132:
24:
33:
375:
The compound behaves as a source of the carbanion as well as a source of highly reactive Mg. With electrophiles, the compound reacts to give dihydroanthracene derivatives C
88:
211:
391:, organotin chlorides, and organoaluminium chlorides. Ethylene inserts into one Mg-C bond. Hydrogen induces release of anthracene, yielding
482:
80:
176:
445:
L. M. Engelhardt; S. Harvey; C. L. Raston; A. H. White (1988). "Organomagnesium
Reagents: The Crystal Structures of and ".
309:
348:, this air- and water-sensitive orange solid is obtained by heating a suspension of magnesium in a thf solution of
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3 thf: InChI=1S/C14H10.3C5H10O.Mg/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1;3*1-2-4-6-5-3-1;/h1-10H;3*1-5H2;
325:
418:
Borislav
Bogdanovic (1988). "Magnesium Anthracene Systems and Their Application in Synthesis and Catalysis".
127:
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InChI=1S/C14H10.Mg/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1;/h1-10H;/q;+2
431:
291:
140:
372:
ligand sphere. The fold angle between the two benzo groups is 72.6°.
329:
302:
Except where otherwise noted, data are given for materials in their
224:
3 thf: C1CCOCC1.C1CCOCC1.C1CCOCC1.C1=CC=C2C=C3C=CC=CC3=CC2=C1.
87:
79:
69:
32:
161:
152:
55:
364:, the Mg center is 5-coordinate, occupying a C
8:
328:that is almost invariably isolated as its
130:
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15:
413:
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216:
181:
121:
336:(thf) ligands. With the formula Mg(C
198:Key: RWNAQYFPPNXQES-UHFFFAOYSA-N
188:Key: UUHXXHJSGPKOGI-UHFFFAOYSA-N
7:
387:. Electrophiles include ketones, CO
447:Journal of Organometallic Chemistry
143:
14:
257:
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31:
22:
306:(at 25 °C , 100 kPa).
260:
245:
1:
420:Accounts of Chemical Research
459:10.1016/0022-328X(88)89061-2
219:C1=CC=C2C=C3C=CC=CC3=CC2=C1.
499:
483:Organomagnesium compounds
300:
232:
207:
172:
39:
30:
21:
356:Structure and reactivity
326:organomagnesium compound
157: with charge error
362:X-ray crystallography
17:Magnesium anthracene
322:Magnesium anthracene
432:10.1021/ar00151a002
278: g·mol
18:
310:Infobox references
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393:magnesium hydride
318:Chemical compound
316:
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89:Interactive image
81:Interactive image
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240:Chemical formula
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334:tetrahydrofuran
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426:(7): 261–267.
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304:standard state
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360:According to
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286:orange solid
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122:ECHA InfoCard
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160:3 thf:
107:3 thf:
86:3 thf:
40:Identifiers
478:Anthracenes
453:(1–3): 39.
332:with three
296:1.184 g/cm
283:Appearance
233:Properties
128:100.210.465
472:Categories
403:References
350:anthracene
271:Molar mass
100:ChemSpider
68:3D model (
57:86901-19-1
47:CAS Number
163:10863500
154:21928237
292:Density
276:418.860
141:PubChem
110:9038788
344:)(thf)
330:adduct
324:is an
212:SMILES
177:InChI
70:JSmol
395:(MgH
455:doi
451:341
428:doi
399:).
144:CID
474::
449:.
424:21
422:.
410:^
381:10
377:14
352:.
342:10
338:14
258:Mg
255:34
249:26
461:.
457::
434:.
430::
397:2
389:2
385:2
383:E
379:H
370:3
368:O
366:2
346:3
340:H
264:3
261:O
252:H
246:C
72:)
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