266:
54:
44:
1905:
777:
626:
in gaseous sulfur. In liquid sulfur the molecule is not common until the temperature is high, such as 500 °C (932 °F). However, small molecules like this contribute to most of the reactivity of liquid sulfur.
949:), and is expected to occur naturally at depth in the Earth's crust where subduction or high pressure metamorphism occurs. This ion is probably important in movement of copper and gold in
1434:
Chivers T, Elder PJ (2013). "Ubiquitous trisulfur radical anion: fundamentals and applications in materials science, electrochemistry, analytical chemistry and geochemistry".
1008:
in a matrix. The material is strongly blue-coloured when dry and changes colour to green and yellow in the presence of trace amounts of water. Another way to make it is with
1769:
Gao Q, Xiu Y, Li Gd, Chen Js (2010). "Sensor material based on occluded trisulfur anionic radicals for convenient detection of trace amounts of water molecules".
1937:
319:
2054:
1877:
1753:
1607:
1371:
1172:
601:
comprises a large proportion of liquid sulfur. However its existence was unproven until the experiments of J. Berkowitz in 1964. Using
280:
1188:
McCarthy MC, Thorwirth S, Gottlieb CA, Patrick T (11 March 2004). "The rotational spectrum and geometrical structure of thiozone, S
1930:
53:
1846:
2049:
436:
1923:
244:
2059:
1436:
870:
1114:
1013:
539:
1118:
956:
131:
43:
1164:
946:
842:
491:
487:
73:
1909:
494:). It has been observed at cryogenic temperatures as a solid. Under ordinary conditions it converts to
1884:
1696:
1641:
1526:
1473:
Linguerri R, Komiha N, Fabian J, Rosmus P (2008). "Electronic states of the ultramarine chromophore S
1201:
579:, where the sulfur atoms are arranged in an equilateral triangle with three single bonds (similar to
261:
692:
475:
143:
97:
1324:
1236:
1964:
1946:
1665:
1550:
1499:
1038:
950:
392:
1279:"Ueber Thiozonide, ein Beitrag zur Kenntniss des Schwefels und seiner ringförmigen Verbindungen"
1281:[On thiozonide, an article on the knowledge of sulfur and its ring-forming compounds].
1749:
1724:
1657:
1603:
1542:
1452:
1367:
1259:
1217:
1168:
1137:
602:
417:
1949:
1855:
1817:
1778:
1714:
1704:
1649:
1534:
1491:
1444:
1416:
1339:
1290:
1251:
1209:
1156:
735:
351:
195:
107:
1032:
912:
731:
495:
265:
1878:"Raman microscopy of diverse samples of lapis lazuli at multiple excitation wavelengths"
1700:
1645:
1530:
1205:
587:), is calculated to be lower in energy than the bent structure experimentally observed.
175:
163:
1796:
Chivers T, Drummond I (October 1972). "Characterization of the trisulfur radical anion
1745:
Inorganic Rings and
Polymers of the p-Block Elements: From Fundamentals to Applications
1719:
1684:
430:
421:
2043:
1974:
1669:
1554:
1133:
942:
483:
1503:
232:
907:
846:
591:
584:
580:
547:
543:
220:
1743:
1597:
1361:
941:
ion has been shown to be stable in aqueous solution under a pressure of 0.5
709:. The reddish colour of Venus' atmosphere at lower levels is likely to be due to
1994:
1495:
1110:
1009:
854:
807:
821:
is abundant. It exhibits an intense blue colour. The anion is sometimes called
1915:
972:
918:
874:
648:
368:
186:
1517:
Manning CE (25 February 2011). "Sulfur surprises in deep geological fluids".
1294:
1984:
1709:
1653:
1632:
ion is stable in geological fluids at elevated temperatures and pressures".
1538:
900:
681:
663:
560:
1835:
Lunsford JH, Johnson DP (1973). "Electron paramagnetic resonance study of S
1728:
1661:
1546:
1456:
1420:
1263:
1221:
1904:
748:
Formation of compounds with a defined number of sulfur atoms is possible:
2024:
850:
780:
1821:
1343:
17:
1448:
1387:
Steudel R, Steudel Y (2 November 2004). "The thermal decomposition of S
826:
207:
1859:
1808:
in blue solutions of alkali polysulfides in hexamethylphosphoramide".
1255:
1213:
1782:
897:
electronic state in the ion, causing a strong absorption band at 610–
479:
1683:
Pokrovsky GS, Kokh MA, Guillaume D, et al. (3 November 2015) .
1278:
776:
429:
Except where otherwise noted, data are given for materials in their
1053:, and it can be used non-destructively in paintings. The bands are
695:
at heights of 20 to 30 km, where it is in thermal equilibrium with
2004:
1237:"Transition metal complexes of cyclic and open ozone and thiozone"
775:
528:
413:
154:
142:
130:
120:
1004:
1919:
1002:
radical anion was also made by reducing gaseous sulfur with
975:
solvation dissociates acetone and related donor solvents to
249:
52:
42:
478:. It comprises about 10% of vaporised sulfur at 713
1623:
Pokrovski GS, Dubrovinsky LS (25 February 2011). "The S
1685:"Sulfur radical species form gold deposits on Earth"
1235:
Flemmig B, Wolczanski PT, Hoffmann R (1 June 2005).
1031:
include reacting sulfur with partially hydroxylated
911:(in the orange region of the visible spectrum). The
1956:
1748:. Royal Society of Chemistry. pp. 295–296.
1065:for bending. Natural materials can also contain
638:(violet) with a tail extending into blue light.
231:
219:
1689:Proceedings of the National Academy of Sciences
889:radical anion. The blue colour is due to the CA
106:
612:molecule. Above 1,200 °C (2,190 °F)
1931:
1871:
1869:
8:
1468:
1466:
605:, he showed that sulfur vapour contains the
1318:
1316:
1314:
1312:
1310:
1308:
1306:
1304:
564:, and with an angle at the central atom of
1938:
1924:
1916:
1599:Elemental Sulfur and Sulfur-Rich Compounds
971:, another polysulfide radical anion) with
806:is elusive under ordinary conditions, the
482:(440 °C; 824 °F) and 1,333
264:
194:
31:
1718:
1708:
1363:Physics and Chemistry of the Solar System
619:is the second most common molecule after
553:The S–S distances are equivalent and are
550:, the bonding situation is more complex.
2026:
2016:
2006:
1996:
1986:
1976:
1966:
1244:Journal of the American Chemical Society
1194:Journal of the American Chemical Society
1124:
802:
762:
758:
754:
741:
726:
712:
705:
698:
687:
676:
658:
654:
643:
630:
622:
615:
608:
597:
575:
534:
523:
508:
504:
452:
359:
1355:
1353:
1148:
662:embedded in a glass or matrix of solid
324:
285:
260:
922:and another infrared absorption is at
1602:. Vol. 2. Springer. p. 16.
306:Key: WMXWXNVGXOWZRJ-UHFFFAOYSA-M
292:Key: NVSDADJBGGUCLP-UHFFFAOYSA-N
174:
162:
7:
1484:Zeitschrift für Physikalische Chemie
1077:which has an optical absorption at
210:
1568:Steudel R (2003). "Cluster anions
590:The name thiozone was invented by
520:In terms of structure and bonding
303:: InChI=1S/HS3/c1-3-2/h1H/p-1
25:
1283:Justus Liebigs Annalen der Chemie
57:Ball-and-stick model of trisulfur
1903:
691:is also likely to appear in the
546:. Although represented with S=S
2055:Homonuclear triatomic molecules
1847:The Journal of Chemical Physics
1019:Other methods of production of
433:(at 25 °C , 100 kPa).
1771:Journal of Materials Chemistry
1132:. The bonds are single. It is
1016:where it gives a blue colour.
594:in 1908 who hypothesized that
1:
1742:Chivers T, Manners I (2009).
1844:formed on magnesium oxide".
1407:O — an ab initio MO study".
1113:series. The sulfur chain is
1061:for asymmetric stretch, and
1496:10.1524/zpch.2008.222.1.163
1128:) has a S–S bond length of
38:
2076:
634:has an absorption peak of
538:) are similar. Both adopt
373:96.198 g/mol
1161:Chemistry of the Elements
647:can also be generated by
427:
402:
385:
344:
315:
276:
90:
82:
72:
67:
37:
1295:10.1002/jlac.19083620202
1117:at an angle of 107.88°.
1041:can be used to identify
871:International Klein Blue
853:(from which the pigment
1710:10.1073/pnas.1506378112
1654:10.1126/science.1199911
1539:10.1126/science.1202468
1057:for symmetric stretch,
1014:hexamethylphosphoramide
684:in volcanic emissions.
1421:10.1002/chin.200444022
1323:Meyer B (March 1975).
825:, by analogy with the
796:
58:
48:
1165:Butterworth-Heinemann
1159:, Earnshaw A (1997).
973:tetramethylenediamine
843:valence isoelectronic
779:
516:Structure and bonding
56:
46:
2050:Allotropes of sulfur
1912:at Wikimedia Commons
1167:. pp. 645–662.
1119:Strontium trisulfide
893:transition to the XB
877:, also contains the
857:is derived) contain
680:occurs naturally on
1876:Hark RR, Clark RJ.
1822:10.1021/ic50116a047
1810:Inorganic Chemistry
1701:2015PNAS..11213484P
1695:(44): 13484–13489.
1646:2011Sci...331.1052P
1640:(6020): 1052–1054.
1531:2011Sci...331.1018M
1525:(6020): 1018–1019.
1344:10.1021/cr60301a003
1206:2004JAChS.126.4096M
957:Lithium hexasulfide
951:hydrothermal fluids
693:atmosphere of Venus
476:allotrope of sulfur
34:
1449:10.1039/C3CS60119F
1366:. Academic Press.
1325:"Elemental sulfur"
1277:Erdmann H (1908).
1081:and Raman band at
1039:Raman spectroscopy
797:
670:Natural occurrence
572:. However, cyclic
474:, is a cherry-red
437:Infobox references
403:Related compounds
289:InChI=1S/S3/c1-3-2
59:
49:
32:
2037:
2036:
1950:chemical elements
1908:Media related to
1860:10.1063/1.1679473
1816:(10): 2525–2527.
1777:(16): 3307–3312.
1755:978-1-84755-906-7
1609:978-3-540-40378-4
1443:(14): 5996–6005.
1373:978-0-12-446744-6
1360:Lewis JS (2004).
1256:10.1021/ja044809d
1214:10.1021/ja049645f
1200:(13): 4096–4097.
1174:978-0-08-037941-8
1138:sulfur dichloride
841:, to which it is
603:mass spectrometry
445:Chemical compound
443:
442:
418:Disulfur monoxide
409:Related compounds
245:CompTox Dashboard
144:Interactive image
132:Interactive image
63:
62:
27:Chemical compound
16:(Redirected from
2067:
2060:Gases with color
2030:
2020:
2010:
2000:
1990:
1980:
1970:
1940:
1933:
1926:
1917:
1907:
1892:
1891:
1889:
1883:. Archived from
1882:
1873:
1864:
1863:
1854:(5): 2079–2083.
1843:
1842:
1832:
1826:
1825:
1807:
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1786:
1783:10.1039/B925233A
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1332:Chemical Reviews
1329:
1320:
1299:
1298:
1274:
1268:
1267:
1250:(4): 1278–1285.
1241:
1232:
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1179:
1178:
1163:(2nd ed.).
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1080:
1076:
1075:
1074:
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1056:
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1050:
1047:
1035:at 400 °C.
1030:
1029:
1028:
1025:
1007:
1001:
1000:
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996:
986:
985:
984:
981:
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965:
959:(which contains
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935:
925:
921:
910:
903:
888:
887:
886:
883:
868:
867:
866:
863:
849:and the mineral
840:
839:
838:
835:
820:
819:
818:
815:
805:
794:
793:
792:
789:
766:
744:
736:carbonyl sulfide
729:
715:
708:
701:
690:
679:
661:
646:
637:
633:
625:
618:
611:
600:
578:
571:
569:
563:
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511:
472:triatomic sulfur
455:
362:
352:Chemical formula
269:
268:
253:
251:
235:
223:
212:
198:
178:
166:
146:
134:
110:
39:
35:
21:
2075:
2074:
2070:
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2066:
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2064:
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2039:
2038:
2033:
2028:
2023:
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2013:
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2003:
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1973:
1968:
1963:
1952:
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1900:
1895:
1887:
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1875:
1874:
1867:
1841:
1838:
1837:
1836:
1834:
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1799:
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1794:
1790:
1768:
1767:
1763:
1756:
1741:
1740:
1736:
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1681:
1677:
1629:
1626:
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1624:
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1621:
1617:
1610:
1592:
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1586:
1585:
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1578:
1573:
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1571:
1569:
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1566:
1562:
1516:
1515:
1511:
1479:
1476:
1475:
1474:
1472:
1471:
1464:
1437:Chem. Soc. Rev.
1433:
1432:
1428:
1406:
1402:
1398:
1394:
1390:
1386:
1385:
1381:
1374:
1359:
1358:
1351:
1327:
1322:
1321:
1302:
1276:
1275:
1271:
1239:
1234:
1233:
1229:
1191:
1187:
1186:
1182:
1175:
1155:
1154:
1150:
1146:
1129:
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1122:
1109:is part of the
1104:
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1078:
1072:
1069:
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1062:
1058:
1054:
1048:
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1044:
1042:
1033:magnesium oxide
1026:
1023:
1022:
1020:
1003:
997:
994:
993:
991:
982:
979:
978:
976:
966:
963:
962:
960:
936:
933:
932:
930:
923:
916:
913:Raman frequency
905:
898:
896:
892:
884:
881:
880:
878:
873:, developed by
864:
861:
860:
858:
845:. The gemstone
836:
833:
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816:
813:
812:
810:
804:
800:
790:
787:
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774:
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743:
739:
732:carbon monoxide
728:
724:
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540:bent structures
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496:cyclooctasulfur
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410:
395:
393:Molecular shape
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332:Trisulfanidyl S
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299:Trisulfanidyl S
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226:Trisulfanidyl S
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1898:External links
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1890:on 2011-07-26.
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1089:Trisulfide ion
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91:Identifiers
83:Other names
29:
1130:205 pm
1111:polysulfide
1083:590 cm
1079:390 nm
1063:259 cm
1059:585 cm
1055:549 cm
1010:polysulfide
924:580 cm
855:ultramarine
636:425 nm
544:diamagnetic
458:, known as
381:Cherry-red
378:Appearance
345:Properties
176:CHEBI:29399
164:CHEBI:29388
2044:Categories
1409:ChemInform
1144:References
1095:trisulfide
906:2.07
875:Yves Klein
823:thiozonide
649:photolysis
559:0.01
386:Structure
369:Molar mass
187:ChemSpider
119:3D model (
108:12597-03-4
98:CAS Number
74:IUPAC name
33:Trisulfur
1947:Triatomic
1910:Trisulfur
1670:206530875
1555:206532249
917:523
899:620
799:Although
783:contains
720:Reactions
664:noble gas
460:trisulfur
77:Trisulfur
1729:26460040
1662:21350173
1547:21350156
1504:95495454
1457:23628896
1264:15669867
1222:15053585
851:lazurite
781:Lazurite
767:(cyclic)
734:to make
542:and are
468:thiozone
456:molecule
336:: S
85:Thiozone
18:Thiozone
1720:4640777
1697:Bibcode
1642:Bibcode
1634:Science
1527:Bibcode
1519:Science
1202:Bibcode
829:anion,
827:ozonide
566:117.36°
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570:0.006°
555:191.70
320:SMILES
221:139340
68:Names
1888:(PDF)
1881:(PDF)
1666:S2CID
1551:S2CID
1500:S2CID
1403:and S
1328:(PDF)
1240:(PDF)
1097:ion,
761:O → S
529:ozone
507:→ 3 S
470:, or
414:Ozone
398:bent
281:InChI
196:62201
155:ChEBI
121:JSmol
1957:List
1750:ISBN
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