971:
38:
315:
182:
47:
807:
703:
698:
693:
802:
1574:
938:
808:
805:
2409:
2261:
Eremenko, B. V.; Bezuglaya, T. N.; Savitskaya, A. N.; Malysheva, M. L.; Kozlov, I. S.; Bogodist, L. G. (2001). "Stability of
Aqueous Dispersions of the Hydrated Titanium Dioxide Prepared by Titanium Tetrachloride Hydrolysis".
711:
673:
1557:
since it produces a heavy, white smoke that has little tendency to rise. "Tickle" was the standard means of producing on-set smoke effects for motion pictures, before being phased out in the 1980s due to concerns about
830:
1029:, a reaction that was formerly exploited for use in smoke machines. It is sometimes referred to as "tickle" or "tickle 4", as a phonetic representation of the symbols of its molecular formula (
777:
2407:
806:
951:
1340:
is undesirable, which has motivated the development of alternative technologies. Instead of directly using ilmenite, "rutile slag" is used. This material, an impure form of
1050:
is a dense, colourless liquid, although crude samples may be yellow or even red-brown. It is one of the rare transition metal halides that is a liquid at room temperature,
3008:
364:
3187:
2454:
2833:
M. E. Davie; T. Foerster; S. Parsons; C. Pulham; D. W. H. Rankin; B. A. Smart (2006). "The
Crystal Structure of Tetrakis(dimethylamino)titanium(IV)".
773:
2498:
Heinz Sibum; Volker Güther; Oskar Roidl; Fathi
Habashi; Hans Uwe Wolf; Carsten Siemers (2017). "Titanium, Titanium Alloys, and Titanium Compounds".
5574:
1660:
37:
2079:, useful in organic chemistry, is an aluminium-containing derivative of titanocene that arises from the reaction of titanocene dichloride with
2955:
2929:
2772:
2695:
2658:
2618:
2515:
2374:
619:
1612:, as the hydrochloric acid aerosol and titanium dioxide that is formed scatter light very efficiently. This smoke is corrosive, however.
3869:
2676:
2739:
329:
781:
3001:
2731:"Organotitanium Reagents in Organic Synthesis (Reactivity and Structure Concepts in Organic Chemistry, Vol 24)" Manfred T. Reetz
5559:
3301:
1725:
2390:
2429:
651:
765:
958:
837:
3724:
759:
262:
3752:
3425:
2994:
1968:. These reactions highlight the influence of electrostatics on the structures of compounds with highly ionic bonding.
293:
2072:
213:
2532:
816:
702:
5227:
4214:
3738:
2416:
5569:
5508:
5484:
5393:
3710:
189:
4184:
3934:
1570:
Titanium tetrachloride is a versatile reagent that forms diverse derivatives including those illustrated below.
5501:
5400:
5311:
5288:
5250:
4626:
4619:
4232:
3626:
2034:
207:
119:
751:
5476:
5460:
5445:
5437:
5357:
5304:
5242:
5211:
4781:
4763:
4677:
4670:
4655:
4640:
4612:
4575:
4482:
4397:
3862:
3825:
3782:
3694:
3570:
3149:
2028:
769:
506:
4861:
692:
177:
5491:
5453:
5370:
5350:
5280:
5265:
5235:
5087:
4883:
4854:
4838:
4755:
4693:
4663:
4648:
4633:
4582:
4568:
4527:
4463:
4390:
4375:
4353:
4346:
4324:
4225:
4172:
4146:
3670:
3265:
3257:
3128:
3120:
1988:
1171:= 0, 1, 2, 3, 4. Magnetic resonance measurements also indicate that halide exchange is also rapid between
1051:
1011:
920:
904:
595:
5422:
5415:
5408:
5378:
5342:
5319:
5296:
5258:
5095:
4999:
4992:
4984:
4977:
4926:
4912:
4904:
4890:
4876:
4846:
4685:
4590:
4560:
4509:
4497:
4382:
4368:
4339:
4317:
4206:
4135:
3952:
3817:
3473:
3385:
3215:
3166:
3112:
3090:
3031:
2947:
2477:
2459:
2154:
2049:
1656:
1370:
1120:
916:
881:
725:
697:
685:
554:
59:
46:
5468:
5429:
5385:
5335:
5327:
5219:
5049:
5045:
5037:
5011:
4970:
4948:
4933:
4919:
4897:
4868:
4774:
4748:
4725:
4597:
4535:
4475:
4427:
4360:
4262:
4139:
4112:
4090:
4023:
4004:
3847:
3534:
3345:
3285:
3277:
3245:
3136:
3068:
3047:
2835:
2189:
1997:
1129:
1075:
900:
877:
5273:
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5026:
4955:
4941:
4812:
4789:
4718:
4604:
4520:
4490:
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4447:
4435:
4420:
4295:
4244:
4101:
4060:
3982:
3766:
3678:
3610:
3465:
3457:
3228:
3154:
3073:
3055:
2864:
2715:
2226:
Hazards posed by titanium tetrachloride generally arise from its reaction with water that releases
885:
310:
85:
5564:
5018:
4962:
4801:
4793:
4714:
4550:
4443:
4412:
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3017:
2782:
2279:
2080:
1332:
982:
566:
3829:
2902:
Gundersen, L.-L.; Rise, F.; Undheim, K. (2004). "Titanium(IV) chloride". In
Paquette, L. (ed.).
2076:
1742:, a yellow, benzene-soluble liquid: This molecule is tetrahedral, with planar nitrogen centers.
1347:, is derived from ilmenite by removal of iron, either using carbon reduction or extraction with
970:
5105:
5064:
5057:
4545:
4504:
4405:
4309:
4255:
4079:
4068:
4041:
3971:
3945:
3923:
3894:
3401:
3365:
3207:
2951:
2925:
2768:
2735:
2691:
2654:
2614:
2541:
2511:
2448:
2370:
2227:
2177:
1652:
1648:
1647:
can adopt complex structures ranging from monomers to tetramers. Such compounds are useful in
1597:
1559:
1487:
1381:
1026:
851:
666:
2808:
Bradey, D. C.; Thomas, M. (1960). "Some
Dialkylamino-derivatives of Titanium and Zirconium".
2322:
1996:) and tetrachloride have contrasting properties: the trichloride is a colored solid, being a
5072:
5007:
4822:
4805:
4740:
4733:
4706:
4299:
4269:
4083:
4037:
4011:
3993:
3910:
3658:
3642:
3598:
3562:
3546:
3325:
3313:
3223:
3144:
3039:
2939:
2869:
2844:
2815:
2760:
2683:
2646:
2606:
2583:
2549:
2503:
2271:
2105:
1721:
1465:
1359:
1275:
1015:
1000:
986:
519:
463:
387:
2687:
271:
159:
5110:
4827:
4701:
4159:
3963:
3821:
3526:
3433:
3293:
2794:
2601:
Manzer, L. E. (1982). "31. Tetragtdrfuran
Complexes of Selected Early Transition Metals".
2413:
2188:, and the electron-transfer properties of its reduced titanium halides. It is used in the
2045:
2005:
1798:
480:
95:
2886:
Mariappan
Periasamy (2002): "New synthetic methods using the TiCl4-NR3 reagent system",
2862:
139:
314:
181:
4049:
4030:
2981:
2192:
1601:
1446:
1438:
929:
731:
495:
5553:
5129:
4455:
3798:
3774:
2810:
2587:
2230:, which is severely corrosive itself and whose vapors are also extremely irritating.
1681:
1677:
1664:
1416:
1348:
1071:
452:
442:
170:
17:
2283:
1089:
has a "closed" electronic shell, with the same number of electrons as the noble gas
857:
3833:
3333:
2001:
1609:
1554:
1302:
1199:
735:
2971:
2507:
2433:
235:
5524:
4130:
3586:
1605:
1404:
The world's supply of titanium metal, about 250,000 tons per year, is made from
1094:
743:
2848:
2764:
2610:
5145:
5121:
2348:
2275:
2238:
2181:
1791:
1787:
1593:
1476:
1230:
474:
404:
150:
2650:
2130:; see figure above). This reaction illustrates the high Lewis acidity of the
2185:
1984:
1412:
538:
282:
1108:) surrounded by four identical ligands. This configuration leads to highly
2297:
5532:
4277:
3879:
3634:
2873:
2819:
2203:
2143:
1644:
1298:
1283:
1109:
1059:
being another example. This property reflects the fact that molecules of
996:
836:
829:
822:
815:
788:
5516:
5157:
5137:
2888:
1573:
1234:
1195:
1067:
747:
488:
484:
432:
222:
190:
2553:
2986:
2976:
2207:
1520:
1442:
1294:
1250:
1246:
1242:
578:
2574:-Arene Derivatives of Titanium(IV), Zirconium(IV) and Hafnium(IV)".
928:
Except where otherwise noted, data are given for materials in their
2533:"Intermolecular Self-Interactions of the Titanium Tetrahalides TiX
2241:, which exothermically forms adducts with even weak bases such as
2086:
1795:
1698:
1636:
1411:. The conversion involves the reduction of the tetrachloride with
1279:
1203:
1090:
969:
246:
130:
118:
108:
974:
Crystals of frozen titanium tetrachloride melting into the liquid
823:
2755:-[Dihalobis(2,4-Pentaedionato)Titanium(IV)] Complexes".
2570:
Calderazzo, F.; Ferri, I.; Pampaloni, G.; Troyanov, S. (1996). "
2419:– "Titanium Tetrachloride: Stepping Stone to Amazing Technology"
2008:
solution, the Ti(III) product converts to the light-blue adduct
739:
422:
3851:
2990:
2242:
2071:. This compound and many of its derivatives are precursors to
1238:
1014:
liquid. Upon contact with humid air, it forms thick clouds of
894:
871:
1663:
results from treatment of titanium tetrachloride with excess
1572:
1070:, wherein the chloride atoms bridge between the metals. Its
298:
2637:
Völz, Hans G.; et al. (2006). "Pigments, Inorganic".
1112:
structures, hence the tetrahedral shape of the molecule.
800:
1724:
is formed. An illustrative reaction is the synthesis of
1358:
contains a variety of other volatile halides, including
1104:
is consistent with its description as a d metal center (
1608:. Titanium tetrachloride has been used to create naval
995:. It is an important intermediate in the production of
946:
2298:"titanium(IV) chloride, 1M soln. in dichloromethane"
1987:
results in one-electron reduction. The trichloride (
348:
InChI=1/4ClH.Ti/h4*1H;/q;;;;+4/p-4/rCl4Ti/c1-5(2,3)4
3810:
3519:
3200:
3182:
3100:
3085:
3024:
2675:
2972:Titanium tetrachloride: Health Hazard Information
2323:"Titanium(IV) chloride solution 1.0 M in toluene"
1643:= 1, 2, 4). As indicated by their formula, these
2751:Wilkie, C. A.; Lin, G.; Haworth, D. T. (1979). "
1066:weakly self-associate. Most metal chlorides are
234:
2369:(6th ed.). Houghton-Mifflin. p. A23.
1137:; the three compounds share many similarities.
804:
665:Toxic, corrosive, reacts with water to release
94:
2904:Encyclopedia of Reagents for Organic Synthesis
2643:Ullmann's Encyclopedia of Industrial Chemistry
2500:Ullmann's Encyclopedia of Industrial Chemistry
2083:. It is used for the "olefination" reactions.
3863:
3002:
2142:entity, which is generated by abstraction of
8:
457:136.4 °C (277.5 °F; 409.5 K)
447:−24.1 °C (−11.4 °F; 249.1 K)
2727:
2725:
2195:Key to this application is the tendency of
3870:
3856:
3848:
3516:
3179:
3082:
3009:
2995:
2987:
2674:Schaschke, Carl (2014). "Hunter process".
2493:
2491:
2489:
2487:
1301:at 900 °C. Impurities are removed by
313:
180:
158:
29:
2565:
2563:
2462:– "Chemistry Material Safety Data Sheets"
270:
5494:
3759:
3755:
3745:
3741:
3731:
3727:
3717:
3713:
2233:
2213:
2198:
2172:
2157:
2149:
2126:
2118:
2114:
2110:
2100:
2096:
2092:
2067:
2063:
2059:
2055:
2044:. An important reaction involves sodium
2040:
2015:
2011:
1991:
1979:
1963:
1959:
1955:
1951:
1947:
1943:
1935:
1931:
1927:
1919:
1915:
1911:
1907:
1903:
1899:
1892:
1884:
1880:
1876:
1872:
1868:
1861:
1853:
1845:
1841:
1833:
1829:
1822:
1815:
1811:
1804:
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1752:
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1734:
1730:
1711:
1704:
1689:
1685:
1673:
1629:
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1618:
1588:
1541:
1537:
1533:
1529:
1515:
1504:
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1471:
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1429:
1425:
1407:
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1354:
1343:
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1315:
1311:
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1225:
1217:
1213:
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1190:
1181:
1174:
1161:
1154:
1147:
1140:
1132:
1123:
1115:
1100:
1078:
1062:
1054:
1046:
1032:
1021:
1006:
991:
395:
2253:
1661:Titanium bis(acetylacetonate)dichloride
1464:production is used to make the pigment
369:
334:
309:
212:
3900:
3878:Salts and covalent derivatives of the
2982:ChemSub Online: Titanium tetrachloride
2790:
2780:
2632:
2630:
2502:. Weinheim: Wiley-VCH. pp. 1–35.
2453:: CS1 maint: archived copy as title (
2446:
1720:-containing) complexes. With ammonia,
1562:'s effects on the respiratory system.
1415:metal. This procedure is known as the
171:
5200:
2004:. When the reduction is conducted in
1858:. The reaction of chloride ions with
341:Key: XJDNKRIXUMDJCW-UHFFFAOYSA-J
138:
7:
3890:
2920:Holleman, A. F.; Wiberg, E. (2001).
2906:. New York, NY: J. Wiley & Sons.
2688:10.1093/acref/9780199651450.001.0001
2678:A Dictionary of Chemical Engineering
2472:Earnshaw, A.; Greenwood, N. (1997).
2360:
2358:
1708:to give complexes containing amido (
2531:Webb, S. P.; Gordon, M. S. (1999).
1622:to give alkoxides with the formula
351:Key: XJDNKRIXUMDJCW-FOGBWSKZAG
338:InChI=1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
225:
2759:. Vol. 19. pp. 145–148.
2222:Toxicity and safety considerations
2037:of titanium typically starts from
1896:gives the pentacoordinate complex
1808:reacts to give yellow crystals of
1282:of titanium oxide ores, typically
25:
2924:. San Diego, CA: Academic Press.
2605:. Vol. 21. pp. 135–40.
1790:as implicated by its tendency to
1581:Alcoholysis and related reactions
2977:NIST Standard Reference Database
2391:"Classifications - CL Inventory"
936:
701:
696:
691:
45:
36:
1726:tetrakis(dimethylamido)titanium
932:(at 25 °C , 100 kPa).
469:reacts (exothermic hydrolysis)
5575:Reagents for organic chemistry
1453:Production of titanium dioxide
652:Occupational safety and health
1:
3183:Organotitanium(III) compounds
2508:10.1002/14356007.a27_095.pub2
1776:Complexes with simple ligands
1655:. A well known derivative is
1596:, signaled by the release of
1585:A characteristic reaction of
1119:adopts similar structures to
3811:Organotitanium(IV) compounds
3086:Organotitanium(II) compounds
2588:10.1016/0022-328X(96)06194-3
2166:Reagent in organic synthesis
1826:reacts to form sequentially
1553:It has been used to produce
1400:Production of titanium metal
1391:), which must be separated.
1151:react to give mixed halides
2682:. Oxford University Press.
2365:Zumdahl, Steven S. (2009).
1865:depends on the counterion.
1475:). The conversion involves
1206:form complexes of the type
409:189.679 g/mol
27:Inorganic chemical compound
5591:
5202:
2849:10.1016/j.poly.2005.10.019
2765:10.1002/9780470132500.ch33
2611:10.1002/9780470132524.ch31
2417:American Chemistry Council
2026:
1519:is oxidised directly with
1249:(L) give pentacoordinated
3902:
3887:
2944:Chemistry of the Elements
2942:; Earnshaw, Alan (1997).
2474:Chemistry of the Elements
926:
863:
672:
649:
644:
588:
547:
380:
360:
325:
78:
68:
58:
53:
44:
35:
2651:10.1002/14356007.n20_n04
2176:finds occasional use in
2035:organometallic chemistry
2023:Organometallic chemistry
1850:(see figure above), and
1716:-containing) and imido (
1241:to give hexacoordinated
1040:Properties and structure
760:Precautionary statements
2645:. Weinheim: Wiley-VCH.
2276:10.1023/A:1016673605744
2206:(RCHO) by formation of
2073:Ziegler–Natta catalysts
2029:Organotitanium compound
1819:. With chloride salts,
1486:, a process that forms
507:Magnetic susceptibility
71:Titanium tetrachloride
31:Titanium tetrachloride
5560:Titanium(IV) compounds
2180:, capitalizing on its
1659:, which is a monomer.
1577:
1449:instead of magnesium.
1074:is similar to that of
999:metal and the pigment
979:Titanium tetrachloride
975:
921:Titanium(III) chloride
905:Zirconium(IV) chloride
811:
513:−54.0·10 cm/mol
427:penetrating acid odor
214:Titanium+tetrachloride
2948:Butterworth-Heinemann
2940:Greenwood, Norman N.
2712:The Royal Navy at War
2478:Butterworth-Heinemann
2460:Iowa State University
2106:piano-stool complexes
2050:titanocene dichloride
1657:titanium isopropoxide
1576:
1371:silicon tetrachloride
1278:, which involves the
973:
917:Titanium(II) chloride
882:Titanium(IV) fluoride
810:
555:Coordination geometry
500:1.3 kPa (20 °C)
63:Titanium(IV) chloride
18:Titanium(IV) chloride
2874:10.1039/DT9750001402
2820:10.1039/JR9600003857
2347:Butts, Edward H De.
2190:Lewis acid catalysed
1998:coordination polymer
1615:Alcohols react with
1331:The coproduction of
901:Hafnium(IV) chloride
878:Titanium(IV) bromide
793:(fire diamond)
533:1.61 (10.5 °C)
2922:Inorganic Chemistry
2757:Inorganic Syntheses
2716:Imperial War Museum
2603:Inorganic Syntheses
2367:Chemical Principles
2349:"patent US3021349A"
1274:is produced by the
886:Titanium(IV) iodide
464:Solubility in water
73:Tetrachlorotitanium
32:
3520:Titanate compounds
3018:Titanium compounds
2639:Inorganic Pigments
2576:J. Organomet. Chem
2412:2013-02-17 at the
2104:react to give the
2081:trimethylaluminium
1924:, whereas smaller
1759:→ 4 LiCl + Ti(N(CH
1578:
1566:Chemical reactions
1457:Around 90% of the
983:inorganic compound
976:
959:Infobox references
864:Related compounds
812:
417:Colourless liquid
30:
5547:
5546:
5541:
5540:
3845:
3844:
3841:
3840:
3196:
3195:
3096:
3095:
2957:978-0-08-037941-8
2931:978-0-12-352651-9
2868:(14): 1402–1405.
2774:978-0-470-13250-0
2697:978-0-19-965145-0
2660:978-3-527-30673-2
2620:978-0-470-13252-4
2554:10.1021/ja983339i
2548:(11): 2552–2560.
2542:J. Am. Chem. Soc.
2517:978-3-527-30673-2
2376:978-0-618-94690-7
2228:hydrochloric acid
2178:organic synthesis
1653:organic synthesis
1649:materials science
1488:hydrogen chloride
1382:tin tetrachloride
1027:hydrochloric acid
967:Chemical compound
965:
964:
912:Related compounds
852:Safety data sheet
726:Hazard statements
640:−763 kJ·mol
613:355 J·mol·K
294:CompTox Dashboard
120:Interactive image
16:(Redirected from
5582:
5570:Titanium halides
5497:
3891:
3872:
3865:
3858:
3849:
3762:
3748:
3734:
3720:
3517:
3511:
3510:
3509:
3501:
3500:
3492:
3491:
3483:
3482:
3180:
3083:
3011:
3004:
2997:
2988:
2961:
2946:(2nd ed.).
2935:
2908:
2907:
2899:
2893:
2884:
2878:
2877:
2859:
2853:
2852:
2830:
2824:
2823:
2805:
2799:
2798:
2792:
2788:
2786:
2778:
2748:
2742:
2729:
2720:
2719:
2708:
2702:
2701:
2681:
2671:
2665:
2664:
2634:
2625:
2624:
2598:
2592:
2591:
2582:(1–2): 189–196.
2567:
2558:
2557:
2537:(X = F, Cl, Br)"
2528:
2522:
2521:
2495:
2482:
2481:
2476:(2nd ed.).
2469:
2463:
2458:
2452:
2444:
2442:
2441:
2432:. Archived from
2426:
2420:
2405:
2399:
2398:
2387:
2381:
2380:
2362:
2353:
2352:
2344:
2338:
2337:
2335:
2333:
2319:
2313:
2312:
2310:
2308:
2294:
2288:
2287:
2258:
2236:
2217:
2201:
2175:
2160:
2152:
2141:
2140:
2139:
2136:
2129:
2122:
2103:
2070:
2046:cyclopentadienyl
2043:
2018:
1994:
1982:
1967:
1939:
1923:
1895:
1888:
1864:
1857:
1849:
1837:
1825:
1818:
1807:
1785:
1771:
1741:
1722:titanium nitride
1719:
1715:
1707:
1693:
1634:
1621:
1591:
1544:
1518:
1508:
1485:
1474:
1466:titanium dioxide
1463:
1433:
1410:
1390:
1379:
1368:
1360:vanadyl chloride
1357:
1346:
1338:
1327:
1292:
1276:chloride process
1273:
1259:
1228:
1221:
1193:
1184:
1177:
1166:
1150:
1143:
1135:
1126:
1118:
1107:
1103:
1088:
1081:
1065:
1057:
1049:
1035:
1024:
1016:titanium dioxide
1009:
1001:titanium dioxide
994:
949:
943:
940:
939:
841:
840:
832:
825:
818:
803:
783:
779:
775:
771:
767:
753:
749:
745:
741:
737:
733:
705:
700:
695:
636:
609:
589:Thermochemistry
520:Refractive index
398:
388:Chemical formula
318:
317:
302:
300:
274:
238:
227:
216:
192:
184:
173:
162:
142:
122:
98:
49:
40:
33:
21:
5590:
5589:
5585:
5584:
5583:
5581:
5580:
5579:
5550:
5549:
5548:
5543:
5542:
5536:
5528:
5520:
5512:
5507:
5505:
5496:
5492:
5490:
5488:
5480:
5472:
5464:
5459:
5457:
5449:
5441:
5433:
5428:
5426:
5421:
5419:
5414:
5412:
5404:
5399:
5397:
5389:
5384:
5382:
5374:
5361:
5356:
5354:
5346:
5341:
5339:
5331:
5323:
5315:
5310:
5308:
5300:
5292:
5284:
5279:
5277:
5269:
5264:
5262:
5254:
5246:
5241:
5239:
5231:
5223:
5215:
5161:
5153:
5149:
5141:
5133:
5125:
5114:
5091:
5086:
5084:
5076:
5068:
5063:
5061:
5053:
5048:
5041:
5036:
5034:
5030:
5022:
5017:
5015:
5010:
5003:
4998:
4996:
4988:
4983:
4981:
4976:
4974:
4966:
4961:
4959:
4954:
4952:
4947:
4945:
4937:
4932:
4930:
4925:
4923:
4918:
4916:
4908:
4903:
4901:
4896:
4894:
4889:
4887:
4882:
4880:
4872:
4867:
4865:
4860:
4858:
4850:
4842:
4831:
4816:
4811:
4809:
4804:
4797:
4792:
4785:
4780:
4778:
4773:
4771:
4767:
4759:
4754:
4752:
4744:
4739:
4737:
4729:
4724:
4722:
4717:
4710:
4697:
4689:
4681:
4676:
4674:
4669:
4667:
4659:
4654:
4652:
4644:
4639:
4637:
4632:
4630:
4625:
4623:
4618:
4616:
4608:
4603:
4601:
4596:
4594:
4586:
4581:
4579:
4574:
4572:
4564:
4554:
4531:
4526:
4524:
4519:
4517:
4513:
4503:
4501:
4496:
4494:
4486:
4481:
4479:
4471:
4466:
4459:
4451:
4446:
4439:
4431:
4426:
4424:
4416:
4411:
4409:
4401:
4396:
4394:
4386:
4381:
4379:
4374:
4372:
4364:
4359:
4357:
4352:
4350:
4345:
4343:
4335:
4330:
4328:
4323:
4321:
4313:
4303:
4298:
4281:
4273:
4268:
4266:
4261:
4259:
4254:
4252:
4248:
4238:
4236:
4231:
4229:
4224:
4222:
4218:
4210:
4205:
4203:
4199:
4194:
4192:
4188:
4180:
4175:
4168:
4150:
4145:
4143:
4138:
4129:
4127:
4122:
4120:
4116:
4111:
4109:
4105:
4100:
4098:
4094:
4089:
4087:
4082:
4078:
4076:
4072:
4067:
4064:
4059:
4057:
4053:
4045:
4040:
4036:
4034:
4029:
4027:
4019:
4014:
4010:
4008:
4003:
4001:
3997:
3992:
3990:
3986:
3981:
3979:
3975:
3967:
3962:
3960:
3956:
3951:
3949:
3944:
3942:
3938:
3933:
3931:
3927:
3919:
3883:
3876:
3846:
3837:
3806:
3802:
3794:
3786:
3778:
3770:
3761:
3757:
3753:
3747:
3743:
3739:
3733:
3729:
3725:
3719:
3715:
3711:
3706:
3702:
3698:
3690:
3686:
3682:
3674:
3666:
3662:
3654:
3650:
3646:
3638:
3630:
3622:
3618:
3614:
3606:
3602:
3594:
3590:
3582:
3578:
3574:
3566:
3558:
3554:
3550:
3542:
3538:
3530:
3515:
3508:
3505:
3504:
3503:
3499:
3496:
3495:
3494:
3490:
3487:
3486:
3485:
3481:
3478:
3477:
3476:
3474:
3469:
3461:
3453:
3445:
3441:
3437:
3429:
3421:
3417:
3413:
3409:
3405:
3397:
3393:
3389:
3381:
3377:
3373:
3369:
3361:
3357:
3353:
3349:
3341:
3337:
3329:
3321:
3317:
3309:
3305:
3297:
3289:
3281:
3273:
3269:
3261:
3253:
3249:
3241:
3232:
3219:
3211:
3192:
3190:
3178:
3174:
3170:
3162:
3158:
3140:
3132:
3124:
3116:
3092:
3081:
3077:
3059:
3051:
3043:
3035:
3020:
3015:
2968:
2958:
2938:
2932:
2919:
2916:
2914:General reading
2911:
2901:
2900:
2896:
2885:
2881:
2861:
2860:
2856:
2832:
2831:
2827:
2807:
2806:
2802:
2789:
2779:
2775:
2750:
2749:
2745:
2730:
2723:
2714:(DVD). London:
2710:
2709:
2705:
2698:
2673:
2672:
2668:
2661:
2636:
2635:
2628:
2621:
2600:
2599:
2595:
2569:
2568:
2561:
2536:
2530:
2529:
2525:
2518:
2497:
2496:
2485:
2471:
2470:
2466:
2445:
2439:
2437:
2430:"Archived copy"
2428:
2427:
2423:
2414:Wayback Machine
2406:
2402:
2389:
2388:
2384:
2377:
2364:
2363:
2356:
2346:
2345:
2341:
2331:
2329:
2321:
2320:
2316:
2306:
2304:
2296:
2295:
2291:
2264:Colloid Journal
2260:
2259:
2255:
2251:
2235:
2231:
2224:
2215:
2211:
2200:
2196:
2174:
2170:
2168:
2159:
2155:
2151:
2147:
2137:
2134:
2133:
2131:
2128:
2124:
2120:
2116:
2112:
2108:
2102:
2098:
2094:
2090:
2077:Tebbe's reagent
2069:
2065:
2061:
2057:
2053:
2042:
2038:
2031:
2025:
2017:
2013:
2009:
1993:
1989:
1981:
1977:
1974:
1965:
1961:
1957:
1953:
1949:
1945:
1941:
1937:
1933:
1929:
1925:
1921:
1917:
1913:
1909:
1905:
1901:
1897:
1894:
1890:
1886:
1882:
1878:
1874:
1870:
1866:
1863:
1859:
1855:
1851:
1847:
1843:
1839:
1835:
1831:
1827:
1824:
1820:
1817:
1813:
1809:
1806:
1802:
1784:
1780:
1778:
1770:
1766:
1762:
1758:
1754:
1750:
1746:
1740:
1736:
1732:
1728:
1717:
1713:
1709:
1706:
1702:
1691:
1687:
1675:
1671:
1633:
1627:
1623:
1620:
1616:
1602:titanium oxides
1590:
1586:
1583:
1568:
1551:
1543:
1539:
1535:
1531:
1527:
1517:
1513:
1512:In some cases,
1506:
1502:
1498:
1494:
1484:
1480:
1473:
1469:
1462:
1458:
1455:
1431:
1427:
1423:
1409:
1405:
1402:
1397:
1389:
1385:
1378:
1374:
1367:
1363:
1356:
1352:
1345:
1341:
1337:
1333:
1325:
1321:
1317:
1313:
1309:
1291:
1287:
1272:
1268:
1266:
1257:
1253:
1227:
1223:
1219:
1215:
1211:
1207:
1192:
1188:
1183:
1179:
1176:
1172:
1165:
1159:
1152:
1149:
1145:
1142:
1138:
1134:
1130:
1125:
1121:
1117:
1113:
1105:
1102:
1098:
1086:
1080:
1076:
1064:
1060:
1056:
1052:
1048:
1044:
1042:
1034:
1030:
1023:
1019:
1008:
1004:
993:
989:
968:
961:
956:
955:
954: ?)
945:
941:
937:
933:
919:
913:
903:
897:
884:
880:
874:
846:
845:
844:
843:
838:
834:
827:
820:
813:
809:
801:
762:
728:
714:
688:
662:
637:
634:
628:
624:
621:
620:Std enthalpy of
610:
607:
600:
597:
581:
569:
567:Molecular shape
557:
530:
528:
510:
481:dichloromethane
466:
397:
393:
390:
376:
373:
368:
367:
356:
353:
352:
349:
343:
342:
339:
333:
332:
321:
303:
296:
277:
257:
241:
228:
202:
165:
145:
125:
112:
101:
88:
74:
72:
64:
28:
23:
22:
15:
12:
11:
5:
5588:
5586:
5578:
5577:
5572:
5567:
5562:
5552:
5551:
5545:
5544:
5539:
5538:
5534:
5530:
5526:
5522:
5518:
5514:
5510:
5503:
5499:
5486:
5482:
5478:
5474:
5470:
5466:
5462:
5455:
5451:
5447:
5443:
5439:
5435:
5431:
5424:
5417:
5410:
5406:
5402:
5395:
5391:
5387:
5380:
5376:
5372:
5368:
5364:
5363:
5359:
5352:
5348:
5344:
5337:
5333:
5329:
5325:
5321:
5317:
5313:
5306:
5302:
5298:
5294:
5290:
5286:
5282:
5275:
5271:
5267:
5260:
5256:
5252:
5248:
5244:
5237:
5233:
5229:
5225:
5221:
5217:
5213:
5209:
5205:
5204:
5201:
5198:
5197:
5194:
5191:
5188:
5185:
5182:
5179:
5176:
5173:
5170:
5167:
5164:
5159:
5155:
5151:
5147:
5143:
5139:
5135:
5131:
5127:
5123:
5119:
5116:
5112:
5108:
5102:
5101:
5098:
5093:
5089:
5082:
5078:
5074:
5070:
5066:
5059:
5055:
5051:
5043:
5039:
5032:
5028:
5024:
5020:
5013:
5005:
5001:
4994:
4990:
4986:
4979:
4972:
4968:
4964:
4957:
4950:
4943:
4939:
4935:
4928:
4921:
4914:
4910:
4906:
4899:
4892:
4885:
4878:
4874:
4870:
4863:
4856:
4852:
4848:
4844:
4840:
4836:
4833:
4829:
4825:
4819:
4818:
4814:
4807:
4799:
4795:
4787:
4783:
4776:
4769:
4765:
4761:
4757:
4750:
4746:
4742:
4735:
4731:
4727:
4720:
4712:
4708:
4704:
4699:
4695:
4691:
4687:
4683:
4679:
4672:
4665:
4661:
4657:
4650:
4646:
4642:
4635:
4628:
4621:
4614:
4610:
4606:
4599:
4592:
4588:
4584:
4577:
4570:
4566:
4562:
4558:
4556:
4552:
4548:
4542:
4541:
4538:
4533:
4529:
4522:
4515:
4511:
4507:
4499:
4492:
4488:
4484:
4477:
4473:
4469:
4461:
4457:
4453:
4449:
4441:
4437:
4433:
4429:
4422:
4418:
4414:
4407:
4403:
4399:
4392:
4388:
4384:
4377:
4370:
4366:
4362:
4355:
4348:
4341:
4337:
4333:
4326:
4319:
4315:
4311:
4307:
4305:
4301:
4293:
4287:
4286:
4283:
4279:
4275:
4271:
4264:
4257:
4250:
4246:
4242:
4234:
4227:
4220:
4216:
4212:
4208:
4201:
4197:
4190:
4186:
4182:
4178:
4170:
4166:
4162:
4156:
4155:
4152:
4148:
4141:
4133:
4125:
4118:
4114:
4107:
4103:
4096:
4092:
4085:
4074:
4070:
4062:
4055:
4051:
4047:
4043:
4032:
4025:
4021:
4017:
4006:
3999:
3995:
3988:
3984:
3977:
3973:
3969:
3965:
3958:
3954:
3947:
3940:
3936:
3929:
3925:
3921:
3917:
3913:
3907:
3906:
3903:
3901:
3899:
3897:
3889:
3888:
3885:
3884:
3877:
3875:
3874:
3867:
3860:
3852:
3843:
3842:
3839:
3838:
3836:
3835:
3831:
3827:
3823:
3819:
3814:
3812:
3808:
3807:
3805:
3804:
3800:
3796:
3792:
3788:
3784:
3780:
3776:
3772:
3768:
3764:
3750:
3736:
3722:
3708:
3704:
3700:
3696:
3692:
3688:
3684:
3680:
3676:
3672:
3668:
3664:
3660:
3656:
3652:
3648:
3644:
3640:
3636:
3632:
3628:
3624:
3620:
3616:
3612:
3608:
3604:
3600:
3596:
3592:
3588:
3584:
3580:
3576:
3572:
3568:
3564:
3560:
3556:
3552:
3548:
3544:
3540:
3536:
3532:
3528:
3523:
3521:
3514:
3513:
3506:
3497:
3488:
3479:
3471:
3467:
3463:
3459:
3455:
3451:
3447:
3443:
3439:
3435:
3431:
3427:
3423:
3419:
3415:
3411:
3407:
3403:
3399:
3395:
3391:
3387:
3383:
3379:
3375:
3371:
3367:
3363:
3359:
3355:
3351:
3347:
3343:
3339:
3335:
3331:
3327:
3323:
3319:
3315:
3311:
3307:
3303:
3299:
3295:
3291:
3287:
3283:
3279:
3275:
3271:
3267:
3263:
3259:
3255:
3251:
3247:
3243:
3239:
3235:
3230:
3226:
3221:
3217:
3213:
3209:
3204:
3202:
3198:
3197:
3194:
3193:
3188:
3186:
3184:
3177:
3176:
3172:
3168:
3164:
3160:
3156:
3152:
3147:
3142:
3138:
3134:
3130:
3126:
3122:
3118:
3114:
3110:
3104:
3102:
3098:
3097:
3094:
3093:
3089:
3087:
3080:
3079:
3075:
3071:
3066:
3061:
3057:
3053:
3049:
3045:
3041:
3037:
3033:
3028:
3026:
3022:
3021:
3016:
3014:
3013:
3006:
2999:
2991:
2985:
2984:
2979:
2974:
2967:
2966:External links
2964:
2963:
2962:
2956:
2936:
2930:
2915:
2912:
2910:
2909:
2894:
2879:
2854:
2843:(4): 923–929.
2825:
2800:
2791:|journal=
2773:
2743:
2721:
2703:
2696:
2666:
2659:
2626:
2619:
2593:
2559:
2534:
2523:
2516:
2483:
2464:
2421:
2400:
2395:echa.europa.eu
2382:
2375:
2354:
2339:
2314:
2289:
2270:(2): 173–178.
2252:
2250:
2247:
2223:
2220:
2193:aldol addition
2167:
2164:
2027:Main article:
2024:
2021:
1973:
1970:
1777:
1774:
1773:
1772:
1695:
1694:
1582:
1579:
1567:
1564:
1550:
1547:
1546:
1545:
1510:
1509:
1454:
1451:
1447:reducing agent
1439:Hunter process
1435:
1434:
1401:
1398:
1396:
1393:
1329:
1328:
1318:+ 6 C → 2 TiCl
1297:under flowing
1265:
1262:
1231:exothermically
1194:is soluble in
1097:structure for
1041:
1038:
966:
963:
962:
957:
935:
934:
930:standard state
927:
924:
923:
914:
911:
908:
907:
898:
892:
889:
888:
875:
869:
866:
865:
861:
860:
855:
848:
847:
835:
828:
821:
814:
799:
798:
797:
796:
794:
785:
784:
778:P305+P351+P338
770:P301+P330+P331
763:
758:
755:
754:
729:
724:
721:
720:
715:
710:
707:
706:
689:
684:
681:
680:
670:
669:
663:
660:
657:
656:
647:
646:
642:
641:
638:
632:
626:
618:
615:
614:
611:
605:
594:
591:
590:
586:
585:
582:
577:
574:
573:
570:
565:
562:
561:
558:
553:
550:
549:
545:
544:
541:
535:
534:
531:
526:
518:
515:
514:
511:
505:
502:
501:
498:
496:Vapor pressure
492:
491:
477:
471:
470:
467:
462:
459:
458:
455:
449:
448:
445:
439:
438:
435:
429:
428:
425:
419:
418:
415:
411:
410:
407:
401:
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391:
386:
383:
382:
378:
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371:
363:
362:
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357:
355:
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350:
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344:
340:
337:
336:
328:
327:
326:
323:
322:
320:
319:
306:
304:
292:
289:
288:
285:
279:
278:
276:
275:
267:
265:
259:
258:
256:
255:
251:
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210:
204:
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200:
196:
194:
186:
185:
175:
167:
166:
164:
163:
155:
153:
147:
146:
144:
143:
135:
133:
127:
126:
124:
123:
115:
113:
106:
103:
102:
100:
99:
91:
89:
84:
81:
80:
76:
75:
70:
66:
65:
62:
56:
55:
51:
50:
42:
41:
26:
24:
14:
13:
10:
9:
6:
4:
3:
2:
5587:
5576:
5573:
5571:
5568:
5566:
5563:
5561:
5558:
5557:
5555:
5537:
5531:
5529:
5523:
5521:
5515:
5513:
5506:
5500:
5498:
5489:
5483:
5481:
5475:
5473:
5467:
5465:
5458:
5452:
5450:
5444:
5442:
5436:
5434:
5427:
5420:
5413:
5407:
5405:
5398:
5392:
5390:
5383:
5377:
5375:
5369:
5366:
5365:
5362:
5355:
5349:
5347:
5340:
5334:
5332:
5326:
5324:
5318:
5316:
5309:
5303:
5301:
5295:
5293:
5287:
5285:
5278:
5272:
5270:
5263:
5257:
5255:
5249:
5247:
5240:
5234:
5232:
5226:
5224:
5218:
5216:
5210:
5207:
5206:
5199:
5195:
5192:
5189:
5186:
5183:
5180:
5177:
5174:
5171:
5168:
5165:
5163:
5156:
5154:
5144:
5142:
5136:
5134:
5128:
5126:
5120:
5117:
5115:
5109:
5107:
5104:
5103:
5099:
5097:
5094:
5092:
5085:
5079:
5077:
5071:
5069:
5062:
5056:
5054:
5047:
5044:
5042:
5035:
5025:
5023:
5016:
5009:
5006:
5004:
4997:
4991:
4989:
4982:
4975:
4969:
4967:
4960:
4953:
4946:
4940:
4938:
4931:
4924:
4917:
4911:
4909:
4902:
4895:
4888:
4881:
4875:
4873:
4866:
4859:
4853:
4851:
4845:
4843:
4837:
4834:
4832:
4826:
4824:
4821:
4820:
4817:
4810:
4803:
4800:
4798:
4791:
4788:
4786:
4779:
4772:
4762:
4760:
4753:
4747:
4745:
4738:
4732:
4730:
4723:
4716:
4713:
4711:
4705:
4703:
4700:
4698:
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4690:
4684:
4682:
4675:
4668:
4662:
4660:
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4611:
4609:
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4460:
4454:
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4434:
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4425:
4419:
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4410:
4404:
4402:
4395:
4389:
4387:
4380:
4373:
4367:
4365:
4358:
4351:
4344:
4338:
4336:
4329:
4322:
4316:
4314:
4308:
4306:
4304:
4297:
4294:
4292:
4289:
4288:
4284:
4282:
4276:
4274:
4267:
4260:
4253:
4243:
4241:
4237:
4230:
4223:
4213:
4211:
4204:
4193:
4183:
4181:
4174:
4171:
4169:
4163:
4161:
4158:
4157:
4153:
4151:
4144:
4137:
4134:
4132:
4128:
4121:
4110:
4099:
4088:
4081:
4077:
4066:
4058:
4048:
4046:
4039:
4035:
4028:
4022:
4020:
4013:
4009:
4002:
3991:
3980:
3970:
3968:
3961:
3950:
3943:
3932:
3922:
3920:
3914:
3912:
3909:
3908:
3904:
3898:
3896:
3893:
3892:
3886:
3881:
3873:
3868:
3866:
3861:
3859:
3854:
3853:
3850:
3834:
3832:
3830:
3828:
3826:
3824:
3822:
3820:
3818:
3816:
3815:
3813:
3809:
3803:
3797:
3795:
3789:
3787:
3781:
3779:
3773:
3771:
3765:
3763:
3751:
3749:
3737:
3735:
3723:
3721:
3709:
3707:
3693:
3691:
3677:
3675:
3669:
3667:
3657:
3655:
3641:
3639:
3633:
3631:
3625:
3623:
3609:
3607:
3597:
3595:
3585:
3583:
3569:
3567:
3561:
3559:
3545:
3543:
3533:
3531:
3525:
3524:
3522:
3518:
3512:
3472:
3470:
3464:
3462:
3456:
3454:
3448:
3446:
3432:
3430:
3424:
3422:
3400:
3398:
3384:
3382:
3364:
3362:
3344:
3342:
3332:
3330:
3324:
3322:
3312:
3310:
3300:
3298:
3292:
3290:
3284:
3282:
3276:
3274:
3264:
3262:
3256:
3254:
3244:
3242:
3236:
3234:
3227:
3225:
3222:
3220:
3214:
3212:
3206:
3205:
3203:
3199:
3191:
3185:
3181:
3175:
3165:
3163:
3153:
3151:
3148:
3146:
3143:
3141:
3135:
3133:
3127:
3125:
3119:
3117:
3111:
3109:
3106:
3105:
3103:
3101:Titanium(III)
3099:
3091:
3088:
3084:
3078:
3072:
3070:
3067:
3065:
3062:
3060:
3054:
3052:
3046:
3044:
3038:
3036:
3030:
3029:
3027:
3023:
3019:
3012:
3007:
3005:
3000:
2998:
2993:
2992:
2989:
2983:
2980:
2978:
2975:
2973:
2970:
2969:
2965:
2959:
2953:
2949:
2945:
2941:
2937:
2933:
2927:
2923:
2918:
2917:
2913:
2905:
2898:
2895:
2892:, p. 151-166.
2891:
2890:
2883:
2880:
2875:
2871:
2867:
2866:
2865:Dalton Trans.
2858:
2855:
2850:
2846:
2842:
2838:
2837:
2829:
2826:
2821:
2817:
2814:: 3857–3861.
2813:
2812:
2811:J. Chem. Soc.
2804:
2801:
2796:
2784:
2776:
2770:
2766:
2762:
2758:
2754:
2747:
2744:
2741:
2740:0-387-15784-0
2737:
2734:
2728:
2726:
2722:
2717:
2713:
2707:
2704:
2699:
2693:
2689:
2685:
2680:
2679:
2670:
2667:
2662:
2656:
2652:
2648:
2644:
2640:
2633:
2631:
2627:
2622:
2616:
2612:
2608:
2604:
2597:
2594:
2589:
2585:
2581:
2577:
2573:
2566:
2564:
2560:
2555:
2551:
2547:
2544:
2543:
2538:
2527:
2524:
2519:
2513:
2509:
2505:
2501:
2494:
2492:
2490:
2488:
2484:
2479:
2475:
2468:
2465:
2461:
2456:
2450:
2436:on 2014-03-19
2435:
2431:
2425:
2422:
2418:
2415:
2411:
2408:
2404:
2401:
2396:
2392:
2386:
2383:
2378:
2372:
2368:
2361:
2359:
2355:
2350:
2343:
2340:
2328:
2327:Sigma-Aldrich
2324:
2318:
2315:
2303:
2299:
2293:
2290:
2285:
2281:
2277:
2273:
2269:
2265:
2257:
2254:
2248:
2246:
2244:
2240:
2229:
2221:
2219:
2209:
2205:
2194:
2191:
2187:
2183:
2182:Lewis acidity
2179:
2165:
2163:
2161:
2145:
2107:
2088:
2084:
2082:
2078:
2074:
2051:
2047:
2036:
2030:
2022:
2020:
2007:
2003:
1999:
1995:
1986:
1976:Reduction of
1971:
1969:
1800:
1797:
1793:
1789:
1775:
1745:
1744:
1743:
1727:
1723:
1700:
1683:
1679:
1670:
1669:
1668:
1666:
1665:acetylacetone
1662:
1658:
1654:
1650:
1646:
1642:
1638:
1632:
1613:
1611:
1607:
1603:
1599:
1595:
1580:
1575:
1571:
1565:
1563:
1561:
1556:
1555:smoke screens
1549:Smoke screens
1548:
1526:
1525:
1524:
1522:
1493:
1492:
1491:
1489:
1478:
1467:
1452:
1450:
1448:
1444:
1440:
1422:
1421:
1420:
1418:
1417:Kroll process
1414:
1399:
1394:
1392:
1383:
1372:
1361:
1350:
1349:sulfuric acid
1339:
1308:
1307:
1306:
1304:
1300:
1296:
1285:
1281:
1277:
1263:
1261:
1252:
1248:
1244:
1240:
1236:
1232:
1205:
1201:
1200:chlorocarbons
1197:
1186:
1170:
1164:
1158:
1136:
1127:
1111:
1096:
1092:
1084:
1082:
1073:
1072:melting point
1069:
1058:
1039:
1037:
1028:
1017:
1013:
1002:
998:
988:
984:
980:
972:
960:
953:
948:
931:
925:
922:
918:
915:
910:
909:
906:
902:
899:
896:
891:
890:
887:
883:
879:
876:
873:
868:
867:
862:
859:
856:
853:
850:
849:
842:
833:
826:
819:
795:
792:
791:
787:
786:
764:
761:
757:
756:
730:
727:
723:
722:
719:
716:
713:
709:
708:
704:
699:
694:
690:
687:
683:
682:
678:
676:
671:
668:
664:
659:
658:
654:
653:
648:
643:
639:
631:
623:
617:
616:
612:
604:
599:
593:
592:
587:
583:
580:
579:Dipole moment
576:
575:
571:
568:
564:
563:
559:
556:
552:
551:
546:
542:
540:
537:
536:
532:
525:
521:
517:
516:
512:
508:
504:
503:
499:
497:
494:
493:
490:
486:
482:
478:
476:
473:
472:
468:
465:
461:
460:
456:
454:
453:Boiling point
451:
450:
446:
444:
443:Melting point
441:
440:
436:
434:
431:
430:
426:
424:
421:
420:
416:
413:
412:
408:
406:
403:
402:
392:
389:
385:
384:
379:
370:
366:
359:
345:
335:
331:
324:
316:
312:
311:DTXSID8042476
308:
307:
305:
295:
291:
290:
286:
284:
281:
280:
273:
269:
268:
266:
264:
261:
260:
253:
252:
250:
248:
245:
244:
237:
233:
232:
230:
224:
220:
219:
215:
211:
209:
206:
205:
198:
197:
195:
193:
188:
187:
183:
179:
176:
174:
172:ECHA InfoCard
169:
168:
161:
157:
156:
154:
152:
149:
148:
141:
137:
136:
134:
132:
129:
128:
121:
117:
116:
114:
110:
105:
104:
97:
93:
92:
90:
87:
83:
82:
77:
67:
61:
57:
52:
48:
43:
39:
34:
19:
4331:
3237:
3201:Titanium(IV)
3025:Titanium(II)
2943:
2921:
2903:
2897:
2887:
2882:
2863:
2857:
2840:
2834:
2828:
2809:
2803:
2756:
2752:
2746:
2732:
2711:
2706:
2677:
2669:
2642:
2638:
2602:
2596:
2579:
2575:
2571:
2545:
2540:
2526:
2499:
2473:
2467:
2438:. Retrieved
2434:the original
2424:
2403:
2394:
2385:
2366:
2342:
2330:. Retrieved
2326:
2317:
2305:. Retrieved
2301:
2292:
2267:
2263:
2256:
2237:is a strong
2225:
2202:to activate
2186:oxophilicity
2169:
2085:
2032:
2002:paramagnetic
1975:
1779:
1696:
1640:
1630:
1614:
1610:smokescreens
1606:oxychlorides
1592:is its easy
1584:
1569:
1560:hydrated HCl
1552:
1511:
1456:
1436:
1403:
1395:Applications
1330:
1303:distillation
1267:
1187:
1168:
1162:
1156:
1085:
1043:
978:
977:
789:
717:
674:
661:Main hazards
650:
629:
602:
572:Tetrahedral
523:
372:Cl(Cl)(Cl)Cl
247:RTECS number
140:CHEBI:231499
79:Identifiers
69:Other names
3442:·20TiO
3434:NiO·Sb
2245:and water.
1794:. With the
1701:react with
1651:as well as
1624:[Ti(OR)
1600:vapors and
1424:2 Mg + TiCl
1233:with donor
1110:symmetrical
1095:tetrahedral
712:Signal word
655:(OHS/OSH):
560:Tetragonal
479:soluble in
437:1.726 g/cm
414:Appearance
381:Properties
178:100.028.584
5554:Categories
3783:Pb(Zr,Ti)O
2836:Polyhedron
2440:2013-04-10
2302:Alfa Aesar
2249:References
2239:Lewis acid
2212:(RCHO)TiCl
2089:, such as
1918:][TiCl
1788:Lewis acid
1594:hydrolysis
1477:hydrolysis
1264:Production
1245:. Bulkier
1202:. Certain
686:Pictograms
548:Structure
543:827 μPa s
475:Solubility
405:Molar mass
272:8O3PJE5T7Q
151:ChemSpider
107:3D model (
86:CAS Number
60:IUPAC name
5565:Chlorides
3386:Ti(OCH(CH
2793:ignored (
2783:cite book
2204:aldehydes
2109:[Ti(C
2000:, and is
1985:aluminium
1942:[N(CH
1926:[N(CH
1898:[N(CH
1867:[N(CH
1852:[TiCl
1792:hydrolyze
1645:alkoxides
1441:, liquid
1413:magnesium
1280:reduction
985:with the
782:P308+P310
774:P304+P340
677:labelling
622:formation
596:Std molar
539:Viscosity
283:UN number
254:XR1925000
199:231-441-9
191:EC Number
96:7550-45-0
3880:chloride
2449:cite web
2410:Archived
2284:93971747
2210:such as
2144:chloride
2123:(R = H,
2048:to give
1747:4 LiN(CH
1697:Organic
1428:→ 2 MgCl
1351:. Crude
1322:+ 2 FeCl
1299:chlorine
1293:), with
1284:ilmenite
1237:such as
1235:solvents
1167:, where
1068:polymers
1012:volatile
997:titanium
790:NFPA 704
645:Hazards
509:(χ)
5203:
3627:EuBaTiO
2889:Arkivoc
2718:. 2005.
2332:7 March
2307:7 March
2208:adducts
1958:[Ti
1840:[Ti
1828:[Ti
1729:Ti(N(CH
1692:+ 2 HCl
1507:+ 4 HCl
1503:O → TiO
1445:is the
1437:In the
1380:), and
1310:2 FeTiO
1251:adducts
1247:ligands
1243:adducts
1229:reacts
1208:[(C
1196:toluene
987:formula
981:is the
952:what is
950: (
895:cations
598:entropy
489:pentane
485:toluene
433:Density
399:
223:PubChem
3587:CaZrTi
3426:KTiOPO
3402:Ti(OCH
3302:Ti(NMe
3246:Ti(ClO
2954:
2928:
2771:
2738:
2694:
2657:
2617:
2514:
2373:
2282:
2216:OC(H)R
2184:, its
2087:Arenes
1940:gives
1755:+ TiCl
1699:amines
1540:+ 2 Cl
1521:oxygen
1443:sodium
1326:+ 6 CO
1314:+ 7 Cl
1295:carbon
1204:arenes
1093:. The
1025:) and
947:verify
944:
893:Other
872:anions
870:Other
854:(SDS)
718:Danger
365:SMILES
54:Names
3799:ZnTiO
3791:SrTiO
3775:PbTiO
3767:NiTiO
3671:MnTiO
3635:FeTiO
3563:CaTiO
3527:BaTiO
3314:Ti(NO
3294:TiOSO
3229:TiS(S
2280:S2CID
2146:from
2014:(THF)
1983:with
1972:Redox
1814:(THF)
1796:ether
1786:is a
1680:→ Ti(
1678:Hacac
1637:alkyl
1635:(R =
1536:→ TiO
1499:+ 2 H
1288:FeTiO
1216:)TiCl
1091:argon
1010:is a
330:InChI
287:1838
236:24193
160:22615
131:ChEBI
109:JSmol
5533:NoCl
5525:MdCl
5517:FmCl
5509:EsCl
5502:EsCl
5493:CfCl
5485:CfCl
5477:BkCl
5469:CmCl
5461:AmCl
5454:AmCl
5446:PuCl
5438:NpCl
5401:PaCl
5394:PaCl
5386:ThCl
5379:ThCl
5371:AcCl
5358:YbCl
5351:YbCl
5343:TmCl
5336:TmCl
5328:ErCl
5320:HoCl
5312:DyCl
5305:DyCl
5297:TbCl
5289:GdCl
5281:EuCl
5274:EuCl
5266:SmCl
5259:SmCl
5251:PmCl
5243:NdCl
5236:NdCl
5228:PrCl
5220:CeCl
5212:LaCl
5138:DbCl
5130:RfCl
5122:LrCl
5111:RaCl
5106:FrCl
5096:AtCl
5088:PoCl
5081:PoCl
5073:BiCl
5065:PbCl
5058:PbCl
5050:TlCl
5046:TlCl
5038:HgCl
5019:AuCl
5012:(Au)
5008:AuCl
5000:PtCl
4993:PtCl
4985:IrCl
4978:IrCl
4971:IrCl
4963:OsCl
4956:OsCl
4949:OsCl
4942:OsCl
4934:ReCl
4927:ReCl
4920:ReCl
4913:ReCl
4869:TaCl
4862:TaCl
4855:TaCl
4847:HfCl
4839:LuCl
4828:BaCl
4823:CsCl
4813:XeCl
4806:XeCl
4802:XeCl
4782:TeCl
4775:TeCl
4756:SbCl
4749:SbCl
4741:SnCl
4734:SnCl
4726:InCl
4719:InCl
4715:InCl
4707:CdCl
4702:AgCl
4694:PdCl
4686:RhCl
4678:RuCl
4671:RuCl
4664:RuCl
4656:TcCl
4649:TcCl
4641:MoCl
4634:MoCl
4627:MoCl
4620:MoCl
4613:MoCl
4605:NbCl
4598:NbCl
4591:NbCl
4583:ZrCl
4576:ZrCl
4569:ZrCl
4551:SrCl
4546:RbCl
4536:BrCl
4528:SeCl
4521:SeCl
4498:AsCl
4491:AsCl
4483:GeCl
4476:GeCl
4468:GaCl
4464:GaCl
4456:ZnCl
4448:CuCl
4444:CuCl
4436:NiCl
4428:CoCl
4421:CoCl
4413:FeCl
4406:FeCl
4398:MnCl
4391:MnCl
4383:CrCl
4376:CrCl
4369:CrCl
4332:TiCl
4325:TiCl
4318:TiCl
4310:ScCl
4300:CaCl
4296:CaCl
4207:SiCl
4177:AlCl
4173:AlCl
4165:MgCl
4160:NaCl
3916:BeCl
3911:LiCl
3571:CaCu
3475:Ti(C
3466:TiSi
3458:TiSe
3370:(OCH
3346:Ti(C
3238:TiCl
3216:TiBr
3121:TiCl
3113:TiBr
3108:TiAl
3074:TiSi
3048:TiBr
3032:TiCl
2952:ISBN
2926:ISBN
2795:help
2769:ISBN
2736:ISBN
2733:1986
2692:ISBN
2655:ISBN
2615:ISBN
2512:ISBN
2455:link
2371:ISBN
2334:2018
2309:2018
2232:TiCl
2197:TiCl
2171:TiCl
2156:AlCl
2148:TiCl
2132:TiCl
2054:TiCl
2039:TiCl
2033:The
2010:TiCl
1990:TiCl
1978:TiCl
1891:TiCl
1889:and
1860:TiCl
1821:TiCl
1810:TiCl
1803:TiCl
1781:TiCl
1703:TiCl
1682:acac
1676:+ 2
1672:TiCl
1617:TiCl
1604:and
1587:TiCl
1528:TiCl
1514:TiCl
1495:TiCl
1481:TiCl
1459:TiCl
1432:+ Ti
1406:TiCl
1386:SnCl
1375:SiCl
1364:VOCl
1353:TiCl
1334:FeCl
1269:TiCl
1254:TiCl
1224:TiCl
1198:and
1189:TiCl
1178:and
1173:TiCl
1153:TiCl
1146:TiBr
1144:and
1139:TiCl
1128:and
1122:TiBr
1114:TiCl
1099:TiCl
1061:TiCl
1045:TiCl
1031:TiCl
1005:TiCl
990:TiCl
858:MSDS
766:P280
752:H372
748:H370
744:H335
740:H330
736:H317
732:H314
584:0 D
423:Odor
394:TiCl
263:UNII
208:MeSH
5430:UCl
5423:UCl
5416:UCl
5409:UCl
5367:**
5196:Og
5193:Ts
5190:Lv
5187:Mc
5184:Fl
5181:Nh
5178:Cn
5175:Rg
5172:Ds
5169:Mt
5166:Hs
5158:BhO
5146:SgO
5118:**
5100:Rn
4905:WCl
4898:WCl
4891:WCl
4884:WCl
4877:WCl
4794:ICl
4790:ICl
4561:YCl
4540:Kr
4505:+As
4361:VCl
4354:VCl
4347:VCl
4340:VCl
4291:KCl
4285:Ar
4270:+SO
4263:SCl
4256:SCl
4233:PCl
4226:PCl
4154:Ne
4147:ClF
4140:ClF
4136:ClF
4124:ClO
4084:ClO
4080:ClO
4042:+NO
4031:ClN
4024:NCl
4016:+CO
4005:CCl
3964:+BO
3946:BCl
3905:He
3895:HCl
3882:ion
3758:TiF
3744:TiF
3730:TiF
3716:TiF
3703:TiO
3701:0.5
3697:0.5
3663:TiO
3603:TiO
3539:TiO
3450:TiS
3338:TiO
3326:TiO
3286:TiI
3278:TiH
3270:TiF
3258:TiF
3224:TiC
3208:TiB
3150:TiP
3145:TiN
3137:TiI
3129:TiF
3069:TiS
3064:TiO
3056:TiI
3040:TiH
2870:doi
2845:doi
2816:doi
2761:doi
2753:Cis
2684:doi
2647:doi
2607:doi
2584:doi
2580:518
2550:doi
2546:121
2504:doi
2272:doi
2243:THF
2153:by
2117:)Cl
2095:(CH
2006:THF
1887:]Cl
1799:THF
1598:HCl
1532:+ O
1479:of
1470:TiO
1369:),
1342:TiO
1239:THF
1180:VCl
1131:TiI
1077:CCl
1053:VCl
1036:).
1020:TiO
675:GHS
667:HCl
633:298
606:298
299:EPA
226:CID
5556::
5208:*
5162:Cl
5150:Cl
5031:Cl
5027:Hg
4835:*
4768:Cl
4764:Te
4514:Cl
4510:Se
4278:Cl
4249:Cl
4240:+P
4219:Cl
4200:Cl
4196:Si
4191:12
4189:Cl
4185:Si
4131:+O
4113:Cl
4102:Cl
4091:Cl
4069:Cl
4061:Cl
4050:Cl
4038:+N
4012:+C
3998:Cl
3987:Cl
3976:Cl
3957:Cl
3941:12
3939:Cl
3937:12
3928:Cl
3754:Rb
3740:Li
3712:Na
3699:Bi
3695:Na
3683:Ti
3679:Na
3659:Li
3647:Ti
3643:Ho
3615:Ti
3611:Dy
3599:Cs
3581:12
3575:Ti
3557:12
3551:Ti
3547:Bi
3535:Ba
3414:CH
3410:CH
3406:CH
3380:16
3374:CH
3366:Ti
3167:Ti
3155:Ti
2950:.
2841:25
2839:.
2787::
2785:}}
2781:{{
2767:.
2724:^
2690:.
2653:.
2641:.
2629:^
2613:.
2578:.
2562:^
2539:.
2510:.
2486:^
2451:}}
2447:{{
2393:.
2357:^
2325:.
2300:.
2278:.
2268:63
2266:.
2218:.
2162:.
2125:CH
2075:.
2058:(C
2052:,
2019:.
1964:10
1962:Cl
1946:CH
1930:CH
1910:CH
1906:CH
1902:CH
1879:CH
1875:CH
1871:CH
1846:10
1844:Cl
1838:,
1832:Cl
1801:,
1718:RN
1688:Cl
1667::
1639:,
1523::
1490::
1419::
1305:.
1260:.
1222:.
1185:.
1160:Br
1155:4−
1106:Ti
1087:Ti
1083:.
1003:.
780:,
776:,
772:,
768:,
750:,
746:,
742:,
738:,
734:,
679::
625:(Δ
487:,
483:,
5535:2
5527:2
5519:2
5511:3
5504:2
5495:2
5487:3
5479:3
5471:3
5463:3
5456:2
5448:3
5440:3
5432:6
5425:5
5418:4
5411:3
5403:5
5396:4
5388:4
5381:3
5373:3
5360:3
5353:2
5345:3
5338:2
5330:3
5322:3
5314:3
5307:2
5299:3
5291:3
5283:3
5276:2
5268:3
5261:2
5253:3
5245:3
5238:2
5230:3
5222:3
5214:3
5160:3
5152:2
5148:2
5140:5
5132:4
5124:3
5113:2
5090:4
5083:2
5075:3
5067:4
5060:2
5052:3
5040:2
5033:2
5029:2
5021:3
5014:2
5002:4
4995:2
4987:4
4980:3
4973:2
4965:5
4958:4
4951:3
4944:2
4936:6
4929:5
4922:4
4915:3
4907:6
4900:5
4893:4
4886:3
4879:2
4871:5
4864:4
4857:3
4849:4
4841:3
4830:2
4815:4
4808:2
4796:3
4784:4
4777:2
4770:2
4766:3
4758:5
4751:3
4743:4
4736:2
4728:3
4721:2
4709:2
4696:2
4688:3
4680:4
4673:3
4666:2
4658:4
4651:3
4643:6
4636:5
4629:4
4622:3
4615:2
4607:5
4600:4
4593:3
4585:4
4578:3
4571:2
4563:3
4553:2
4530:4
4523:2
4516:2
4512:2
4500:5
4493:3
4485:4
4478:2
4470:3
4458:2
4450:2
4438:2
4430:3
4423:2
4415:3
4408:2
4400:3
4393:2
4385:4
4378:3
4371:2
4363:5
4356:4
4349:3
4342:2
4334:4
4327:3
4320:2
4312:3
4302:2
4280:2
4272:4
4265:4
4258:2
4251:2
4247:2
4245:S
4235:5
4228:3
4221:4
4217:2
4215:P
4209:4
4202:6
4198:2
4187:5
4179:3
4167:2
4149:5
4142:3
4126:4
4119:7
4117:O
4115:2
4108:6
4106:O
4104:2
4097:4
4095:O
4093:2
4086:2
4075:2
4073:O
4071:2
4065:O
4063:2
4056:y
4054:O
4052:x
4044:3
4033:3
4026:3
4018:3
4007:4
4000:6
3996:2
3994:C
3989:4
3985:2
3983:C
3978:2
3974:2
3972:C
3966:3
3959:4
3955:2
3953:B
3948:3
3935:B
3930:4
3926:4
3924:B
3918:2
3871:e
3864:t
3857:v
3801:3
3793:3
3785:3
3777:3
3769:3
3760:6
3756:2
3746:6
3742:2
3732:6
3728:2
3726:K
3718:6
3714:2
3705:3
3689:7
3687:O
3685:3
3681:2
3673:3
3665:3
3661:2
3653:7
3651:O
3649:2
3645:2
3637:3
3629:4
3621:7
3619:O
3617:2
3613:2
3605:3
3601:2
3593:7
3591:O
3589:2
3579:O
3577:4
3573:3
3565:3
3555:O
3553:3
3549:4
3541:4
3537:2
3529:3
3507:4
3502:)
3498:3
3493:O
3489:5
3484:H
3480:3
3468:2
3460:2
3452:2
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3440:3
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3436:2
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3420:4
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3416:3
3412:2
3408:2
3404:2
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3394:)
3392:2
3390:)
3388:3
3378:)
3376:3
3372:2
3368:4
3360:4
3358:)
3356:2
3354:O
3352:3
3350:H
3348:2
3340:4
3336:4
3334:H
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3320:4
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3316:3
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3304:2
3296:4
3288:4
3280:4
3272:6
3268:2
3266:H
3260:4
3252:4
3250:)
3248:4
3240:4
3233:)
3231:2
3218:4
3210:2
3189:2
3173:3
3171:S
3169:2
3161:3
3159:O
3157:2
3139:3
3131:3
3123:3
3115:3
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3058:2
3050:2
3042:2
3034:2
3010:e
3003:t
2996:v
2960:.
2934:.
2876:.
2872::
2851:.
2847::
2822:.
2818::
2797:)
2777:.
2763::
2700:.
2686::
2663:.
2649::
2623:.
2609::
2590:.
2586::
2572:η
2556:.
2552::
2535:4
2520:.
2506::
2480:.
2457:)
2443:.
2397:.
2379:.
2351:.
2336:.
2311:.
2286:.
2274::
2234:4
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2135:+
2127:3
2121:]
2119:3
2115:6
2113:R
2111:6
2101:6
2099:)
2097:3
2093:6
2091:C
2068:2
2066:)
2064:5
2062:H
2060:5
2056:2
2041:4
2016:3
2012:3
1992:3
1980:4
1966:]
1960:2
1956:2
1954:]
1952:4
1950:)
1948:3
1944:2
1938:]
1936:4
1934:)
1932:3
1928:2
1922:]
1920:5
1916:4
1914:)
1912:3
1908:2
1904:2
1900:2
1893:4
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1883:)
1881:3
1877:2
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1869:2
1862:4
1856:]
1854:6
1848:]
1842:2
1836:]
1834:9
1830:2
1823:4
1816:2
1812:4
1805:4
1783:4
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1767:)
1765:2
1763:)
1761:3
1757:4
1753:2
1751:)
1749:3
1739:4
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1733:)
1731:3
1714:N
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1705:4
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1674:4
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1628:]
1626:4
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1468:(
1461:4
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1426:4
1408:4
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1384:(
1377:4
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817:3
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630:H
627:f
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603:S
601:(
529:)
527:D
524:n
522:(
396:4
301:)
297:(
111:)
20:)
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