1669:
1645:
1639:
1628:
1622:
1621:
1601:
1595:
1594:
1574:
1568:
1567:
1539:
1533:
1532:
1530:
1529:
1514:
1508:
1507:
1496:
1477:titanium sulfide
1450:releases these.
1430:hydrogen sulfide
1407:
1399:
1391:
1372:
1364:
1356:
1348:
1333:
1325:
1317:
1193:photoluminescent
1078:
990:Carbon disulfide
912:Hydrogen sulfide
885:
865:–O–O– bond. The
855:carbon disulfide
840:
839:
838:
787:functional group
763:dimethyl sulfide
740:
739:
738:
730:
729:
642:disulfide), and
444:hydrogen sulfide
408:Hydrogen sulfide
404:dimethyl sulfide
306:
293:
292:
291:
279:Chemical formula
222:
202:
191:
177:
157:
137:
113:
48:
44:
21:
2083:
2082:
2078:
2077:
2076:
2074:
2073:
2072:
2038:
2037:
2036:
2031:
2024:
2017:
2010:
2003:
1996:
1978:
1971:
1964:
1957:
1950:
1943:
1925:
1918:
1911:
1904:
1897:
1890:
1872:
1865:
1858:
1851:
1844:
1837:
1824:
1817:
1810:
1803:
1796:
1789:
1776:
1769:
1756:
1751:Monatomic anion
1748:
1704:
1699:
1698:
1688:
1687:
1683:
1647:
1646:
1642:
1629:
1625:
1618:
1603:
1602:
1598:
1576:
1575:
1571:
1541:
1540:
1536:
1527:
1525:
1516:
1515:
1511:
1498:
1497:
1490:
1485:
1456:
1442:
1418:
1409:
1401:
1393:
1385:
1374:
1366:
1358:
1350:
1335:
1327:
1319:
1303:
1277:
1245:
1234:
1217:
1213:
1183:devices in the
1135:
1107:
1076:
1072:
1068:
1064:
1060:
1036:
986:
936:can be used in
934:Cadmium sulfide
907:
883:
860:
852:
848:
837:
834:
833:
832:
830:
828:
819:oxidation state
816:
803:
792:
784:
780:
772:
768:
751:
737:
734:
733:
732:
728:
725:
724:
723:
721:
673:
668:
634:sulfide), and
618:sulfide), and
563:Many important
561:
559:sulfide mineral
555:
538:
526:
522:
510:
503:
499:
495:
456:
437:
429:
424:
413:
381:British English
370:
363:
358:
344:
340:
334:
304:
290:
288:
287:
286:
284:
281:
267:
262:
261:
250:
247:
246:
243:
237:
236:
225:
205:
192:
180:
160:
140:
127:
116:
103:
89:
88:
86:
39:
28:
23:
22:
15:
12:
11:
5:
2081:
2079:
2071:
2070:
2065:
2060:
2055:
2050:
2040:
2039:
2033:
2032:
2030:
2029:
2022:
2015:
2008:
2001:
1993:
1991:
1980:
1979:
1977:
1976:
1969:
1962:
1955:
1948:
1940:
1938:
1927:
1926:
1924:
1923:
1916:
1909:
1902:
1895:
1887:
1885:
1874:
1873:
1871:
1870:
1863:
1856:
1849:
1842:
1834:
1832:
1826:
1825:
1823:
1822:
1815:
1808:
1801:
1794:
1786:
1784:
1778:
1777:
1775:
1774:
1766:
1764:
1758:
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1746:
1739:
1732:
1724:
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1717:
1703:
1702:External links
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1486:
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1437:sulfur dioxide
1417:
1414:
1413:
1412:
1411:
1410:
1403:
1395:
1387:
1383:
1382:Example: M + H
1377:
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1157:
1154:
1140:Sodium sulfide
1137:
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1123:
1121:
1119:
1112:Silver sulfide
1109:
1105:
1101:
1100:
1095:
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1082:Sulfur mustard
1079:
1074:
1070:
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1056:
1051:
1049:
1047:
1042:, the mineral
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960:polysulfide ("
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557:Main article:
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533:cadmium yellow
524:
520:
509:
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493:
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440:
439:
438:O → SH + OH
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355:standard state
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313:Conjugate acid
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242:InChI=1S/S/q-2
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1995:
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1989:
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1981:
1974:
1970:
1967:
1963:
1960:
1956:
1953:
1949:
1946:
1942:
1941:
1939:
1936:
1935:Chalcogenides
1932:
1928:
1921:
1917:
1914:
1910:
1907:
1903:
1900:
1896:
1893:
1889:
1888:
1886:
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1573:
1570:
1565:
1561:
1557:
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1549:
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1538:
1535:
1523:
1519:
1513:
1510:
1505:
1501:
1495:
1493:
1489:
1482:
1480:
1478:
1474:
1469:
1465:
1461:
1453:
1451:
1449:
1444:
1438:
1433:
1431:
1427:
1426:gastric acids
1423:
1415:
1381:
1380:
1378:
1343:Example: MgSO
1342:
1341:
1339:
1311:
1310:
1308:
1307:
1306:
1300:
1294:
1291:
1289:
1286:
1283:
1279:
1273:
1272:
1269:
1266:
1264:
1261:
1258:
1254:
1250:
1247:
1241:
1240:
1237:
1233:
1230:
1228:
1226:
1223:
1220:
1209:
1208:
1205:
1202:
1199:
1197:
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1138:
1131:
1130:
1127:
1124:
1122:
1120:
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542:
541:semiconductor
534:
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491:
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483:
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475:
471:
470:polythionates
467:
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1626:
1606:
1599:
1585:(16): 2345.
1582:
1578:
1572:
1547:
1543:
1537:
1526:. Retrieved
1522:the original
1512:
1503:
1463:
1460:sulfanediide
1459:
1457:
1454:Nomenclature
1445:
1434:
1424:, including
1419:
1304:
1187:part of the
1175:is used for
1173:Zinc sulfide
1012:Lead sulfide
804:
752:
715:
696:
669:
644:chalcopyrite
562:
544:
511:
500:+ 8 MgI
466:polysulfides
460:
450:S + H → SH
441:
425:
395:
376:
372:
371:
94:Identifiers
18:Sulphide ore
2068:Sulfur ions
1464:sulfide(2−)
1312:Example: Fe
1301:Preparation
1257:Selsun Blue
1044:molybdenite
1014:is used in
962:lime sulfur
899:CAS number
718:thiosulfate
694:factories.
692:Kraft paper
604:pentlandite
596:molybdenite
594:sulfide),
523:S, NaHS, Na
453:SH + H → H
272:Properties
155:CHEBI:15138
2042:Categories
1544:Chem. Comm
1528:2022-08-24
1483:References
1253:antifungal
1236:25212-74-2
1232:26125-40-6
1179:and other
1126:21548-73-2
938:photocells
853:, whereas
801:Disulfides
628:sphalerite
626:sulfide),
610:sulfide),
602:sulfide),
600:molybdenum
586:sulfide),
578:sulfide),
484:, forming
300:Molar mass
220:G15I91XETI
166:ChemSpider
122:3D model (
111:18496-25-8
101:CAS Number
2053:Corrosion
1882:Pnictides
1754:compounds
1676:2296-6846
1293:1317-66-4
1268:7488-56-4
1204:1314-98-3
1163:1313-82-2
1054:1317-33-5
1027:1314-87-0
1016:infra-red
970:gardening
966:fungicide
949:1306-23-6
924:7783-06-4
867:disulfide
807:disulfide
759:thioether
700:(MIC) or
684:oil wells
572:argentite
529:inorganic
462:Oxidation
416:bisulfide
385:inorganic
346:Telluride
318:Bisulfide
32:thioether
2058:Sulfides
1984:Group 17
1931:Group 16
1878:Group 15
1830:Group 14
1782:Group 13
1714:Sulfides
1564:29404555
1466:, valid
1189:spectrum
1185:infrared
1118:tarnish.
1098:505-60-2
1018:sensors.
881:Examples
871:proteins
863:peroxide
710:sewerage
660:isotopes
656:minerals
624:antimony
620:stibnite
580:cinnabar
482:halogens
383:) is an
377:sulphide
342:selenide
42:Sulfide
1988:Halides
1762:Group 1
1448:biomass
1443:) gas.
1262:<100
1181:optical
1002:75-15-0
958:Calcium
888:Formula
875:enzymes
849:–S–S–CH
616:arsenic
612:realgar
584:mercury
553:Geology
517:cations
478:sulfate
474:sulfite
414:S) and
396:Sulfide
373:Sulfide
294:
187:PubChem
2048:Anions
1674:
1660:: 70.
1634:
1614:
1562:
1416:Safety
1282:pyrite
1251:is an
1177:lenses
1116:silver
995:−111.6
920:−60.20
823:pyrite
652:copper
636:pyrite
608:nickel
588:galena
576:silver
486:sulfur
434:S + H
392:sulfur
375:(also
332:anions
330:Other
259:SMILES
75:Names
1468:IUPAC
1367:+ 4CO
1359:→ MgS
1328:→ FeS
1147:paper
1144:kraft
1091:13–14
1069:–S–CH
1061:Cl–CH
917:−85.7
825:, FeS
795:thiol
769:–S–CH
765:is CH
565:metal
476:, or
388:anion
338:oxide
305:32.06
234:InChI
200:29109
175:27079
146:ChEBI
124:JSmol
1672:ISSN
1632:ISBN
1612:ISBN
1560:PMID
1475:and
1462:and
1422:acid
1402:+ 2H
1394:→ MS
1351:+ 4C
1200:1850
1159:1180
1021:1114
943:1750
813:(MoS
690:and
648:iron
640:iron
632:zinc
592:lead
568:ores
211:UNII
1662:doi
1587:doi
1552:doi
1439:(SO
1320:+ S
1287:600
1274:FeS
1242:SeS
1169:ZnS
1156:920
1094:217
1077:–Cl
1033:MoS
1008:PbS
968:in
930:CdS
809:".
753:In
688:oil
496:→ S
390:of
379:in
190:CID
2044::
2026:At
2012:Br
2005:Cl
1973:Po
1966:Te
1959:Se
1920:Bi
1913:Sb
1906:As
1867:Pb
1860:Sn
1853:Ge
1846:Si
1819:Tl
1812:In
1805:Ga
1798:Al
1670:.
1656:.
1652:.
1583:22
1581:.
1558:.
1548:54
1546:.
1502:.
1491:^
1432:.
1406:aq
1345:4(
1132:Na
1104:Ag
1073:CH
1065:CH
998:46
983:CS
877:.
773:.
472:,
468:,
446::
410:(H
406:.
2019:I
1998:F
1990:)
1986:(
1952:S
1945:O
1937:)
1933:(
1899:P
1892:N
1884:)
1880:(
1839:C
1791:B
1771:H
1743:e
1736:t
1729:v
1678:.
1664::
1658:8
1638:.
1620:.
1593:.
1589::
1566:.
1554::
1531:.
1441:2
1408:)
1404:(
1400:)
1398:s
1396:(
1392:)
1390:g
1388:(
1386:S
1384:2
1373:)
1371:g
1369:(
1365:)
1363:s
1361:(
1357:)
1355:s
1353:(
1349:)
1347:s
1334:)
1332:s
1330:(
1326:)
1324:s
1322:(
1318:)
1316:s
1314:(
1276:2
1244:2
1218:S
1216:4
1214:H
1212:6
1210:C
1153:.
1136:S
1134:2
1108:S
1106:2
1075:2
1071:2
1067:2
1063:2
1035:2
985:2
972:.
940:.
908:S
906:2
904:H
859:2
851:3
847:3
836:2
831:S
827:2
815:2
791:3
783:4
781:H
779:6
771:3
767:3
736:3
731:O
727:2
722:S
720:(
672:2
650:-
646:(
638:(
630:(
622:(
614:(
606:(
598:(
590:(
582:(
574:(
537:2
525:2
521:2
502:2
498:8
494:2
457:S
455:2
436:2
428:2
412:2
285:S
126:)
38:.
20:)
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