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States. Minerals
Separation, Limited obtained U.S. Patent No. 835,120, issued on November 6, 1906, to Henry Livingston Sulman, Hugh Fitzalis Kirkpatrick-Picard (the two prominent consultant metallurgists and directors of the firm) and John Ballot. As stated in the specification of the patent, the claimed discovery related "to improvements in the process for the concentration of ores, the object being to separate metalliferous matter from gangue by means of oils, fatty acids, or other substances which have a preferential affinity for such metalliferous matter over gangue." Between 1910 and 1912, Minerals Separation Limited acquired use of the process of
52:. In 1914, they also acquired the important Bradford patent for differential flotation. And in 1923, Minerals Separation staff chemists in the San Francisco office, Cornelius Keller and Carl Lewis under director Edward H. Nutter, perfected the use of chemical xanthates, replacing the use of oil and easing the workings in the froth cells. The firm moved into research for the use of flotation in nonmetals as well, such as potash.
60:. It was also well known that this selective property of oils and oily substances was increased when applied to some ores by the addition of a small amount of acid to the ore and water used in process of concentration. Authors of early books on the flotation process related tales of froth flotation roots back to the writings of Herodotus, and listed a series of "flotation" patents back to the mid-nineteenth century.
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critical and minute compared with the amount used in prior processes, amounting to a fraction of 1 percent on the ore and in impregnating with air the mass of ore and water by agitation. Xanthates all but eliminated the need for the oils and instigated another round of lawsuits in the 1920s, which
Minerals Separation again won.
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Minerals
Separation, Ltd, organized subsidiaries. In 1911, the company opened an office in San Francisco under Edward Nutter, which eventually incorporated as the Minerals Separation North American Corporation. During World War I, John Ballot relocated to the United States, as president of the firm
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Its most important patent was the discovery that a small percentage of oil, agitated into a froth, was needed to make the process commercially successful at Broken Hill. The patent was received for this process in
Britain in 1905 and then the next year around the world but especially in the United
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mill tailings. By the 1910s, the firm's
Australian process was generally accepted as so great an advance over any process known before that it promptly came into extensive use for the concentration of ores in most of the principal mining countries of the world. It largely replaced all earlier ore
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companies (Utah Copper, Nevada Con, Ray Con, Chino, Butte & Superior and others), which netted $ 5,000,000 in back license fees. With the expiration of the patents, and the royalties received for licensing, the
Minerals Separation NA went out of the flotation research and patent business and
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Because of the many claims of primacy, the
Minerals Separation Lt history is one of constant litigation over its patents, with the British House of Lords and the U. S. Supreme Court (twice) deciding in its favor. The process of the patent in suit consisted in the use of an amount of oil which is
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Prior to these discoveries, it was well known that oil and oily substances had a selective affinity or attraction for, and would unite mechanically with, the minute particles of metal and metallic compounds found in crushed or powdered ores, but would not so unite with the quartz, or rocky
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Organized in 1903 by South
African John Ballot, the firm moved to experiment with new processes as well as acquire patents of others until they had perfected a
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These court victories "earned for itself (Minerals
Separation, Ltd) the cordial detestation of many in the mining world."
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with headquarters in New York. He died a few months before the 1922 final settlement of a suit with the
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175:. New York, New York: American Institute of Mining and Metallurgical Engineers. p. 453.
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The Role of
Minerals Separation Ltd. in the Development of the Flotation Process
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110:. Victoria, Australia: Zlota Press. pp. passim.
201:"MINERALS SEPARATION v. HYDE , 242 U.S. 261 (1916)"
188:. Australian Science and Technology Heritage Centre
135:. New York, New York: McGraw-Hill. pp. 1–7.
230:Defunct mining companies of the United Kingdom
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150:. London: Reaktion Books Ltd. p. 208.
36:extraction processes and is today known as
186:"Historical Note: Minerals Separation Ltd"
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203:. FindLaw, a Thomson Reuters business
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31:process. This was perfected on
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50:De Bavay's Sulphide Process
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76:dissolved in the 1950s.
171:Parsons, A. B. (1933).
148:Mining in World History
106:Birrell, Ralph (2000).
17:Minerals Separation Ltd
146:Lynch, Martin (2002).
131:Gaudin, A. M. (1932).
33:Broken Hill, Australia
173:The Porphyry Coppers
73:Daniel C. Jackling
225:History of mining
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