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Fullerene

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fullerene is not a global maximum for 80-atom boron clusters and hence can not be found in nature; the most stable configurations have complex. The same paper concluded that boron's energy landscape, unlike others, has many disordered low-energy structures, hence pure boron fullerenes are unlikely to
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infrared telescope in a cloud of cosmic dust surrounding a star 6500 light years away. Kroto commented: "This most exciting breakthrough provides convincing evidence that the buckyball has, as I long suspected, existed since time immemorial in the dark recesses of our galaxy." According to astronomer
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To indicate the position of substituted or attached elements, the fullerene atoms are usually numbered in a spiral path, usually starting with the ring on one of the main axes. If the structure of the fullerene does not allow such numbering, another starting atom was chosen to still achieve a spiral
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However, they found that the asymmetrical molecule could theoretically collapse to form nearly every known fullerene and metallofullerene. Minor perturbations involving the breaking of a few molecular bonds cause the cage to become highly symmetrical and stable. This insight supports the theory that
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within the "isolated pentagon rule", which states that two pentagons in a fullerene should not share edges. "Mol.Symm." is the symmetry of the molecule, whereas "Cryst.Symm." is that of the crystalline framework in the solid state. Both are specified for the most experimentally abundant form(s). The
1239:). The number of six-member rings in this molecule is 20 and number of five-member rings is 12. There is an additional atom in the center of each six-member ring, bonded to each atom surrounding it. By employing a systematic global search algorithm, it was later found that the previously proposed 1120:
are cylindrical fullerenes. These tubes of carbon are usually only a few nanometres wide, but they can range from less than a micrometer to several millimeters in length. They often have closed ends, but can be open-ended as well. There are also cases in which the tube reduces in diameter before
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Two theories have been proposed to describe the molecular mechanisms that make fullerenes. The older, “bottom-up” theory proposes that they are built atom-by-atom. The alternative “top-down” approach claims that fullerenes form when much larger structures break into constituent parts.
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Fullerenes had been predicted for some time, but only after their accidental synthesis in 1985 were they detected in nature and outer space. The discovery of fullerenes greatly expanded the number of known allotropes of carbon, which had previously been limited to graphite,
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Pesado-Gómez, Casandra; Serrano-García, Juan S.; Amaya-Flórez, Andrés; Pesado-Gómez, Gustavo; Soto-Contreras, Anell; Morales-Morales, David; Colorado-Peralta, Raúl (2024). "Fullerenes: Historical background, novel biological activities versus possible health risks".
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electrons, free to delocalize. These should try to delocalize over the whole molecule. The quantum mechanics of such an arrangement should be like only one shell of the well-known quantum mechanical structure of a single atom, with a stable filled shell for
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have heteroatoms substituting carbons in cage or tube-shaped structures. They were discovered in 1993 and greatly expand the overall fullerene class of compounds and can have dangling bonds on their surfaces. Notable examples include boron, nitrogen
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causes the bond angles to decrease from about 120° in the sp orbitals to about 109.5° in the sp orbitals. This decrease in bond angles allows for the bonds to bend less when closing the sphere or tube, and thus, the molecule becomes more stable.
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skeleton, consisting of its vertices and edges. The Schlegel diagram is a projection of that skeleton onto one of the faces of the polyhedron, through a point just outside that face; so that all other vertices project inside that face.
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There are two major families of fullerenes, with fairly distinct properties and applications: the closed buckyballs and the open-ended cylindrical carbon nanotubes. However, hybrid structures exist between those two classes, such as
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Under high pressure and temperature, buckyballs collapse to form various one-, two-, or three-dimensional carbon frameworks. Single-strand polymers are formed using the Atom Transfer Radical Addition Polymerization (ATRAP) route.
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molecule was a subset of the shape of a football, and hypothesised that a full ball shape could also exist. Japanese scientific journals reported his idea, but neither it nor any translations of it reached Europe or the Americas.
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In 2013, a comprehensive review on the toxicity of fullerene was published reviewing work beginning in the early 1990s to present and concluded that very little evidence gathered since the discovery of fullerenes indicate that
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structure and made a model of it. Unfortunately, the evidence for that new form of carbon was very weak at the time, so the proposal was met with skepticism, and was never published. It was acknowledged only in 1999.
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Bochvar, D.A.; Galpern, E.G. (1973). "О гипотетических системах: карбододекаэдре, s-икосаэдре и карбо-s-икосаэдре" [On hypothetical systems: carbon dodecahedron, S-icosahedron and carbon-S-icosahedron].
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crystals are grown from toluene solution they have a monoclinic symmetry. The crystal structure contains toluene molecules packed between the spheres of the fullerene. However, evaporation of the solvent from
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Zhang, J.; Bowles, F. L.; Bearden, D. W.; et al. (2013). "A missing link in the transformation from asymmetric to symmetric metallofullerene cages implies a top-down fullerene formation mechanism".
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whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to seven atoms. The molecules may have hollow
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is a coined term frequently used to describe material produced by high-pressure high-temperature (HPHT) processing of fullerite. Such treatment converts fullerite into a nanocrystalline form of
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which he popularized; which, if they were extended to a full sphere, would also have the icosahedral symmetry group. The "ene" ending was chosen to indicate that the carbons are
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IUPAC defines fullerenes as "polyhedral closed cages made up entirely of n three-coordinate carbon atoms and having 12 pentagonal and (n/2-10) hexagonal faces, where n ≥ 20."
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Luann, B.; Poreda, Robert J.; Hunt, Andrew G.; et al. (2007). "Impact Event at the Permian-Triassic Boundary: Evidence from Extraterrestrial Noble Gases in Fullerenes".
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A closed fullerene with sphere-like shell must have at least some cycles that are pentagons or heptagons. More precisely, if all the faces have 5 or 6 sides, it follows from
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Buckminsterfullerene is the smallest fullerene molecule containing pentagonal and hexagonal rings in which no two pentagons share an edge (which can be destabilizing, as in
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Hiorns, R.C.; Cloutet, Eric; Ibarboure, Emmanuel; et al. (2010). "Synthesis of Donor-Acceptor Multiblock Copolymers Incorporating Fullerene Backbone Repeat Units".
658:, collaborating with T. Venkatesan, directed studies blasting graphite with lasers, producing carbon clusters of atoms, which would be later identified as "fullerenes." 6857: 3366:
Fullerene production generally starts by producing fullerene-rich soot. The original (and still current) method was to send a large electric current between two nearby
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In 2013 researchers discovered that asymmetrical fullerenes formed from larger structures settle into stable fullerenes. The synthesized substance was a particular
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and calculated its electronic structure. The paper was published in 1973, but the scientific community did not give much importance to this theoretical prediction.
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G. Lalwani and B. Sitharaman, Multifunctional fullerene and metallofullerene based nanobiomaterials, NanoLIFE 08/2013; 3:1342003. DOI: 10.1142/S1793984413420038
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Fullerenes are normally electrical insulators, but when crystallized with alkali metals, the resultant compound can be conducting or even superconducting.
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number when known. Fullerenes with fewer than 60 carbon atoms have been called "lower fullerenes", and those with more than 70 atoms "higher fullerenes".
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Researchers have been able to increase the reactivity of fullerenes by attaching active groups to their surfaces. Buckminsterfullerene does not exhibit "
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Since each carbon atom is connected to only three neighbors, instead of the usual four, it is customary to describe those bonds as being a mixture of
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symmetric structure was vibrationally unstable and the resulting cage would undergo a spontaneous symmetry break, yielding a puckered cage with rare T
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De, S.; Willand, A.; Amsler, M.; et al. (2011). "Energy Landscape of Fullerene Materials: A Comparison of Boron to Boron Nitride and Carbon".
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Interactive 3D models of cyclohexane, benzene, graphene, graphite, chiral & non-chiral nanotubes, and C60 Buckyballs – WeCanFigureThisOut.org.
6025: 3026: 1141:(as it is cylindrical and "planar" — that is, it has no "exposed" atoms that can be easily displaced). One proposed use of carbon nanotubes is in 354: 3060:)fullerene. The name of the point group should be retained in any derivative of said fullerene, even if that symmetry is lost by the derivation. 972:
of the type made of twenty hexagons and twelve pentagons, with a carbon atom at the vertices of each polygon and a bond along each polygon edge.
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It was recommended to assess the pharmacology of every new fullerene- or metallofullerene-based complex individually as a different compound.
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Sun, Marc C. Nicklaus; Rui-hua, Xie (2005). "Structure, Stability, and NMR Properties of Lower Fullerenes C38−C50 and Azafullerene C44N6".
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suggested the possibility of making giant hollow carbon molecules by distorting a plane hexagonal net with the addition of impurity atoms.
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Thilgen, Carlo; Herrmann, Andreas; Diederich, François (14 November 1997). "The Covalent Chemistry of Higher Fullerenes: C70 and Beyond".
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Functionalized fullerenes have been researched extensively for several potential biomedical applications including high-performance MRI
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of the product, discrete peaks appeared corresponding to molecules with the exact mass of sixty or seventy or more carbon atoms, namely
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These processes yield a mixture of various fullerenes and other forms of carbon. The fullerenes are then extracted from the soot using
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Iijima, S (1980). "Direct observation of the tetrahedral bonding in graphitized carbon black by high resolution electron microscopy".
3722: 3455: 1086:, 15,655,672 of which have no adjacent pentagons. Optimized structures of many fullerene isomers are published and listed on the web. 171: 3591: 7108: 4641:
Hedberg, Kenneth; Hedberg, Lise; Bethune, Donald S.; Brown, C. A.; Dorn, H. C.; Johnson, Robert D.; De Vries, M. (18 October 1991).
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at 6,6-double bonds, which reduces angle strain by changing sp-hybridized carbons into sp-hybridized ones. The change in hybridized
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Buckyballs and carbon nanotubes have been used as building blocks for a great variety of derivatives and larger structures, such as
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Margadonna, Serena; Brown, Craig M.; Dennis, T. John S.; et al. (July 1998). "Crystal Structure of the Higher Fullerene C".
2993:-symmetric, and have been successfully resolved. Research efforts are ongoing to develop specific sensors for their enantiomers. 2469: 2376: 1146: 8341: 6453: 6412: 5024: 4715: 2646:
Fullerenes are stable, but not totally unreactive. The sp-hybridized carbon atoms, which are at their energy minimum in planar
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Semenov, K. N.; Charykov, N. A.; Keskinov, V. A.; et al. (2010). "Solubility of Light Fullerenes in Organic Solvents".
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are often used to clarify the 3D structure of closed-shell fullerenes, as 2D projections are often not ideal in this sense.
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Letizia Stanghellini, "It’s possible that buckyballs from outer space provided seeds for life on Earth." In 2019, ionized C
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In 1973, independently from Henson, D. A. Bochvar and E. G. Galpern made a quantum-chemical analysis of the stability of
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Reilly, P. T. A.; Gieray, R. A.; Whitten, W. B.; Ramsey, J. M. (2000). "Fullerene Evolution in Flame-Generated Soot".
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The buckminsterfullerene molecule has two bond lengths. The 6:6 ring bonds (between two hexagons) can be considered "
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Manolopoulos, David E.; Fowler, Patrick W. (1991). "Structural proposals for endohedral metal-fullerene complexes".
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Hu, Zhen; Zhang, Chunhua; Huang, Yudong; et al. (2012). "Photodynamic anticancer activities of water-soluble
690: 8304: 8074: 8034: 7248: 7176: 7028: 7023: 7013: 7005: 2453: 1856: 1660: 1342: 1122: 904: 220: 118: 3029:, to name a fullerene, one must cite the number of member atoms for the rings which comprise the fullerene, its 8438: 8229: 7865: 7850: 7828: 7438: 7199: 7143: 7128: 7038: 6974: 6585: 5167: 5073: 4978:
Mitchel, D.R.; Brown, R. Malcolm Jr. (2001). "The Synthesis of Megatubes: New Dimensions in Carbon Materials".
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closing off. Their unique molecular structure results in extraordinary macroscopic properties, including high
6643: 831:. Thanks to their efforts, by 1990 it was relatively easy to produce gram-sized samples of fullerene powder. 8178: 8039: 8012: 7236: 7184: 7133: 7120: 5284:
Zhai, Hua-Jin; Ya-Fan Zhao; Wei-Li Li; et al. (13 July 2014). "Observation of an all-boron fullerene".
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Arikawa, Mineyuki (2006). "Fullerenes—an attractive nano carbon material and its production technology".
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Gopakumar, G.; Nguyen, M.T.; Ceulemans, A. (2008). "The boron buckyball has an unexpected Th symmetry".
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Blank, V.; Popov, M.; Pivovarov, G.; et al. (1998). "Ultrahard and superhard phases of fullerite
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of carbon that can be dissolved in common solvents at room temperature. Among the best solvents is
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Below is a table of main closed carbon fullerenes synthesized and characterized so far, with their
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Buseck, P.R.; Tsipursky, S.J.; Hettich, R. (1992). "Fullerenes from the Geological Environment".
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discharges in the atmosphere. In 1992, fullerenes were found in a family of mineraloids known as
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Sano, N.; Wang, H.; Chhowalla, M.; et al. (2001). "Synthesis of carbon 'onions' in water".
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Ugarte, D. (1992). "Curling and closure of graphitic networks under electron-beam irradiation".
983:(nm). The nucleus to nucleus diameter of a buckminsterfullerene molecule is about 0.71 nm. 586: 6023:
Johansson, M.P.; Jusélius, J.; Sundholm, D. (2005). "Sphere Currents of Buckminsterfullerene".
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Cui, Li-Feng; Xin Huang; Lei-Ming Wang; et al. (1 August 2006). "Pb122-: Plumbaspherene".
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After the discovery of C60, many fullerenes have been synthesized (or studied theoretically by
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Additional atoms, ions, clusters, or small molecules can be trapped inside fullerenes to form
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was prepared in 2014. This complex has two hexagonal faces and four heptagonal faces with in D
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Cui, Li-Feng; Xin Huang; Lei-Ming Wang; et al. (1 July 2006). "Sn122-: Stannaspherene".
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is not only dose- and time-dependent, but also depends on a number of other factors such as:
8389: 8351: 8064: 7980: 7940: 7652: 7582: 7488: 7217: 6879: 6826: 6818: 6779: 6730: 6616: 6518: 6501: 6462: 6421: 6347: 6320: 6266: 6210: 6173: 6134: 6077: 6034: 5989: 5944: 5933:: An improbable, egg-shaped endohedral fullerene that violates the isolated pentagon rule". 5883: 5828: 5762: 5715: 5630: 5600: 5565: 5538: 5503: 5418: 5367: 5301: 5250: 5194: 5139: 5090: 5041: 4989: 4944: 4927: 4891: 4874: 4844: 4834: 4732: 4693: 4654: 4615: 4512: 4391: 4344: 4309: 4197: 4180: 4117: 4041: 4024: 4001: 3949: 3912: 3897: 3868: 3860: 3790: 3685: 3586: 3379: 3332: 3006: 2748: 2543: 2492: 2476: 2417:, which violates the isolated pentagon rule. Evidence for a meteor impact at the end of the 2217: 2202: 1138: 1117: 790: 452: 4642: 3730: 2546:
modelling, which showed the existence of strong diamagnetic sphere currents in the cation.
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would satisfy this rule, and should be aromatic. This has been shown to be the case using
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Icosahedral or distorted-icosahedral fullerene-like complexes have also been prepared for
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fullerenes can be formed from graphene when the appropriate molecular bonds are severed.
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structure, with each atom forming 5 or 6 bonds, was predicted to be more stable than the
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Cami, J; Bernard-Salas, J.; Peeters, E.; Malek, S. E. (2 September 2010). "Detection of
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Fullerene: An Ab Initio Prediction of Geometry, Stability, and Electronic Structure".
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Li, Y.; Huang, Y.; Du, Shixuan; Liu, Ruozhuang (2001). "Structures and stabilities of
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Qiao, Rui; Roberts, Aaron P.; Mount, Andrew S.; et al. (2007). "Translocation of
4045: 945:). It is also most common in terms of natural occurrence, as it can often be found in 8427: 8247: 8101: 7870: 7823: 7745: 7667: 7521: 7420: 7386: 7075: 6899: 6222: 5848: 5621:
Diederich, Francois; Whetten, Robert L. (1992). "Beyond C60: The higher fullerenes".
5604: 4526: 4455:"The Hubble Space Telescope Has Just Found Solid Evidence of Interstellar Buckyballs" 4135: 4121: 4019: 3581: 3553: 2736: 2593: 2519: 2360: 2298: 2213: 2176: 1142: 763: 655: 283: 274: 210: 161: 88: 6214: 6191:
Bezmel'nitsyn, V.N.; Eletskii, A.V.; Okun', M.V. (1998). "Fullerenes in solutions".
6009: 5903: 5774: 5748:"Nomenclature for the C60-Ih and C70-D5h(6) Fullerenes (IUPAC Recommendations 2002)" 5270: 5206: 4752: 4222: 3924: 3810: 796:
After their discovery, minute quantities of fullerenes were found to be produced in
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Schultz, H.P. (1965). "Topological Organic Chemistry. Polyhedranes and Prismanes".
3705: 3474: 3375: 2294: 2290: 1333:; some of these complexes are spacious enough to hold most transition metal atoms. 1267: 1094: 1014: 835:
remains a challenge to chemists and to a large extent determines fullerene prices.
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Diana, Nooramalina; Yamada, Yasuhiro; Gohda, Syun; et al. (1 February 2021).
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Nested buckyballs ("carbon nano-onions" or "buckyonions") proposed for lubricants;
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Sivaraman, N.; Dhamodaran, R.; Kaliappan, I.; et al. (1994). "Solubility of
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spectra. Results of such calculations can be compared with experimental results.
8259: 8000: 7995: 7887: 7765: 7750: 7740: 7619: 7598: 7341: 3649: 3596: 2651: 2357: 2353: 1371: 1028:. There are no fullerenes with 22 vertices. The number of different fullerenes C 987: 877: 694: 647:, where it formed the core of a particle with the structure of a "bucky onion". 578: 516: 488: 200: 5832: 4517: 4480: 4370:
Krätschmer, W.; Lamb, Lowell D.; Fostiropoulos, K.; Huffman, Donald R. (1990).
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functional groups used to water-solubilize these nanoparticles (e.g.: OH, COOH)
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in extra virgin olive oil, showing the characteristic purple color of pristine
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methods) in which some or all the carbon atoms are replaced by other elements.
705:, discovered fullerenes in the sooty residue created by vaporising carbon in a 8253: 8241: 7960: 7845: 7268: 6883: 6783: 6324: 6177: 5887: 4736: 4005: 3601: 3571: 3324: 2766:
Solutions of pure buckminsterfullerene have a deep purple color. Solutions of
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Kawada, H.; Fujii, Y.; Nakao, H.; et al. (1995). "Structural aspects of
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from benzene solution below 30 °C (when solubility is maximum) yields a
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atoms, instead of the usual carbon, was predicted and described in 2007. The
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Ruoff, R.S.; Tse, Doris S.; Malhotra, Ripudaman; Lorents, Donald C. (1993).
5993: 5863: 5766: 4839: 3916: 3794: 3409:. One can obtain milligram quantities of fullerenes with 80 atoms or more. C 3387: 3371: 3319:
In IUPAC's nomenclature, fully saturated analogues of fullerenes are called
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Kim, Jungpil; Yamada, Yasuhiro; Kawai, Miki; et al. (1 October 2015).
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axis goes through a pentagon surrounded by hexagons rather than pentagons.
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Inorganic (carbon-free) fullerene-type structures have been built with the
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Shvartsburg, A.A.; Hudgins, R. R.; Gutierrez, Rafael; et al. (1999).
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atoms inside the cage. The process produced approximately 100 micrograms.
789:, and the list was much expanded in the following years. Carbon nanotubes 32: 17: 8326: 8321: 7907: 7892: 7813: 7662: 7503: 7366: 7360: 3367: 2647: 839: 805: 480: 288: 7683: 6270: 5634: 4811:
Pushparaj, V.L.; Shaijumon, Manikoth M.; Kumar, A.; et al. (2007).
4791:
Harris, D.J. "Discovery of Nitroballs: Research in Fullerene Chemistry"
4064: 3953: 1171:
Linked "ball-and-chain" dimers (two buckyballs linked by a carbon chain)
737:. The team identified their structure as the now familiar "buckyballs". 7783: 7614: 7335: 7284: 6620: 5305: 3382:
that then cools into sooty residue. Alternatively, soot is produced by
3010: 3009:
consisting of 84 carbon atoms with two additional carbon atoms and two
2849: 2732: 2728: 2617: 2510: 2418: 809: 468: 390:
Fullerenes with a closed mesh topology are informally denoted by their
6466: 6425: 6351: 6081: 5948: 5569: 5507: 5422: 5371: 5045: 4993: 4619: 4348: 3864: 1036: = 12, 13, 14, ..., roughly in proportion to 815:
The production techniques were improved by many scientists, including
8132: 4948: 4895: 4395: 4313: 4201: 3727:
Interactive Nano-Visualization in Science & Engineering Education
2620:
which has been reported to exhibit remarkable mechanical properties.
2539: 2113: 785:
Kroto and the Rice team already discovered other fullerenes besides C
706: 413: 376: 6770:
derivatives and their biological consequences in a HeLa cell line".
3394:. Combustion of benzene is the most efficient process, developed at 3037:, and the total number of atoms. For example, buckminsterfullerene C 903:
with isosurface of ground state electron density as calculated with
96: 4499: 3350:. When bonds are removed (both sigma and pi), the compound becomes 2623: 2157:
transforms it into a face-centered cubic form. Both monoclinic and
6522: 5237: 5181: 4292:
Iijima, Sumio (1991). "Helical microtubules of graphitic carbon".
3354:; if some new bonds are added in an unconventional order, it is a 2695: 2676: 2622: 2562: 1227:
buckyball. However, subsequent analysis found that the predicted I
1200: 909: 887: 510: 63: 55: 43: 31: 6966: 6480:
Arndt, M.; Nairz, Olaf; Vos-Andreae, Julian; et al. (1999).
2650:, must be bent to form the closed sphere or tube, which produces 2367:
has been reported to be sp. The bonding state can be analyzed by
4481:"Confirming Interstellar C60 + Using the Hubble Space Telescope" 1330: 946: 797: 561:
cage was mentioned in 1965 as a possible topological structure.
476: 8136: 7687: 7288: 6970: 6805:
Mroz, Pawel; Pawlak, Anna; Satti, Minahil; et al. (2007).
4166:
Kroto, H.W.; Heath, J. R.; Obrien, S. C.; et al. (1985). "
4813:"Flexible energy storage devices based on nanocomposite paper" 2340:
must be even, and that there must be exactly 12 pentagons and
1326: 6644:"Nanostructures and computer simulations in material science" 3535:
method of administration (e.g.: intravenous, intraperitoneal)
3327:
substituted for one or more carbons, the compound is named a
2518:= 2, 8, 18, 32, 50, 72, 98, 128, etc. (i.e., twice a perfect 777:
for their roles in the discovery of this class of molecules.
2743:. Solubilities are generally rather low, such as 8 g/L for C 2117:
asterisk * marks symmetries with more than one chiral form.
459:. The bulk solid form of pure or mixed fullerenes is called 6962:
Giant Fullerenes, a short video looking at Giant Fullerenes
5746:
Powell, W. H.; Cozzi, F.; Moss, G. P.; et al. (2002).
5108:
Gonzalez Szwacki, N.; Sadrzadeh, A.; Yakobson, B. (2007). "
2561:
in water tends to pick up two more electrons and become an
1042: 408:
is the number of carbon atoms. However, for some values of
1050:). For instance, there are 1812 non-isomorphic fullerenes 740:
The name "buckminsterfullerene" was eventually chosen for
5452:
W. L. F. Armarego; Christina Li Lin Chai (11 May 2009).
2495:": that is, the electrons in the hexagonal rings do not 427:), the most famous member, which in turn is named after 8383:
The Last Dymaxion: Buckminster Fuller’s Dream Restored
2448:
There are many calculations that have been done using
998:
Another fairly common fullerene has empirical formula
6673:. Springer Science & Business Media. p. 29. 2336:
are the numbers of vertices, edges, and faces), that
1274:
symmetry interleaved with a network of 48 triangles.
6727:
Nanostructured materials for solar energy conversion
6586:
Support for top-down theory of how 'buckyballs’ form
6558:
Nanostructured materials for solar energy conversion
6152:
Beck, Mihály T.; Mándi, Géza (1997). "Solubility of
4793:
http://www.usc.edu/CSSF/History/1993/CatWin_S05.html
2112:
In the table, "Num.Isom." is the number of possible
8281: 8210: 8170: 7953: 7906: 7774: 7728: 7721: 7643: 7573: 7512: 7479: 7429: 7350: 7322: 7198: 7175: 7152: 7119: 7074: 7037: 7004: 5017:"Ball-and-Chain Dimers from a Hot Fullerene Plasma" 2401:. An unusual example is the egg-shaped fullerene Tb 5531:Angewandte Chemie International Edition in English 4544: 4061:"The History of Carbon 60 or Buckminsterfullerene" 6107:: Comparison with diamond on hardness and wear". 3442:for tumor treatment, and drug and gene delivery. 3295:IUPAC name is methyl 4-(3’-phenyl-3’H-cyclopropa( 2445:are some of the more heavily studied properties. 952:The empirical formula of buckminsterfullerene is 762:for the vague similarity of the structure to the 8347:R. Buckminster Fuller and Anne Hewlett Dome Home 3200:Non-equivalent bonds shown by different colours. 2289:The Schlegel diagram of a closed fullerene is a 2161:(fcc) phases are known for better-characterized 1191:, in particular, have attracted much attention. 979:of a buckminsterfullerene molecule is about 1.1 6723:"Fullerene Thin Films as Photovoltaic Material" 6554:"Fullerene Thin Films as Photovoltaic Material" 6166:Fullerenes, Nanotubes and Carbon Nanostructures 5335:Genuth, Iddo; Yaffe, Tomer (15 February 2006). 4818:Proceedings of the National Academy of Sciences 4427:"Buckyballs Could Be Plentiful in the Universe" 2654:. The characteristic reaction of fullerenes is 2522:), but this series does not include 60. This 2( 773:Kroto, Curl, and Smalley were awarded the 1996 8148: 7699: 7300: 6982: 5809:"Carbon materials with high pentagon density" 4690:"Buckminsterfullerene: Molecule of the Month" 4588:and Its Derivatives Across a Lipid Bilayer". 4479:Cordiner, M.A.; et al. (22 April 2019). 348: 8: 6897:Jones, D. (1966). "Note in Ariadne column". 6852: 6850: 6451:in Benzene, Hexane, and Toluene Solutions". 4538: 4536: 4161: 4159: 4157: 3898:"Nomenclature and Terminology of Fullerenes" 3717: 3715: 3661: 3659: 3547:Examples of fullerenes appear frequently in 2884:. Above 30 °C one obtains solvate-free 2301:(or "cubic"; meaning that all vertices have 1168:Nested carbon nanotubes ("carbon megatubes") 577:in 1970. He noticed that the structure of a 531:, another member of the family of fullerenes 5741: 5739: 5737: 5616: 5614: 3090:)fullerene in IUPAC notation. The symmetry 1290:), long used as a graphite-like lubricant, 447:. Nested closed fullerenes have been named 8155: 8141: 8133: 8115: 7725: 7706: 7692: 7684: 7307: 7293: 7285: 6989: 6975: 6967: 6340:Journal of Chemical & Engineering Data 3750: 3748: 3452:Health and safety hazards of nanomaterials 2452:quantum methods applied to fullerenes. By 2425:preserved by being trapped in fullerenes. 1179:Heterofullerenes and non-carbon fullerenes 355: 341: 79: 6830: 6128: 5802: 5800: 5236: 5218: 5216: 5180: 4848: 4838: 4609: 4516: 4498: 3872: 3822: 3820: 2475:Fullerene is an unusual reactant in many 451:. Cylindrical fullerenes are also called 6670:Perspectives of Fullerene Nanotechnology 6365:Talyzin, A.V. (1997). "Phase Transition 5936:Journal of the American Chemical Society 5706:crystals studied by x-ray diffraction". 5654:. New Age International. pp. 126–. 5458:. Butterworth-Heinemann. pp. 214–. 5360:Journal of the American Chemical Society 4337:Journal of the American Chemical Society 4236:. Sussex Fullerene Group. chm.bris.ac.uk 3337: 3097:means that this is the isomer where the 2915:applied to molecules such as fullerene. 1347: 1104: 6951:Nanocarbon: From Graphene to Buckyballs 6581: 6579: 6577: 6026:Angewandte Chemie International Edition 3619: 3473:is toxic. The toxicity of these carbon 3106: 2751:. Still, fullerenes are the only known 2727:Fullerenes are soluble in many organic 2231: 1097:), oxygen, and phosphorus derivatives. 1013:The smallest possible fullerene is the 273: 184: 146: 103: 87: 7971:Differential technological development 5651:Symmetry And Spectroscopy Of Molecules 4765:Fowler, P. W. and Manolopoulos, D. E. 4724:Analytical and Bioanalytical Chemistry 3967:Osawa, E. (1970). "Superaromaticity". 1145:, developed in 2007 by researchers at 439:for their resemblance to the standard 8375:Buckminster Fuller: Thinking Out Loud 6439:Talyzin, A.V.; Engström, I. (1998). " 5337:"Protecting the soldiers of tomorrow" 2580:described below may be the result of 2534:is the three-dimensional analogue of 2220:zero) can be represented as a convex 791:were first discovered and synthesized 643:from an electron microscope image of 431:. The closed fullerenes, especially C 7: 8187:Operating Manual for Spaceship Earth 7243: 6642:Bobrowsky, Maciej (1 October 2019). 5455:Purification of laboratory chemicals 3331:. If a double bond is replaced by a 2233:Schlegel diagrams of some fullerenes 1174:Rings of buckyballs linked together. 594:Atomic Energy Research Establishment 536:Predictions and limited observations 8060:Future-oriented technology analysis 6823:10.1016/j.freeradbiomed.2007.05.005 6811:Free Radical Biology & Medicine 6588:. kurzweilai.net. 24 September 2013 5403:The Journal of Physical Chemistry A 4543:Miessler, G.L.; Tarr, D.A. (2004). 4425:Atkinson, Nancy (27 October 2010). 4269:"A new buckyball bounces into town" 4247:"The Nobel Prize in Chemistry 1996" 752:by the discoverers as an homage to 7819:High-temperature superconductivity 5917:Beavers, C.M.; Zuo, T. (2006). "Tb 3456:Toxicology of carbon nanomaterials 2363:. The hybridization of carbon in C 863:in the space between those stars. 25: 8332:Proposed Brooklyn Dodgers stadium 4486:The Astrophysical Journal Letters 4453:Starr, Michelle (29 April 2019). 4372:"Solid C60: a new form of carbon" 3607:Truncated rhombic triacontahedron 3438:, X-ray imaging contrast agents, 2759:, which will dissolve 51 g/L of C 859:molecules were detected with the 40:fullerene (buckminsterfullerene). 8114: 7931:Self-reconfiguring modular robot 7267: 7255: 7242: 7231: 7230: 6922: 6735:10.1016/B978-044452844-5/50014-7 6313:Fullerene Science and Technology 5648:K Veera Reddy (1 January 1998). 3896:Godly, E.W.; Taylor, R. (1997). 3827:Stars reveal carbon 'spaceballs' 3275: 3240: 3205: 3172: 3139: 3109: 2377:X-ray photoelectron spectroscopy 2277: 2263: 2251: 2237: 1147:Rensselaer Polytechnic Institute 322: 310: 95: 7342:Lonsdaleite (hexagonal diamond) 6772:Chemico-Biological Interactions 6560:. Elsevier. pp. 372, 381. 6454:Journal of Physical Chemistry B 6413:Journal of Physical Chemistry B 6215:10.1070/PU1998v041n11ABEH000502 5025:Journal of Physical Chemistry A 4716:"Goldberg Variations Challenge" 3993:Chemical & Engineering News 3342:, the resulting structure is a 1199:A type of buckyball which uses 445:association football ("soccer") 83:Part of a series of articles on 8272:Expo 67 United States Pavilion 7824:High-temperature superfluidity 6872:Coordination Chemistry Reviews 6729:. Elsevier. pp. 361–443. 5255:10.1103/PhysRevLett.106.225502 3986:Halford, B. (9 October 2006). 3779:in a Young Planetary Nebula". 2907:In 1999, researchers from the 2421:period was found by analyzing 880:meshes or larger "buckybuds". 1: 8087:Technology in science fiction 7190:Scanning tunneling microscope 6258:Journal of Physical Chemistry 6139:10.1016/S0925-9635(97)00232-X 6109:Diamond and Related Materials 5623:Accounts of Chemical Research 5144:10.1103/PhysRevLett.98.166804 5095:10.1016/S0009-2614(01)00064-1 4688:Locke, W. (13 October 1996). 4046:10.1016/S0008-6223(99)00191-8 3988:"The World According to Rick" 3839:Belkin, A.; et., al. (2015). 3592:Goldberg–Coxeter construction 2808:Millimeter-sized crystals of 1062:. Note that only one form of 435:, are also informally called 8369:Buckminster Fuller Challenge 8342:Old Man River's City project 8317:Cloud Nine tensegrity sphere 5868:Journal of Materials Science 5813:Journal of Materials Science 5605:10.1016/0009-2614(91)90475-O 5199:10.1016/j.cplett.2007.11.030 4659:10.1126/science.254.5030.410 4267:Mraz, S.J. (14 April 2005). 4122:10.1016/0022-0248(80)90013-5 3941:Journal of Organic Chemistry 3690:10.1126/science.257.5067.215 3421:are available commercially. 3403:appropriate organic solvents 3378:vaporizes the carbon into a 3067:The latter is the case for C 2629:scanning electron microscope 7162:Molecular scale electronics 6250:) in a variety of solvents" 2526: + 1) rule (with 2208:In mathematical terms, the 631:identified the molecule of 565:predicted the existence of 412:there may be more than one 60:Model of a carbon nanotube. 8455: 8092:Technology readiness level 8028:Technological unemployment 7673:Aggregated diamond nanorod 6957:Introduction to fullerites 6696:Nanotechnology Perceptions 6482:"Wave-particle duality of 6238:"Solubility of fullerene ( 5833:10.1007/s10853-020-05392-x 5755:Pure and Applied Chemistry 3905:Pure and Applied Chemistry 3723:"The allotropes of carbon" 3449: 3374:atmosphere. The resulting 3314:)fullerene-3’-yl)butyrate. 2922: 2805:have a variety of colors. 2670: 2639: 2386: 2310:Euler's polyhedron formula 934: 829:Konstantinos Fostiropoulos 650:Also in the 1980s at MIT, 419:The family is named after 8403: 8305:Design science revolution 8110: 8075:Technological singularity 8035:Technological convergence 7851:Multi-function structures 7471:(cyclo[18]carbon) 7226: 7177:Scanning probe microscopy 6884:10.1016/j.ccr.2023.215550 6784:10.1016/j.cbi.2011.11.003 6725:. In Sōga, Tetsuo (ed.). 6556:. In Sōga, Tetsuo (ed.). 6325:10.1080/15363839408009549 6178:10.1080/15363839708011993 5888:10.1007/s10853-015-9229-0 4737:10.1007/s00216-006-0358-9 4178:: Buckminsterfullerene". 4102:Journal of Crystal Growth 4006:10.1021/cen-v084n041.p013 3628:"Definition of BUCKYTUBE" 3041:is systematically named ( 2778:are a reddish brown. The 2502:A spherical fullerene of 2499:over the whole molecule. 1652: 1649: 1636: 1109:This rotating model of a 970:association football ball 8230:Dymaxion deployment unit 7866:Molecular nanotechnology 7829:Linear acetylenic carbon 7455:(cyclo[6]carbon) 7439:Linear acetylenic carbon 7200:Molecular nanotechnology 7144:Solid lipid nanoparticle 7129:Self-assembled monolayer 5720:10.1103/PhysRevB.51.8723 5585:Chemical Physics Letters 5168:Chemical Physics Letters 5074:Chemical Physics Letters 4798:29 November 2015 at the 4518:10.3847/2041-8213/ab14e5 4136:"Mildred S. Dresselhaus" 1235:symmetry (symmetry of a 850:were observed by NASA's 775:Nobel Prize in Chemistry 299:Nanocrystalline material 275:Nanostructured materials 8179:Nine Chains to the Moon 8040:Technological evolution 8013:Exploratory engineering 7185:Atomic force microscope 7134:Supramolecular assembly 7121:Molecular self-assembly 5994:10.1126/science.1057243 5792:Encyclopædia Britannica 5767:10.1351/pac200274040629 5225:Physical Review Letters 5123:Physical Review Letters 4840:10.1073/pnas.0706508104 3917:10.1351/pac199769071411 3795:10.1126/science.1192035 3632:www.merriam-webster.com 2592:trying to form a loose 2460:methods one can obtain 2272:(truncated icosahedron) 1127:electrical conductivity 1113:shows its 3D structure. 964:and its structure is a 926:, one kind of fullerene 72:fullerite (bulk solid C 8050:Technology forecasting 8045:Technological paradigm 8018:Proactionary principle 7499:Carbide-derived carbon 7381:(buckminsterfullerene) 6311:in Organic Solvents". 6039:10.1002/anie.200462348 5558:Chemistry of Materials 5543:10.1002/anie.199722681 4223:Buckminsterfullerene, 4140:The Franklin Institute 2937:Some fullerenes (e.g. 2741:1,2,3-trichloropropane 2724: 2693: 2656:electrophilic addition 2632: 2224:; more precisely, its 2210:combinatorial topology 1284:molybdenum(IV) sulfide 1254:However, an irregular 1114: 1032:grows with increasing 977:van der Waals diameter 927: 907: 876:— nanotubes capped by 861:Hubble Space Telescope 833:Fullerene purification 532: 77: 61: 53: 41: 8289:Allegra Fuller Snyder 7976:Disruptive innovation 7839:Metamaterial cloaking 7715:Emerging technologies 7274:Technology portal 4714:Meija, Juris (2006). 4082:Dokl. Akad. Nauk SSSR 4022:(1999). "Editorial". 3392:aromatic hydrocarbons 2913:wave-particle duality 2699: 2680: 2626: 2614:"Ultrahard fullerite" 2532:spherical aromaticity 2399:endohedral fullerenes 2389:Endohedral fullerenes 1108: 968:, which resembles an 966:truncated icosahedron 913: 891: 514: 329:Technology portal 124:Mechanical properties 67: 59: 47: 35: 8362:Buckminsterfullerene 8295:Current solar income 8023:Technological change 7966:Collingridge dilemma 7316:Allotropes of carbon 7061:Green nanotechnology 6721:Katz, E. A. (2006). 6667:Osawa, Eiji (2002). 6552:Katz, E. A. (2006). 6410:in Liquid Benzene". 3829:, BBC, 22 July 2010. 3440:photodynamic therapy 3035:Schoenflies notation 3031:symmetry point group 2925:Buckminsterfullerene 2909:University of Vienna 2673:Fullerene solubility 2483:discovered in 1993. 1189:Non-carbon nanotubes 937:Buckminsterfullerene 931:Buckminsterfullerene 781:Further developments 683:University of Sussex 421:buckminsterfullerene 294:Nanoporous materials 157:Buckminsterfullerene 8202:Dymaxion Chronofile 8080:Technology scouting 8055:Accelerating change 7926:Powered exoskeleton 7883:Programmable matter 7761:Smart manufacturing 7756:Molecular assembler 7736:3D microfabrication 7208:Molecular assembler 6613:2013NatCh...5..880Z 6515:1999Natur.401..680A 6271:10.1021/j100115a049 6207:1998PhyU...41.1091B 6121:1998DRM.....7..427B 6074:2010MaMol..43.6033H 5986:2001Sci...291.1530B 5880:2015JMatS..50.6739K 5825:2021JMatS..56.2912D 5635:10.1021/ar00015a004 5597:1991CPL...187....1M 5500:2005JPCA..109.4617S 5415:2006JPCA..11010169C 5409:(34): 10169–10172. 5298:2014NatCh...6..727Z 5247:2011PhRvL.106v5502D 5191:2008CPL...450..175G 5136:2007PhRvL..98p6804G 5087:2001CPL...335..524L 5038:1999JPCA..103.5275S 4981:Inorganic Chemistry 4941:2001Natur.414..506S 4888:1992Natur.359..707U 4831:2007PNAS..10413574P 4602:2007NanoL...7..614Q 4547:Inorganic Chemistry 4509:2019ApJ...875L..28C 4388:1990Natur.347..354K 4343:(47): 11596–11601. 4306:1991Natur.354...56I 4281:on 13 October 2008. 4194:1985Natur.318..162K 4114:1980JCrGr..50..675I 4038:1999Carbo..37.1677. 3954:10.1021/jo01016a005 3857:2015NatSR...5E8323B 3789:(5996): 1180–1182. 3682:1992Sci...257..215B 3652:on 23 October 2015. 3446:Safety and toxicity 2757:1-chloronaphthalene 2642:Fullerene chemistry 2395:inclusion compounds 2159:face-centered cubic 1139:chemical inactivity 840:spectral signatures 821:Wolfgang Krätschmer 709:atmosphere. In the 652:Mildred Dresselhaus 387:, or other shapes. 373:allotrope of carbon 196:Carbon quantum dots 27:Allotrope of carbon 8386:(2012 documentary) 8378:(1996 documentary) 8164:Buckminster Fuller 8097:Technology roadmap 7799:Conductive polymer 7594:(cyclopropatriene) 7575:hypothetical forms 7396:Fullerene whiskers 7262:Science portal 7139:DNA nanotechnology 6621:10.1038/nchem.1748 5306:10.1038/nchem.1999 4782:. nanotube.msu.edu 3323:. If the mesh has 3134:Carbon numbering. 2989:because they are D 2911:demonstrated that 2725: 2694: 2633: 2369:Raman spectroscopy 1185:molecular modeling 1115: 928: 908: 760:Buckminster Fuller 533: 429:Buckminster Fuller 317:Science portal 129:Optical properties 78: 62: 54: 42: 8421: 8420: 8130: 8129: 7949: 7948: 7898:Synthetic diamond 7794:Artificial muscle 7776:Materials science 7681: 7680: 7549:(diatomic carbon) 7481:mixed sp/sp forms 7282: 7281: 6744:978-0-444-52844-5 6680:978-0-7923-7174-8 6567:978-0-444-52844-5 6467:10.1021/jp9815255 6461:(34): 6477–6481. 6426:10.1021/jp9720303 6420:(47): 9679–9681. 6352:10.1021/je900296s 6265:(13): 3379–3383. 6201:(11): 1091–1114. 6082:10.1021/ma100694y 6068:(14): 6033–6044. 5949:10.1021/ja063636k 5874:(20): 6739–6747. 5714:(14): 8723–8730. 5708:Physical Review B 5661:978-81-224-1142-3 5570:10.1021/cm980183c 5537:(21): 2268–2280. 5508:10.1021/jp0450181 5494:(20): 4617–4622. 5465:978-1-85617-567-8 5423:10.1021/jp063617x 5372:10.1021/ja062052f 5366:(26): 8390–8391. 5347:on 26 March 2008. 5046:10.1021/jp9906379 5032:(27): 5275–5284. 4994:10.1021/ic000551q 4882:(6397): 707–709. 4653:(5030): 410–412. 4620:10.1021/nl062515f 4562:978-0-13-120198-9 4553:Pearson Education 4382:(6291): 354–358. 4349:10.1021/ja003521v 4188:(6042): 162–163. 4032:(11): 1677–1678. 3865:10.1038/srep08323 3405:and separated by 3370:electrodes in an 3167:Carbon numbering. 3025:According to the 3021:Systematic naming 2987:inherently chiral 2919:Superconductivity 2903:Quantum mechanics 2780:higher fullerenes 2506:carbon atoms has 2477:organic reactions 2443:superconductivity 2203:Schlegel diagrams 2110: 2109: 1251:exist in nature. 1135:heat conductivity 914:Rotating view of 485:materials science 400:, often written C 392:empirical formula 365: 364: 177:Carbon allotropes 16:(Redirected from 8446: 8390:Karlis Johansons 8352:Ephemeralization 8157: 8150: 8143: 8134: 8118: 8117: 8065:Horizon scanning 7981:Ephemeralization 7941:Uncrewed vehicle 7861:Carbon nanotubes 7726: 7708: 7701: 7694: 7685: 7653:Activated carbon 7609: 7608: 7607: 7593: 7592: 7591: 7564: 7563: 7562: 7548: 7547: 7546: 7532: 7531: 7530: 7489:Amorphous carbon 7470: 7469: 7468: 7454: 7453: 7452: 7309: 7302: 7295: 7286: 7272: 7271: 7260: 7259: 7246: 7245: 7234: 7233: 7218:Mechanosynthesis 7109:characterization 6991: 6984: 6977: 6968: 6926: 6925: 6909: 6908: 6894: 6888: 6887: 6866: 6860: 6854: 6845: 6844: 6834: 6802: 6796: 6795: 6769: 6768: 6767: 6755: 6749: 6748: 6718: 6712: 6711: 6691: 6685: 6684: 6664: 6658: 6657: 6655: 6653: 6648: 6639: 6633: 6632: 6601:Nature Chemistry 6595: 6589: 6583: 6572: 6571: 6549: 6543: 6542: 6498: 6493: 6492: 6491: 6477: 6471: 6470: 6450: 6449: 6448: 6436: 6430: 6429: 6409: 6408: 6407: 6399: 6398: 6388: 6387: 6386: 6376: 6375: 6374: 6362: 6356: 6355: 6335: 6329: 6328: 6310: 6309: 6308: 6296: 6290: 6289: 6287: 6285: 6279: 6273:. Archived from 6254: 6249: 6248: 6247: 6233: 6227: 6226: 6188: 6182: 6181: 6163: 6162: 6161: 6149: 6143: 6142: 6132: 6115:(2–5): 427–431. 6106: 6105: 6104: 6092: 6086: 6085: 6057: 6051: 6050: 6020: 6014: 6013: 5980:(5508): 1530–3. 5967: 5961: 5960: 5932: 5931: 5930: 5914: 5908: 5907: 5859: 5853: 5852: 5819:(4): 2912–2943. 5804: 5795: 5785: 5779: 5778: 5752: 5743: 5732: 5731: 5705: 5704: 5703: 5693: 5692: 5691: 5679: 5673: 5672: 5670: 5668: 5645: 5639: 5638: 5618: 5609: 5608: 5580: 5574: 5573: 5564:(7): 1742–1744. 5553: 5547: 5546: 5526: 5520: 5519: 5483: 5477: 5476: 5474: 5472: 5449: 5443: 5442: 5398: 5392: 5391: 5355: 5349: 5348: 5343:. Archived from 5332: 5326: 5325: 5286:Nature Chemistry 5281: 5275: 5274: 5240: 5220: 5211: 5210: 5184: 5175:(4–6): 175–177. 5162: 5156: 5155: 5119: 5118: 5117: 5105: 5099: 5098: 5081:(5–6): 524–532. 5070: 5069: 5068: 5056: 5050: 5049: 5021: 5012: 5006: 5005: 4975: 4969: 4968: 4949:10.1038/35107141 4922: 4916: 4915: 4896:10.1038/359707a0 4869: 4863: 4862: 4852: 4842: 4808: 4802: 4789: 4783: 4779: 4778: 4777: 4763: 4757: 4756: 4720: 4711: 4705: 4704: 4702: 4700: 4694:Imperial College 4685: 4679: 4678: 4638: 4632: 4631: 4613: 4587: 4586: 4585: 4573: 4567: 4566: 4551:(3rd ed.). 4550: 4540: 4531: 4530: 4520: 4502: 4476: 4470: 4469: 4467: 4465: 4459:ScienceAlert.com 4450: 4444: 4443: 4441: 4439: 4422: 4416: 4415: 4396:10.1038/347354a0 4367: 4361: 4360: 4332: 4326: 4325: 4314:10.1038/354056a0 4289: 4283: 4282: 4277:. Archived from 4264: 4258: 4257: 4255: 4253: 4243: 4237: 4234: 4233: 4232: 4220: 4214: 4213: 4202:10.1038/318162a0 4177: 4176: 4175: 4163: 4152: 4151: 4149: 4147: 4142:. 5 October 2016 4132: 4126: 4125: 4097: 4091: 4090: 4075: 4069: 4068: 4067:on 15 June 2013. 4063:. Archived from 4056: 4050: 4049: 4016: 4010: 4009: 3983: 3977: 3976: 3964: 3958: 3957: 3948:(5): 1361–1364. 3935: 3929: 3928: 3911:(7): 1411–1434. 3902: 3893: 3887: 3886: 3876: 3836: 3830: 3824: 3815: 3814: 3778: 3777: 3776: 3766: 3765: 3764: 3752: 3743: 3742: 3740: 3738: 3729:. Archived from 3719: 3710: 3709: 3663: 3654: 3653: 3648:. Archived from 3642: 3636: 3635: 3624: 3587:Fullerene ligand 3528: 3527: 3526: 3516: 3515: 3514: 3504: 3503: 3502: 3492: 3491: 3490: 3472: 3471: 3470: 3341: 3333:methylene bridge 3325:other element(s) 3306: 3305: 3304: 3292: 3291: 3290: 3279: 3262: 3261: 3260: 3244: 3227: 3226: 3225: 3209: 3190: 3189: 3188: 3176: 3157: 3156: 3155: 3143: 3127: 3126: 3125: 3113: 3082: 3081: 3080: 3052: 3051: 3050: 3007:metallofullerene 2984: 2983: 2982: 2972: 2971: 2970: 2960: 2959: 2958: 2948: 2947: 2946: 2898: 2897: 2896: 2883: 2882: 2881: 2873: 2872: 2862: 2861: 2860: 2843: 2842: 2841: 2831: 2830: 2829: 2819: 2818: 2817: 2804: 2803: 2802: 2792: 2791: 2790: 2777: 2776: 2775: 2749:carbon disulfide 2722: 2721: 2720: 2710: 2709: 2708: 2691: 2690: 2689: 2591: 2590: 2589: 2579: 2578: 2577: 2560: 2559: 2558: 2544:quantum chemical 2493:superaromaticity 2433:In the field of 2416: 2415: 2414: 2281: 2267: 2255: 2241: 2187: 2186: 2185: 2173: 2172: 2171: 2156: 2155: 2154: 2143: 2142: 2141: 2131: 2130: 2129: 2082: 2081: 2080: 2042: 2041: 2040: 2002: 2001: 2000: 1962: 1961: 1960: 1926: 1902: 1901: 1900: 1845: 1844: 1843: 1829: 1828: 1827: 1789: 1788: 1787: 1745: 1744: 1743: 1705: 1647: 1646: 1645: 1603: 1602: 1601: 1559: 1558: 1557: 1515: 1514: 1513: 1471: 1470: 1469: 1427: 1426: 1425: 1348: 1265: 1264: 1263: 1249: 1248: 1247: 1226: 1225: 1224: 1214: 1213: 1212: 1123:tensile strength 1118:Carbon nanotubes 1101:Carbon nanotubes 1090:Heterofullerenes 1085: 1084: 1083: 1073: 1072: 1071: 1061: 1060: 1059: 1045: 1027: 1026: 1025: 1009: 1008: 1007: 994:Other fullerenes 963: 962: 961: 925: 924: 923: 902: 901: 900: 751: 750: 749: 736: 735: 734: 724: 723: 722: 673: 672: 671: 642: 641: 640: 623: 622: 621: 607: 606: 605: 576: 575: 574: 560: 559: 558: 550: 549: 540:The icosahedral 530: 529: 528: 453:carbon nanotubes 357: 350: 343: 327: 326: 315: 314: 266:Titanium dioxide 105:Carbon nanotubes 99: 80: 21: 8454: 8453: 8449: 8448: 8447: 8445: 8444: 8443: 8439:1985 in science 8424: 8423: 8422: 8417: 8399: 8395:Kenneth Snelson 8277: 8206: 8166: 8161: 8131: 8126: 8106: 7945: 7902: 7804:Femtotechnology 7789:Amorphous metal 7770: 7717: 7712: 7682: 7677: 7639: 7630:Metallic carbon 7606: 7603: 7602: 7601: 7599: 7590: 7587: 7586: 7585: 7583: 7569: 7561: 7558: 7557: 7556: 7554: 7545: 7542: 7541: 7540: 7538: 7533:(atomic carbon) 7529: 7526: 7525: 7524: 7522: 7508: 7494:Carbon nanofoam 7475: 7467: 7464: 7463: 7462: 7460: 7451: 7448: 7447: 7446: 7444: 7425: 7390: 7380: 7346: 7336:Diamond (cubic) 7318: 7313: 7283: 7278: 7266: 7254: 7222: 7194: 7171: 7167:Nanolithography 7154:Nanoelectronics 7148: 7115: 7070: 7033: 7024:Popular culture 7000: 6995: 6947: 6946: 6945: 6927: 6923: 6918: 6913: 6912: 6896: 6895: 6891: 6868: 6867: 6863: 6855: 6848: 6804: 6803: 6799: 6766: 6763: 6762: 6761: 6759: 6757: 6756: 6752: 6745: 6720: 6719: 6715: 6693: 6692: 6688: 6681: 6666: 6665: 6661: 6651: 6649: 6646: 6641: 6640: 6636: 6607:(10): 880–885. 6597: 6596: 6592: 6584: 6575: 6568: 6551: 6550: 6546: 6509:(6754): 680–2. 6496: 6490: 6487: 6486: 6485: 6483: 6479: 6478: 6474: 6447: 6444: 6443: 6442: 6440: 6438: 6437: 6433: 6406: 6403: 6402: 6401: 6397: 6394: 6393: 6392: 6390: 6385: 6382: 6381: 6380: 6378: 6373: 6370: 6369: 6368: 6366: 6364: 6363: 6359: 6337: 6336: 6332: 6307: 6304: 6303: 6302: 6300: 6298: 6297: 6293: 6283: 6281: 6277: 6252: 6246: 6243: 6242: 6241: 6239: 6235: 6234: 6230: 6194:Physics-Uspekhi 6190: 6189: 6185: 6160: 6157: 6156: 6155: 6153: 6151: 6150: 6146: 6130:10.1.1.520.7265 6103: 6100: 6099: 6098: 6096: 6094: 6093: 6089: 6059: 6058: 6054: 6022: 6021: 6017: 5969: 5968: 5964: 5943:(35): 11352–3. 5929: 5926: 5925: 5924: 5922: 5920: 5916: 5915: 5911: 5861: 5860: 5856: 5806: 5805: 5798: 5786: 5782: 5750: 5745: 5744: 5735: 5702: 5699: 5698: 5697: 5695: 5690: 5687: 5686: 5685: 5683: 5681: 5680: 5676: 5666: 5664: 5662: 5647: 5646: 5642: 5620: 5619: 5612: 5582: 5581: 5577: 5555: 5554: 5550: 5528: 5527: 5523: 5485: 5484: 5480: 5470: 5468: 5466: 5451: 5450: 5446: 5400: 5399: 5395: 5357: 5356: 5352: 5334: 5333: 5329: 5283: 5282: 5278: 5222: 5221: 5214: 5164: 5163: 5159: 5116: 5113: 5112: 5111: 5109: 5107: 5106: 5102: 5067: 5064: 5063: 5062: 5060: 5058: 5057: 5053: 5019: 5014: 5013: 5009: 4977: 4976: 4972: 4935:(6863): 506–7. 4924: 4923: 4919: 4871: 4870: 4866: 4825:(34): 13574–7. 4810: 4809: 4805: 4800:Wayback Machine 4790: 4786: 4776: 4771: 4770: 4769: 4767: 4764: 4760: 4718: 4713: 4712: 4708: 4698: 4696: 4687: 4686: 4682: 4640: 4639: 4635: 4611:10.1.1.725.7141 4584: 4581: 4580: 4579: 4577: 4575: 4574: 4570: 4563: 4542: 4541: 4534: 4478: 4477: 4473: 4463: 4461: 4452: 4451: 4447: 4437: 4435: 4424: 4423: 4419: 4369: 4368: 4364: 4334: 4333: 4329: 4300:(6348): 56–58. 4291: 4290: 4286: 4266: 4265: 4261: 4251: 4249: 4245: 4244: 4240: 4231: 4228: 4227: 4226: 4224: 4221: 4217: 4174: 4171: 4170: 4169: 4167: 4165: 4164: 4155: 4145: 4143: 4134: 4133: 4129: 4099: 4098: 4094: 4077: 4076: 4072: 4058: 4057: 4053: 4018: 4017: 4013: 3985: 3984: 3980: 3966: 3965: 3961: 3937: 3936: 3932: 3900: 3895: 3894: 3890: 3838: 3837: 3833: 3825: 3818: 3775: 3772: 3771: 3770: 3768: 3763: 3760: 3759: 3758: 3756: 3754: 3753: 3746: 3736: 3734: 3733:on 18 June 2010 3721: 3720: 3713: 3676:(5067): 215–7. 3665: 3664: 3657: 3644: 3643: 3639: 3626: 3625: 3621: 3616: 3611: 3567: 3549:popular culture 3545: 3543:Popular culture 3525: 3522: 3521: 3520: 3518: 3513: 3510: 3509: 3508: 3506: 3501: 3498: 3497: 3496: 3494: 3489: 3486: 3485: 3484: 3482: 3469: 3466: 3465: 3464: 3462: 3458: 3450:Main articles: 3448: 3436:contrast agents 3432: 3427: 3420: 3416: 3412: 3386:of graphite or 3364: 3339: 3335: 3329:heterofullerene 3315: 3313: 3303: 3300: 3299: 3298: 3296: 3294: 3293:-PCBM, -isomer. 3289: 3286: 3285: 3284: 3282: 3280: 3271: 3269: 3259: 3256: 3255: 3254: 3252: 3245: 3236: 3234: 3224: 3221: 3220: 3219: 3217: 3210: 3201: 3199: 3197: 3187: 3184: 3183: 3182: 3180: 3177: 3168: 3166: 3164: 3154: 3151: 3150: 3149: 3147: 3144: 3135: 3133: 3124: 3121: 3120: 3119: 3117: 3114: 3103: 3096: 3089: 3079: 3076: 3075: 3074: 3072: 3070: 3064:path sequence. 3059: 3049: 3046: 3045: 3044: 3042: 3040: 3023: 2999: 2992: 2981: 2978: 2977: 2976: 2974: 2969: 2966: 2965: 2964: 2962: 2957: 2954: 2953: 2952: 2950: 2945: 2942: 2941: 2940: 2938: 2935: 2927: 2921: 2905: 2895: 2892: 2891: 2890: 2888: 2880: 2877: 2876: 2875: 2871: 2868: 2867: 2866: 2864: 2859: 2856: 2855: 2854: 2852: 2840: 2837: 2836: 2835: 2833: 2828: 2825: 2824: 2823: 2821: 2816: 2813: 2812: 2811: 2809: 2801: 2798: 2797: 2796: 2794: 2789: 2786: 2785: 2784: 2782: 2774: 2771: 2770: 2769: 2767: 2762: 2746: 2719: 2716: 2715: 2714: 2712: 2707: 2704: 2703: 2702: 2700: 2688: 2685: 2684: 2683: 2681: 2675: 2669: 2644: 2638: 2607: 2602: 2588: 2585: 2584: 2583: 2581: 2576: 2573: 2572: 2571: 2569: 2557: 2554: 2553: 2552: 2550: 2489: 2481:Bingel reaction 2439:heat resistance 2431: 2413: 2410: 2409: 2408: 2406: 2404: 2391: 2385: 2373:IR spectroscopy 2366: 2350: 2285: 2282: 2273: 2271: 2268: 2259: 2256: 2247: 2245: 2242: 2226:one-dimensional 2200: 2195: 2184: 2181: 2180: 2179: 2177: 2170: 2167: 2166: 2165: 2163: 2153: 2150: 2149: 2148: 2146: 2140: 2137: 2136: 2135: 2133: 2128: 2125: 2124: 2123: 2121: 2079: 2076: 2075: 2074: 2072: 2039: 2036: 2035: 2034: 2032: 1999: 1996: 1995: 1994: 1992: 1959: 1956: 1955: 1954: 1952: 1924: 1915: 1911: 1899: 1896: 1895: 1894: 1892: 1864: 1853: 1849: 1842: 1839: 1838: 1837: 1835: 1826: 1823: 1822: 1821: 1819: 1786: 1783: 1782: 1781: 1779: 1754: 1742: 1739: 1738: 1737: 1735: 1703: 1668: 1656: 1644: 1641: 1640: 1639: 1637: 1612: 1600: 1597: 1596: 1595: 1593: 1568: 1556: 1553: 1552: 1551: 1549: 1524: 1512: 1509: 1508: 1507: 1505: 1480: 1468: 1465: 1464: 1463: 1461: 1436: 1424: 1421: 1420: 1419: 1417: 1411: 1380: 1367: 1362: 1355: 1339: 1337:Main fullerenes 1311: 1303: 1295: 1289: 1280: 1273: 1266:complex dubbed 1262: 1259: 1258: 1257: 1255: 1246: 1243: 1242: 1241: 1240: 1234: 1230: 1223: 1220: 1219: 1218: 1216: 1211: 1208: 1207: 1206: 1204: 1197: 1181: 1159: 1143:paper batteries 1137:, and relative 1111:carbon nanotube 1103: 1082: 1079: 1078: 1077: 1075: 1070: 1067: 1066: 1065: 1063: 1058: 1055: 1054: 1053: 1051: 1041: 1031: 1024: 1021: 1020: 1019: 1017: 1006: 1003: 1002: 1001: 999: 996: 960: 957: 956: 955: 953: 939: 933: 922: 919: 918: 917: 915: 899: 896: 895: 894: 892: 886: 874:carbon nanobuds 869: 858: 849: 845: 788: 783: 748: 745: 744: 743: 741: 733: 730: 729: 728: 726: 721: 718: 717: 716: 714: 703:Rice University 699:Richard Smalley 685:, working with 675: 670: 667: 666: 665: 663: 639: 636: 635: 634: 632: 620: 617: 616: 615: 613: 604: 601: 600: 599: 597: 596:) proposed the 573: 570: 569: 568: 566: 557: 554: 553: 552: 548: 545: 544: 543: 541: 538: 527: 524: 523: 522: 520: 509: 501: 475:carbon such as 434: 426: 399: 361: 321: 309: 206:Aluminium oxide 75: 71: 51: 39: 28: 23: 22: 15: 12: 11: 5: 8452: 8450: 8442: 8441: 8436: 8426: 8425: 8419: 8418: 8416: 8415: 8410: 8404: 8401: 8400: 8398: 8397: 8392: 8387: 8379: 8371: 8366: 8365: 8364: 8354: 8349: 8344: 8339: 8334: 8329: 8324: 8319: 8314: 8313: 8312: 8310:Design science 8307: 8297: 8292: 8285: 8283: 8279: 8278: 8276: 8275: 8269: 8266:Fly's Eye Dome 8263: 8257: 8251: 8245: 8239: 8233: 8227: 8221: 8218:Dymaxion house 8214: 8212: 8208: 8207: 8205: 8204: 8199: 8191: 8183: 8174: 8172: 8168: 8167: 8162: 8160: 8159: 8152: 8145: 8137: 8128: 8127: 8125: 8124: 8111: 8108: 8107: 8105: 8104: 8099: 8094: 8089: 8084: 8083: 8082: 8077: 8072: 8067: 8062: 8057: 8047: 8042: 8037: 8032: 8031: 8030: 8020: 8015: 8010: 8009: 8008: 8003: 7998: 7993: 7983: 7978: 7973: 7968: 7963: 7957: 7955: 7951: 7950: 7947: 7946: 7944: 7943: 7938: 7936:Swarm robotics 7933: 7928: 7923: 7918: 7912: 7910: 7904: 7903: 7901: 7900: 7895: 7890: 7885: 7880: 7878:Picotechnology 7875: 7874: 7873: 7868: 7863: 7856:Nanotechnology 7853: 7848: 7843: 7842: 7841: 7831: 7826: 7821: 7816: 7811: 7806: 7801: 7796: 7791: 7786: 7780: 7778: 7772: 7771: 7769: 7768: 7763: 7758: 7753: 7748: 7743: 7738: 7732: 7730: 7723: 7719: 7718: 7713: 7711: 7710: 7703: 7696: 7688: 7679: 7678: 7676: 7675: 7670: 7665: 7660: 7655: 7649: 7647: 7641: 7640: 7638: 7637: 7635:Penta-graphene 7632: 7627: 7622: 7617: 7612: 7604: 7596: 7588: 7579: 7577: 7571: 7570: 7568: 7567: 7559: 7551: 7543: 7535: 7527: 7518: 7516: 7510: 7509: 7507: 7506: 7501: 7496: 7491: 7485: 7483: 7477: 7476: 7474: 7473: 7465: 7457: 7449: 7441: 7435: 7433: 7427: 7426: 7424: 7423: 7418: 7388: 7378: 7369: 7364: 7356: 7354: 7348: 7347: 7345: 7344: 7339: 7331: 7329: 7320: 7319: 7314: 7312: 7311: 7304: 7297: 7289: 7280: 7279: 7277: 7276: 7264: 7252: 7240: 7227: 7224: 7223: 7221: 7220: 7215: 7210: 7204: 7202: 7196: 7195: 7193: 7192: 7187: 7181: 7179: 7173: 7172: 7170: 7169: 7164: 7158: 7156: 7150: 7149: 7147: 7146: 7141: 7136: 7131: 7125: 7123: 7117: 7116: 7114: 7113: 7112: 7111: 7101: 7100: 7099: 7094: 7086: 7080: 7078: 7072: 7071: 7069: 7068: 7063: 7058: 7056:Nanotoxicology 7053: 7047: 7045: 7035: 7034: 7032: 7031: 7026: 7021: 7016: 7010: 7008: 7002: 7001: 6998:Nanotechnology 6996: 6994: 6993: 6986: 6979: 6971: 6965: 6964: 6959: 6954: 6928: 6921: 6920: 6919: 6917: 6916:External links 6914: 6911: 6910: 6889: 6861: 6846: 6817:(5): 711–719. 6797: 6764: 6750: 6743: 6713: 6702:(3): 121–128. 6686: 6679: 6659: 6634: 6590: 6573: 6566: 6544: 6488: 6472: 6445: 6431: 6404: 6395: 6383: 6371: 6357: 6330: 6319:(3): 233–246. 6305: 6291: 6244: 6228: 6183: 6172:(2): 291–310. 6158: 6144: 6101: 6087: 6062:Macromolecules 6052: 6033:(12): 1843–6. 6015: 5962: 5927: 5918: 5909: 5854: 5796: 5780: 5761:(4): 629–695. 5733: 5700: 5688: 5674: 5660: 5640: 5610: 5575: 5548: 5521: 5478: 5464: 5444: 5393: 5350: 5327: 5292:(8): 727–731. 5276: 5231:(22): 225502. 5212: 5157: 5130:(16): 166804. 5114: 5100: 5065: 5051: 5007: 4988:(12): 2751–5. 4970: 4917: 4864: 4803: 4784: 4772: 4758: 4706: 4680: 4633: 4582: 4568: 4561: 4532: 4471: 4445: 4432:Universe Today 4417: 4362: 4327: 4284: 4274:Machine Design 4259: 4238: 4229: 4215: 4172: 4153: 4127: 4108:(3): 675–683. 4092: 4070: 4051: 4011: 3978: 3959: 3930: 3888: 3831: 3816: 3773: 3761: 3744: 3711: 3655: 3637: 3618: 3617: 3615: 3612: 3610: 3609: 3604: 3599: 3594: 3589: 3584: 3579: 3577:Carbocatalysis 3574: 3568: 3566: 3563: 3544: 3541: 3537: 3536: 3533: 3530: 3523: 3511: 3499: 3487: 3467: 3447: 3444: 3431: 3428: 3426: 3423: 3418: 3414: 3410: 3407:chromatography 3384:laser ablation 3363: 3360: 3356:cyclofullerene 3317: 3316: 3311: 3301: 3287: 3281: 3274: 3272: 3267: 3257: 3246: 3239: 3237: 3232: 3222: 3211: 3204: 3202: 3195: 3185: 3178: 3171: 3169: 3162: 3152: 3145: 3138: 3136: 3122: 3115: 3108: 3101: 3094: 3087: 3077: 3068: 3057: 3047: 3038: 3022: 3019: 2998: 2995: 2990: 2979: 2967: 2955: 2943: 2934: 2931: 2923:Main article: 2920: 2917: 2904: 2901: 2893: 2878: 2869: 2857: 2838: 2826: 2814: 2799: 2787: 2772: 2760: 2744: 2717: 2705: 2686: 2671:Main article: 2668: 2665: 2640:Main article: 2637: 2634: 2606: 2605:Polymerization 2603: 2601: 2598: 2586: 2574: 2555: 2488: 2485: 2435:nanotechnology 2430: 2427: 2411: 2402: 2387:Main article: 2384: 2381: 2364: 2361:covalent bonds 2349: 2346: 2287: 2286: 2283: 2276: 2274: 2269: 2262: 2260: 2257: 2250: 2248: 2246:(dodecahedron) 2243: 2236: 2234: 2199: 2196: 2194: 2191: 2182: 2168: 2151: 2138: 2126: 2108: 2107: 2105: 2103: 2101: 2099: 2097: 2095: 2093: 2091: 2089: 2087: 2085: 2083: 2077: 2069: 2068: 2066: 2064: 2062: 2060: 2058: 2056: 2054: 2052: 2050: 2048: 2046: 2043: 2037: 2029: 2028: 2026: 2024: 2022: 2020: 2018: 2016: 2014: 2012: 2010: 2008: 2006: 2003: 1997: 1989: 1988: 1986: 1984: 1982: 1980: 1978: 1976: 1974: 1972: 1970: 1968: 1966: 1963: 1957: 1949: 1948: 1946: 1944: 1941: 1938: 1935: 1932: 1930: 1928: 1921: 1916: 1913: 1909: 1906: 1903: 1897: 1889: 1888: 1886: 1883: 1880: 1877: 1874: 1871: 1868: 1865: 1862: 1859: 1854: 1851: 1847: 1840: 1833: 1830: 1824: 1816: 1815: 1813: 1811: 1809: 1807: 1805: 1803: 1801: 1799: 1797: 1795: 1793: 1790: 1784: 1776: 1775: 1773: 1771: 1769: 1767: 1765: 1763: 1761: 1759: 1757: 1755: 1752: 1749: 1746: 1740: 1732: 1731: 1728: 1725: 1722: 1719: 1716: 1713: 1710: 1707: 1700: 1694: 1693: 1690: 1687: 1684: 1681: 1678: 1675: 1672: 1669: 1666: 1663: 1658: 1654: 1651: 1648: 1642: 1634: 1633: 1631: 1629: 1627: 1625: 1623: 1621: 1619: 1617: 1615: 1613: 1610: 1607: 1604: 1598: 1590: 1589: 1587: 1585: 1583: 1581: 1579: 1577: 1575: 1573: 1571: 1569: 1566: 1563: 1560: 1554: 1546: 1545: 1543: 1541: 1539: 1537: 1535: 1533: 1531: 1529: 1527: 1525: 1522: 1519: 1516: 1510: 1502: 1501: 1499: 1497: 1495: 1493: 1491: 1489: 1487: 1485: 1483: 1481: 1478: 1475: 1472: 1466: 1458: 1457: 1455: 1453: 1451: 1449: 1447: 1445: 1443: 1441: 1439: 1437: 1434: 1431: 1428: 1422: 1414: 1413: 1408: 1403: 1400: 1394: 1388: 1382: 1377: 1374: 1369: 1364: 1359: 1352: 1338: 1335: 1309: 1301: 1293: 1287: 1279: 1278:Other elements 1276: 1271: 1260: 1244: 1232: 1228: 1221: 1209: 1196: 1193: 1180: 1177: 1176: 1175: 1172: 1169: 1166: 1158: 1155: 1151:space elevator 1102: 1099: 1080: 1068: 1056: 1029: 1022: 1004: 995: 992: 958: 935:Main article: 932: 929: 920: 897: 885: 882: 868: 865: 856: 847: 843: 825:Lowell D. Lamb 817:Donald Huffman 786: 782: 779: 764:geodesic domes 746: 731: 719: 687:James R. Heath 674: 668: 660: 637: 618: 602: 585:Also in 1970, 571: 555: 546: 537: 534: 525: 508: 505: 500: 497: 493:nanotechnology 432: 424: 395: 363: 362: 360: 359: 352: 345: 337: 334: 333: 332: 331: 319: 304: 303: 302: 301: 296: 291: 286: 278: 277: 271: 270: 269: 268: 263: 258: 253: 248: 243: 238: 233: 228: 223: 218: 213: 208: 203: 198: 190: 189: 182: 181: 180: 179: 174: 169: 164: 159: 151: 150: 144: 143: 142: 141: 136: 131: 126: 121: 116: 108: 107: 101: 100: 92: 91: 85: 84: 73: 69: 49: 48:Model of the C 37: 36:Model of the C 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 8451: 8440: 8437: 8435: 8432: 8431: 8429: 8414: 8411: 8409: 8406: 8405: 8402: 8396: 8393: 8391: 8388: 8385: 8384: 8380: 8377: 8376: 8372: 8370: 8367: 8363: 8360: 8359: 8358: 8355: 8353: 8350: 8348: 8345: 8343: 8340: 8338: 8335: 8333: 8330: 8328: 8325: 8323: 8320: 8318: 8315: 8311: 8308: 8306: 8303: 8302: 8301: 8298: 8296: 8293: 8290: 8287: 8286: 8284: 8280: 8273: 8270: 8267: 8264: 8261: 8258: 8255: 8252: 8249: 8248:Geodesic dome 8246: 8243: 8240: 8237: 8234: 8231: 8228: 8225: 8222: 8219: 8216: 8215: 8213: 8209: 8203: 8200: 8197: 8196: 8195:Critical Path 8192: 8189: 8188: 8184: 8181: 8180: 8176: 8175: 8173: 8169: 8165: 8158: 8153: 8151: 8146: 8144: 8139: 8138: 8135: 8123: 8122: 8113: 8112: 8109: 8103: 8102:Transhumanism 8100: 8098: 8095: 8093: 8090: 8088: 8085: 8081: 8078: 8076: 8073: 8071: 8068: 8066: 8063: 8061: 8058: 8056: 8053: 8052: 8051: 8048: 8046: 8043: 8041: 8038: 8036: 8033: 8029: 8026: 8025: 8024: 8021: 8019: 8016: 8014: 8011: 8007: 8004: 8002: 7999: 7997: 7994: 7992: 7989: 7988: 7987: 7984: 7982: 7979: 7977: 7974: 7972: 7969: 7967: 7964: 7962: 7959: 7958: 7956: 7952: 7942: 7939: 7937: 7934: 7932: 7929: 7927: 7924: 7922: 7919: 7917: 7914: 7913: 7911: 7909: 7905: 7899: 7896: 7894: 7891: 7889: 7886: 7884: 7881: 7879: 7876: 7872: 7871:Nanomaterials 7869: 7867: 7864: 7862: 7859: 7858: 7857: 7854: 7852: 7849: 7847: 7844: 7840: 7837: 7836: 7835: 7834:Metamaterials 7832: 7830: 7827: 7825: 7822: 7820: 7817: 7815: 7812: 7810: 7807: 7805: 7802: 7800: 7797: 7795: 7792: 7790: 7787: 7785: 7782: 7781: 7779: 7777: 7773: 7767: 7764: 7762: 7759: 7757: 7754: 7752: 7749: 7747: 7746:3D publishing 7744: 7742: 7739: 7737: 7734: 7733: 7731: 7729:Manufacturing 7727: 7724: 7720: 7716: 7709: 7704: 7702: 7697: 7695: 7690: 7689: 7686: 7674: 7671: 7669: 7666: 7664: 7661: 7659: 7656: 7654: 7651: 7650: 7648: 7646: 7642: 7636: 7633: 7631: 7628: 7626: 7623: 7621: 7618: 7616: 7613: 7611: 7610:(prismane C8) 7597: 7595: 7581: 7580: 7578: 7576: 7572: 7566: 7552: 7550: 7536: 7534: 7520: 7519: 7517: 7515: 7511: 7505: 7502: 7500: 7497: 7495: 7492: 7490: 7487: 7486: 7484: 7482: 7478: 7472: 7458: 7456: 7442: 7440: 7437: 7436: 7434: 7432: 7428: 7422: 7421:Glassy carbon 7419: 7416: 7415: 7410: 7409: 7404: 7403: 7398: 7397: 7392: 7391: 7383: 7382: 7373: 7370: 7368: 7365: 7363: 7362: 7358: 7357: 7355: 7353: 7349: 7343: 7340: 7338: 7337: 7333: 7332: 7330: 7328: 7327: 7321: 7317: 7310: 7305: 7303: 7298: 7296: 7291: 7290: 7287: 7275: 7270: 7265: 7263: 7258: 7253: 7251: 7250: 7241: 7239: 7238: 7229: 7228: 7225: 7219: 7216: 7214: 7211: 7209: 7206: 7205: 7203: 7201: 7197: 7191: 7188: 7186: 7183: 7182: 7180: 7178: 7174: 7168: 7165: 7163: 7160: 7159: 7157: 7155: 7151: 7145: 7142: 7140: 7137: 7135: 7132: 7130: 7127: 7126: 7124: 7122: 7118: 7110: 7107: 7106: 7105: 7104:Nanoparticles 7102: 7098: 7095: 7093: 7090: 7089: 7087: 7085: 7082: 7081: 7079: 7077: 7076:Nanomaterials 7073: 7067: 7064: 7062: 7059: 7057: 7054: 7052: 7049: 7048: 7046: 7044: 7040: 7036: 7030: 7027: 7025: 7022: 7020: 7019:Organizations 7017: 7015: 7012: 7011: 7009: 7007: 7003: 6999: 6992: 6987: 6985: 6980: 6978: 6973: 6972: 6969: 6963: 6960: 6958: 6955: 6952: 6949: 6948: 6943: 6942: 6941: 6935: 6931: 6915: 6906: 6902: 6901: 6900:New Scientist 6893: 6890: 6885: 6881: 6877: 6873: 6865: 6862: 6859: 6858:Full Text PDF 6853: 6851: 6847: 6842: 6838: 6833: 6828: 6824: 6820: 6816: 6812: 6808: 6801: 6798: 6793: 6789: 6785: 6781: 6777: 6773: 6754: 6751: 6746: 6740: 6736: 6732: 6728: 6724: 6717: 6714: 6709: 6705: 6701: 6697: 6690: 6687: 6682: 6676: 6672: 6671: 6663: 6660: 6645: 6638: 6635: 6630: 6626: 6622: 6618: 6614: 6610: 6606: 6602: 6594: 6591: 6587: 6582: 6580: 6578: 6574: 6569: 6563: 6559: 6555: 6548: 6545: 6540: 6536: 6532: 6528: 6524: 6523:10.1038/44348 6520: 6516: 6512: 6508: 6504: 6503: 6495: 6476: 6473: 6468: 6464: 6460: 6456: 6455: 6435: 6432: 6427: 6423: 6419: 6415: 6414: 6361: 6358: 6353: 6349: 6345: 6341: 6334: 6331: 6326: 6322: 6318: 6314: 6295: 6292: 6280:on 8 May 2012 6276: 6272: 6268: 6264: 6260: 6259: 6251: 6232: 6229: 6224: 6220: 6216: 6212: 6208: 6204: 6200: 6196: 6195: 6187: 6184: 6179: 6175: 6171: 6167: 6148: 6145: 6140: 6136: 6131: 6126: 6122: 6118: 6114: 6110: 6091: 6088: 6083: 6079: 6075: 6071: 6067: 6063: 6056: 6053: 6048: 6044: 6040: 6036: 6032: 6028: 6027: 6019: 6016: 6011: 6007: 6003: 5999: 5995: 5991: 5987: 5983: 5979: 5975: 5974: 5966: 5963: 5958: 5954: 5950: 5946: 5942: 5938: 5937: 5913: 5910: 5905: 5901: 5897: 5893: 5889: 5885: 5881: 5877: 5873: 5869: 5865: 5858: 5855: 5850: 5846: 5842: 5838: 5834: 5830: 5826: 5822: 5818: 5814: 5810: 5803: 5801: 5797: 5793: 5789: 5784: 5781: 5776: 5772: 5768: 5764: 5760: 5756: 5749: 5742: 5740: 5738: 5734: 5729: 5725: 5721: 5717: 5713: 5709: 5678: 5675: 5663: 5657: 5653: 5652: 5644: 5641: 5636: 5632: 5628: 5624: 5617: 5615: 5611: 5606: 5602: 5598: 5594: 5590: 5586: 5579: 5576: 5571: 5567: 5563: 5559: 5552: 5549: 5544: 5540: 5536: 5532: 5525: 5522: 5517: 5513: 5509: 5505: 5501: 5497: 5493: 5489: 5488:J. Phys. Chem 5482: 5479: 5467: 5461: 5457: 5456: 5448: 5445: 5440: 5436: 5432: 5428: 5424: 5420: 5416: 5412: 5408: 5404: 5397: 5394: 5389: 5385: 5381: 5377: 5373: 5369: 5365: 5361: 5354: 5351: 5346: 5342: 5338: 5331: 5328: 5323: 5319: 5315: 5311: 5307: 5303: 5299: 5295: 5291: 5287: 5280: 5277: 5272: 5268: 5264: 5260: 5256: 5252: 5248: 5244: 5239: 5234: 5230: 5226: 5219: 5217: 5213: 5208: 5204: 5200: 5196: 5192: 5188: 5183: 5178: 5174: 5170: 5169: 5161: 5158: 5153: 5149: 5145: 5141: 5137: 5133: 5129: 5125: 5124: 5104: 5101: 5096: 5092: 5088: 5084: 5080: 5076: 5075: 5055: 5052: 5047: 5043: 5039: 5035: 5031: 5027: 5026: 5018: 5011: 5008: 5003: 4999: 4995: 4991: 4987: 4983: 4982: 4974: 4971: 4966: 4962: 4958: 4954: 4950: 4946: 4942: 4938: 4934: 4930: 4929: 4921: 4918: 4913: 4909: 4905: 4901: 4897: 4893: 4889: 4885: 4881: 4877: 4876: 4868: 4865: 4860: 4856: 4851: 4846: 4841: 4836: 4832: 4828: 4824: 4820: 4819: 4814: 4807: 4804: 4801: 4797: 4794: 4788: 4785: 4781: 4775: 4762: 4759: 4754: 4750: 4746: 4742: 4738: 4734: 4730: 4726: 4725: 4717: 4710: 4707: 4695: 4691: 4684: 4681: 4676: 4672: 4668: 4664: 4660: 4656: 4652: 4648: 4644: 4637: 4634: 4629: 4625: 4621: 4617: 4612: 4607: 4603: 4599: 4595: 4591: 4572: 4569: 4564: 4558: 4554: 4549: 4548: 4539: 4537: 4533: 4528: 4524: 4519: 4514: 4510: 4506: 4501: 4496: 4492: 4488: 4487: 4482: 4475: 4472: 4460: 4456: 4449: 4446: 4434: 4433: 4428: 4421: 4418: 4413: 4409: 4405: 4401: 4397: 4393: 4389: 4385: 4381: 4377: 4373: 4366: 4363: 4358: 4354: 4350: 4346: 4342: 4338: 4331: 4328: 4323: 4319: 4315: 4311: 4307: 4303: 4299: 4295: 4288: 4285: 4280: 4276: 4275: 4270: 4263: 4260: 4248: 4242: 4239: 4235: 4219: 4216: 4211: 4207: 4203: 4199: 4195: 4191: 4187: 4183: 4182: 4162: 4160: 4158: 4154: 4141: 4137: 4131: 4128: 4123: 4119: 4115: 4111: 4107: 4103: 4096: 4093: 4088: 4084: 4083: 4074: 4071: 4066: 4062: 4059:Henson, R.W. 4055: 4052: 4047: 4043: 4039: 4035: 4031: 4027: 4026: 4021: 4020:Thrower, P.A. 4015: 4012: 4007: 4003: 4000:(41): 13–19. 3999: 3995: 3994: 3989: 3982: 3979: 3974: 3970: 3963: 3960: 3955: 3951: 3947: 3943: 3942: 3934: 3931: 3926: 3922: 3918: 3914: 3910: 3906: 3899: 3892: 3889: 3884: 3880: 3875: 3870: 3866: 3862: 3858: 3854: 3850: 3846: 3842: 3835: 3832: 3828: 3823: 3821: 3817: 3812: 3808: 3804: 3800: 3796: 3792: 3788: 3784: 3783: 3751: 3749: 3745: 3732: 3728: 3724: 3718: 3716: 3712: 3707: 3703: 3699: 3695: 3691: 3687: 3683: 3679: 3675: 3671: 3670: 3662: 3660: 3656: 3651: 3647: 3641: 3638: 3633: 3629: 3623: 3620: 3613: 3608: 3605: 3603: 3600: 3598: 3595: 3593: 3590: 3588: 3585: 3583: 3582:Dodecahedrane 3580: 3578: 3575: 3573: 3570: 3569: 3564: 3562: 3560: 3556: 3555: 3554:New Scientist 3550: 3542: 3540: 3534: 3531: 3480: 3479: 3478: 3476: 3475:nanoparticles 3457: 3453: 3445: 3443: 3441: 3437: 3429: 3424: 3422: 3408: 3404: 3399: 3397: 3393: 3389: 3385: 3381: 3377: 3373: 3369: 3361: 3359: 3357: 3353: 3352:secofullerene 3349: 3345: 3344:homofullerene 3334: 3330: 3326: 3322: 3310: 3278: 3273: 3266: 3250: 3243: 3238: 3231: 3215: 3208: 3203: 3194: 3175: 3170: 3161: 3142: 3137: 3131: 3112: 3107: 3105: 3100: 3093: 3086: 3065: 3061: 3056: 3036: 3032: 3028: 3020: 3018: 3014: 3012: 3008: 3003: 2996: 2994: 2988: 2932: 2930: 2926: 2918: 2916: 2914: 2910: 2902: 2900: 2887: 2851: 2847: 2806: 2781: 2764: 2758: 2754: 2750: 2742: 2738: 2737:chlorobenzene 2734: 2730: 2698: 2679: 2674: 2666: 2664: 2661: 2657: 2653: 2649: 2643: 2635: 2630: 2625: 2621: 2619: 2615: 2611: 2604: 2599: 2597: 2595: 2594:metallic bond 2568: 2564: 2549:As a result, 2547: 2545: 2541: 2537: 2536:Hückel's rule 2533: 2530:integer) for 2529: 2525: 2521: 2520:square number 2517: 2512: 2509: 2505: 2500: 2498: 2494: 2486: 2484: 2482: 2478: 2473: 2471: 2467: 2463: 2459: 2455: 2451: 2446: 2444: 2440: 2436: 2428: 2426: 2424: 2420: 2400: 2396: 2390: 2383:Encapsulation 2382: 2380: 2378: 2374: 2370: 2362: 2359: 2355: 2347: 2345: 2343: 2339: 2335: 2331: 2327: 2323: 2319: 2315: 2311: 2306: 2304: 2300: 2296: 2292: 2280: 2275: 2266: 2261: 2254: 2249: 2240: 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Index

Fullerenes




Nanomaterials

Carbon nanotubes
Synthesis
Chemistry
Mechanical properties
Optical properties
Applications
Timeline
Fullerenes
Buckminsterfullerene
C70 fullerene
Chemistry
Health impact
Carbon allotropes
nanoparticles
Carbon quantum dots
Quantum dots
Aluminium oxide
Cellulose
Ceramic
Cobalt oxide
Copper
Gold
Iron

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