116:
175:
108:
190:
289:, and the limit is on the milligrams per kilogram or per litre of sulfur dioxide equivalent. In 2012, a new regulation for organic wines came into force. In the United Kingdom, similar laws apply. Bottles of wine that contain over 10 mg/L (ppm) of "sulfites" (or sulfur dioxide) are required to bear "contains sulphites" on the label. This does not differ if sulfites are naturally occurring or added in the winemaking process.
38:
581:
Generally, U.S. labeling regulations do not require products to indicate the presence of sulfites in foods unless it is added specifically as a preservative; still, many companies voluntarily label sulfite-containing foods. Sulfites used in food processing (but not as a preservative) are required to
612:
In
Australia and New Zealand, sulfites must be declared in the statement of ingredients when present in packaged foods in concentrations of 10 mg/kg (ppm) or more as an ingredient; or as an ingredient of a compound ingredient; or as a food additive or component of a food additive; or as a
273:
wines are not necessarily sulfite-free, but generally have lower amounts and regulations stipulate lower maximum sulfite contents for these wines. In general, white wines contain more sulfites than red wines and sweeter wines contain more sulfites than drier ones.
566:
In 1986, the U.S. Food and Drug
Administration banned the use of sulfites as preservatives on foods intended to be eaten fresh (such as salad ingredients). This has contributed to the increased use of
151:
of zero (neutral), and sulfur is singly bonded to the other two oxygen atoms, which each carry a formal charge of −1, together accounting for the −2 charge on the anion. There is also a non-bonded
95:
Sulfites are substances that naturally occur in some foods and the human body. They are also used as regulated food additives. When in food or drink, sulfites are often lumped together with
1556:
879:
1176:
609:. Products likely to contain sulfites at less than 10 ppm (fruits and alcoholic beverages) do not require ingredients labels, and the presence of sulfites usually is undisclosed.
810:
I. Bernal; J. Cetrullo; W. G. Jackson (1993). "The phenomenon of conglomerate crystallization in coordination compounds. XXIII: The crystallization behavior of ·2H
1375:
765:
631:, "EU law requires food labels to indicate "contains sulfites" (when exceeding 10 milligrams per kilogram or per litre) without specifying the amount".
582:
be listed if they are not incidental additives (21 CFR 101.100(a)(3)), and if there are more than 10 ppm in the finished product (21 CFR 101.100(a)(4))
1274:
1235:
1509:
1560:
1096:
968:
744:
711:
1045:
887:
643:
disease which leads to neurological damage and early death unless treated. Treatment, requiring daily injections, became available in 2009.
277:
In the United States, wines bottled after mid-1987 must have a label stating that they contain sulfites if they contain more than 10
1468:
174:
926:
640:
504:, but a reaction to sulfite is not a true allergy. Some people have positive skin allergy tests to sulfites indicating true (
1060:
1259:
1172:
773:
1299:
325:
1027:
513:
1402:"Sulfites inhibit the growth of four species of beneficial gut bacteria at concentrations regarded as safe for food"
480:
616:
Sulfites that can be added to foods in Canada are potassium bisulfite, potassium metabisulfite, sodium bisulfite,
1637:
1003:
798:
463:
324:
are sometimes treated with sulfites on fishing vessels, the chemical may not appear on the label. In 1986, the
512:, and face have been reported in individuals that regularly use cosmetics or medications containing sulfites.
1600:
1278:
606:
427:
219:
1242:
328:
in the United States banned the addition of sulfites to all fresh fruit and vegetables that are eaten raw.
524:
120:
115:
1517:
1155:
1413:
602:
415:
228:
144:
493:
Allergic reactions to sulfites appear to be very rare in the general population, but more common in
1007:
908:
598:
248:
215:
42:
1137:
835:
571:
278:
1088:
1632:
1464:
1441:
1217:
1129:
1092:
964:
740:
617:
439:
61:
1327:
1431:
1421:
1207:
1121:
1080:
827:
594:
505:
402:
366:
354:
224:
183:
853:
107:
700:
624:. These can also be declared using the common names sulfites, sulfates, sulfiting agents.
567:
451:
189:
147:. In each resonance structure, the sulfur atom is double-bonded to one oxygen atom with a
124:
31:
1417:
1156:"Sulphites - One of the nine most common food products causing severe adverse reactions"
1436:
1401:
1212:
1195:
695:
684:
675:
628:
621:
590:
586:
501:
390:
378:
373:
340:
286:
282:
232:
209:
96:
89:
81:
1626:
1141:
1081:
689:
148:
985:
839:
519:
It may cause breathing difficulty within minutes after eating a food containing it.
554:
A 2017 study has shown negative impacts of sulfites on bacteria found in the human
467:
298:
270:
252:
202:
156:
1581:
1342:
320:
no longer contain sulfites, although some alcoholic ciders contain them. Although
37:
1426:
1125:
1180:
532:
302:
1303:
1241:. California Department of Public Health: Food and Drug Branch. Archived from
945:
575:
555:
260:
168:
1112:
Randhawa S, Bahna SL (2009). "Hypersensitivity reactions to food additives".
661:
336:
256:
152:
85:
1445:
1221:
1133:
1074:
1072:
1070:
799:
REGULATION (EU) No 1169/2011 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
535:
and life-threatening reactions are rare. Other potential symptoms include
143:
The structure of the sulfite anion can be described with three equivalent
548:
536:
509:
285:
an equivalent regulation came into force in
November 2005. This includes
186:
suggests that protonation of the sulfite ion gives a mixture of isomers:
927:"The Truth About Sulfites in Wine & the Myths of Red Wine Headaches"
167:). In the hybrid resonance structure, the S−O bonds are equivalently of
17:
831:
639:
High sulfite content in the blood and urine of babies can be caused by
528:
160:
735:
Housecroft CE, Sharpe AG (2008). "Chapter 16: The group 16 elements".
1538:
1484:
1046:"Sulphite Free Diet: sulphites, sulfites and sulphur dioxide in food"
540:
520:
321:
310:
306:
1302:. American Academy of Allergy Asthma and Immunology. Archived from
1277:. American Academy of Allergy Asthma and Immunology. Archived from
27:
Oxyanion with a central atom of sulfur surrounded by 3 oxygen atoms
857:
544:
494:
361:
349:
114:
106:
36:
578:
such as meats because sulfites can destroy vitamin B1 from foods
516:
to sulfites has been reported to cause persistent skin symptoms.
267:) protects wine not only from oxidation, but also from bacteria.
1400:
Irwin SV, Fisher P, Graham E, Malek A, Robidoux A (2017-10-18).
475:
458:
446:
434:
422:
410:
397:
385:
317:
244:
531:
sensitivity) are at an elevated risk for reaction to sulfites.
1559:. Food Standards Australia New Zealand (FSANZ). Archived from
212:, which is not a sulfite, but a closely related chemical oxide
65:
46:
574:
as preservatives. They also cannot be added to foods high in
585:
Sulfites that are allowed to be added in food in the US are
188:
173:
68:(or the sulfate(IV) ion, from its correct systematic name),
1601:"Doctors risk untried drug to stop baby's brain dissolving"
620:, sodium metabisulfite, sodium sulfite, sulfur dioxide and
508:-mediated) allergy. Chronic skin conditions in the hands,
247:
to some extent. Sulfites are commonly introduced to arrest
1582:"More data on sulfites needed to "fully confirm" safety"
1557:"For asthma sufferers:the facts about sulphites in food"
1177:
Australasian
Society of Clinical Immunology and Allergy
205:
or enhancer. They may come in various forms, such as:
1028:"Commission Implementing Regulation (EU) No 203/2012"
1461:
Handbook of Food
Science, Technology and Engineering
251:
at a desired time, and may also be added to wine as
766:"Sulphites: One of the ten priority food allergens"
1167:
1165:
1114:Current Opinion in Allergy and Clinical Immunology
1083:Food Regulation: Law, Science, Policy and Practice
1061:"7 Myths of Natural Wines with no sulphites added"
1200:Gastroenterology and Hepatology from Bed to Bench
1158:. Canadian Food Inspection Agency. 22 March 2012.
613:processing aid or component of a processing aid.
909:"Why You Shouldn't Worry About Sulfites in Wine"
1196:"Adverse reactions to the sulphite additives"
760:
758:
756:
155:on the sulfur, so the structure predicted by
8:
1328:"Preservative: Sulfur Dioxide and Sulfites"
730:
728:
1435:
1425:
1211:
92:) is elusive, its salts are widely used.
1343:"The role of diet in migraine headaches"
500:Sulfites are counted among the top nine
345:
1376:"What you need to know about sulphites"
1004:"Food Labeling - Community Legislation"
724:
178:Resonance structures of the sulfite ion
1322:
1320:
1032:Official Journal of the European Union
963:(5th ed.). Hoboken, N.J.: Wiley.
986:"Many organic wines contain sulfites"
959:McCarthy E, Ewing-Mulligan M (2012).
712:Grant v The Australian Knitting Mills
7:
1356:(1). Delhi Psychiatry Society: 69–72
793:
791:
1539:"Sulfites - USA | FARRP | Nebraska"
1485:"Sulfites - USA | FARRP | Nebraska"
111:The structure of the sulfite anion
25:
1599:Tedmanson S (November 5, 2009).
854:"Allergies: Sulfite Sensitivity"
737:Inorganic Chemistry, 3rd Edition
243:Sulfites occur naturally in all
1087:. John Wiley and Sons. p.
1586:European Food Safety Authority
1341:Arora H, Kaur R (April 2008).
944:Spencer B (14 November 2007).
641:molybdenum cofactor deficiency
1:
1510:"Foods That Contain Sulfites"
1463:. CRC Press. pp. 83–32.
878:Zacharkiw B (July 15, 2008).
159:is trigonal pyramidal, as in
1427:10.1371/journal.pone.0186629
1330:. World Health Organization.
1126:10.1097/ACI.0b013e32832b2632
946:"Sulfur in Wine Demystified"
562:Use and labeling regulations
326:Food and Drug Administration
201:Sulfites are used as a food
297:Sulfites are often used as
1654:
1516:. 2012-3-7. Archived from
1194:Vally H, Misso NL (2012).
880:"Can't hold the sulphites"
481:Potassium hydrogen sulfite
405:(sodium hydrogen sulfite)
29:
523:and possibly people with
259:at several stages of the
80:. The sulfite ion is the
64:that contain the sulfite
1350:Delhi Psychiatry Journal
739:. Pearson. p. 520.
464:Calcium hydrogen sulfite
255:to prevent spoilage and
30:Not to be confused with
1179:(ASCIA). Archived from
607:potassium metabisulfite
428:Potassium metabisulfite
367:Sulfite ammonia caramel
355:Caustic sulfite caramel
279:parts per million (ppm)
220:potassium metabisulfite
123:. The structure of Co(
119:Sulfite is a ligand in
707:; a sulfate precursor)
525:salicylate sensitivity
193:
184:NMR spectroscopic data
179:
140:
121:coordination chemistry
112:
50:
1275:"Sulfite Sensitivity"
1260:"Sulfite Sensitivity"
514:Occupational exposure
192:
177:
118:
110:
88:. Although its acid (
40:
1063:. Organic Wine Club.
1048:. Organic Wine Club.
603:sodium metabisulfite
416:Sodium metabisulfite
263:. Sulfur dioxide (SO
229:sodium metabisulfite
145:resonance structures
1418:2017PLoSO..1286629I
1262:. Cleveland Clinic.
1008:European Commission
599:potassium bisulfite
216:Potassium bisulfite
171:one and one-third.
43:space-filling model
1079:Fortin ND (2009).
913:www.bonappetit.com
832:10.1007/BF00673698
635:Metabolic diseases
539:, swelling of the
194:
180:
141:
113:
51:
1588:. April 14, 2016.
1514:Sulfite Allergies
1380:Eat Right Ontario
1173:"Sulfite Allergy"
1098:978-0-470-12709-4
970:978-1-118-28872-6
860:. 1 February 2007
746:978-0-13-175553-6
618:sodium dithionite
486:
485:
440:Potassium sulfite
16:(Redirected from
1645:
1638:Sulfur oxyanions
1617:
1616:
1614:
1612:
1596:
1590:
1589:
1578:
1572:
1571:
1569:
1568:
1553:
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1546:
1535:
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1506:
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1499:
1497:
1495:
1481:
1475:
1474:
1456:
1450:
1449:
1439:
1429:
1412:(10): e0186629.
1397:
1391:
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1035:
1024:
1018:
1017:
1015:
1014:
1000:
994:
993:
981:
975:
974:
961:Wine for dummies
956:
950:
949:
941:
935:
934:
923:
917:
916:
905:
899:
898:
896:
895:
886:. Archived from
884:Montreal Gazette
875:
869:
868:
866:
865:
850:
844:
843:
807:
801:
795:
786:
785:
783:
781:
772:. Archived from
762:
751:
750:
732:
660:
659:
595:sodium bisulfite
403:Sodium bisulfite
346:
339:for sulfites as
225:Sodium bisulfite
182:Evidence from O
79:
78:
77:
21:
1653:
1652:
1648:
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1644:
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1493:
1491:
1483:
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1478:
1471:
1459:Hui YH (2006).
1458:
1457:
1453:
1399:
1398:
1394:
1384:
1382:
1374:
1373:
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1171:
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1110:
1106:
1099:
1078:
1077:
1068:
1058:
1057:
1053:
1044:
1043:
1039:
1034:. 8 March 2012.
1026:
1025:
1021:
1012:
1010:
1002:
1001:
997:
983:
982:
978:
971:
958:
957:
953:
943:
942:
938:
925:
924:
920:
915:. 4 April 2016.
907:
906:
902:
893:
891:
877:
876:
872:
863:
861:
852:
851:
847:
817:
814:O (I) and of ·H
813:
809:
808:
804:
796:
789:
779:
777:
764:
763:
754:
747:
734:
733:
726:
721:
706:
701:Sulfur trioxide
696:sulfur oxyacids
683:
674:
670:
658:
655:
654:
653:
649:
637:
568:erythorbic acid
564:
491:
452:Calcium sulfite
334:
295:
266:
241:
199:
197:Commercial uses
166:
138:
134:
130:
125:ethylenediamine
105:
76:
73:
72:
71:
69:
45:of the sulfite
35:
32:Sulfur trioxide
28:
23:
22:
15:
12:
11:
5:
1651:
1649:
1641:
1640:
1635:
1625:
1624:
1619:
1618:
1591:
1573:
1548:
1530:
1501:
1476:
1469:
1451:
1392:
1367:
1333:
1316:
1291:
1265:
1251:
1248:on 2012-07-23.
1227:
1186:
1183:on 2012-03-04.
1161:
1147:
1104:
1097:
1066:
1051:
1037:
1019:
995:
976:
969:
951:
936:
918:
900:
870:
845:
815:
811:
802:
787:
776:on 7 July 2016
752:
745:
723:
722:
720:
717:
716:
715:
708:
704:
698:
692:
690:Sulfite esters
687:
685:sulfur dioxide
681:
678:
676:sulfurous acid
672:
668:
665:
656:
648:
645:
636:
633:
629:European Union
622:sulfurous acid
591:sodium sulfite
587:sulfur dioxide
563:
560:
502:food allergens
490:
489:Health effects
487:
484:
483:
478:
472:
471:
461:
455:
454:
449:
443:
442:
437:
431:
430:
425:
419:
418:
413:
407:
406:
400:
394:
393:
391:Sodium sulfite
388:
382:
381:
379:Sulfur dioxide
376:
370:
369:
364:
358:
357:
352:
341:food additives
333:
330:
294:
291:
287:sulfur dioxide
283:European Union
264:
240:
237:
236:
235:
233:sodium sulfite
222:
213:
210:Sulfur dioxide
198:
195:
164:
136:
132:
128:
104:
101:
97:sulfur dioxide
90:sulfurous acid
82:conjugate base
74:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
1650:
1639:
1636:
1634:
1631:
1630:
1628:
1606:
1602:
1595:
1592:
1587:
1583:
1577:
1574:
1563:on 2011-03-15
1562:
1558:
1552:
1549:
1544:
1543:farrp.unl.edu
1540:
1534:
1531:
1520:on 2016-03-04
1519:
1515:
1511:
1505:
1502:
1490:
1489:farrp.unl.edu
1486:
1480:
1477:
1472:
1470:0-8493-9848-7
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1371:
1368:
1355:
1351:
1344:
1337:
1334:
1329:
1323:
1321:
1317:
1306:on 2008-11-20
1305:
1301:
1295:
1292:
1281:on 2009-04-12
1280:
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1255:
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1127:
1123:
1120:(3): 278–83.
1119:
1115:
1108:
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1094:
1090:
1085:
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1038:
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977:
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952:
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937:
932:
928:
922:
919:
914:
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904:
901:
890:on 2009-02-28
889:
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770:Health Canada
767:
761:
759:
757:
753:
748:
742:
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731:
729:
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709:
703:(uncharged SO
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498:
497:individuals.
496:
495:hyperallergic
488:
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1059:Safonov D.
533:Anaphylaxis
293:Other foods
1627:Categories
1567:2011-01-16
1524:2015-10-21
1310:2008-12-30
1300:"Sulfites"
1285:2008-12-30
1236:"Sulfites"
1013:2007-09-10
984:Breton F.
894:2008-08-05
864:2007-09-10
719:References
576:vitamin B1
556:microbiome
521:Asthmatics
313:products.
261:winemaking
169:bond order
1605:The Times
1142:205434836
818:O (II)".
662:bisulfite
337:E numbers
332:E numbers
281:. In the
257:oxidation
153:lone pair
103:Structure
86:bisulfite
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1633:Sulfites
1607:. London
1446:29045472
1406:PLOS ONE
1360:21 March
1222:24834193
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840:94847897
647:See also
570:and its
549:migraine
537:sneezing
510:perineum
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1414:Bibcode
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547:, and
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311:potato
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572:salts
545:hives
362:E150d
350:E150b
343:are:
318:beers
316:Most
245:wines
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