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Maillard reaction

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is an entirely different process from Maillard browning, though the results of the two processes are sometimes similar to the naked eye (and taste buds). Caramelization may sometimes cause browning in the same foods in which the Maillard reaction occurs, but the two processes are distinct. They are
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In the cooking process, Maillard reactions can produce hundreds of different flavor compounds depending on the chemical constituents in the food, the temperature, the cooking time, and the presence of air. These compounds, in turn, often break down to form yet more flavor compounds.
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Stadler, Richard H.; Robert, Fabien; Riediker, Sonja; Varga, Natalia; Davidek, Tomas; Devaud, Stéphanie; Goldmann, Till; Hau, Jörg; Blank, Imre (August 2004). "In-Depth Mechanistic Study on the Formation of Acrylamide and Other Vinylogous Compounds by the Maillard Reaction".
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The browning reactions that occur when meat is roasted or seared are complex and occur mostly by Maillard browning with contributions from other chemical reactions, including the breakdown of the tetrapyrrole rings of the muscle protein
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or browning of skin tones and can turn hair to a red or ginger tone. The chemical mechanism is the same as in the browning of food, but it develops slowly over time due to the acidic action on the
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of the amino acid and forms a complex mixture of poorly characterized molecules responsible for a range of aromas and flavors. This process is accelerated in an alkaline environment (e.g.,
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steaks, fried dumplings, cookies and other kinds of biscuits, breads, toasted marshmallows, falafel and many other foods undergo this reaction. It is named after French chemist
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Harrison, T. J.; v, G. R. (2005). "An expeditious, high-yielding construction of the food aroma compounds 6-acetyl-1,2,3,4-tetrahydropyridine and 2-acetyl-1-pyrroline".
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is responsible for the biscuit or cracker-like flavor present in baked goods such as bread, popcorn, and tortilla products. The structurally related compound
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Tareke, E.; Rydberg, P.; Karlsson, Patrik; Eriksson, Sune; Törnqvist, Margareta (2002). "Analysis of acrylamide, a carcinogen formed in heated foodstuffs".
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have used the Maillard reaction over the years to make artificial flavors, the majority of patents being related to the production of meat-like flavors.
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bodies and was described by Painter in 1991 as the interaction of anaerobic, acidic, and cold (typically 4 °C (39 °F)) sphagnum acid on the
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In a dry environment, the Maillard reaction—the same chemical process that browns a steak—causes feces to develop a protective outer shell.
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Mottram, Donald S.; Wedzicha, Bronislaw L.; Dodson, Andrew T. (October 2002). "Acrylamide is formed in the Maillard reaction".
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has a similar smell and also occurs naturally without heating. The compound gives varieties of cooked rice and the herb
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published a paper describing the reaction between amino acids and sugars at elevated temperatures. In 1953, chemist
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products undergo further dehydration and deamination to produce dicarbonyls. This is a crucial intermediate.
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call for an oven temperature high enough to ensure that a Maillard reaction occurs. At higher temperatures,
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both promoted by heating, but the Maillard reaction involves amino acids, whereas caramelization is the
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Hodge, J. E. (1953). "Dehydrated Foods, Chemistry of Browning Reactions in Model Systems".
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which typically proceeds rapidly from around 140 to 165 °C (280 to 330 °F). Many
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Champagne: The Essential Guide to the Wines, Producers, and Terroirs of the Iconic Region
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The Maillard reaction is responsible for many colors and flavors in foods, such as the
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Virk-Baker, Mandeep K.; Nagy, Tim R.; Barnes, Stephen; Groopman, John (29 May 2014).
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of the sugar reacts with the amino group of the amino acid, producing N-substituted
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The preparation of French fries at high temperature can lead to the formation of
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can form. This can be discouraged by heating at a lower temperature, adding
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In archaeology, the Maillard process occurs when bodies are preserved in
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Dicarbonyls react with amines to produce Strecker aldehydes through
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Miranda, Gonzalo; Berna, Angel; Mulet, Antonio (4 February 2019).
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Nursten, Harry (2007). "The Chemistry of Nonenzymic Browning".
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Several ways are known for the ketosamines to react further:
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The Maillard reaction also contributes to the preservation of
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of various meats when seared or grilled, the browning and
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On Food and Cooking: The Science and Lore of the Kitchen
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Danehy, James P. (May 19, 1986). Chicester, C.O. (ed.).
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and other crisps, browning of malted barley as found in
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industry's recipes. At high temperatures, a probable
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Cancer.org. Retrieved on 2016-07-24. 724:International Journal of Food Science 446:The unstable glycosylamine undergoes 88: 7: 1313:Nutritional Ecology of the Ruminant 365:. Maillard reactions also occur in 317:6-Acetyl-2,3,4,5-tetrahydropyridine 239:6-Acetyl-2,3,4,5-tetrahydropyridine 25: 878:"The Maillard Reaction Turns 100" 876:Everts, Sarah (October 1, 2012). 1895: 1894: 1475: 1342: 544: 530: 502: 488: 459:Produce two water molecules and 337:below 0.06 nanograms per liter. 155:applied to darken pretzels; see 52: 1097:Dove, Alan (11 February 2016). 1023:. Ten Speed Press. p. 66. 882:Chemical & Engineering News 718:Tamanna, N; Mahmood, N (2015). 635:Chichester, C. O., ed. (1986). 476:fission products can be formed. 199:, or injecting carbon dioxide. 566:Advanced glycation end-product 225:U.S. Department of Agriculture 179:, and hence have an increased 1: 1044:Krystal, Becky (2020-01-31). 144:of the sugar reacts with the 1310:Van Soest, Peter J. (1982). 1226:10.1080/01635581.2014.916323 693:. 2021-09-06. Archived from 271:, the golden-brown color of 121:. The reaction is a form of 1137:10.1039/9781847552570-00005 1071:Cooper, Phil (2 May 2017). 581: 561:Akabori amino-acid reaction 1942: 894:10.1021/cen-09040-scitech2 660:Bui, Andrew (2017-09-29). 411:. It is typically seen on 1892: 1646:Chorleywood bread process 1473: 824:Advances in Food Research 637:Advances in Food Research 472:, and other short-chain 159:), as the amino groups ( 330:Pandanus amaryllifolius 1099:"Hard-core sequencing" 943:McGee, Harold (2004). 357: 345: 248: 240: 217:Louis Camille Maillard 123:non-enzymatic browning 115:Louis Camille Maillard 43: 1129:The Maillard Reaction 830:. Academic Press: 107 448:Amadori rearrangement 351: 343: 246: 238: 33: 1351:at Wikimedia Commons 1214:Nutrition and Cancer 1019:Liem, Peter (2017). 987:10.3390/foods8020056 511:Strecker degradation 321:2-acetyl-1-pyrroline 307:toasted marshmallows 1271:2002Natur.419..448M 1051:The Washington Post 863:10.1021/jf60015a004 782:J. Agric. Food Chem 737:10.1155/2015/526762 519:, a possible human 384:of certain sugars. 373:ages in the bottle 34:The crusts of most 1502:Calcium propanoate 430:Chemical mechanism 358: 346: 249: 241: 231:Foods and products 44: 1908: 1907: 1824:Brand name breads 1661:Maillard reaction 1507:Dough conditioner 1349:Maillard reaction 1347:Media related to 1265:(6906): 448–449. 1175:10.1021/jf0495486 1169:(17): 5550–5558. 1146:978-0-85404-964-6 1131:. pp. 5–30. 954:978-0-684-80001-1 922:10.1021/jo051940a 794:10.1021/jf020302f 788:(17): 4998–5006. 247:2-Acetylpyrroline 205:Flavor scientists 119:protein synthesis 95:chemical reaction 48:Maillard reaction 18:Maillard Reaction 16:(Redirected from 1933: 1898: 1897: 1869:Sourdough breads 1859:Pakistani breads 1803:History of bread 1788:Baker percentage 1686:Sponge and dough 1479: 1379: 1372: 1365: 1356: 1346: 1299: 1298: 1254: 1248: 1247: 1237: 1205: 1199: 1193: 1187: 1186: 1157: 1151: 1150: 1124: 1118: 1117: 1112: 1110: 1094: 1088: 1087: 1085: 1083: 1077:Farm Consultancy 1068: 1062: 1061: 1059: 1058: 1041: 1035: 1034: 1016: 1010: 1009: 999: 989: 965: 959: 958: 940: 934: 933: 916:(26): 10872–74. 904: 898: 897: 873: 867: 866: 846: 840: 839: 837: 835: 821: 812: 806: 805: 777: 768: 767: 757: 739: 715: 706: 705: 703: 702: 683: 677: 676: 674: 672: 657: 651: 650: 632: 626: 625: 604: 586: 554: 549: 548: 534: 506: 492: 174: 169: 168: 165: 92: 87: 81: 75: 74: 71: 70: 67: 64: 61: 58: 21: 1941: 1940: 1936: 1935: 1934: 1932: 1931: 1930: 1911: 1910: 1909: 1904: 1888: 1819:American breads 1807: 1798:Bread in Europe 1766: 1705: 1623: 1617: 1613:Weighing scales 1551: 1527:Leavening agent 1480: 1471: 1388: 1383: 1339: 1307: 1305:Further reading 1302: 1279:10.1038/419448a 1256: 1255: 1251: 1207: 1206: 1202: 1194: 1190: 1159: 1158: 1154: 1147: 1126: 1125: 1121: 1108: 1106: 1096: 1095: 1091: 1081: 1079: 1070: 1069: 1065: 1056: 1054: 1043: 1042: 1038: 1031: 1018: 1017: 1013: 967: 966: 962: 955: 942: 941: 937: 906: 905: 901: 875: 874: 870: 848: 847: 843: 833: 831: 819: 814: 813: 809: 779: 778: 771: 717: 716: 709: 700: 698: 691:Home Cook World 685: 684: 680: 670: 668: 659: 658: 654: 647: 634: 633: 629: 608:Maillard, L. C. 606: 605: 598: 594: 589: 550: 543: 540: 495:The open-chain 432: 417:polysaccharides 397: 335:odor thresholds 311:roasted peanuts 265:coffee roasting 233: 213: 181:nucleophilicity 173: 166: 163: 162: 160: 103:reducing sugars 90:[majaʁ] 85: 79: 55: 51: 38:, such as this 28: 23: 22: 15: 12: 11: 5: 1939: 1937: 1929: 1928: 1926:Name reactions 1923: 1921:Food chemistry 1913: 1912: 1906: 1905: 1893: 1890: 1889: 1887: 1886: 1881: 1876: 1871: 1866: 1861: 1856: 1851: 1846: 1841: 1839:British breads 1836: 1831: 1826: 1821: 1815: 1813: 1809: 1808: 1806: 1805: 1800: 1795: 1793:Bread and salt 1790: 1785: 1780: 1774: 1772: 1768: 1767: 1765: 1764: 1759: 1754: 1749: 1744: 1739: 1734: 1729: 1724: 1719: 1713: 1711: 1707: 1706: 1704: 1703: 1701:Vienna process 1698: 1696:Straight dough 1693: 1688: 1683: 1678: 1673: 1668: 1666:No-knead bread 1663: 1658: 1653: 1648: 1643: 1638: 1633: 1627: 1625: 1619: 1618: 1616: 1615: 1610: 1605: 1600: 1595: 1590: 1585: 1580: 1575: 1570: 1565: 1559: 1557: 1553: 1552: 1550: 1549: 1544: 1539: 1534: 1529: 1524: 1519: 1514: 1509: 1504: 1499: 1494: 1488: 1486: 1482: 1481: 1474: 1472: 1470: 1469: 1464: 1459: 1454: 1449: 1444: 1439: 1437:Sandwich bread 1434: 1429: 1424: 1419: 1414: 1409: 1404: 1398: 1396: 1390: 1389: 1384: 1382: 1381: 1374: 1367: 1359: 1353: 1352: 1338: 1337:External links 1335: 1334: 1333: 1306: 1303: 1301: 1300: 1249: 1220:(5): 774–790. 1200: 1188: 1152: 1145: 1119: 1089: 1063: 1036: 1030:978-1784724474 1029: 1011: 960: 953: 935: 899: 868: 857:(15): 928–43. 841: 807: 769: 707: 678: 652: 645: 627: 617:Comptes Rendus 595: 593: 590: 588: 587: 578: 576:Caramelization 573: 568: 563: 557: 556: 555: 539: 536: 486: 485: 484: 483: 477: 463: 454: 444: 437:carbonyl group 431: 428: 396: 393: 377:Caramelization 290:dulce de leche 285:condensed milk 232: 229: 212: 209: 142:carbonyl group 131:caramelization 26: 24: 14: 13: 10: 9: 6: 4: 3: 2: 1938: 1927: 1924: 1922: 1919: 1918: 1916: 1903: 1902: 1891: 1885: 1882: 1880: 1877: 1875: 1872: 1870: 1867: 1865: 1862: 1860: 1857: 1855: 1854:Indian breads 1852: 1850: 1849:French breads 1847: 1845: 1842: 1840: 1837: 1835: 1832: 1830: 1827: 1825: 1822: 1820: 1817: 1816: 1814: 1812:List articles 1810: 1804: 1801: 1799: 1796: 1794: 1791: 1789: 1786: 1784: 1781: 1779: 1776: 1775: 1773: 1769: 1763: 1760: 1758: 1755: 1753: 1750: 1748: 1745: 1743: 1740: 1738: 1735: 1733: 1732:Bread pudding 1730: 1728: 1725: 1723: 1720: 1718: 1715: 1714: 1712: 1708: 1702: 1699: 1697: 1694: 1692: 1689: 1687: 1684: 1682: 1679: 1677: 1674: 1672: 1669: 1667: 1664: 1662: 1659: 1657: 1654: 1652: 1649: 1647: 1644: 1642: 1639: 1637: 1634: 1632: 1629: 1628: 1626: 1622:Processes and 1620: 1614: 1611: 1609: 1606: 1604: 1601: 1599: 1596: 1594: 1591: 1589: 1586: 1584: 1581: 1579: 1578:Dough scraper 1576: 1574: 1571: 1569: 1568:Bread machine 1566: 1564: 1561: 1560: 1558: 1554: 1548: 1545: 1543: 1540: 1538: 1535: 1533: 1530: 1528: 1525: 1523: 1520: 1518: 1515: 1513: 1510: 1508: 1505: 1503: 1500: 1498: 1495: 1493: 1492:Baker's yeast 1490: 1489: 1487: 1483: 1478: 1468: 1465: 1463: 1460: 1458: 1455: 1453: 1450: 1448: 1445: 1443: 1440: 1438: 1435: 1433: 1430: 1428: 1425: 1423: 1420: 1418: 1415: 1413: 1410: 1408: 1405: 1403: 1400: 1399: 1397: 1395: 1391: 1387: 1380: 1375: 1373: 1368: 1366: 1361: 1360: 1357: 1350: 1345: 1341: 1340: 1336: 1331: 1327: 1323: 1322:9780801427725 1319: 1315: 1314: 1309: 1308: 1304: 1296: 1292: 1288: 1284: 1280: 1276: 1272: 1268: 1264: 1260: 1253: 1250: 1245: 1241: 1236: 1231: 1227: 1223: 1219: 1215: 1211: 1204: 1201: 1197: 1192: 1189: 1184: 1180: 1176: 1172: 1168: 1164: 1156: 1153: 1148: 1142: 1138: 1134: 1130: 1123: 1120: 1116: 1104: 1100: 1093: 1090: 1078: 1074: 1067: 1064: 1053: 1052: 1047: 1040: 1037: 1032: 1026: 1022: 1015: 1012: 1007: 1003: 998: 993: 988: 983: 979: 975: 971: 964: 961: 956: 950: 946: 939: 936: 931: 927: 923: 919: 915: 912: 911: 910:J. Org. Chem. 903: 900: 895: 891: 888:(40): 58–60. 887: 883: 879: 872: 869: 864: 860: 856: 852: 845: 842: 829: 825: 818: 811: 808: 803: 799: 795: 791: 787: 783: 776: 774: 770: 765: 761: 756: 751: 747: 743: 738: 733: 729: 725: 721: 714: 712: 708: 697:on 2022-01-27 696: 692: 688: 682: 679: 667: 666:Tasting Table 663: 656: 653: 648: 646:0-12-016430-2 642: 638: 631: 628: 623: 620:(in French). 619: 618: 613: 609: 603: 601: 597: 591: 585: 584: 579: 577: 574: 572: 569: 567: 564: 562: 559: 558: 553: 547: 542: 537: 535: 533: 528: 526: 522: 518: 514: 512: 507: 505: 500: 498: 493: 491: 482: 478: 475: 471: 470:pyruvaldehyde 467: 464: 462: 458: 457: 455: 453: 449: 445: 442: 441:glycosylamine 438: 434: 433: 429: 427: 425: 420: 418: 414: 410: 406: 402: 394: 392: 390: 385: 383: 378: 374: 372: 368: 364: 355: 350: 342: 338: 336: 332: 331: 326: 322: 318: 314: 312: 308: 304: 300: 296: 292: 291: 286: 282: 278: 274: 270: 266: 262: 258: 254: 245: 237: 230: 228: 226: 222: 221:John E. Hodge 218: 210: 208: 206: 200: 198: 194: 190: 186: 182: 178: 158: 154: 150: 147: 143: 140:The reactive 138: 136: 132: 128: 124: 120: 116: 112: 108: 104: 100: 96: 91: 83: 82: 73: 49: 41: 37: 32: 19: 1899: 1884:Toast dishes 1879:Swiss breads 1874:Sweet breads 1864:Quick breads 1829:Bread dishes 1742:French toast 1727:Bread pakora 1717:Bread crumbs 1660: 1312: 1262: 1258: 1252: 1217: 1213: 1203: 1191: 1166: 1162: 1155: 1128: 1122: 1114: 1107:. Retrieved 1102: 1092: 1080:. Retrieved 1076: 1066: 1055:. Retrieved 1049: 1039: 1020: 1014: 977: 973: 963: 944: 938: 913: 908: 902: 885: 881: 871: 854: 850: 844: 832:. Retrieved 827: 823: 810: 785: 781: 727: 723: 699:. Retrieved 695:the original 690: 681: 669:. Retrieved 665: 655: 636: 630: 621: 615: 529: 515: 508: 501: 494: 487: 421: 398: 386: 375: 359: 328: 324: 315: 299:black garlic 288: 273:French fries 261:fried onions 250: 214: 201: 197:asparaginase 177:deprotonated 146:nucleophilic 139: 47: 45: 1834:Bread rolls 1783:Breadmaking 1681:Pre-slicing 1676:Pre-ferment 1598:Stand mixer 1583:Farinograph 1485:Ingredients 1467:Whole wheat 1462:White bread 1432:Salt-rising 1402:Brown bread 552:Food portal 481:melanoidins 452:ketosamines 395:Archaeology 367:dried fruit 269:baked goods 149:amino group 107:melanoidins 99:amino acids 1915:Categories 1757:Sandwiches 1722:Bread bowl 1624:techniques 1457:Unleavened 1442:Soda bread 1417:Multigrain 1196:Acrylamide 1057:2022-07-28 730:: 526762. 701:2022-01-27 671:6 November 592:References 525:asparagine 521:carcinogen 517:Acrylamide 474:hydrolytic 461:reductones 450:, forming 424:paleofeces 387:In making 354:acrylamide 193:acrylamide 189:carcinogen 105:to create 1656:Leavening 1631:Autolysis 1573:Bread pan 1556:Equipment 1447:Sourdough 1427:Rye bread 1412:Flatbread 980:(2): 56. 746:2314-5765 443:and water 401:peat bogs 382:pyrolysis 371:champagne 369:and when 363:myoglobin 303:chocolate 259:taste in 223:with the 215:In 1912, 185:flavoring 135:pyrolysis 1901:Category 1752:Stuffing 1737:Croutons 1691:Steaming 1671:Proofing 1651:Kneading 1452:Sprouted 1330:29909839 1287:12368844 1244:24875401 1183:15315399 1082:2 August 1006:30720722 930:16356012 834:15 March 802:12166997 764:26904661 624:: 66–68. 610:(1912). 538:See also 466:Diacetyl 413:Iron Age 409:bog body 253:browning 157:lye roll 97:between 1608:Toaster 1295:4360610 1267:Bibcode 1235:4164905 1109:16 June 1103:Science 997:6406843 755:4745522 583:Wok hei 497:Amadori 405:tanning 211:History 191:called 127:recipes 93:) is a 86:French: 40:brioche 1778:Bakery 1636:Baking 1603:Warmer 1328:  1320:  1293:  1285:  1259:Nature 1242:  1232:  1181:  1143:  1027:  1004:  994:  951:  928:  800:  762:  752:  744:  643:  571:Baking 389:silage 325:pandan 309:, and 295:toffee 175:) are 111:Seared 36:breads 1771:Other 1762:Toast 1747:Rusks 1547:Water 1542:Sugar 1522:Flour 1422:Quick 1394:Types 1386:Bread 1291:S2CID 974:Foods 820:(PDF) 281:dried 257:umami 170:→ RNH 1844:Buns 1710:Uses 1641:Biga 1593:Peel 1588:Lame 1563:Oven 1537:Salt 1532:Milk 1512:Eggs 1497:Barm 1326:OCLC 1318:ISBN 1283:PMID 1240:PMID 1179:PMID 1141:ISBN 1111:2021 1084:2022 1025:ISBN 1002:PMID 949:ISBN 926:PMID 836:2024 798:PMID 760:PMID 742:ISSN 728:2015 673:2017 641:ISBN 435:The 283:and 277:malt 263:and 101:and 46:The 1517:Fat 1407:Bun 1275:doi 1263:419 1230:PMC 1222:doi 1171:doi 1133:doi 992:PMC 982:doi 918:doi 890:doi 859:doi 790:doi 750:PMC 732:doi 622:154 161:RNH 153:lye 80:YAR 78:my- 69:ɑːr 1917:: 1324:. 1289:. 1281:. 1273:. 1261:. 1238:. 1228:. 1218:66 1216:. 1212:. 1177:. 1167:52 1165:. 1139:. 1113:. 1101:. 1075:. 1048:. 1000:. 990:. 976:. 972:. 924:. 914:70 886:90 884:. 880:. 853:. 828:30 826:. 822:. 796:. 786:50 784:. 772:^ 758:. 748:. 740:. 726:. 722:. 710:^ 689:. 664:. 599:^ 513:. 468:, 426:. 419:. 313:. 305:, 301:, 297:, 293:, 287:, 84:; 60:aɪ 1378:e 1371:t 1364:v 1332:. 1297:. 1277:: 1269:: 1246:. 1224:: 1185:. 1173:: 1149:. 1135:: 1086:. 1060:. 1033:. 1008:. 984:: 978:8 957:. 932:. 920:: 896:. 892:: 865:. 861:: 855:1 838:. 804:. 792:: 766:. 734:: 704:. 675:. 649:. 356:. 327:( 172:2 167:3 164:+ 72:/ 66:j 63:ˈ 57:m 54:/ 50:( 20:)

Index

Maillard Reaction

breads
brioche
/mˈjɑːr/
my-YAR
[majaʁ]
chemical reaction
amino acids
reducing sugars
melanoidins
Seared
Louis Camille Maillard
protein synthesis
non-enzymatic browning
recipes
caramelization
pyrolysis
carbonyl group
nucleophilic
amino group
lye
lye roll
deprotonated
nucleophilicity
flavoring
carcinogen
acrylamide
asparaginase
Flavor scientists

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