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barrier between the plant and a fungus. A protectant fungicide is not absorbed into the plant and must be applied prior to infection. Ziram can either be directly sprayed on to a plant’s leaf or it can be used as a soil and seed treatment. The top five crops ziram is used on are:
796:
Shen, Shuling; Zhang, Yejun; Peng, Long; Xu, Bing; Du, Yaping; Deng, Manjiao; Xu, Huarui; Wang, Qiangbin (2011). "Generalized
Synthesis of Metal Sulfide Nanocrystals from Single-Source Precursors: Size, Shape and Chemical Composition Control and Their Properties".
418:
and leaf spot in cherries, and scab and anthracnose in pecans. Ziram also began to be used on residential ornaments as a bird and mammal repellent. As a protectant fungicide, it is active on the plant’s surface where it forms a
835:
Mahid
Motevalli; PaulO'Brien; John R.Walsh; Ian M.Watson (1996). "Synthesis, characterization and x-ray crystal structures of asymmetric bis(dialkyldithiocarbamates) of zinc: Potential precursors for ZnS deposition".
584:. Each Zn center is in a distorted pentacoordinate site, with four Zn–S bonds of 2.3 Å length and one Zn–S interaction is over 2.8 Å in length. Mono-zinc derivatives are obtained by adding strong
863:
N. Sreehari; Babu
Varghese; P. T. Manoharan (1990). "Crystal and molecular structure of dimeric biszinc(II) and the study of exchange-coupled copper(II)-copper(II) pairs in its lattice".
744:. Cornell University, Oregon State University, the University of Idaho, and the University of California at Davis and the Institute for Environmental Toxicology, Michigan State University
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in tomatoes. In 1981, additional uses for ziram were approved, including the prevention of leaf blight and scab on almonds, shot-hole in apricots,
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Known as ziram in agriculture, it was introduced in the United States in 1960 as a broad-spectrum fungicide. It was used to address
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Annually, approximately 1.9 million pounds of the active ziram ingredient are used. Ziram is often sold in powder or
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The compound is a prototypical zinc dithiocarbamate, a broad class of
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Zinc bis(diethyldithiocarbamate) complexes degrade thermally to give
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Alternatively, ziram is used as an additive ingredient in industrial
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Except where otherwise noted, data are given for materials in their
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1084:
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Rüdiger
Schubart (2000). "Dithiocarbamic Acid and Derivatives".
456:
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InChI=1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2
913:
222:
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Extension
Toxicology Network Pesticide Information Profiles
670:
Van Gysel, August B.; Musin, Willy (2000). "Methylamines".
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560:Structure of the ethyl-methyl carbamate derivative
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502:), as illustrated with dimethyldithiocarbamate:
184:
718:. United States Environmental Protection Agency
390:of rubber, and other industrial applications.
96:
765:Ullmann's Encyclopedia of Industrial Chemistry
673:Ullmann's Encyclopedia of Industrial Chemistry
382:. It is a pale yellow solid that is used as a
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8:
903:in the Pesticide Properties DataBase (PPDB)
830:
828:
588:(L) such as amines, which give adducts Zn(S
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628:places it in the "highly toxic" category.
580:are dimeric, i.e. their proper formula is
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620:Pesticide Database concluded that its LC
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283:
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265:Key: DUBNHZYBDBBJHD-UHFFFAOYSA-L
7:
644:Nickel bis(dimethyldithiocarbamate)
175:
75:zinc dimethyldithiocarbamate, Ziram
638:Iron tris(dimethyldithiocarbamate)
25:
1464:Aldehyde dehydrogenase inhibitors
900:Zinc bis(dimethyldithiocarbamate)
455:, and paint. It also serves as a
650:Zinc bis(diethyldithiocarbamate)
319:
313:
59:′)(μ-dimethylcarbamodithioato-1κ
33:
1423:Monoamine metabolism modulators
610:Environmental Protection Agency
356:(at 25 °C , 100 kPa).
325:
307:
51:(μ-Dimethylcarbamodithioato-1κ
1:
1415:Monoamine reuptake inhibitors
1395:Receptor/signaling modulators
466:on outdoor ornamental items.
850:10.1016/0277-5387(95)00559-5
614:high risk to aquatic species
372:Zinc dimethyldithiocarbamate
331:
18:Zinc dimethyldithiocarbamate
1480:
1419:Monoamine releasing agents
568:Compounds of the type Zn(S
1459:Monoaminergic neurotoxins
1387:
941:Monoaminergic neurotoxins
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773:10.1002/14356007.a09_001
682:10.1002/14356007.a16_535
618:Pesticide Action Network
767:. Weinheim: Wiley-VCH.
676:. Weinheim: Wiley-VCH.
380:dimethyldithiocarbamate
565:
478:with the formulae Zn(R
476:coordination complexes
286:CN(C)C(=S).CN(C)C(=S).
1318:MDMA (midomafetamine)
559:
402:on apples and pears,
1181:Oxidopamine (6-OHDA)
1103:Oxidopamine (6-OHDA)
1093:-Methylnorsalsolinol
388:sulfur vulcanization
376:coordination complex
1303:MDA (tenamfetamine)
1234:4-CAB (α-ethyl-PCA)
1176:MDA (tenamfetamine)
877:10.1021/ic00345a020
346: g·mol
29:
971:-Cysteinyldopamine
811:10.1039/c0ce00982b
604:Ecological effects
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360:Infobox references
27:
1431:
1430:
1426:
1263:-Dimethyldopamine
1254:α-Me-DA (3,4-DHA)
871:(20): 4011–4015.
844:(16): 2801–2808.
368:Chemical compound
366:
365:
218:CompTox Dashboard
122:Interactive image
16:(Redirected from
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1454:Dithiocarbamates
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1141:2'-Amino-MPTP
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1098:Norsalsolinol
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1030:DOPAL quinone
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1278:Fenfluramine
1260:
1196:Serotonergic
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1020:DOPA quinone
968:
949:Dopaminergic
906:
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868:
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837:
805:(14): 4572.
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799:CrystEngComm
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746:. Retrieved
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720:. Retrieved
715:
671:
665:
607:
567:
546:zinc sulfide
543:
536:
473:
446:
397:
394:Applications
371:
370:
81:Identifiers
73:Other names
64:
60:
56:
52:
1399:Adrenergics
1283:Haloperidol
1050:Haloperidol
1000:Amphetamine
865:Inorg. Chem
408:anthracnose
295:Properties
160:100.004.808
1444:Fungicides
1438:Categories
1219:2,4,5-THMA
1118:Salsolinol
990:disulfiram
962:2,4,5-THMA
838:Polyhedron
782:3527306730
657:References
626:amphibians
434:nectarines
339:Molar mass
206:73D8UA974J
133:ChemSpider
109:3D model (
88:CAS Number
48:IUPAC name
1392:See also:
1214:2,4,5-THA
1146:2,4,5-THA
957:2,4,5-THA
819:1466-8033
748:April 26,
722:April 26,
608:The U.S.
552:Structure
470:Chemistry
464:repellent
449:adhesives
416:brown rot
404:leaf curl
384:fungicide
1362:Unsorted
1186:Xylamine
1113:Rotenone
1108:Paraquat
1065:Mancozeb
1035:Dopamine
1015:Dieldrin
632:See also
453:caulking
444:grapes.
421:chemical
98:137-30-4
1249:5,7-DHT
1244:5,6-DHT
1229:3,4-DCA
1209:2,4-DCA
1166:DOPEGAL
1156:5,7-DHT
1151:5,6-DHT
1010:Daidzin
1005:Benomyl
988:(e.g.,
976:5,6-DHT
738:"Ziram"
709:"Ziram"
586:ligands
539:granule
430:peaches
426:almonds
173:PubChem
1369:5-HIAL
817:
779:
688:
541:form.
461:mammal
442:raisin
412:blight
386:, the
344:305.80
279:SMILES
42:Names
28:Ziram
1379:RHPTP
1239:5-IAI
1171:DSP-4
1123:Ziram
1070:Maneb
1025:DOPAL
712:(PDF)
506:2 (CH
438:pears
374:is a
254:InChI
111:JSmol
1374:RHPP
1348:PCMA
1328:MMAI
1313:MDEA
1308:MDAI
1298:MBDB
1293:HPTP
1224:3-CA
1085:MPTP
1060:HPTP
815:ISSN
777:ISBN
750:2015
724:2015
686:ISBN
459:and
457:bird
410:and
400:scab
197:UNII
186:8722
142:8397
67:)bis
63:′,2κ
1353:PIA
1343:PCA
1338:PBA
1288:HPP
1273:DCA
1268:αET
1055:HPP
873:doi
846:doi
807:doi
769:doi
678:doi
622:50
600:L.
592:CNR
572:CNR
526:NCS
514:NCS
498:NCS
482:NCS
223:EPA
176:CID
55:,2κ
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