52:
487:
264:
189:
43:
454:
385:
398:
310:
511:"(R,R)-N,N'-Bis(3,5-Di-tert-Butylsalicylidene)-1,2-Cyclohexanediamino Manganese(III) Chloride, A Highly Enantioselective Epoxidation Catalyst"
126:
278:
51:
547:
542:
405:
474:
221:
242:
486:
441:
184:
470:
445:
146:
478:
465:
Condensation of this aldehyde with various diamines gives various salen ligands, which are popular for
70:
259:
42:
424:
is an organic compound. It is a pale yellow solid. This aldehyde is a building block for preparing
92:
17:
515:
333:
166:
230:
102:
263:
188:
376:
536:
437:
425:
177:
210:
510:
361:
297:
InChI=1S/C15H22O2/c1-14(2,3)11-7-10(9-16)13(17)12(8-11)15(4,5)6/h7-9,17H,1-6H3
287:
InChI=1S/C15H22O2/c1-14(2,3)11-7-10(9-16)13(17)12(8-11)15(4,5)6/h7-9,17H,1-6H3
157:
466:
453:
197:
137:
375:
Except where otherwise noted, data are given for materials in their
436:
This compound is commercially available. It may be prepared by the
125:
115:
481:
and atmospheric oxygen in the presence of a chloride source.
247:
50:
41:
393:
477:. The catalyst is obtained by further reaction with
209:
101:
8:
509:Jay F. Larrow and Eric N. Jacobsen (2004).
504:
502:
469:. For example, the enantiopure ligand for
262:
187:
165:
26:
229:
498:
315:
283:
258:
178:
473:may be prepared from the appropriate
290:Key: RRIQVLZDOZPJTH-UHFFFAOYSA-N
145:
7:
200:
25:
485:
452:
383:
345:
318:O=Cc1cc(cc(c1O)C(C)(C)C)C(C)(C)C
18:3,5-di-tert-butylsalicylaldehyde
379:(at 25 °C , 100 kPa).
351:
339:
1:
79:-butyl-2-hydroxybenzaldehyde
37:
564:
525:, vol. 10, p. 96
373:
326:
306:
274:
85:
69:
64:
36:
442:2,4-di-tert-butylphenol
475:1,2-diaminocyclohexane
446:hexamethylenetetramine
55:
46:
32:-butylsalicylaldehyde
479:manganese(II) acetate
422:-butylsalicylaldehyde
54:
45:
548:Tert-butyl compounds
543:Hydroxybenzaldehydes
71:Preferred IUPAC name
471:Jacobsen's catalyst
369: g·mol
33:
406:Infobox references
56:
47:
27:
523:Collected Volumes
516:Organic Syntheses
414:Chemical compound
412:
411:
243:CompTox Dashboard
127:Interactive image
60:
59:
16:(Redirected from
555:
528:
526:
519:
506:
489:
456:
396:
390:
387:
386:
368:
353:
347:
341:
334:Chemical formula
267:
266:
251:
249:
233:
213:
202:
191:
180:
169:
149:
129:
105:
38:
34:
21:
563:
562:
558:
557:
556:
554:
553:
552:
533:
532:
531:
521:
508:
507:
500:
496:
463:
434:
415:
408:
403:
402:
401: ?)
392:
388:
384:
380:
366:
356:
350:
344:
336:
322:
319:
314:
313:
302:
299:
298:
292:
291:
288:
282:
281:
270:
252:
245:
236:
216:
203:
172:
152:
132:
119:
108:
95:
81:
80:
23:
22:
15:
12:
11:
5:
561:
559:
551:
550:
545:
535:
534:
530:
529:
497:
495:
492:
491:
490:
462:
459:
458:
457:
433:
430:
413:
410:
409:
404:
382:
381:
377:standard state
374:
371:
370:
364:
358:
357:
354:
348:
342:
337:
332:
329:
328:
324:
323:
321:
320:
317:
309:
308:
307:
304:
303:
301:
300:
296:
295:
293:
289:
286:
285:
277:
276:
275:
272:
271:
269:
268:
260:DTXSID80350777
255:
253:
241:
238:
237:
235:
234:
226:
224:
218:
217:
215:
214:
206:
204:
196:
193:
192:
182:
174:
173:
171:
170:
162:
160:
154:
153:
151:
150:
142:
140:
134:
133:
131:
130:
122:
120:
113:
110:
109:
107:
106:
98:
96:
91:
88:
87:
83:
82:
74:
73:
67:
66:
62:
61:
58:
57:
48:
24:
14:
13:
10:
9:
6:
4:
3:
2:
560:
549:
546:
544:
541:
540:
538:
524:
518:
517:
512:
505:
503:
499:
493:
488:
484:
483:
482:
480:
476:
472:
468:
460:
455:
451:
450:
449:
447:
443:
439:
438:Duff reaction
431:
429:
427:
426:salen ligands
423:
421:
407:
400:
395:
378:
372:
365:
363:
360:
359:
338:
335:
331:
330:
325:
316:
312:
305:
294:
284:
280:
273:
265:
261:
257:
256:
254:
244:
240:
239:
232:
228:
227:
225:
223:
220:
219:
212:
208:
207:
205:
199:
195:
194:
190:
186:
183:
181:
179:ECHA InfoCard
176:
175:
168:
164:
163:
161:
159:
156:
155:
148:
144:
143:
141:
139:
136:
135:
128:
124:
123:
121:
117:
112:
111:
104:
100:
99:
97:
94:
90:
89:
84:
78:
72:
68:
63:
53:
49:
44:
40:
39:
35:
31:
19:
522:
514:
464:
435:
419:
417:
416:
147:ChEMBL427197
86:Identifiers
76:
29:
432:Preparation
327:Properties
185:100.157.837
537:Categories
494:References
362:Molar mass
231:KQA2N5HW8Z
158:ChemSpider
114:3D model (
103:37942-07-7
93:CAS Number
467:catalysis
461:Reactions
418:3,5'-Di-
440:, from
399:what is
397: (
367:234.339
198:PubChem
75:3,5-Di-
28:3,5-Di-
394:verify
391:
311:SMILES
211:688023
167:599518
138:ChEMBL
65:Names
279:InChI
116:JSmol
444:and
420:tert
222:UNII
77:tert
30:tert
248:EPA
201:CID
539::
520:;
513:.
501:^
448::
428:.
349:22
343:15
527:.
389:N
355:2
352:O
346:H
340:C
250:)
246:(
118:)
20:)
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
