421:
metallic to ICCDW, then the material achieves NCCDW when cooling below 350K, and finally entering CCDW below 180K. However, if the temperature change is achieved by raising the temperature, another phase could appear between the CCDW phase and the NCCDW phase. The
Triclinic Charge Density Wave (TCDW) is again the hybrid state between CCDW and ICCDW, the difference is that instead of forming an enclosed hexagon area, the material forms strips with different atom shifts. When 1T-TaS2 is heated at a lower temperature, the first transition is from CCDW to TCDW at 220K; Then, continue heating the material above 280K the phase of the material transits to NCCDW. It is also superconducting under pressure or upon doping, with a familiar dome-like phase diagram as a function of dopant, or substituted isovalent element concentration.
416:
charge density wave phases: commensurate charge density wave (CCDW), nearly commensurate charge density wave (NCCDW), and incommensurate charge density wave (ICCDW). In the CCDW phase, the entire material is covered with the superlattice, but in the ICCDW phase, the atoms do not move. NCCDW is the phase between the two as the SOD clusters are confined within the nearly hexagonal-shaped areas. The phase transition of 1T-TaS2 could be achieved via temperature difference, as it is one of the most investigated methods to achieve phase transition of the material. In common with many other transition metal dichalcogenide (TMD) compounds, which are metallic at high temperatures, it exhibits a series of charge-density-wave (CDW)
452:
499:
483:
177:
122:
35:
962:"Manipulating charge density waves in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>1</mml:mn><mml:mi>T</mml:mi><mml:mtext>−</mml:mtext><mml:msub><mml:mi>TaS</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>by charge-carrier doping: A first-principles investigation"
336:
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Switching of the material to and from the "mosaic", or domain state, by optical or electrical pulses is used for "Charge configuration memory" (CCM) devices. The distinguishing feature of such devices is that they exhibit very efficient and fast non-thermal resistance switching at low temperatures.
415:
CDW, the periodic distortion induced by the electron-phonon interaction, is manifested by formation of a superlattice constituted by clusters of 13 atoms, which is called the Star of David (SOD), where the surrounding 12 Ta atoms move slightly towards the centre of the star. there are three 1T-TaS2
420:
from 550 K to 50 K. It is unusual amongst them in showing a low-temperature insulating state below 200 K, which is believed to arise from electron correlations, similar to many oxides. The insulating state is commonly attributed to a Mott state. When cooling down to 550K, 1T-TaS2 transitions from
1623:
Freitas, D. C.; Rodière, P.; Osorio, M. R.; Navarro-Moratalla, E.; Nemes, N. M.; Tissen, V. G.; Cario, L.; Coronado, E.; García-Hernández, M.; Vieira, S.; Núñez-Regueiro, M.; Suderow, H. (2016). "Strong enhancement of superconductivity at high pressures within the charge-density-wave states of
1427:
Navarro-Moratalla, Efrén; Island, Joshua O.; Mañas-Valero, Samuel; Pinilla-Cienfuegos, Elena; Castellanos-Gomez, Andres; Quereda, Jorge; Rubio-Bollinger, Gabino; Chirolli, Luca; Silva-Guillén, Jose Angel; Agraït, Nicolás; Steele, Gary A.; Guinea, Francisco; Van Der Zant, Herre S. J.; Coronado,
431:
is unique, not only amongst TMDs but also amongst 'quantum materials' in general, in showing a metastable metallic state at low temperatures. Switching from the insulating to the metallic state can be achieved either optically or by the application of electrical pulses. The metallic state is
655:(STM) to the CDW state causes it to drop electrical resistance and creates a "mosaic" or domain state consisting of nanometer-sized domains, where both the domains and their walls exhibit metallic conductivity. This mosaic structure is metastable and gradually disappears upon heating.
432:
persistentbelow ~20K, but its lifetime can be tuned by changing the temperature. The metastable state lifetime can also be tuned by strain. The electrically-induced switching between states is of current interest, because it can be used for ultrafast energy-efficient memory devices.
553:
It can be easily cleaved and has a characteristic golden sheen. Upon extended exposure to air, the formation of an oxide layer causes darkening of the surface. Thin films can be prepared by chemical vapour deposition and molecular beam epitaxy.
498:
435:
Because of the frustrated triangular arrangement of localized electrons, the material is suspected of supporting some form of quantum spin liquid state. It has been the subject of numerous studies as a host for
1278:
Mihailovic, D.; Svetin, D.; Vaskivskyi, I.; Venturini, R.; Lipovsek, B.; Mraz, A. (2021). "Ultrafast non-thermal and thermal switching in charge configuration memory devices based on 1T-TaS2".
1206:
Stojchevska, L.; Vaskivskyi, I.; Mertelj, T.; Kusar, P.; Svetin, D.; Brazovskii, S.; Mihailovic, D. (2014). "Ultrafast
Switching to a Stable Hidden Quantum State in an Electronic Crystal".
1755:
Coleman, R. V.; Giambattista, B.; Hansma, P.K; Johnson, A.; McNairy, W.W.; Slough, C.G. (1988). "Scanning tunnelling microscopy of charge-density waves in transition metal chalcogenides".
492:
where green atoms are S and purple are Ta. (b) and (c) are STM images (6.5 K) before and after application of 2.8 V pulses through the STM tip. Insets show ~10 times magnified images.
349:
1974:
Mohammadzadeh_et_al, Amirmahdi (2021). "Evidence for a thermally driven charge-density-wave transition in 1T-TaS 2 thin-film devices: Prospects for GHz switching speed".
1923:
Liu_et_al, Guanxiong (2016). "A charge-density-wave oscillator based on an integrated tantalum disulfide–boron nitride– graphene device operating at room temperature".
451:
1852:
Ma, Liguo; Ye, Cun; Yu, Yijun; Lu, Xiu Fang; Niu, Xiaohai; Kim, Sejoong; Feng, Donglai; Tománek, David; Son, Young-Woo; Chen, Xian Hui; Zhang, Yuanbo (2016).
2045:
213:
3671:
729:
Wilson, J.A.; Di Salvo, F.J.; Mahajan, S. (1975). "Charge-density waves and superlattices in the metallic layered transition metal dichalcogenides".
466:
695:
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Vaskivskyi, I.; Gospodaric, J.; Brazovskii, S.; Svetin, D.; Sutar, P.; Goreshnik, E.; Mihailovic, I.A.; Mertelj, T.; Mihailovic, D. (2014).
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Room temperature operation of a charge-density-wave oscillator and thermally-driven GHz modulation of the CDW state has been demonstrated.
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708:
191:
2038:
579:
402:
2379:
1685:
Tanda, Satoshi; Sambongi, Takashi; Tani, Toshiro; Tanaka, Shoji (1984). "X-Ray Study of Charge
Density Wave Structure in 1T-TaS
2275:
652:
389:
with three-coordinate sulfide centres and trigonal prismatic or octahedral metal centres. It is structurally similar to
3666:
2031:
155:
1502:
Cho, Doohee; Cheon, Sangmo; Kim, Ki-Seok; Lee, Sung-Hoon; Cho, Yong-Heum; Cheong, Sang-Wook; Yeom, Han Woong (2016).
2287:
1081:
Wang, Y. D.; Yao, W. L.; Xin, Z. M.; Han, T. T.; Wang, Z. G.; Chen, L.; Cai, C.; Li, Yuan; Zhang, Y. (2020-08-24).
356:
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437:
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pattern. Application of (e.g. 50fs) optical laser pulses or voltage pulses (~2–3 V) through electrodes or in a
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1993:
1932:
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Tanda, Satoshi; Sambongi, Takashi (1985). "X-ray study of the new charge-density-wave phase in 1T-TaS
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value increases up to ~8 K at 10 GPa and then saturates with increasing pressure. In contrast, 1T-TaS
578:
3R with three S-Ta-S sheets per cell; 4H and 6R phases are also observed, but less frequently. These
398:
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1T-TaS2, 2H-TaS2, and 3R-TaS2, representing trigonal, hexagonal, and rhombohedral respectively.
372:
314:
960:
Shao, D. F.; Xiao, R. C.; Lu, W. J.; Lv, H. Y.; Li, J. Y.; Zhu, X. B.; Sun, Y. P. (2016-09-14).
593:= 0.5 K, which increases to 2.2 K in flakes with a thickness of a few atomic layers. The bulk T
582:
mostly differ by the relative arrangement of the S-Ta-S sheet rather than the sheet structure.
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2068:
899:"On the origin of charge-density waves in select layered transition-metal dichalcogenides"
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1997:
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327:
1504:"Nanoscale manipulation of the Mott insulating state coupled to charge order in 1T-TaS
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2877:
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2013:
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1307:
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875:
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110:
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946:
898:
34:
3031:
2806:
2586:
1575:"Superconducting tantalum disulfide nanotapes; growth, structure and stoichiometry"
1189:
1022:
Sipos, B.; Kusmartseva, A. F.; Akrap, A.; Berger, H.; Forró, L.; Tutiš, E. (2008).
575:
1365:
Sung, S.; Schnitzer, N.; Novak, S.; Kourkoutis, L.; Heron, J.; Hovden, R. (2022).
1141:
859:
143:
17:
1165:
961:
808:
1795:"Ultrafast Switching to a Stable Hidden Quantum State in an Electronic Crystal"
1663:
1391:
1338:
1099:
987:
757:
2611:
1776:
809:"Pressure-induced semimetal-metal and metal-metal transitions in 1T and 2H TaS
785:
742:
251:
1820:
1574:
1245:
1173:
1108:
995:
930:
883:
844:
793:
1367:"Two-dimensional charge order stabilized in clean polytype heterostructures"
1237:
700:
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1952:
1944:
1909:
1838:
1811:
1609:
1559:
1485:
1410:
1253:
1181:
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1059:
938:
1854:"A metallic mosaic phase and the origin of Mott-insulating state in 1T-TaS
567:
518:
376:
1891:
1710:
1541:
1467:
1023:
2447:
1601:
379:
269:
130:
2005:
1299:
601:
starts superconducting only at ~2 GPa; as a function of pressure its T
2023:
1051:
530:
522:
326:
Except where otherwise noted, data are given for materials in their
1988:
1874:
1646:
1524:
1450:
978:
1220:
98:
88:
2416:
1140:
Burk, B.; Thomson, R. E.; Clarke, John; Zettl, A. (1992-07-17).
807:
Grant, A J; Griffiths, T M; Yoffe, A D; Pitt, G D (1974-07-21).
2420:
2027:
1573:
Dunnill, Charles W.; MacLaren, Ian; Gregory, Duncan H. (2010).
1321:
Revelli, J. F.; Disalvo, F. J. (1995). "Tantalum
Disulfide (TaS
308:
1142:"Surface and Bulk Charge Density Wave Structure in 1 T-TaS2"
160:
589:
is a superconductor with the bulk transition temperature T
1083:"Band insulator to Mott insulator transition in 1T-TaS2"
1333:. Inorganic Syntheses. Vol. 30. pp. 155–169.
344:
605:
quickly rises up to 5 K at ~4 GPa and then saturates.
758:"Diffraction evidence for the Kohn anomaly in 1T TaS
756:
Williams, P. M.; Parry, G. S.; Scrub, C. B. (1974).
632:~ 280 K, to an incommensurate CDW (ICCDW) state at T
525:
at ~900 °C. It is purified and crystallized by
2323:
2200:
2140:
2117:
2080:
2061:
40:
Crystal structure showing two stacked S-Ta-S sheets
1430:"Enhanced superconductivity in atomically thin TaS
508:(298 K). Acquired using HAADF STEM. Scale bar 2nm.
488:(a): Schematic of the David star pattern in 1T-TaS
858:Duffey, J.R.; Kirby, R.D.; Coleman, R.V. (1976).
562:Three major crystalline phases are known for TaS
264:golden or black crystals, depending on polytype
142:
1024:"From Mott state to superconductivity in 1T-TaS
659:Memory devices and other potential applications
608:At ambient pressure and low temperatures 1T-TaS
74:
1201:
1199:
2432:
2039:
8:
574:, hexagonal 2H with two S-Ta-S sheets, and
2439:
2425:
2417:
2320:
2114:
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2032:
2024:
175:
120:
26:
1987:
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1645:
1549:
1523:
1475:
1449:
1400:
1390:
1219:
1116:
1098:
977:
817:Journal of Physics C: Solid State Physics
616:. Upon heating it changes to a Triclinic
2967:
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724:
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720:
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1273:
1271:
676:
447:
218:
196:
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111:
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1497:
1495:
1422:
1420:
696:CRC Handbook of Chemistry and Physics
688:
686:
684:
682:
680:
647:lattice deforms to create a periodic
636:~ 350 K, and to a metallic state at T
7:
2460:
1325:) and Its Intercalation Compounds".
1017:
1015:
1013:
903:Journal of Physics: Condensed Matter
517:is prepared by reaction of powdered
476:crystals grown by transport reaction
133:
624:~ 220 K, to a nearly commensurate
25:
1331:) and Its Intercalation Compounds
699:(92nd ed.). Boca Raton, FL:
504:Atomic resolution image of 1T-TaS
3672:Transition metal dichalcogenides
693:Haynes, William M., ed. (2011).
497:
481:
465:
450:
412:polytype have been described.
397:, and numerous other transition
334:
33:
860:"Raman scattering from 1T-TaS2"
401:. Tantalum disulfide has three
330:(at 25 °C , 100 kPa).
923:10.1088/0953-8984/23/21/213001
1:
653:scanning tunneling microscope
570:1T with one S-Ta-S sheet per
1742:10.1016/0379-6779(85)90177-8
1166:10.1126/science.257.5068.362
876:10.1016/0038-1098(76)91073-5
408:The properties of the 1T-TaS
897:Rossnagel, K (2011-05-11).
533:as the transporting agent:
256:245.078 g/mol
3693:
3339:
1664:10.1103/PhysRevB.93.184512
1392:10.1038/s41467-021-27947-5
1339:10.1002/9780470132616.ch32
1100:10.1038/s41467-020-18040-4
988:10.1103/physrevb.94.125126
864:Solid State Communications
837:10.1088/0022-3719/7/14/001
457:Sample polycrystalline TaS
2476:
2457:
1777:10.1080/00018738800101439
786:10.1080/14786437408213248
743:10.1080/00018737500101391
324:
300:
229:
209:
187:
58:
50:
45:
32:
643:In the CDW state the TaS
527:chemical vapor transport
1327:Tantalum Disulfide (TaS
1238:10.1126/science.1241591
1945:10.1038/nnano.2016.108
1812:10.1126/sciadv.1500168
766:Philosophical Magazine
1925:Nature Nanotechnology
1862:Nature Communications
1512:Nature Communications
1438:Nature Communications
1087:Nature Communications
440:of electron donors.
399:metal dichalcogenides
28:Tantalum(IV) sulfide
391:molybdenum disulfide
369:Tantalum(IV) sulfide
2119:Organotantalum(III)
1998:2021ApPhL.118i3102M
1937:2016NatNa..11..845L
1892:10.1038/ncomms10956
1884:2016NatCo...710956M
1769:1988AdPhy..37..559C
1757:Advances in Physics
1711:10.1143/JPSJ.53.476
1703:1984JPSJ...53..476T
1656:2016PhRvB..93r4512F
1594:2010Nanos...2...90D
1542:10.1038/ncomms10453
1534:2016NatCo...710453C
1468:10.1038/ncomms11043
1460:2016NatCo...711043N
1383:2022NatCo..13..413S
1292:2021ApPhL.119a3106M
1230:2014Sci...344..177S
1158:1992Sci...257..362B
1044:2008NatMa...7..960S
915:2011JPCM...23u3001R
829:1974JPhC....7L.249G
778:1974PMag...29..695W
731:Advances in Physics
626:charge density wave
618:charge density wave
319:Tantalum diselenide
291:Solubility in water
29:
3667:Tantalum compounds
2055:Tantalum compounds
1602:10.1039/B9NR00224C
628:(NCCDW) state at T
373:inorganic compound
357:Infobox references
315:Tantalum telluride
301:Related compounds
53:tantalum disulfide
27:
18:Tantalum disulfide
3649:
3648:
3643:
3642:
2414:
2413:
2410:
2409:
2325:Organotantalum(V)
2136:
2135:
2006:10.1063/5.0044459
1805:(6180): 177–180.
1691:J. Phys. Soc. Jpn
1634:Physical Review B
1300:10.1063/5.0052311
1214:(6180): 177–180.
1152:(5068): 362–364.
966:Physical Review B
823:(14): L249–L253.
620:(TCDW) state at T
418:phase transitions
375:with the formula
365:Chemical compound
363:
362:
156:CompTox Dashboard
100:Interactive image
16:(Redirected from
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1991:
1976:Appl. Phys. Lett
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1730:Synthetic Metals
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1428:Eugenio (2016).
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1280:Appl. Phys. Lett
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1032:Nature Materials
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703:. p. 4.93.
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387:layered compound
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237:Chemical formula
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3149:
3147:
3139:
3134:
3132:
3124:
3116:
3108:
3104:
3099:
3083:
3067:
3057:
3055:
3051:
3046:
3044:
3040:
3030:
3028:
3023:
3016:
3012:
2998:
2985:
2981:
2969:
2965:
2961:
2959:
2956:
2952:
2947:
2942:
2940:
2932:
2924:
2916:
2912:
2897:
2894:
2876:
2874:
2864:
2862:
2858:
2853:
2851:
2847:
2837:
2835:
2830:
2823:
2819:
2814:
2800:
2797:
2789:
2786:
2783:
2780:
2773:
2770:
2767:
2764:
2757:
2753:
2748:
2741:
2736:
2729:
2725:
2720:
2713:
2709:
2704:
2702:
2697:
2690:
2685:
2683:
2679:
2674:
2672:
2667:
2660:
2656:
2651:
2636:
2618:
2615:
2614:
2613:
2605:
2603:
2600:
2597:
2594:
2585:
2583:
2578:
2571:
2567:
2553:
2533:
2523:
2521:
2513:
2508:
2506:
2502:
2488:
2468:
2453:
2450:
2445:
2415:
2406:
2403:
2399:
2391:
2387:
2383:
2375:
2371:
2367:
2359:
2355:
2347:
2343:
2339:
2335:
2319:
2315:
2311:
2307:
2303:
2295:
2291:
2283:
2279:
2271:
2263:
2255:
2247:
2243:
2235:
2227:
2219:
2211:
2196:
2192:
2188:
2180:
2167:
2159:
2151:
2132:
2129:
2113:
2109:
2091:
2076:
2072:
2057:
2052:
2022:
2021:
1973:
1972:
1968:
1931:(10): 845–850.
1922:
1921:
1917:
1857:
1851:
1850:
1846:
1792:
1791:
1784:
1754:
1753:
1749:
1727:
1723:
1722:
1718:
1688:
1684:
1683:
1679:
1631:
1627:
1622:
1621:
1617:
1577:
1572:
1571:
1567:
1507:
1501:
1500:
1493:
1433:
1426:
1425:
1418:
1364:
1363:
1356:
1349:
1330:
1324:
1320:
1319:
1315:
1277:
1276:
1269:
1205:
1204:
1197:
1139:
1138:
1134:
1080:
1079:
1075:
1027:
1021:
1020:
1011:
959:
958:
954:
896:
895:
891:
857:
856:
852:
812:
806:
805:
801:
761:
755:
754:
750:
728:
727:
718:
711:
692:
691:
678:
672:
670:
661:
646:
639:
635:
631:
623:
611:
604:
600:
596:
592:
588:
565:
560:
548:
544:
540:
516:
509:
507:
502:
493:
491:
486:
477:
475:
470:
461:
460:
455:
446:
430:
411:
396:
383:
366:
359:
354:
353:
352: ?)
343:
339:
335:
331:
317:
311:
293:
245:
239:
225:
222:
217:
216:
205:
202:
201:
195:
194:
183:
165:
158:
149:
136:
105:
92:
81:
68:
54:
41:
38:
23:
22:
15:
12:
11:
5:
3690:
3688:
3680:
3679:
3674:
3669:
3664:
3654:
3653:
3647:
3646:
3641:
3640:
3637:
3634:
3631:
3628:
3625:
3622:
3619:
3616:
3613:
3610:
3606:
3598:
3595:
3591:
3587:
3583:
3579:
3575:
3571:
3570:
3566:
3562:
3554:
3550:
3546:
3538:
3534:
3530:
3522:
3518:
3514:
3506:
3502:
3498:
3490:
3486:
3482:
3474:
3470:
3466:
3458:
3454:
3450:
3442:
3438:
3434:
3426:
3422:
3418:
3410:
3406:
3402:
3394:
3390:
3386:
3378:
3374:
3370:
3362:
3358:
3354:
3346:
3342:
3341:
3338:
3335:
3334:
3331:
3328:
3325:
3322:
3319:
3316:
3313:
3310:
3307:
3304:
3301:
3298:
3295:
3292:
3289:
3286:
3283:
3280:
3276:
3275:
3272:
3269:
3264:
3260:
3256:
3252:
3248:
3240:
3235:
3231:
3226:
3222:
3218:
3210:
3206:
3202:
3194:
3190:
3183:
3179:
3175:
3168:
3160:
3156:
3152:
3145:
3141:
3137:
3130:
3126:
3122:
3118:
3114:
3110:
3106:
3102:
3094:
3091:
3086:
3081:
3076:
3075:
3072:
3069:
3065:
3061:
3053:
3049:
3042:
3038:
3034:
3026:
3018:
3014:
3010:
3006:
3001:
2996:
2992:
2987:
2983:
2979:
2975:
2972:
2949:
2945:
2938:
2934:
2930:
2926:
2922:
2918:
2914:
2910:
2906:
2904:
2899:
2896:
2892:
2887:
2886:
2883:
2880:
2872:
2868:
2860:
2856:
2849:
2845:
2841:
2833:
2825:
2821:
2817:
2809:
2804:
2795:
2791:
2785:
2779:
2775:
2769:
2763:
2759:
2755:
2751:
2743:
2739:
2731:
2727:
2723:
2715:
2711:
2707:
2700:
2692:
2688:
2681:
2677:
2670:
2662:
2658:
2654:
2646:
2644:
2639:
2634:
2629:
2628:
2625:
2622:
2616:
2609:
2599:
2593:
2589:
2581:
2573:
2569:
2565:
2561:
2556:
2551:
2546:
2545:
2542:
2539:
2536:
2531:
2527:
2519:
2515:
2511:
2504:
2500:
2496:
2491:
2486:
2481:
2480:
2477:
2475:
2473:
2471:
2466:
2459:
2458:
2455:
2454:
2446:
2444:
2443:
2436:
2429:
2421:
2412:
2411:
2408:
2407:
2405:
2401:
2397:
2393:
2389:
2385:
2381:
2377:
2373:
2369:
2365:
2361:
2357:
2353:
2349:
2345:
2341:
2337:
2333:
2329:
2327:
2318:
2317:
2313:
2309:
2305:
2301:
2297:
2293:
2289:
2285:
2281:
2277:
2273:
2269:
2265:
2261:
2257:
2253:
2249:
2245:
2241:
2237:
2233:
2229:
2225:
2221:
2217:
2213:
2209:
2204:
2202:
2198:
2197:
2195:
2194:
2190:
2186:
2182:
2178:
2174:
2169:
2165:
2161:
2157:
2153:
2149:
2144:
2142:
2138:
2137:
2134:
2133:
2131:
2127:
2123:
2121:
2112:
2111:
2107:
2103:
2098:
2093:
2089:
2084:
2082:
2078:
2077:
2075:
2074:
2070:
2065:
2063:
2059:
2058:
2053:
2051:
2050:
2043:
2036:
2028:
2020:
2019:
1966:
1915:
1855:
1844:
1782:
1763:(6): 559–644.
1747:
1725:
1716:
1686:
1677:
1640:(18): 184512.
1629:
1625:
1615:
1565:
1505:
1491:
1431:
1416:
1354:
1347:
1328:
1322:
1313:
1267:
1195:
1132:
1073:
1025:
1009:
972:(12): 125126.
952:
909:(21): 213001.
889:
870:(6): 617–621.
850:
810:
799:
772:(3): 695–699.
759:
748:
737:(2): 117–201.
716:
709:
675:
674:
669:
666:
660:
657:
644:
637:
633:
629:
621:
614:Mott insulator
609:
602:
598:
594:
590:
586:
563:
559:
556:
551:
550:
546:
542:
538:
514:
511:
510:
505:
503:
496:
494:
489:
487:
480:
478:
473:
471:
464:
462:
458:
456:
449:
445:
442:
428:
425:Metastability.
409:
394:
381:
364:
361:
360:
355:
333:
332:
328:standard state
325:
322:
321:
312:
306:
303:
302:
298:
297:
294:
289:
286:
285:
282:
276:
275:
272:
266:
265:
262:
258:
257:
254:
248:
247:
243:
240:
235:
232:
231:
227:
226:
224:
223:
220:
212:
211:
210:
207:
206:
204:
203:
200:InChI=1S/2S.Ta
199:
198:
190:
189:
188:
185:
184:
182:
181:
168:
166:
154:
151:
150:
148:
147:
139:
137:
129:
126:
125:
115:
107:
106:
104:
103:
95:
93:
86:
83:
82:
80:
79:
71:
69:
64:
61:
60:
56:
55:
52:
48:
47:
43:
42:
39:
24:
14:
13:
10:
9:
6:
4:
3:
2:
3689:
3678:
3675:
3673:
3670:
3668:
3665:
3663:
3660:
3659:
3657:
3638:
3635:
3632:
3629:
3626:
3623:
3620:
3617:
3614:
3611:
3609:
3602:
3599:
3596:
3594:
3588:
3586:
3576:
3573:
3572:
3569:
3558:
3555:
3553:
3542:
3539:
3537:
3526:
3523:
3521:
3510:
3507:
3505:
3494:
3491:
3489:
3478:
3475:
3473:
3462:
3459:
3457:
3446:
3443:
3441:
3430:
3427:
3425:
3414:
3411:
3409:
3398:
3395:
3393:
3382:
3379:
3377:
3366:
3363:
3361:
3350:
3347:
3344:
3343:
3336:
3332:
3329:
3326:
3323:
3320:
3317:
3314:
3311:
3308:
3305:
3302:
3299:
3296:
3293:
3290:
3287:
3284:
3281:
3278:
3277:
3273:
3270:
3268:
3265:
3263:
3253:
3251:
3244:
3241:
3239:
3232:
3230:
3227:
3225:
3214:
3207:
3205:
3198:
3195:
3193:
3186:
3176:
3174:
3161:
3159:
3148:
3142:
3140:
3133:
3127:
3125:
3119:
3117:
3111:
3109:
3098:
3095:
3092:
3090:
3087:
3085:
3078:
3077:
3073:
3070:
3068:
3062:
3060:
3056:
3045:
3035:
3033:
3029:
3022:
3019:
3017:
3007:
3005:
3002:
3000:
2993:
2991:
2988:
2986:
2976:
2973:
2971:
2958:
2950:
2948:
2941:
2935:
2933:
2927:
2925:
2919:
2917:
2907:
2905:
2903:
2900:
2898:
2889:
2888:
2884:
2881:
2879:
2875:
2869:
2867:
2863:
2852:
2842:
2840:
2836:
2829:
2826:
2824:
2813:
2810:
2808:
2805:
2803:
2799:
2792:
2790:
2776:
2774:
2760:
2758:
2747:
2744:
2742:
2735:
2732:
2730:
2719:
2716:
2714:
2703:
2696:
2693:
2691:
2684:
2673:
2666:
2663:
2661:
2650:
2647:
2645:
2643:
2640:
2638:
2631:
2630:
2626:
2623:
2621:
2610:
2608:
2604:
2590:
2588:
2584:
2577:
2574:
2572:
2562:
2560:
2557:
2555:
2548:
2547:
2543:
2540:
2537:
2535:
2528:
2526:
2522:
2516:
2514:
2507:
2497:
2495:
2492:
2490:
2483:
2482:
2478:
2472:
2470:
2463:
2462:
2456:
2449:
2442:
2437:
2435:
2430:
2428:
2423:
2422:
2419:
2404:
2394:
2392:
2378:
2376:
2362:
2360:
2350:
2348:
2330:
2328:
2326:
2322:
2316:
2298:
2296:
2286:
2284:
2274:
2272:
2266:
2264:
2258:
2256:
2250:
2248:
2238:
2236:
2230:
2228:
2222:
2220:
2214:
2212:
2206:
2205:
2203:
2199:
2193:
2183:
2181:
2175:
2173:
2170:
2168:
2162:
2160:
2154:
2152:
2146:
2145:
2143:
2139:
2130:
2124:
2122:
2120:
2116:
2110:
2104:
2102:
2099:
2097:
2094:
2092:
2086:
2085:
2083:
2081:Tantalum(III)
2079:
2073:
2067:
2066:
2064:
2060:
2056:
2049:
2044:
2042:
2037:
2035:
2030:
2029:
2026:
2015:
2011:
2007:
2003:
1999:
1995:
1990:
1985:
1982:(9): 093102.
1981:
1977:
1970:
1967:
1962:
1958:
1954:
1950:
1946:
1942:
1938:
1934:
1930:
1926:
1919:
1916:
1911:
1907:
1902:
1897:
1893:
1889:
1885:
1881:
1876:
1871:
1867:
1863:
1859:
1848:
1845:
1840:
1836:
1831:
1826:
1822:
1818:
1813:
1808:
1804:
1800:
1796:
1789:
1787:
1783:
1778:
1774:
1770:
1766:
1762:
1758:
1751:
1748:
1743:
1739:
1736:(2): 85–100.
1735:
1731:
1720:
1717:
1712:
1708:
1704:
1700:
1696:
1692:
1681:
1678:
1673:
1669:
1665:
1661:
1657:
1653:
1648:
1643:
1639:
1635:
1619:
1616:
1611:
1607:
1603:
1599:
1595:
1591:
1587:
1583:
1576:
1569:
1566:
1561:
1557:
1552:
1547:
1543:
1539:
1535:
1531:
1526:
1521:
1517:
1513:
1509:
1498:
1496:
1492:
1487:
1483:
1478:
1473:
1469:
1465:
1461:
1457:
1452:
1447:
1443:
1439:
1435:
1423:
1421:
1417:
1412:
1408:
1403:
1398:
1393:
1388:
1384:
1380:
1376:
1372:
1368:
1361:
1359:
1355:
1350:
1348:9780470132616
1344:
1340:
1336:
1332:
1317:
1314:
1309:
1305:
1301:
1297:
1293:
1289:
1286:(1): 013106.
1285:
1281:
1274:
1272:
1268:
1263:
1259:
1255:
1251:
1247:
1243:
1239:
1235:
1231:
1227:
1222:
1217:
1213:
1209:
1202:
1200:
1196:
1191:
1187:
1183:
1179:
1175:
1171:
1167:
1163:
1159:
1155:
1151:
1147:
1143:
1136:
1133:
1128:
1124:
1119:
1114:
1110:
1106:
1101:
1096:
1092:
1088:
1084:
1077:
1074:
1069:
1065:
1061:
1057:
1053:
1049:
1045:
1041:
1038:(12): 960–5.
1037:
1033:
1029:
1018:
1016:
1014:
1010:
1005:
1001:
997:
993:
989:
985:
980:
975:
971:
967:
963:
956:
953:
948:
944:
940:
936:
932:
928:
924:
920:
916:
912:
908:
904:
900:
893:
890:
885:
881:
877:
873:
869:
865:
861:
854:
851:
846:
842:
838:
834:
830:
826:
822:
818:
814:
803:
800:
795:
791:
787:
783:
779:
775:
771:
767:
763:
752:
749:
744:
740:
736:
732:
725:
723:
721:
717:
712:
710:1-4398-5511-0
706:
702:
698:
697:
689:
687:
685:
683:
681:
677:
673:
667:
665:
658:
656:
654:
650:
649:Star of David
641:
627:
619:
615:
606:
583:
581:
577:
573:
569:
557:
555:
536:
535:
534:
532:
528:
524:
520:
500:
495:
484:
479:
468:
463:
453:
448:
443:
441:
439:
438:intercalation
433:
426:
422:
419:
413:
406:
404:
400:
392:
388:
384:
378:
374:
370:
358:
351:
346:
329:
323:
320:
316:
313:
310:
305:
304:
299:
295:
292:
288:
287:
283:
281:
280:Melting point
278:
277:
273:
271:
268:
267:
263:
260:
259:
255:
253:
250:
249:
241:
238:
234:
233:
228:
219:
215:
208:
197:
193:
186:
178:
174:
173:DTXSID6065260
170:
169:
167:
157:
153:
152:
145:
141:
140:
138:
132:
128:
127:
123:
119:
116:
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112:ECHA InfoCard
109:
108:
101:
97:
96:
94:
90:
85:
84:
77:
73:
72:
70:
67:
63:
62:
57:
49:
44:
36:
31:
19:
3120:
2147:
2141:Tantalum(IV)
2062:Tantalum(II)
1979:
1975:
1969:
1928:
1924:
1918:
1865:
1861:
1847:
1802:
1798:
1760:
1756:
1750:
1733:
1729:
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1694:
1690:
1680:
1637:
1633:
1618:
1585:
1581:
1568:
1515:
1511:
1441:
1437:
1374:
1370:
1326:
1316:
1283:
1279:
1211:
1207:
1149:
1145:
1135:
1090:
1086:
1076:
1035:
1031:
969:
965:
955:
906:
902:
892:
867:
863:
853:
820:
816:
802:
769:
765:
751:
734:
730:
694:
671:
662:
642:
607:
584:
576:rhombohedral
561:
552:
512:
434:
424:
423:
414:
407:
368:
367:
284:>3000 °C
59:Identifiers
51:Other names
2201:Tantalum(V)
1628:and 2H−TaSe
1588:(1): 90–7.
1371:Nat. Commun
1093:(1): 4215.
444:Preparation
261:Appearance
230:Properties
118:100.032.047
3677:Monolayers
3662:Disulfides
3656:Categories
1989:2101.06703
1875:1507.01312
1697:(2): 476.
1647:1603.00425
1525:1505.00690
1451:1604.05656
1377:(1): 413.
979:1512.06553
668:References
580:polymorphs
558:Properties
403:polymorphs
385:. It is a
296:Insoluble
274:6.86 g/cm
252:Molar mass
87:3D model (
76:12143-72-5
66:CAS Number
2126:Ta(SiOBu)
2014:231632205
1961:205454331
1868:: 10956.
1821:0036-8075
1582:Nanoscale
1518:: 10453.
1444:: 11043.
1308:237851661
1262:206550327
1246:0036-8075
1221:1401.6786
1174:0036-8075
1109:2041-1723
1068:205402097
1004:118471561
996:2469-9950
931:0953-8984
884:0038-1098
845:0022-3719
794:0031-8086
701:CRC Press
640:~ 600 K.
572:unit cell
2448:Sulfides
1953:27376243
1910:26961788
1839:24723607
1672:54705510
1610:20648369
1560:26795073
1486:26984768
1411:35058434
1254:24723607
1182:17832831
1127:32839433
1060:18997775
947:11260341
939:21558606
568:trigonal
519:tantalum
3340:
1994:Bibcode
1933:Bibcode
1901:4792954
1880:Bibcode
1830:4646782
1799:Science
1765:Bibcode
1699:Bibcode
1652:Bibcode
1590:Bibcode
1551:4735893
1530:Bibcode
1477:5512558
1456:Bibcode
1402:8776735
1379:Bibcode
1288:Bibcode
1226:Bibcode
1208:Science
1190:8530734
1154:Bibcode
1146:Science
1118:7445232
1040:Bibcode
911:Bibcode
825:Bibcode
774:Bibcode
350:what is
348: (
270:Density
246:
131:PubChem
2012:
1959:
1951:
1908:
1898:
1837:
1827:
1819:
1670:
1624:2H−TaS
1608:
1558:
1548:
1484:
1474:
1409:
1399:
1345:
1306:
1260:
1252:
1244:
1188:
1180:
1172:
1125:
1115:
1107:
1066:
1058:
1002:
994:
945:
937:
929:
882:
843:
792:
707:
585:2H-TaS
531:iodine
529:using
523:sulfur
472:1T-TaS
427:1T-TaS
371:is an
345:verify
342:
309:anions
307:Other
214:SMILES
46:Names
2268:LuTaO
2260:NdTaO
2252:LiTaO
2010:S2CID
1984:arXiv
1957:S2CID
1870:arXiv
1668:S2CID
1642:arXiv
1578:(PDF)
1520:arXiv
1446:arXiv
1304:S2CID
1258:S2CID
1216:arXiv
1186:S2CID
1064:S2CID
1000:S2CID
974:arXiv
943:S2CID
634:ICCDW
630:NCCDW
612:is a
549:+ 2 S
545:⇌ TaI
541:+ 2 I
192:InChI
144:82945
89:JSmol
2396:TaCp
2380:Ta(C
2364:TaCl
2224:TaBr
2216:TaCl
2177:TaTe
2156:TaSe
2106:TaCl
2096:TaAs
2088:TaAl
1949:PMID
1906:PMID
1835:PMID
1817:ISSN
1606:PMID
1556:PMID
1482:PMID
1407:PMID
1343:ISBN
1250:PMID
1242:ISSN
1178:PMID
1170:ISSN
1123:PMID
1105:ISSN
1056:PMID
992:ISSN
935:PMID
927:ISSN
880:ISSN
841:ISSN
790:ISSN
705:ISBN
622:TCDW
521:and
221:S==S
3639:No
3636:Md
3633:Fm
3630:Es
3627:Cf
3624:Bk
3621:Cm
3618:Am
3615:Pu
3612:Np
3597:Pa
3590:ThS
3574:**
3557:YbS
3541:TmS
3525:ErS
3509:HoS
3493:DyS
3477:TbS
3461:GdS
3445:EuS
3429:SmS
3413:PmS
3397:NdS
3381:PrS
3365:CeS
3349:LaS
3333:Og
3330:Ts
3327:Lv
3324:Mc
3321:Fl
3318:Nh
3315:Cn
3312:Rg
3309:Ds
3306:Mt
3303:Hs
3300:Bh
3297:Sg
3294:Db
3291:Rf
3288:Lr
3285:**
3282:Ra
3279:Fr
3274:Rn
3271:At
3267:PoS
3247:PbS
3243:PbS
3229:HgS
3201:PtS
3197:PtS
3189:IrS
3164:OsS
3144:ReS
3121:TaS
3113:HfS
3097:LuS
3089:BaS
3074:Xe
3064:TeS
3059:-Sb
3032:-Sn
3025:SnS
3021:SnS
3004:CdS
2990:PdS
2974:Ru
2953:TcS
2944:MoS
2937:MoS
2929:NbS
2921:ZrS
2902:SrS
2885:Kr
2882:Br
2878:+Se
2871:SeS
2866:-As
2839:-Ge
2832:GeS
2828:GeS
2812:GaS
2807:ZnS
2802:CuS
2746:FeS
2738:MnS
2734:MnS
2718:CrS
2687:TiS
2669:TiS
2665:TiS
2649:ScS
2642:CaS
2627:Ar
2624:Cl
2587:-Si
2580:SiS
2576:SiS
2559:MgS
2544:Ne
2534:)SH
2530:(NH
2525:COS
2510:+BO
2494:BeS
2479:He
2451:(S)
2368:(CH
2352:TaC
2336:(OC
2292:TaF
2280:TaF
2232:TaI
2208:TaF
2189:HfC
2172:TaC
2164:TaI
2148:TaS
2101:TaN
2069:TaB
2002:doi
1980:118
1941:doi
1896:PMC
1888:doi
1825:PMC
1807:doi
1803:344
1773:doi
1738:doi
1728:".
1707:doi
1689:".
1660:doi
1632:".
1598:doi
1546:PMC
1538:doi
1472:PMC
1464:doi
1397:PMC
1387:doi
1335:doi
1296:doi
1284:119
1234:doi
1212:344
1162:doi
1150:257
1113:PMC
1095:doi
1048:doi
984:doi
919:doi
872:doi
833:doi
782:doi
739:doi
537:TaS
513:TaS
393:MoS
242:TaS
161:EPA
134:CID
3658::
3605:US
3601:US
3578:Ac
3561:Yb
3545:Tm
3529:Er
3513:Ho
3497:Dy
3481:Tb
3465:Gd
3449:Eu
3433:Sm
3417:Pm
3401:Nd
3385:Pr
3369:Ce
3353:La
3345:*
3255:Bi
3234:Tl
3217:Au
3209:Au
3178:Ir
3151:Re
3136:WS
3129:WS
3101:Lu
3093:*
3080:Cs
3071:I
3048:Sb
3037:Sb
3009:In
2995:Ag
2978:Rh
2962:Tc
2891:Rb
2855:As
2844:As
2816:Ga
2794:Cu
2778:Ni
2762:Co
2750:Fe
2722:Cr
2699:VS
2695:VS
2676:Ti
2653:Sc
2612:-S
2607:-P
2564:Al
2550:Na
2541:F
2538:O
2518:CS
2485:Li
2388:N)
2358:15
2346:10
2332:Ta
2304:Ta
2240:Ta
2185:Ta
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3259:S
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3249:2
3238:S
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3223:3
3221:S
3219:2
3213:S
3211:2
3203:2
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3182:S
3180:2
3169:4
3157:7
3155:S
3153:2
3146:2
3138:3
3131:2
3123:2
3115:2
3107:3
3105:S
3103:2
3084:S
3082:2
3066:2
3054:5
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3043:3
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