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Liangbin Huang, Matthias Arndt, Käthe Gooßen, Heinrich Heydt, and Lukas J. Gooßen "Late
Transition Metal-Catalyzed Hydroamination and Hydroamidation" Chem. Rev., 2015, 115 (7), pp 2596–2697.
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Deng, Weiping, et al. "Catalytic amino acid production from biomass-derived intermediates." Proceedings of the
National Academy of Sciences 115.20 (2018): 5093-5098.
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can be converted into amino acids directly using aqueous ammonia solution, hydrogen gas and a heterogeneous metallic
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Many alkyl amines are produced industrially by the amination of alcohols using ammonia in the presence of
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Eller, Karsten; Henkes, Erhard; Rossbacher, Roland; Höke, Hartmut (2000). "Amines, Aliphatic".
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169:, and other N–O substrates. When the amine is used as an electrophile, the reaction is called
173:. Electron-rich organic substrates that may be used as nucleophiles for this process include
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157:. This sense of reactivity may be reversed for some electron-deficient amines, including
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37:. This type of reaction is important because organonitrogen compounds are pervasive.
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58:. Amination can occur in a number of ways including reaction with
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is not useful in this case because it produces too much waste.
264:Ullmann's Encyclopedia of Industrial Chemistry
90:catalysts. Illustrative is the production of
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153:with another organic compound acting as the
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7:
33:group is introduced into an organic
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149:Usually, the amine reacts as the
200:Metal-catalyzed hydroamination
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82:Acid-catalysed hydroamination
29:is the process by which an
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54:this reaction are termed
273:10.1002/14356007.a02_001
19:Not to be confused with
301:10.1073/pnas.1800272115
267:. Weinheim: Wiley-VCH.
171:electrophilic amination
145:Electrophilic amination
234:, the addition of an
224:, the addition of an
185:Miscellaneous methods
190:Alpha hydroxy acids
72:reductive amination
335:Organic reactions
317:10.1021/cr300389u
16:Chemical reaction
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208:, amines add to
139:hydrogen cyanide
76:Mannich reaction
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131:Ritter reaction
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46:Aminase enzymes
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238:group (-C(O)R)
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206:hydroamination
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163:hydroxylamines
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94:-butylamine:
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50:Enzymes that
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159:oxaziridines
155:electrophile
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242:Deamination
151:nucleophile
66:such as an
62:or another
282:3527306730
248:References
222:Alkylation
196:catalyst.
175:carbanions
88:solid acid
68:alkylation
232:Acylation
194:ruthenium
135:isobutene
41:Reactions
27:Amination
21:animation
329:Category
216:See also
179:enolates
74:and the
56:aminases
52:catalyse
35:molecule
210:alkenes
60:ammonia
279:
167:oximes
228:group
226:alkyl
137:with
118:NC(CH
114:→ H
106:=C(CH
102:+ CH
64:amine
31:amine
277:ISBN
236:acyl
177:and
129:The
92:tert
313:doi
297:doi
269:doi
204:In
133:of
331::
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212:.
181:.
165:,
161:,
98:NH
78:.
70:,
315::
299::
285:.
271::
124:3
122:)
120:3
116:2
112:2
110:)
108:3
104:2
100:3
23:.
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