Knowledge (XXG)

Carbonate

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Crucially, a similar buffer operates in the oceans. It is a major factor in climate change and the long-term carbon cycle, due to the large number of marine organisms (especially coral) which are made of calcium carbonate. Increased solubility of carbonate through increased temperatures results in
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In solution the equilibrium between carbonate, bicarbonate, carbon dioxide and carbonic acid is sensitive to pH, temperature, and pressure. Although di- and trivalent carbonates have low solubility, bicarbonate salts are far more soluble. This difference is related to the disparate
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within a larger molecule that contains a carbon atom bound to three oxygen atoms, one of which is double bonded. These compounds are also known as organocarbonates or carbonate esters, and have the general formula
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This structure is incompatible with the observed symmetry of the ion, which implies that the three bonds are the same length and that the three oxygen atoms are equivalent. As in the case of the
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Milewski, Jarosław; Wejrzanowski, Tomasz; Fung, Kuan-Zong; Szczśniak, Arkadiusz; Ćwieka, Karol; Tsai, Shu-Yi; Dybiński, Olaf; Skibiński, Jakub; Tang, Jhih-Yu; Szabłowski, Łukasz (2021-04-21).
3455: 751: 610:, and more. New applications of alkali metal carbonates include: thermal energy storage, catalysis and electrolyte both in fuel cell technology as well as in electrosynthesis of 814: 2265:
show evidence for carbonates in space, where aqueous alteration similar to that on Earth is unlikely. Other minerals have been proposed which would fit the observations.
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Carbonate/bicarbonate/carbonic acid equilibrium in water: pH of solutions, buffer capacity, titration and species distribution vs. pH computed with a free spreadsheet
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have not been found on Mars via remote sensing or in situ missions, even though Martian meteorites contain small amounts. Groundwater may have existed at
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available is on a geological scale and substantial quantities may eventually be redissolved into the sea and released to the atmosphere, increasing
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Kemper, F., Molster, F.J., Jager, C. and Waters, L.B.F.M. (2001) The mineral composition and spatial distribution of the dust ejecta of NGC 6302.
3441: 735: 2705: 2636: 1105:. The result is to make the blood more alkaline (raise pH). By the same principle, when the pH is too high, the kidneys excrete bicarbonate ( 2473:"Temperature dependence of high-temperature corrosion on nickel-based alloy in molten carbonates for concentrated solar power applications" 1215: 843:
carbonates are water-soluble salts, but carbonates of 2+ and 3+ ions are often poorly soluble in water. Of the insoluble metal carbonates,
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Metal carbonates generally decompose on heating, liberating carbon dioxide leaving behind an oxide of the metal. This process is called
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Lambrecht, Mickaël; García-Martín, Gustavo; de Miguel, María Teresa; Lasanta, María Isabel; Pérez, Francisco Javier (2023-08-01).
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of the carbonate ion has two (long) single bonds to negative oxygen atoms, and one short double bond to a neutral oxygen atom.
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and increased concentration of atmospheric carbon dioxide. This, in turn, increases Earth temperature. The amount of
188: 68: 3294: 2357: 940:, is in equilibrium with carbonic acid – the equilibrium lies strongly towards carbon dioxide. Thus 2839:"Overview of the Opportunity Mars Exploration Rover Mission to Meridiani Planum: Eagle Crater to Purgatory Ripple" 2931: 2725: 3352: 2094: 2062: 2003: 1208: 3369: 2613:
Anodic generation of hydrogen peroxide in continuous flow, DOI: 10.1039/D2GC02575B (Paper) Green Chem., 2022,
2158: 2022: 1781: 1702: 1532: 2142: 2110: 2078: 2046: 2038: 1861: 1548: 1524: 2182: 2126: 1821: 1572: 2522:"Simple methods for the synthesis of N -substituted acryl amides using Na 2 CO 3 /SiO 2 or NaHSO 4 /SiO 2" 1615: 1384: 1596: 1971: 1829: 1485: 1408: 727: 136: 74: 2568: 2415: 916:. In strongly basic conditions, the carbonate ion predominates, while in weakly basic conditions, the 3133: 2853: 2778: 2521: 2484: 1849: 1608: 1588: 1564: 1331: 1145: 913: 124: 3719: 3482: 3203: 3189: 3175: 3147: 2373: 2328: 1955: 1762: 1671: 1501: 1473: 1420: 1400: 1283: 1275: 1201: 1184: 991: 828: 580: 154: 35: 2627: 594:, have been used since antiquity for cleaning and preservation, as well as for the manufacture of 3724: 3537: 3433: 3308: 3161: 3119: 3094: 3088: 3084: 2812: 2596: 2549: 2453: 2294: 2269: 1659: 1556: 1463: 1444: 1376: 1354: 1315: 987: 983: 945: 840: 832: 654: 550: 531: 480: 768: 3582: 3562: 3422: 3228: 3034: 2804: 2763: 2701: 2588: 2541: 2502: 2445: 2365: 1750: 1722: 1493: 1455: 1436: 1343: 1303: 1263: 963: 844: 836: 820: 611: 508: 3554: 3532: 3516: 3508: 3059: 3014: 3004: 2871: 2861: 2794: 2786: 2580: 2533: 2492: 2435: 2427: 2277: 2259: 2197: 1884: 1770: 1710: 1364: 1291: 967: 941: 909: 824: 565: 500: 487:(which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, 461: 397: 325: 55: 1193: 253: 208: 3594: 3570: 3524: 3500: 3487: 3105: 3024: 2994: 2968: 2393: 2323: 1299: 1011: 957: 861: 704: 644: 632: 599: 598:. Carbonates are widely used in industry, such as in iron smelting, as a raw material for 436: 164: 42: 31: 2657: 2857: 2782: 2488: 3683: 3678: 3542: 3492: 3388: 3347: 3045: 2973: 2255: 1841: 1631: 921: 902: 868: 743: 666: 603: 484: 465: 420: 374: 360: 3713: 3688: 3393: 2600: 2553: 2457: 2388: 2289: 1240: 785: 720: 697: 662: 607: 401: 2899: 2677: 2575:. International Workshop of Molten Carbonates & Related Topics 2019 (IWMC2019). 499:. Carbonate minerals are extremely varied and ubiquitous in chemically precipitated 3416: 3364: 2905: 2816: 2584: 2273: 468:
gas under pressure or by dissolving carbonate or bicarbonate salts into the water.
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Hayakawa, Mamiko; Tashiro, Kenshiro; Sumiya, Daiki; Aoyama, Tadashi (2023-06-18).
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feature metal ions covalently bonded to carbonate in a variety of bonding modes.
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is strong evidence for the presence of liquid water. Recent observations of the
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Navarrete, N.; Nithiyanantham, U.; Hernández, L.; Mondragón, R. (2022-03-01).
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and other carbonated beverages – either by the addition of
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of solids composed of mono- vs dianions, as well as mono- vs dications.
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is rich in this material, giving rise to the need for infrastructural
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This resonance can be summarized by a model with fractional bonds and
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IPCC Special Report on the Ocean and Cryosphere in a Changing Climate
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Except where otherwise noted, data are given for materials in their
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Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005
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is weakly basic, while carbon dioxide itself is a weak acid.
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It is generally thought that the presence of carbonates in
1007: 2764:"Pyroclastic Activity at Home Plate in Gusev Crater, Mars" 856:, it accumulates in and impedes flow through pipes. 815:
Transition metal carbonate and bicarbonate complexes
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Stalactites and stalagmites are carbonate minerals.
2348:International Union of Pure and Applied Chemistry 867:Acidification of carbonates generally liberates 813:, carbonate is a ligand for many metal cations. 232: 163: 2356:(IUPAC Recommendations 2005). Cambridge (UK): 3449: 2939: 1209: 452:The term is also used as a verb, to describe 8: 2654:"Chemical of the Week -- Biological Buffers" 2403:(11th ed.). Cambridge University Press. 435:. The word "carbonate" may also refer to a 3456: 3442: 3434: 2946: 2932: 2924: 1216: 1202: 1194: 207: 47: 2865: 2798: 2683:The Merck Manual of Diagnosis and Therapy 2496: 2439: 479:, the term "carbonate" can refer both to 252: 3329: 3325: 3315: 3311: 3301: 3297: 3287: 3283: 3273: 3269: 3259: 3255: 3245: 3241: 3223: 3219: 3210: 3206: 3196: 3192: 3182: 3178: 3168: 3164: 3154: 3150: 3140: 3136: 3126: 3122: 3112: 3108: 3097: 3079: 3075: 3066: 3062: 3052: 3048: 3037: 3027: 3017: 3007: 2997: 2976: 2846:Journal of Geophysical Research: Planets 2698:Human physiology. An integrated approach 2573:International Journal of Hydrogen Energy 2383: 2381: 2311: 2304: 2300: 1171: 1139: 1132: 1128: 1097: 1093: 1085: 1077: 1066: 1062: 1053: 1049: 1045: 1041: 1033: 1029: 1014:to stabilise it in the range 7.37–7.43: 978: 935: 927: 889: 885: 881: 877: 847: 802: 798: 692: 688: 657:. It has a molecular mass of 60.01  618: 614: 590: 586: 575: 571: 556: 541: 537: 514: 445: 411: 407: 2340: 1006:Three reversible reactions control the 932:, is the main form, which, with water, 726:ion, the symmetry can be achieved by a 415:, characterized by the presence of the 307: 276:InChI=1S/CH2O3/c2-1(3)4/h(H2,2,3,4)/p-2 272: 2420:Solar Energy Materials and Solar Cells 1253: 897:Thus, scale can be removed with acid. 286:InChI=1/CH2O3/c2-1(3)4/h(H2,2,3,4)/p-2 1944: 982:. Important organocarbonates include 852:is important because, in the form of 439:, an organic compound containing the 279:Key: BVKZGUZCCUSVTD-UHFFFAOYSA-L 7: 2837:Squyres, S. W.; et al. (2006). 2762:Squyres, S. W.; et al. (2007). 1236: 3233:Ethylenetetracarboxylic dianhydride 2353:Nomenclature of Inorganic Chemistry 809:As illustrated by its affinity for 606:manufacture, in the composition of 289:Key: BVKZGUZCCUSVTD-NUQVWONBAE 223: 2678:Acid–Base Regulation and Disorders 631:The carbonate ion is the simplest 522:(as well as the main component of 25: 2696:Silverthorn, Dee Unglaub (2016). 1125:is generated from carbonic acid ( 784:, the Latin name of quicklime or 685:, which is the conjugate base of 3653:Graphite intercalation compounds 2885:from the original on 2017-08-08. 2826:from the original on 2017-09-22. 2315:, a hypothetic unstable molecule 994:, and the phosgene replacement, 966:a carbonate can also refer to a 755: 750: 734: 711: 534:, a calcium-magnesium carbonate 86: 67: 54: 34:. For the town in Colorado, see 2642:from the original on 2017-05-18 671:hydrogencarbonate (bicarbonate) 377:(at 25 °C , 100 kPa). 2585:10.1016/j.ijhydene.2020.12.073 1010:balance of blood and act as a 27:Salt or ester of carbonic acid 1: 3382:Compounds derived from oxides 2538:10.1080/00397911.2023.2201454 1117:) into urine as urea via the 2747:Astronomy & Astrophysics 2498:10.1016/j.corsci.2023.111262 2432:10.1016/j.solmat.2021.111525 30:For organic carbonates, see 1152:lower production of marine 518:, the chief constituent of 77:structure of the carbonate 3741: 2726:"Summary for Policymakers" 1946: 1182: 955: 40: 29: 1255: 1233: 1224:Compounds containing the 1090:, which in turn consumes 639:atom surrounded by three 460:ions in water to produce 371: 318: 298: 263: 147: 135: 123: 118: 85: 66: 53: 2526:Synthetic Communications 1103:Le Châtelier's principle 730:among three structures: 41:Not to be confused with 2791:10.1126/science.1139045 2400:Encyclopædia Britannica 986:, the cyclic compounds 3465:Inorganic compounds of 2635:, IUPAC, p. 137, 2250:Presence outside Earth 773: 568:("soda" or "natron"), 503:. The most common are 771: 635:. It consists of one 627:Structure and bonding 137:Systematic IUPAC name 2867:10.1029/2006JE002771 2686:Professional Edition 1146:cellular respiration 1136:), which comes from 661:and carries a total 125:Preferred IUPAC name 2858:2006JGRE..11112S12S 2783:2007Sci...316..738S 2579:(28): 14977–14987. 2489:2023Corro.22011262L 2374:Electronic version. 2329:Sodium percarbonate 1190:Carbonate overview: 1185:Category:Carbonates 992:propylene carbonate 914:dynamic equilibrium 764:Chemical properties 581:potassium carbonate 355: g·mol 50: 36:Carbonate, Colorado 3667:Oxides and related 3423:Peroxydicarbonates 3089:1,3-Dioxetanedione 3085:1,2-Dioxetanedione 2394:"Carbonates"  2295:Orthocarbonic acid 2270:carbonate deposits 1175:levels even more. 988:ethylene carbonate 984:dimethyl carbonate 952:Organic carbonates 946:sodium bicarbonate 774: 655:molecular symmetry 647:arrangement, with 623:in aqueous media. 551:iron(II) carbonate 481:carbonate minerals 381:Infobox references 48: 3707: 3706: 3431: 3430: 3229:Cyclohexanehexone 2777:(5825): 738–742. 2707:978-1-292-09493-9 2477:Corrosion Science 2246: 2245: 2240: 2239: 964:organic chemistry 665:of −2. It is the 509:calcium carbonate 423:with the formula 389:Chemical compound 387: 386: 189:Interactive image 141:Trioxidocarbonate 16:(Redirected from 3732: 3470:and related ions 3458: 3451: 3444: 3435: 3332: 3318: 3304: 3290: 3276: 3262: 3248: 3226: 3213: 3199: 3185: 3171: 3157: 3143: 3129: 3115: 3101: 3082: 3069: 3055: 3041: 3030: 3020: 3010: 3000: 2979: 2948: 2941: 2934: 2925: 2920: 2918: 2916: 2887: 2886: 2884: 2869: 2843: 2834: 2828: 2827: 2825: 2802: 2800:2060/20070016011 2768: 2759: 2753: 2743: 2737: 2736: 2735:. pp. 3–35. 2730: 2718: 2712: 2711: 2693: 2687: 2675: 2669: 2668: 2666: 2665: 2656:. Archived from 2650: 2644: 2643: 2641: 2634: 2624: 2618: 2611: 2605: 2604: 2564: 2558: 2557: 2517: 2511: 2510: 2500: 2468: 2462: 2461: 2443: 2411: 2405: 2404: 2396: 2385: 2376: 2345: 2314: 2307: 2278:Meridiani Planum 2260:planetary nebula 1237: 1218: 1211: 1204: 1195: 1174: 1167: 1166: 1165: 1162: 1143: 1135: 1124: 1116: 1115: 1114: 1111: 1100: 1089: 1081: 1070: 1057: 1036: 1027: 1026: 1023: 981: 974: 968:functional group 942:sodium carbonate 939: 931: 910:aqueous solution 903:lattice energies 893: 850: 812: 805: 759: 754: 738: 715: 695: 684: 683: 682: 679: 621: 593: 578: 566:Sodium carbonate 559: 544: 517: 501:sedimentary rock 498: 497: 496: 493: 462:carbonated water 448: 434: 433: 432: 429: 414: 354: 341: 340: 339: 336: 326:Chemical formula 256: 236: 225: 211: 191: 167: 107: 97: 90: 71: 58: 51: 21: 3740: 3739: 3735: 3734: 3733: 3731: 3730: 3729: 3710: 3709: 3708: 3703: 3684:Metal carbonyls 3662: 3641: 3599: 3590: 3586: 3578: 3574: 3566: 3558: 3550: 3546: 3528: 3520: 3512: 3504: 3496: 3471: 3462: 3432: 3427: 3389:Metal carbonyls 3377: 3373: 3360: 3356: 3336: 3331: 3327: 3323: 3317: 3313: 3309: 3303: 3299: 3295: 3289: 3285: 3281: 3275: 3271: 3267: 3261: 3257: 3253: 3247: 3243: 3239: 3225: 3221: 3217: 3212: 3208: 3204: 3198: 3194: 3190: 3184: 3180: 3176: 3170: 3166: 3162: 3156: 3152: 3148: 3142: 3138: 3134: 3128: 3124: 3120: 3114: 3110: 3106: 3099: 3095: 3081: 3077: 3073: 3068: 3064: 3060: 3054: 3050: 3046: 3039: 3035: 3029: 3025: 3019: 3015: 3009: 3005: 2999: 2995: 2983: 2978: 2974: 2957: 2952: 2914: 2912: 2904: 2896: 2891: 2890: 2882: 2841: 2836: 2835: 2831: 2823: 2766: 2761: 2760: 2756: 2744: 2740: 2728: 2720: 2719: 2715: 2708: 2695: 2694: 2690: 2676: 2672: 2663: 2661: 2652: 2651: 2647: 2639: 2632: 2626: 2625: 2621: 2612: 2608: 2566: 2565: 2561: 2532:(12): 883–892. 2519: 2518: 2514: 2470: 2469: 2465: 2413: 2412: 2408: 2387: 2386: 2379: 2346: 2342: 2337: 2324:Peroxocarbonate 2313: 2309: 2306: 2302: 2298: 2286: 2268:Until recently 2252: 2247: 2242: 2241: 2205: 2201: 2190: 2186: 2170: 2166: 2162: 2154: 2150: 2146: 2138: 2134: 2130: 2122: 2118: 2114: 2106: 2102: 2098: 2090: 2086: 2082: 2074: 2070: 2066: 2058: 2054: 2050: 2045: 2042: 2034: 2030: 2026: 2015: 2011: 2007: 1999: 1995: 1991: 1983: 1979: 1975: 1967: 1963: 1959: 1888: 1869: 1865: 1857: 1853: 1845: 1837: 1833: 1825: 1793: 1789: 1785: 1774: 1766: 1761: 1758: 1754: 1726: 1718: 1714: 1706: 1675: 1667: 1663: 1635: 1627: 1623: 1619: 1612: 1607: 1604: 1600: 1592: 1584: 1580: 1576: 1571: 1568: 1560: 1552: 1544: 1540: 1536: 1531: 1528: 1509: 1505: 1500: 1497: 1489: 1484: 1481: 1477: 1459: 1448: 1443: 1440: 1432: 1428: 1424: 1416: 1412: 1407: 1404: 1396: 1392: 1388: 1383: 1380: 1375: 1372: 1368: 1347: 1342: 1339: 1335: 1330: 1327: 1323: 1319: 1311: 1307: 1302: 1295: 1287: 1279: 1274: 1271: 1267: 1248: 1244: 1229: 1222: 1187: 1181: 1179:Carbonate salts 1173: 1169: 1163: 1160: 1159: 1157: 1141: 1137: 1134: 1130: 1126: 1122: 1112: 1109: 1108: 1106: 1099: 1095: 1091: 1087: 1083: 1079: 1075: 1068: 1064: 1060: 1055: 1051: 1047: 1043: 1039: 1035: 1031: 1024: 1021: 1020: 1018: 1004: 980: 976: 972: 960: 958:Carbonate ester 954: 937: 933: 929: 925: 891: 887: 883: 879: 875: 862:water softening 849: 845: 810: 804: 800: 796: 766: 705:Lewis structure 694: 690: 686: 680: 677: 676: 674: 653: 645:trigonal planar 633:oxocarbon anion 629: 620: 616: 612: 600:Portland cement 592: 588: 584: 577: 573: 569: 560:, an important 558: 554: 543: 539: 535: 516: 512: 494: 491: 490: 488: 447: 443: 441:carbonate group 437:carbonate ester 430: 427: 426: 424: 413: 409: 405: 390: 383: 378: 352: 337: 334: 333: 331: 328: 314: 311: 306: 305: 294: 291: 290: 287: 281: 280: 277: 271: 270: 259: 239: 226: 214: 194: 181: 170: 157: 143: 142: 131: 130: 114: 113: 105: 103: 95: 93:Carbonate anion 91: 81: 72: 62: 61:Carbonate anion 59: 46: 43:Carbon trioxide 39: 32:Carbonate ester 28: 23: 22: 15: 12: 11: 5: 3738: 3736: 3728: 3727: 3722: 3712: 3711: 3705: 3704: 3702: 3701: 3696: 3691: 3686: 3681: 3676: 3670: 3668: 3664: 3663: 3661: 3660: 3655: 3649: 3647: 3646:Nanostructures 3643: 3642: 3640: 3639: 3634: 3629: 3624: 3619: 3614: 3607: 3605: 3601: 3600: 3598: 3597: 3592: 3588: 3584: 3580: 3576: 3572: 3568: 3564: 3560: 3556: 3552: 3548: 3544: 3540: 3535: 3530: 3526: 3522: 3518: 3514: 3510: 3506: 3502: 3498: 3494: 3490: 3485: 3479: 3477: 3473: 3472: 3463: 3461: 3460: 3453: 3446: 3438: 3429: 3428: 3426: 3425: 3420: 3409:Polycarbonates 3406: 3401: 3396: 3391: 3385: 3383: 3379: 3378: 3376: 3375: 3371: 3367: 3362: 3358: 3354: 3350: 3348:Graphite oxide 3344: 3342: 3338: 3337: 3335: 3334: 3320: 3306: 3292: 3278: 3264: 3250: 3236: 3215: 3201: 3187: 3173: 3159: 3145: 3131: 3117: 3103: 3092: 3071: 3057: 3043: 3032: 3022: 3012: 3002: 2991: 2989: 2985: 2984: 2982: 2981: 2971: 2965: 2963: 2959: 2958: 2953: 2951: 2950: 2943: 2936: 2928: 2922: 2921: 2910:Dictionary.com 2902: 2895: 2894:External links 2892: 2889: 2888: 2829: 2754: 2738: 2713: 2706: 2688: 2670: 2645: 2619: 2606: 2559: 2512: 2463: 2406: 2391:, ed. (1911). 2389:Chisholm, Hugh 2377: 2339: 2338: 2336: 2333: 2332: 2331: 2326: 2321: 2316: 2292: 2290:Cap carbonates 2285: 2282: 2251: 2248: 2244: 2243: 2238: 2237: 2234: 2231: 2228: 2225: 2222: 2219: 2216: 2213: 2210: 2207: 2203: 2199: 2195: 2192: 2188: 2184: 2180: 2177: 2173: 2172: 2168: 2164: 2160: 2156: 2152: 2148: 2144: 2140: 2136: 2132: 2128: 2124: 2120: 2116: 2112: 2108: 2104: 2100: 2096: 2092: 2088: 2084: 2080: 2076: 2072: 2068: 2064: 2060: 2056: 2052: 2048: 2040: 2036: 2032: 2028: 2024: 2020: 2017: 2013: 2009: 2005: 2001: 1997: 1993: 1989: 1985: 1981: 1977: 1973: 1969: 1965: 1961: 1957: 1953: 1949: 1948: 1945: 1942: 1941: 1938: 1935: 1932: 1929: 1926: 1923: 1920: 1917: 1914: 1911: 1908: 1905: 1902: 1899: 1896: 1893: 1890: 1886: 1882: 1878: 1877: 1874: 1871: 1867: 1863: 1859: 1855: 1851: 1847: 1843: 1839: 1835: 1831: 1827: 1823: 1819: 1816: 1813: 1810: 1807: 1804: 1801: 1798: 1795: 1791: 1787: 1783: 1779: 1776: 1772: 1768: 1764: 1756: 1752: 1747: 1746: 1743: 1740: 1737: 1734: 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667:conjugate base 651: 628: 625: 608:ceramic glazes 485:carbonate rock 466:carbon dioxide 421:polyatomic ion 388: 385: 384: 379: 375:standard state 372: 369: 368: 363: 361:Conjugate acid 357: 356: 350: 344: 343: 329: 324: 321: 320: 316: 315: 313: 312: 309: 301: 300: 299: 296: 295: 293: 292: 288: 285: 284: 282: 278: 275: 274: 266: 265: 264: 261: 260: 258: 257: 249: 247: 241: 240: 238: 237: 229: 227: 219: 216: 215: 213: 212: 204: 202: 196: 195: 193: 192: 184: 182: 175: 172: 171: 169: 168: 160: 158: 153: 150: 149: 145: 144: 140: 139: 133: 132: 128: 127: 121: 120: 116: 115: 104: 94: 92: 83: 82: 73: 64: 63: 60: 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 3737: 3726: 3723: 3721: 3718: 3717: 3715: 3700: 3697: 3695: 3692: 3690: 3689:Carbonic acid 3687: 3685: 3682: 3680: 3677: 3675: 3672: 3671: 3669: 3665: 3659: 3656: 3654: 3651: 3650: 3648: 3644: 3638: 3637:Thiofulminate 3635: 3633: 3630: 3628: 3625: 3623: 3620: 3618: 3615: 3612: 3609: 3608: 3606: 3602: 3596: 3593: 3591: 3581: 3579: 3569: 3567: 3561: 3559: 3553: 3551: 3541: 3539: 3536: 3534: 3531: 3529: 3523: 3521: 3515: 3513: 3507: 3505: 3499: 3497: 3491: 3489: 3486: 3484: 3481: 3480: 3478: 3474: 3469: 3466: 3459: 3454: 3452: 3447: 3445: 3440: 3439: 3436: 3424: 3421: 3418: 3417:Tricarbonates 3414: 3410: 3407: 3405: 3402: 3400: 3397: 3395: 3394:Carbonic acid 3392: 3390: 3387: 3386: 3384: 3380: 3374: 3368: 3366: 3363: 3361: 3351: 3349: 3346: 3345: 3343: 3339: 3333: 3321: 3319: 3307: 3305: 3293: 3291: 3279: 3277: 3265: 3263: 3251: 3249: 3237: 3234: 3230: 3216: 3214: 3202: 3200: 3188: 3186: 3174: 3172: 3160: 3158: 3146: 3144: 3132: 3130: 3118: 3116: 3104: 3102: 3093: 3090: 3086: 3072: 3070: 3058: 3056: 3044: 3042: 3033: 3031: 3023: 3021: 3013: 3011: 3003: 3001: 2993: 2992: 2990: 2988:Exotic oxides 2986: 2980: 2972: 2970: 2967: 2966: 2964: 2962:Common oxides 2960: 2956: 2949: 2944: 2942: 2937: 2935: 2930: 2929: 2926: 2911: 2907: 2903: 2901: 2898: 2897: 2893: 2881: 2877: 2873: 2868: 2863: 2859: 2855: 2851: 2847: 2840: 2833: 2830: 2822: 2818: 2814: 2810: 2806: 2801: 2796: 2792: 2788: 2784: 2780: 2776: 2772: 2765: 2758: 2755: 2751: 2748: 2742: 2739: 2734: 2727: 2723: 2717: 2714: 2709: 2703: 2699: 2692: 2689: 2685: 2684: 2679: 2674: 2671: 2660:on 2011-07-21 2659: 2655: 2649: 2646: 2638: 2631: 2630: 2623: 2620: 2616: 2610: 2607: 2602: 2598: 2594: 2590: 2586: 2582: 2578: 2574: 2570: 2563: 2560: 2555: 2551: 2547: 2543: 2539: 2535: 2531: 2527: 2523: 2516: 2513: 2508: 2504: 2499: 2494: 2490: 2486: 2482: 2478: 2474: 2467: 2464: 2459: 2455: 2451: 2447: 2442: 2437: 2433: 2429: 2425: 2421: 2417: 2410: 2407: 2402: 2401: 2395: 2390: 2384: 2382: 2378: 2375: 2371: 2370:0-85404-438-8 2367: 2363: 2359: 2355: 2354: 2349: 2344: 2341: 2334: 2330: 2327: 2325: 2322: 2320: 2317: 2296: 2293: 2291: 2288: 2287: 2283: 2281: 2279: 2275: 2271: 2266: 2264: 2261: 2257: 2249: 2235: 2232: 2229: 2226: 2223: 2220: 2217: 2214: 2211: 2208: 2206: 2196: 2193: 2191: 2181: 2178: 2175: 2174: 2171: 2157: 2155: 2141: 2139: 2125: 2123: 2109: 2107: 2093: 2091: 2077: 2075: 2061: 2059: 2043: 2037: 2035: 2021: 2018: 2016: 2002: 2000: 1986: 1984: 1970: 1968: 1954: 1951: 1950: 1943: 1939: 1936: 1933: 1930: 1927: 1924: 1921: 1918: 1915: 1912: 1909: 1906: 1903: 1900: 1897: 1894: 1891: 1889: 1883: 1880: 1879: 1875: 1872: 1870: 1860: 1858: 1848: 1846: 1840: 1838: 1828: 1826: 1820: 1817: 1814: 1811: 1808: 1805: 1802: 1799: 1796: 1794: 1780: 1777: 1775: 1769: 1767: 1759: 1749: 1748: 1744: 1741: 1738: 1735: 1732: 1729: 1727: 1721: 1719: 1709: 1707: 1701: 1698: 1695: 1692: 1689: 1686: 1683: 1680: 1678: 1676: 1670: 1668: 1658: 1657: 1653: 1650: 1647: 1644: 1641: 1638: 1636: 1630: 1628: 1613: 1605: 1595: 1593: 1587: 1585: 1569: 1563: 1561: 1555: 1553: 1547: 1545: 1529: 1523: 1520: 1517: 1514: 1512: 1510: 1498: 1492: 1490: 1482: 1472: 1471: 1467: 1465: 1462: 1460: 1454: 1451: 1449: 1441: 1435: 1433: 1419: 1417: 1405: 1399: 1397: 1381: 1373: 1363: 1362: 1358: 1356: 1353: 1350: 1348: 1340: 1328: 1314: 1312: 1301: 1298: 1296: 1290: 1288: 1282: 1280: 1272: 1262: 1261: 1257: 1251: 1249: 1239: 1238: 1232: 1227: 1219: 1214: 1212: 1207: 1205: 1200: 1199: 1196: 1189: 1188: 1186: 1178: 1176: 1155: 1149: 1147: 1120: 1104: 1059: 1038: 1017: 1016: 1015: 1013: 1009: 1001: 999: 997: 993: 989: 985: 969: 965: 959: 951: 949: 947: 943: 923: 919: 915: 911: 906: 904: 898: 874: 873: 872: 870: 865: 863: 859: 855: 851: 842: 838: 834: 830: 826: 822: 818: 816: 795: 794: 793: 791: 787: 786:calcium oxide 783: 779: 770: 763: 758: 753: 749: 748: 747: 745: 737: 733: 732: 731: 729: 725: 722: 721:isoelectronic 714: 710: 709: 708: 706: 701: 699: 698:carbonic acid 672: 668: 664: 663:formal charge 660: 656: 650: 646: 642: 638: 634: 626: 624: 622: 609: 605: 601: 597: 582: 567: 563: 552: 548: 533: 529: 525: 521: 510: 506: 502: 486: 482: 478: 474: 469: 467: 463: 459: 455: 450: 442: 438: 422: 418: 417:carbonate ion 403: 402:carbonic acid 399: 395: 382: 376: 370: 367: 364: 362: 359: 358: 351: 349: 346: 345: 330: 327: 323: 322: 317: 308: 304: 297: 283: 273: 269: 262: 255: 251: 250: 248: 246: 243: 242: 235: 231: 230: 228: 222: 218: 217: 210: 206: 205: 203: 201: 198: 197: 190: 186: 185: 183: 179: 174: 173: 166: 162: 161: 159: 156: 152: 151: 146: 138: 134: 126: 122: 117: 111: 101: 89: 84: 80: 76: 70: 65: 57: 52: 44: 37: 33: 19: 3698: 3694:Bicarbonates 3413:Dicarbonates 3403: 3399:Bicarbonates 2913:. Retrieved 2909: 2852:(E12): n/a. 2849: 2845: 2832: 2774: 2770: 2757: 2749: 2746: 2741: 2732: 2716: 2697: 2691: 2681: 2673: 2662:. Retrieved 2658:the original 2648: 2628: 2622: 2614: 2609: 2576: 2572: 2562: 2529: 2525: 2515: 2480: 2476: 2466: 2441:10234/196651 2423: 2419: 2409: 2398: 2351: 2343: 2267: 2253: 1225: 1150: 1144:produced by 1073: 1005: 961: 907: 899: 896: 866: 819: 808: 781: 775: 741: 718: 702: 648: 643:atoms, in a 630: 583:("potash"), 530:skeletons); 470: 451: 440: 416: 393: 391: 148:Identifiers 3627:Thiocyanate 3604:Carbon ions 2906:"Carbonate" 2617:, 7931-7940 1300:(RO)(R'O)CO 996:triphosgene 918:bicarbonate 778:calcination 744:delocalized 526:shells and 458:bicarbonate 454:carbonation 366:Bicarbonate 319:Properties 3720:Carbonates 3714:Categories 3699:Carbonates 3658:Fullerides 3404:Carbonates 2955:Oxocarbons 2876:1893/17165 2752:, 679–690. 2664:2010-09-05 2483:: 111262. 2426:: 111525. 2335:References 1183:See also: 1119:urea cycle 944:is basic, 858:Hard water 801:→ CaO + CO 477:mineralogy 348:Molar mass 254:7UJQ5OPE7D 200:ChemSpider 176:3D model ( 155:CAS Number 49:Carbonate 18:Carbonates 3725:Oxyanions 3632:Fulminate 3476:Compounds 2601:234180559 2593:0360-3199 2554:258197818 2546:0039-7911 2507:0010-938X 2458:245455194 2450:0927-0248 1226:carbonate 1082:depletes 1065:(aq) ⇌ CO 829:potassium 790:lime kiln 746:charges: 728:resonance 520:limestone 394:carbonate 165:3812-32-6 129:Carbonate 3679:Nitrides 3611:Carbides 3341:Polymers 2880:Archived 2821:Archived 2809:17478719 2724:(2019). 2637:archived 2350:(2005). 2284:See also 2263:NGC 6302 1074:Exhaled 1052:(aq) + H 841:ammonium 833:rubidium 780:, after 562:iron ore 547:siderite 532:dolomite 444:O=C(−O−) 75:Resonant 3622:Cyanate 3617:Cyanide 2915:5 April 2854:Bibcode 2817:9687521 2779:Bibcode 2771:Science 2485:Bibcode 2319:Oxalate 1947:  1154:calcite 1019:H + HCO 837:caesium 821:Lithium 724:nitrate 669:of the 536:CaMg(CO 524:mollusc 505:calcite 473:geology 342: 310:C(=O)() 221:PubChem 3674:Oxides 3468:carbon 2815:  2807:  2704:  2599:  2591:  2552:  2544:  2505:  2456:  2448:  2368:  1502:Ca(HCO 1409:Mg(HCO 1012:buffer 1002:Buffer 839:, and 825:sodium 641:oxygen 637:carbon 579:, and 545:; and 353:60.008 303:SMILES 119:Names 110:Oxygen 108:  106:  100:Carbon 98:  96:  2883:(PDF) 2842:(PDF) 2824:(PDF) 2813:S2CID 2767:(PDF) 2729:(PDF) 2640:(PDF) 2633:(PDF) 2597:S2CID 2550:S2CID 2454:S2CID 2362:IUPAC 2310:C(OH) 2308:, or 2274:Gusev 2183:Th(CO 1862:Po(CO 1850:(BiO) 1763:CsHCO 1377:NaHCO 1276:LiHCO 1228:group 977:RR′CO 975:, or 854:scale 673:ion, 659:g/mol 596:glass 549:, or 528:coral 396:is a 268:InChI 234:19660 209:18519 178:JSmol 79:anion 3613:, , 3415:and 3231:and 3087:and 2917:2014 2805:PMID 2722:IPCC 2702:ISBN 2589:ISSN 2542:ISSN 2503:ISSN 2446:ISSN 2366:ISBN 2276:and 2256:rock 2039:EuCO 1885:RaCO 1842:PbCO 1822:HgCO 1771:BaCO 1723:CdCO 1703:PdCO 1672:SrCO 1632:ZnCO 1624:(OH) 1609:CuCO 1589:NiCO 1565:CoCO 1557:FeCO 1549:MnCO 1525:CrCO 1494:CaCO 1486:KHCO 1445:+SiO 1437:SiCO 1401:MgCO 1389:H(CO 1284:BeCO 1088:(aq) 1048:⇌ CO 990:and 930:(aq) 884:+ CO 876:CaCO 846:CaCO 797:CaCO 782:calx 703:The 604:lime 602:and 555:FeCO 513:CaCO 483:and 475:and 419:, a 398:salt 245:UNII 3595:SiC 3563:CSe 3533:COS 2872:hdl 2862:doi 2850:111 2795:hdl 2787:doi 2775:316 2750:394 2680:at 2581:doi 2534:doi 2493:doi 2481:220 2436:hdl 2428:doi 2424:236 2372:. 2358:RSC 2236:No 2233:Md 2230:Fm 2227:Es 2224:Cf 2221:Bk 2218:Cm 2215:Am 2212:Pu 2209:Np 2194:Pa 2179:Ac 2176:** 2163:(CO 2147:(CO 2131:(CO 2115:(CO 2099:(CO 2083:(CO 2067:(CO 2051:(CO 2027:(CO 2019:Pm 2008:(CO 1992:(CO 1976:(CO 1960:(CO 1940:Og 1937:Ts 1934:Lv 1931:Mc 1928:Fl 1925:Nh 1922:Cn 1919:Rg 1916:Ds 1913:Mt 1910:Hs 1907:Bh 1904:Sg 1901:Db 1898:Rf 1895:Lr 1892:** 1881:Fr 1876:Rn 1873:At 1818:Au 1815:Pt 1812:Ir 1809:Os 1806:Re 1800:Ta 1797:Hf 1786:(CO 1745:Xe 1739:Te 1736:Sb 1733:Sn 1730:In 1699:Rh 1696:Ru 1693:Tc 1690:Mo 1687:Nb 1684:Zr 1654:Kr 1651:Br 1648:Se 1645:As 1642:Ge 1639:Ga 1577:(CO 1537:(CO 1518:Ti 1515:Sc 1468:Ar 1464:+Cl 1456:+SO 1425:(CO 1359:Ne 1344:+NO 1336:HCO 1316:(NH 1292:+BO 1258:He 1142:(g) 1107:HCO 1080:(g) 1069:(g) 1028:⇌ H 962:In 908:In 888:+ H 675:HCO 507:or 471:In 400:of 224:CID 112:, O 102:, C 3716:: 3555:CS 3538:CS 3525:CO 3517:CO 3509:CO 3501:CO 3493:CO 3488:CO 3483:CF 3370:CO 3365:CO 3330:12 3326:12 3312:12 3298:12 3288:10 3284:10 3270:10 3026:CO 3016:CO 3006:CO 2996:CO 2975:CO 2969:CO 2908:. 2878:. 2870:. 2860:. 2848:. 2844:. 2819:. 2811:. 2803:. 2793:. 2785:. 2773:. 2769:. 2731:. 2615:24 2595:. 2587:. 2577:46 2571:. 2548:. 2540:. 2530:53 2528:. 2524:. 2501:. 2491:. 2479:. 2475:. 2452:. 2444:. 2434:. 2422:. 2418:. 2397:. 2380:^ 2364:. 2303:CO 2297:, 2280:. 2202:CO 2198:UO 2159:Yb 2143:Tm 2127:Er 2111:Ho 2095:Dy 2079:Tb 2063:Gd 2047:Eu 2023:Sm 2004:Nd 1988:Pr 1972:Ce 1956:La 1952:* 1854:CO 1834:CO 1830:Tl 1803:W 1782:Lu 1778:* 1755:CO 1751:Cs 1742:I 1715:CO 1711:Ag 1681:Y 1664:CO 1660:Rb 1620:CO 1616:Cu 1614:, 1601:CO 1597:Cu 1573:Co 1533:Cr 1521:V 1478:CO 1452:P 1421:Al 1385:Na 1369:CO 1365:Na 1355:+F 1351:O 1332:NH 1324:CO 1304:+C 1268:CO 1264:Li 1245:CO 1170:CO 1161:2− 1158:CO 1148:. 1138:CO 1131:CO 1096:CO 1084:CO 1076:CO 1061:CO 1044:CO 1032:CO 1008:pH 998:. 926:CO 924:, 871:: 864:. 835:, 831:, 827:, 823:, 811:Ca 792:: 700:. 696:, 691:CO 652:3h 589:CO 574:CO 570:Na 564:. 553:, 511:, 492:2− 489:CO 449:. 428:2− 425:CO 410:CO 404:, 392:A 335:2− 332:CO 3589:2 3587:S 3585:3 3583:C 3577:2 3575:O 3573:3 3571:C 3565:2 3557:2 3549:2 3547:S 3545:2 3543:C 3527:6 3519:5 3511:4 3503:3 3495:2 3457:e 3450:t 3443:v 3419:) 3411:( 3372:2 3359:2 3357:O 3355:3 3353:C 3328:O 3324:C 3316:9 3314:O 3310:C 3302:6 3300:O 3296:C 3286:O 3282:C 3274:8 3272:O 3268:C 3260:9 3258:O 3256:9 3254:C 3246:8 3244:O 3242:8 3240:C 3235:) 3227:( 3224:6 3222:O 3220:6 3218:C 3211:5 3209:O 3207:5 3205:C 3197:2 3195:O 3193:5 3191:C 3183:6 3181:O 3179:4 3177:C 3169:4 3167:O 3165:4 3163:C 3155:2 3153:O 3151:4 3149:C 3141:6 3139:O 3137:3 3135:C 3127:3 3125:O 3123:3 3121:C 3113:2 3111:O 3109:3 3107:C 3100:O 3098:3 3096:C 3091:) 3083:( 3080:4 3078:O 3076:2 3074:C 3067:3 3065:O 3063:2 3061:C 3053:2 3051:O 3049:2 3047:C 3040:O 3038:2 3036:C 3028:6 3018:5 3008:4 2998:3 2977:2 2947:e 2940:t 2933:v 2919:. 2874:: 2864:: 2856:: 2797:: 2789:: 2781:: 2710:. 2667:. 2603:. 2583:: 2556:. 2536:: 2509:. 2495:: 2487:: 2460:. 2438:: 2430:: 2360:– 2312:4 2305:4 2301:4 2299:H 2204:3 2200:2 2189:2 2187:) 2185:3 2169:3 2167:) 2165:3 2161:2 2153:3 2151:) 2149:3 2145:2 2137:3 2135:) 2133:3 2129:2 2121:3 2119:) 2117:3 2113:2 2105:3 2103:) 2101:3 2097:2 2089:3 2087:) 2085:3 2081:2 2073:3 2071:) 2069:3 2065:2 2057:3 2055:) 2053:3 2049:2 2044:, 2041:3 2033:3 2031:) 2029:3 2025:2 2014:3 2012:) 2010:3 2006:2 1998:3 1996:) 1994:3 1990:2 1982:3 1980:) 1978:3 1974:2 1966:3 1964:) 1962:3 1958:2 1887:3 1868:2 1866:) 1864:3 1856:3 1852:2 1844:3 1836:3 1832:2 1824:3 1792:3 1790:) 1788:3 1784:2 1773:3 1765:3 1760:, 1757:3 1753:2 1725:3 1717:3 1713:2 1705:3 1674:3 1666:3 1662:2 1634:3 1626:2 1622:3 1618:2 1611:3 1606:, 1603:3 1599:2 1591:3 1583:3 1581:) 1579:3 1575:2 1570:, 1567:3 1559:3 1551:3 1543:3 1541:) 1539:3 1535:2 1530:, 1527:3 1508:2 1506:) 1504:3 1499:, 1496:3 1488:3 1483:, 1480:3 1476:2 1474:K 1458:4 1447:4 1442:, 1439:4 1431:3 1429:) 1427:3 1423:2 1415:2 1413:) 1411:3 1406:, 1403:3 1395:2 1393:) 1391:3 1387:3 1382:, 1379:3 1374:, 1371:3 1367:2 1346:3 1341:, 1338:3 1334:4 1329:, 1326:3 1322:2 1320:) 1318:4 1310:4 1308:O 1306:2 1294:3 1286:3 1278:3 1273:, 1270:3 1266:2 1247:3 1243:2 1241:H 1217:e 1210:t 1203:v 1172:2 1164:3 1140:2 1133:3 1129:2 1127:H 1123:H 1113:3 1110:− 1098:3 1094:2 1092:H 1086:2 1078:2 1067:2 1063:2 1056:O 1054:2 1050:2 1046:3 1042:2 1040:H 1034:3 1030:2 1025:3 1022:− 979:3 938:O 936:2 934:H 928:2 892:O 890:2 886:2 882:2 878:3 848:3 803:2 799:3 693:3 689:2 687:H 681:3 678:− 649:D 619:2 617:O 615:2 613:H 591:3 587:2 585:K 576:3 572:2 557:3 542:2 540:) 538:3 515:3 495:3 446:2 431:3 412:3 408:2 406:H 338:3 180:) 45:. 38:. 20:)

Index

Carbonates
Carbonate ester
Carbonate, Colorado
Carbon trioxide


Resonant
anion
Ball-and-stick model of the carbonate anion
Carbon
Oxygen
Preferred IUPAC name
Systematic IUPAC name
CAS Number
3812-32-6
JSmol
Interactive image
ChemSpider
18519
PubChem
19660
UNII
7UJQ5OPE7D
InChI
SMILES
Chemical formula
Molar mass
Conjugate acid
Bicarbonate
standard state

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