Knowledge (XXG)

Titanium aluminide

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wristwatch was made, using gamma titanium aluminide for the case, backcase and crown, and a titanium dial and mechanism in Ti 6/4 (grade 5). The retail price of this watch at £37,240 was nine times that of the basic Seamaster and comparable to the top of the range platinum-cased version with a
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TiAl-based alloys have potential to increase the thrust-to-weight ratio in aircraft engines. This is especially the case with the engine's low-pressure turbine blades and the high-pressure compressor blades. These are traditionally made of Ni-based superalloy, which is nearly twice as dense as
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in the engineering and aerospace fields are limited by its poor ductility. In addition, the loss of ductility at ambient temperature is usually accompanied by a change of fracture mode from ductile transgranular to brittle intergranular or to brittle cleavage. Despite the fact that a lot of
257:. The density of γ-TiAl is about 4.0 g/cm. It finds use in several applications including aircraft, jet engines, sporting equipment and automobiles. The development of TiAl based alloys began circa 1970. The alloys have been used in these applications only since about 2000. 436:
toughening strategies have been developed to improve their toughness, machining quality is still a difficult problem to tackle. Near-net shape manufacturing technology is considered as one of the best choices for preparing such materials. {date=July 2022}
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TiAl-based alloys. Some gamma titanium aluminide alloys retain strength and oxidation resistance to 1000 °C, which is 400 °C higher than the operating temperature limit of conventional titanium alloys.
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Machining of the Stage 6, and Stage 7 LPT blades is performed by Moeller Manufacturing. An alternate pathway for production of the gamma TiAl blades for the GEnx and GE9x engines using
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aircraft. This was the first large-scale use of this material on a commercial jet engine when it entered service in 2011. The TiAl LPT blades are cast by
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Pole figures displaying crystallographic texture of gamma-TiAl in a rolled sheet of alpha2-gamma alloy, as measured by high energy X-rays.
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Voskoboinikov R, Lumpkin G, Middleburgh S (2013). "Preferential formation of Al self-interstitial defects in γ-TiAl under irradiation".
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Gamma TiAl has excellent mechanical properties and oxidation and corrosion resistance at elevated temperatures (over 600
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Bewlay BP, Nag S, Suzuki A, Weimer MJ (2016). "TiAl alloys in commercial aircraft engines".
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and the best oxidation resistance even at 1 000 °C. However, the applications of TiAl
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has the lowest density of 3.4 g/cm, the highest micro hardness of 465–670 kg/mm
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Machining Gamma Titanium Aluminide Components - Moeller Manufacturing
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Except where otherwise noted, data are given for materials in their
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Moeller Manufacturing, Aerospace Division, in Wixom, Michigan, USA
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Titanium Aluminide Applications in the HighSpeed Civil Transport
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Edward A. Loria (2001). "Quo vadis gamma titanium aluminide".
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Titanium aluminide has three major intermetallic compounds:
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uses gamma TiAl for the low-pressure turbine blades on its
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Kassner, Michael E, Pérez-Prado, María-Teresa (2004).
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ASM International. p. 131. 14: 195: 621:Heidi Milkert (18 August 2014). 384: 198: 220:(at 25 °C , 100 kPa). 16:Intermetallic chemical compound 542:Materials at High Temperatures 469:10.1016/j.intermet.2012.07.026 1: 945:Organotitanium(III) compounds 700:10.1016/S0966-9795(01)00064-4 640:Tim Barber (31 August 2019). 563:10.1080/09603409.2016.1183068 360:g lightweight version of the 1573:Organotitanium(IV) compounds 848:Organotitanium(II) compounds 707:Donachie, Matthew J (2000). 502:10.1080/07303300310001634952 710:Titanium: a technical guide 1646: 291:Applications of gamma-TiAl 210:74.849 g/mol 734:. Elsevier. p. 175. 343:Precision Castparts Corp. 333:engine, which powers the 214: 182: 162: 137: 41: 31: 26: 262:gamma titanium aluminide 315:components in aircraft 393:This section is empty. 351:additive manufacturing 300: 489:Textures Microstruct. 298: 555:2016MaHT...33..549B 353:is being explored. 23: 22:Titanium aluminide 1282:Titanate compounds 780:Titanium compounds 301: 238:(chemical formula 236:Titanium aluminide 224:Infobox references 21: 1607: 1606: 1603: 1602: 958: 957: 858: 857: 741:978-0-08-043637-1 720:978-0-87170-686-7 591:. 21 October 2015 413: 412: 251:chemical compound 232:Chemical compound 230: 229: 83:Interactive image 36:aluminum;titanium 1637: 1524: 1510: 1496: 1482: 1279: 1273: 1272: 1271: 1263: 1262: 1254: 1253: 1245: 1244: 942: 845: 773: 766: 759: 750: 745: 724: 703: 694:(12): 997–1001. 652: 651: 637: 631: 630: 618: 612: 607: 601: 600: 598: 596: 581: 575: 574: 549:(4–5): 549–559. 536: 530: 529: 513: 507: 506: 504: 479: 473: 472: 450: 408: 405: 395:You can help 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Retrieved 589:AviationPros 588: 579: 546: 540: 534: 525: 521: 511: 492: 487: 477: 460: 454: 448: 422: 401: 397:adding to it 392: 367:complication 355: 339:Boeing 747-8 325: 321: 302: 281: 273: 269: 265: 261: 259: 243: 242:), commonly 239: 235: 234: 42:Identifiers 18: 1204:·20TiO 1196:NiO·Sb 463:: 230–232. 347:Avio s.p.a. 183:Properties 1620:Aluminides 1614:Categories 1545:Pb(Zr,Ti)O 440:References 373:Alpha 2-Ti 365:moonphase 335:Boeing 787 313:superalloy 274:alpha 2-Ti 266:gamma TiAl 206:Molar mass 94:ChemSpider 70:3D model ( 59:12003-96-2 49:CAS Number 33:IUPAC name 1148:Ti(OCH(CH 595:10 August 571:138071925 404:July 2020 319:engines. 255:ductility 246:, is an 128:10290735 1389:EuBaTiO 551:Bibcode 528:: 1–11. 317:turbine 115:PubChem 103:8466204 1349:CaZrTi 1188:KTiOPO 1164:Ti(OCH 1064:Ti(NMe 1008:Ti(ClO 738:  717:  569:  358:  311:based 305:  270:γ-TiAl 167:SMILES 27:Names 1561:ZnTiO 1553:SrTiO 1537:PbTiO 1529:NiTiO 1433:MnTiO 1397:FeTiO 1325:CaTiO 1289:BaTiO 1076:Ti(NO 1056:TiOSO 991:TiS(S 647:Wired 567:S2CID 142:InChI 72:JSmol 1333:CaCu 1237:Ti(C 1228:TiSi 1220:TiSe 1132:(OCH 1108:Ti(C 1000:TiCl 978:TiBr 883:TiCl 875:TiBr 870:TiAl 836:TiSi 810:TiBr 794:TiCl 736:ISBN 715:ISBN 597:2017 423:TiAl 416:TiAl 345:and 337:and 331:GEnx 282:TiAl 280:and 240:TiAl 1520:TiF 1506:TiF 1492:TiF 1478:TiF 1465:TiO 1463:0.5 1459:0.5 1425:TiO 1365:TiO 1301:TiO 1212:TiS 1100:TiO 1088:TiO 1048:TiI 1040:TiH 1032:TiF 1020:TiF 986:TiC 970:TiB 912:TiP 907:TiN 899:TiI 891:TiF 831:TiS 826:TiO 818:TiI 802:TiH 696:doi 559:doi 497:doi 465:doi 399:. 272:), 118:CID 1616:: 1516:Rb 1502:Li 1474:Na 1461:Bi 1457:Na 1445:Ti 1441:Na 1421:Li 1409:Ti 1405:Ho 1377:Ti 1373:Dy 1361:Cs 1343:12 1337:Ti 1319:12 1313:Ti 1309:Bi 1297:Ba 1176:CH 1172:CH 1168:CH 1142:16 1136:CH 1128:Ti 929:Ti 917:Ti 690:. 644:. 625:. 587:. 565:. 557:. 547:33 545:. 524:. 520:. 493:35 486:. 461:32 459:. 377:Al 369:. 309:Ni 278:Al 268:, 199:Ti 196:Al 1563:3 1555:3 1547:3 1539:3 1531:3 1522:6 1518:2 1508:6 1504:2 1494:6 1490:2 1488:K 1480:6 1476:2 1467:3 1451:7 1449:O 1447:3 1443:2 1435:3 1427:3 1423:2 1415:7 1413:O 1411:2 1407:2 1399:3 1391:4 1383:7 1381:O 1379:2 1375:2 1367:3 1363:2 1355:7 1353:O 1351:2 1341:O 1339:4 1335:3 1327:3 1317:O 1315:3 1311:4 1303:4 1299:2 1291:3 1269:4 1264:) 1260:3 1255:O 1251:5 1246:H 1242:3 1230:2 1222:2 1214:2 1206:2 1202:3 1200:O 1198:2 1190:4 1182:4 1180:) 1178:3 1174:2 1170:2 1166:2 1158:4 1156:) 1154:2 1152:) 1150:3 1140:) 1138:3 1134:2 1130:4 1122:4 1120:) 1118:2 1116:O 1114:3 1112:H 1110:2 1102:4 1098:4 1096:H 1090:2 1082:4 1080:) 1078:3 1070:4 1068:) 1066:2 1058:4 1050:4 1042:4 1034:6 1030:2 1028:H 1022:4 1014:4 1012:) 1010:4 1002:4 995:) 993:2 980:4 972:2 951:2 935:3 933:S 931:2 923:3 921:O 919:2 901:3 893:3 885:3 877:3 838:2 820:2 812:2 804:2 796:2 772:e 765:t 758:v 744:. 723:. 702:. 698:: 692:9 650:. 629:. 599:. 573:. 561:: 553:: 526:3 505:. 499:: 471:. 467:: 433:3 429:2 425:3 418:3 406:) 402:( 375:3 284:3 276:3 264:( 174:. 74:)

Index

IUPAC name
CAS Number
12003-96-2
JSmol
Interactive image
ChemSpider
8466204
PubChem
10290735
InChI
SMILES
Chemical formula
Molar mass
standard state
Infobox references
intermetallic
chemical compound
ductility

Ni
superalloy
turbine
General Electric
GEnx
Boeing 787
Boeing 747-8
Precision Castparts Corp.
Avio s.p.a.
additive manufacturing
Omega Seamaster

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