Knowledge (XXG)

Triphenylmethanethiol

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Arulsamy, N.; Bohle, D. S.; Butt, J. A.; Irvine, G. J.; Jordan, P. A.; Sagan, E. (1999). "Interrelationships between conformational dynamics and the redox chemistry of
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The compound forms a number of unusual derivatives that are more stable than less bulky analogues. The
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Garnsey, Michelle R.; Wengryniuk, Sarah E.; Coltart, Don M. (2009). "Triphenylmethanethiol".
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Senning, Alexander (1991). "Triphenylmethanethiol and triphenylmethanesulfenyl chloride".
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InChI=1S/C19H16S/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H
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Except where otherwise noted, data are given for materials in their
520: 411: 95: 85: 23: 550:. It in turn reacts with ammonia to form the sulfenamide (C 215: 345:103–107 °C (217–225 °F; 376–380 K) 177: 566:. The thiol reacts with nitrous acid to give 71: 603:Encyclopedia of Reagents for Organic Synthesis 8: 230: 137: 115: 15: 279:C1=CC=C(C=C1)C(C2=CC=CC=C2)(C3=CC=CC=C3)S 197: 659:Journal of the American Chemical Society 593: 276: 251: 226: 128: 546:CSCl is obtained from the thiol with 258:Key: JQZIKLPHXXBMCA-UHFFFAOYSA-N 7: 523:derivative of the bulky substituent 168: 14: 373: 306: 22: 485:(at 25 °C , 100 kPa). 312: 300: 1: 571:-nitrosotriphenylmethanethiol 711: 611:10.1002/047084289X.rn01030 479: 354: 349: 287: 267: 242: 55: 47: 35: 30: 21: 420:Precautionary statements 17:Triphenylmethanethiol 505:organosulfur compound 501:Triphenylmethanethiol 41:Triphenylmethanethiol 37:Preferred IUPAC name 507:with the formula (C 327: g·mol 18: 489:Infobox references 16: 671:10.1021/ja9901314 665:(30): 7115–7123. 657:-nitrosothiols". 548:sulfuryl chloride 532:sulfenyl chloride 527:(called trityl). 497:Chemical compound 495: 494: 398:Hazard statements 211:CompTox Dashboard 97:Interactive image 702: 695:Phenyl compounds 675: 674: 650: 644: 643: 631: 625: 624: 598: 519:CSH. It is the 475: 471: 467: 463: 459: 455: 451: 447: 443: 439: 435: 431: 427: 413: 409: 405: 377: 326: 314: 308: 302: 295:Chemical formula 235: 234: 219: 217: 201: 181: 170: 149: 141: 130: 119: 99: 75: 50:Trityl mercaptan 26: 19: 710: 709: 705: 704: 703: 701: 700: 699: 680: 679: 678: 652: 651: 647: 642:(4–5): 183–192. 633: 632: 628: 621: 600: 599: 595: 591: 584: 580: 576: 565: 561: 557: 553: 545: 541: 537: 525:triphenylmethyl 518: 514: 510: 498: 491: 486: 422: 400: 386: 370: 324: 311: 305: 297: 283: 280: 275: 274: 263: 260: 259: 256: 250: 249: 238: 220: 213: 204: 184: 171: 159: 122: 102: 89: 78: 65: 51: 43: 42: 12: 11: 5: 708: 706: 698: 697: 692: 682: 681: 677: 676: 645: 636:Sulfur Letters 626: 620:978-0471936237 619: 592: 590: 587: 582: 578: 574: 563: 559: 555: 551: 543: 539: 535: 516: 512: 508: 496: 493: 492: 487: 483:standard state 480: 477: 476: 454:P305+P351+P338 423: 418: 415: 414: 401: 396: 393: 392: 387: 382: 379: 378: 371: 366: 363: 362: 352: 351: 347: 346: 343: 337: 336: 333: 329: 328: 322: 316: 315: 309: 303: 298: 293: 290: 289: 285: 284: 282: 281: 278: 270: 269: 268: 265: 264: 262: 261: 257: 254: 253: 245: 244: 243: 240: 239: 237: 236: 223: 221: 209: 206: 205: 203: 202: 194: 192: 186: 185: 183: 182: 174: 172: 164: 161: 160: 158: 157: 153: 151: 143: 142: 132: 124: 123: 121: 120: 112: 110: 104: 103: 101: 100: 92: 90: 83: 80: 79: 77: 76: 68: 66: 61: 58: 57: 53: 52: 49: 45: 44: 40: 39: 33: 32: 28: 27: 13: 10: 9: 6: 4: 3: 2: 707: 696: 693: 691: 688: 687: 685: 672: 668: 664: 660: 656: 649: 646: 641: 637: 630: 627: 622: 616: 612: 608: 604: 597: 594: 588: 586: 572: 570: 549: 533: 528: 526: 522: 506: 502: 490: 484: 478: 424: 421: 417: 416: 402: 399: 395: 394: 391: 388: 385: 381: 380: 376: 372: 369: 365: 364: 360: 358: 353: 348: 344: 342: 341:Melting point 339: 338: 335:yellow solid 334: 331: 330: 323: 321: 318: 317: 299: 296: 292: 291: 286: 277: 273: 266: 252: 248: 241: 233: 229: 228:DTXSID1063142 225: 224: 222: 212: 208: 207: 200: 196: 195: 193: 191: 188: 187: 180: 176: 175: 173: 167: 163: 162: 155: 154: 152: 150: 145: 144: 140: 136: 133: 131: 129:ECHA InfoCard 126: 125: 118: 114: 113: 111: 109: 106: 105: 98: 94: 93: 91: 87: 82: 81: 74: 70: 69: 67: 64: 60: 59: 54: 46: 38: 34: 29: 25: 20: 662: 658: 654: 648: 639: 635: 629: 602: 596: 568: 529: 500: 499: 389: 356: 56:Identifiers 48:Other names 384:Signal word 332:Appearance 288:Properties 135:100.020.928 684:Categories 589:References 368:Pictograms 320:Molar mass 199:T7AQN86QSJ 108:ChemSpider 84:3D model ( 63:CAS Number 470:P337+P313 466:P332+P313 450:P304+P340 446:P304+P312 442:P302+P352 359:labelling 156:223-020-3 148:EC Number 73:3695-77-0 350:Hazards 390:Warning 166:PubChem 690:Thiols 617:  585:CSNO. 503:is an 325:276.40 272:SMILES 31:Names 521:thiol 247:InChI 179:77281 117:69703 86:JSmol 615:ISBN 562:CSNH 474:P362 462:P321 458:P312 438:P280 434:P271 430:P264 426:P261 412:H332 408:H319 404:H315 190:UNII 667:doi 663:121 607:doi 357:GHS 216:EPA 169:CID 686:: 661:. 640:12 638:. 613:. 605:. 573:(C 534:(C 472:, 468:, 464:, 460:, 456:, 452:, 448:, 444:, 440:, 436:, 432:, 428:, 410:, 406:, 361:: 310:16 304:19 673:. 669:: 655:S 623:. 609:: 583:3 581:) 579:5 577:H 575:6 569:S 564:2 560:3 558:) 556:5 554:H 552:6 544:3 542:) 540:5 538:H 536:6 517:3 515:) 513:5 511:H 509:6 313:S 307:H 301:C 218:) 214:( 88:)

Index


Preferred IUPAC name
CAS Number
3695-77-0
JSmol
Interactive image
ChemSpider
69703
ECHA InfoCard
100.020.928
Edit this at Wikidata
EC Number
PubChem
77281
UNII
T7AQN86QSJ
CompTox Dashboard
DTXSID1063142
Edit this at Wikidata
InChI
SMILES
Chemical formula
Molar mass
Melting point
GHS labelling
Pictograms
GHS07: Exclamation mark
Signal word
Hazard statements
Precautionary statements

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