Knowledge (XXG)

:Molecular structure diagram - Knowledge (XXG)

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Stereochemistry demands special attention because three-dimensionality is the most difficult part of a structure to visualize. Techniques for presenting 3-dimensional structures reflect the tastes of the artist. Three dimensionality is best highlighted by the depictions of bonds, using wedges,
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Depictions of molecular compounds is well accomplished using ChemDraw and related software. Cations and anions are also typically discrete and can be depicted unambiguously. For simple structures, say <10 atoms, it is helpful to depict all atoms explicitly. For more complex molecules, most
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bolding, and hashed formats. Some artists highlight three-dimensionality by varying fonts sizes, e.g. slightly larger fonts for the "front" atoms. In organic chemistry, double bonds and C-H bonds are shorter than most single bonds.
118:, adopt low-dimensional structures, in which case the layers (2-D) or chains (1-D) should be shown. Some inorganic solids dissociate - or crack - into molecular species heating or upon dissolving, e.g. 147: 95:. It is a matter of taste whether one includes the lone pair in a drawing. Lone pairs of electrons are more common for depictions that emphasize bonding, as in simple gaseous molecules, such as 142: 64:. The structures of many reagents are often misunderstood because simplified formulas are presented in reaction schemes whereas the actual structures are more complex. Examples are 130: 76:
hydrogen atoms attached to carbon are omitted, and carbon atoms are represented by vertices. For ease of readability,
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Chemical structures are presented to help readers understand the nature of the titled material. One can subdivide
69: 57: 72:. Readers of Knowledge (XXG) often comment (complain) that structures shown are incorrect for this reason. 119: 61: 37: 16: 126: 45: 49: 125:
Some important chemical species cannot be easily represented with simple pictures, e.g.
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fonts are preferred. Many artists employ color to highlight parts of the molecules.
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Knowledge (XXG):WikiProject Chemistry/Structure drawing workgroup
110:, are best represented with colour-coded spheres that emphasise 53: 143:
Knowledge (XXG):Manual of Style/Chemistry/Structure drawing
60:, and nonmolecular species, which includes most purely 48:
into two main groups: molecules, which includes most
8: 7: 91:of electrons, which are sometimes 14: 1: 106:Nonmolecular compounds, e.g. 131:non-stoichiometric compounds 164: 70:lithium diisopropylamide 58:organometallic compounds 93:stereochemically active 41: 34: 27: 20: 40: 33: 26: 19: 114:. Many solids, e.g. 87:Most molecules have 62:inorganic compounds 120:Aluminium chloride 46:chemical compounds 42: 35: 28: 21: 127:hydrochloric acid 155: 163: 162: 158: 157: 156: 154: 153: 152: 139: 12: 11: 5: 161: 159: 151: 150: 145: 138: 135: 108:sodium hydride 66:methyl lithium 13: 10: 9: 6: 4: 3: 2: 160: 149: 146: 144: 141: 140: 136: 134: 132: 128: 123: 121: 117: 113: 109: 104: 102: 98: 94: 90: 85: 81: 79: 73: 71: 67: 63: 59: 55: 52:, polyatomic 51: 47: 39: 32: 25: 18: 124: 105: 101:nitric oxide 86: 82: 74: 43: 89:lone pairs 78:sans-serif 137:See also 116:graphite 112:packing 97:ammonia 50:organic 56:, and 54:gases 129:and 99:and 68:and 133:. 103:.

Index





chemical compounds
organic
gases
organometallic compounds
inorganic compounds
methyl lithium
lithium diisopropylamide
sans-serif
lone pairs
stereochemically active
ammonia
nitric oxide
sodium hydride
packing
graphite
Aluminium chloride
hydrochloric acid
non-stoichiometric compounds
Knowledge (XXG):Manual of Style/Chemistry/Structure drawing
Knowledge (XXG):WikiProject Chemistry/Structure drawing workgroup

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